今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 1 篇,Composites Science and Technology 1 篇
Development of an extrapolation method to predict the flexural properties of glass-fiber/epoxy composites subject to hygrothermal aging
Geovane de A.S. da Silva, José R.M. d’Almeida, Daniel C.T. Cardoso, Priscilla S.C. Vieira, Bruno J. Lopes, Antonio H.M. da F.T. da Silva, Valber A. Perrut
doi:10.1016/j.compstruct.2025.119038
玻璃纤维/环氧复合材料湿热老化弯曲性能的外推法研究
This work deals with the mechanical degradation of glass-fiber/epoxy composites used in repairs of offshore metal pipelines exposed to aging in a saline environment. The materials used were a bicomponent DGEBA epoxy and a woven bidirectional E-glass fabric. In order to simulate the harsh environment, the composite was exposed to accelerated hygrothermal aging tests in three independent salt spray chambers at temperatures of 35, 55 and 70 °C. The composite had its mass gain and three-point bending properties monitored over time. It was observed that temperature played a major role in accelerating properties’ degradation. Additionally, for long-term exposure, the retention of mechanical properties presented a plateau, which could be perfectly modeled by the modified Phani and Bose model, proposed in this work. An innovative predictive methodology was developed based on this model, allowing extrapolation of long-term aging tests to temperatures different from those analyzed experimentally, including ambient temperature. The methodology developed is the key strength to be highlighted in the work, which allowed data extrapolation, reducing the number of experiments to evaluate the aging process of composites.
这项工作涉及玻璃纤维/环氧复合材料的机械降解,用于修复暴露在盐水环境中老化的海上金属管道。使用的材料是双组分DGEBA环氧树脂和双向编织e -玻璃织物。为了模拟恶劣环境,复合材料在3个独立的盐雾室中分别进行了温度为35、55和70 °C的加速湿热老化试验。随着时间的推移,对复合材料的质量增益和三点弯曲性能进行了监测。结果表明,温度在加速材料性能的降解中起主要作用。此外,对于长期暴露,力学性能的保留呈现平台期,这可以通过改进的Phani和Bose模型完美地建模。基于该模型,开发了一种创新的预测方法,允许将长期老化试验外推到不同于实验分析的温度,包括环境温度。所开发的方法是工作中突出的关键优势,它允许数据外推,减少了评估复合材料老化过程的实验次数。
A Bayesian framework for quantifying uncertainty in the thermal history of curing composite structures
Arghyanil Bhattacharjee, Kamyar Gordnian, Reza Vaziri, Trevor Campbell, Anoush Poursartip
doi:10.1016/j.compositesa.2025.108843
一个贝叶斯框架量化固化复合材料结构热历史的不确定性
The development of thermal management approaches for composites manufacturing based on physics-based process simulation has become well-established in recent years. However, estimation of thermal boundary conditions, typically in the form of heat-transfer coefficients (HTCs) at the air-part and air-tool interfaces, during convective heat transfer-based curing processes (such as autoclaves and ovens) remains a challenge and a major source of uncertainty. Current deterministic process simulation methods are not suitable for capturing the effect of these HTC uncertainties and their consequential effects on the corresponding thermal histories of curing parts. This work develops and demonstrates the applicability of statistical inference-based models to estimate HTC distributions and the associated uncertainties using synthetic datasets generated from finite element simulations. An experimental case study with real data from the cooling of a heated tool is then presented on using the validated model for inferring, as well as quantifying the uncertainties in HTCs.
近年来,基于物理过程模拟的复合材料制造热管理方法的发展已经成熟。然而,在基于对流传热的固化过程(如高压灭菌器和烤箱)中,热边界条件的估计(通常以空气-部件和空气-工具界面的传热系数(HTCs)的形式)仍然是一个挑战,也是不确定性的主要来源。目前的确定性过程模拟方法不适合捕捉这些HTC不确定性的影响以及它们对固化部件相应热历史的相应影响。这项工作发展并证明了基于统计推断的模型的适用性,该模型使用由有限元模拟生成的合成数据集来估计HTC分布和相关不确定性。然后,利用加热工具冷却的真实数据进行了实验案例研究,并使用验证模型来推断和量化高温碳化物的不确定性。
Optimization of 3D printed truss meta-structure for structural performance and switchable vibration attenuation
Samuel Kim, Hyunsoo Hong, Jaemoon Jeong, Wonvin Kim, Wonki Kim, Gyumin Sim, Jieun Lee, Seong Su Kim
doi:10.1016/j.compositesa.2025.108845
3D打印桁架元结构结构性能优化及可切换减振
In this study, a truss-based metastructure is proposed that simultaneously considers structural and vibration attenuation performance. To enhance vibration characteristics, the unit cell is designed to induce local resonance and the inertial amplification effect. Finite element analysis (FEA) was conducted to evaluate the compression stiffness and transmissibility of the unit cell with respect to its shape, and the switchable vibration characteristics depending on the presence of water were analyzed through dispersion relation. In addition, an optimal vibration attenuation metastructure satisfying the target stiffness was derived using a genetic algorithm. To validate the FEA results of the optimal structure, the metastructure was fabricated using stereolithography 3D printing, followed by structural and vibration tests. The fabricated truss-based metastructure showed good agreement with the vibration analysis results and excellent vibration reduction characteristics.
