今日更新:Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 1 篇
The role of compressive stress Enhancement in the shear mechanism of Nickel Foam/Polyurethane composites
Yi Su, Jiacheng Tian, Hengyuan Zhang
doi:10.1016/j.compositesa.2024.108699
压缩应力增强在泡沫镍/聚氨酯复合材料剪切机制中的作用
Compressive stress can enhance the shear performance of Nickel Foam (NF)/Polyurethane (PU), but its mechanism is not yet fully understood. Using X-CT, a fine-scale finite element model of NF/PU was reconstructed, revealing the shear synergistic mechanism at both macro/meso-scale. The results indicate that the “cell morphology of the embedded NF skeleton” and the “number of cell edge fractures” are key factors affecting shear performance under compressive stress. This was confirmed through cyclic shear tests under compression. Low-cycle fatigue shear tests further demonstrate that compressive stress helps stabilize cyclic stress softening. Based on this, an NF/PU skeleton model considering both compressive and shear effects was developed, and the relationship between maximum shear stress and the number of loading cycles under different shear amplitudes was established. This provides guidance for its broad applications in vehicle manufacturing, aerospace, vibration control, and civil engineering.
压缩应力可以提高泡沫镍/聚氨酯(PU)的抗剪性能,但其作用机理尚不完全清楚。利用X-CT重建了NF/PU的精细有限元模型,揭示了宏观/中观尺度的剪切协同机制。结果表明,在压应力作用下,“内埋NF骨架的细胞形态”和“细胞边缘断裂数”是影响抗剪性能的关键因素。通过压缩下的循环剪切试验证实了这一点。低周疲劳剪切试验进一步证明,压应力有助于稳定循环应力软化。在此基础上,建立了考虑压剪效应的NF/PU骨架模型,建立了不同剪切幅值下最大剪应力与加载循环次数的关系。这为其在汽车制造、航空航天、振动控制和土木工程中的广泛应用提供了指导。
In situ coupling of crosslinked CNTs and Li-Excess Disordered Rock Salt Vanadium Oxide Nanowires for High-Performance Li Storage
Xinhao Xu, Jianming Han, Qiyuan Chen, Baitao Cui, Yilin Liao, Shasha Zhu, Junxin Tan, Yiting Peng, Qunjie Xu, Yulin Min
doi:10.1016/j.compositesb.2024.112100
交联碳纳米管与锂过量无序岩盐氧化钒纳米线原位耦合用于高性能锂存储
Lithium-rich disordered rock salt (DRS) materials with appropriate intercalation potentials and three-dimensional Li percolation pathways receive intensive attention as a promising anode candidate for fast-charging lithium-ion batteries. However, the current bulk DRS structures address a great challenge due to the poor conductivity and multiscale complex percolation network. Herein, we present a two-step fabrication of in situ coupling CNTs and DRS-Li3V2O5 nanowires composites via combining hydrothermal and electro-redox reactions. The robust hybrid architecture endows the nanocomposite with Li-ion and electron transport pathways, a highly reversible percolation