本文提出了一种同时考虑结构性能和减振性能的桁架元结构。为了提高振动特性,设计了引起局部共振和惯性放大效应的单元胞。采用有限元分析方法对单晶胞的抗压刚度和透射率进行了分析,并通过色散关系分析了单晶胞在存在水时的可切换振动特性。此外,利用遗传算法推导出满足目标刚度的最优减振元结构。为了验证最优结构的有限元分析结果,采用立体光刻3D打印技术制作了元结构,然后进行了结构和振动测试。预制桁架结构与振动分析结果吻合较好,具有良好的减振性能。
Cationic defect engineering induces LOM-enhanced electrocatalysts derived from in situ semi-transformed NiFe-LDH/MOF heterostructure for efficient overall water-splitting
Yu Zhu, Yun Zhao, Chang Xi, Kairan Hu, Sheng Han, Jibo Jiang
doi:10.1016/j.compositesb.2025.112356
阳离子缺陷工程诱导了原位半转化NiFe-LDH/MOF异质结构的lom增强电催化剂,用于高效的整体水分解
Unraveling the lattice oxygen mechanism (LOM) pathway and its association with inherent electrocatalytic performance is key to designing electrocatalyst for water-splitting but unfortunately remains elusive. Herein, a 3D nanoflower-like NiFe-LDH/MOF heterostructured electrocatalyst based on MXene is successfully prepared by an in situ semi-transformation (ISST) strategy. Chemical probe tests and pH-dependent tests indicate that the introduction of defects in the catalysts reduce the energy of the metal-oxygen bond and promote the release of lattice oxygen during the OER process, further enhancing the LOM pathway. Density Functional Theory (DFT) calculations also demonstrated that electronic coupling at heterogeneous interfaces and defect engineering optimised the adsorption process of the reaction intermediates and markedly improved the intrinsic catalytic activity. As expected, the catalysts exhibited good electrochemical performance, with HER and OER requiring only 143 mV and 176 mV. In addition, the overall water-splitting tests indicate that merely 1.55 V of cell voltage is needed for the catalyst to attain a current density of 10 mA cm-2. Excellent stability is also observed at high current densities, demonstrating its potential to be used as a bifunctional catalyst for large-scale industrialized applications.
揭示晶格氧机制(LOM)途径及其与固有电催化性能的关系是设计水分解电催化剂的关键,但不幸的是,这一问题仍然难以解决。本文采用原位半转化(ISST)策略,成功制备了基于MXene的三维纳米花状nfe - ldh /MOF异质结构电催化剂。化学探针测试和ph依赖性测试表明,催化剂中缺陷的引入降低了金属-氧键的能量,促进了OER过程中晶格氧的释放,进一步增强了LOM途径。密度泛函理论(DFT)计算也表明,非均相界面上的电子耦合和缺陷工程优化了反应中间体的吸附过程,显著提高了本征催化活性。正如预期的那样,催化剂表现出良好的电化学性能,HER和OER仅需要143 mV和176 mV。此外,总体的水分解测试表明,催化剂只需要1.55 V的电池电压就能达到10 mA cm-2的电流密度。在高电流密度下也观察到优异的稳定性,表明其有潜力作为大规模工业化应用的双功能催化剂。
Electrical and Thermal Conductive Composites with Thermal Management and Electromagnetic Shielding Enhanced by 3D Network
Chengwei Jiang, Changxiang Hao, Chunfang Zi, Jing Li, Weijun Liu, Yingman Bian, Fangyuan Sun, Yiqi Xu, Yuanxin Yan, Liyang Wang, Fengyu Su, Yanqing Tian
doi:10.1016/j.compscitech.2025.111135
三维网络增强热管理和电磁屏蔽的导电和导热复合材料
The increasing integration and power density of electronic devices demands materials with superior thermal management and electromagnetic interference (EMI) shielding properties. Herein, we developed a three-dimensional conductive polymer composite by combining amino-silane modified graphene nanoplates (mGNPs) and carboxylated carbon nanotubes (CNT-COOHs) through salt template-assisted assembly and vacuum impregnation. The composite exhibited dramatically enhanced thermal conductivity from 0.154 W/m·K of pure Polydimethylsiloxane (PDMS) to 9.86 W/m·K (In-plane) and 7.62 W/m·K (Out-plane), along with superior EMI shielding effectiveness from 3.1 dB to 78.6 dB at merely 9.78 wt.% fillers (e.g. mGNPs and CNT-COOHs) loading. The remarkable improvement stems from the synergistic effects of the 3D network architecture and improved interfacial compatibility. Practical tests demonstrated excellent heat dissipation capabilities in LED devices, maintaining the device temperature at 34.3°C compared to 127.3°C with pure PDMS. The superior thermal and EMI shielding performances of these composites indicate great potential for both thermal management and electromagnetic protection in advanced electronic applications.
电子器件的集成度和功率密度的提高要求材料具有优异的热管理和电磁干扰(EMI)屏蔽性能。本文通过盐模板辅助组装和真空浸渍,将氨基硅烷修饰的石墨烯纳米板(mGNPs)和羧化碳纳米管(CNT-COOHs)结合在一起,制备了一种三维导电聚合物复合材料。该复合材料的导热系数从纯聚二甲基硅氧烷(PDMS)的0.154 W/m·K显著提高到9.86 W/m·K(面内)和7.62 W/m·K(面外),同时在9.78 wt.%的填料(如mGNPs和cnt - cooh)负载下,其EMI屏蔽效率从3.1 dB提高到78.6 dB。这种显著的改进源于三维网络结构的协同效应和界面兼容性的提高。实际测试表明LED器件具有出色的散热能力,与纯PDMS的127.3°C相比,器件温度保持在34.3°C。这些复合材料具有优异的热屏蔽和电磁干扰屏蔽性能,在高级电子应用中具有很大的热管理和电磁保护潜力。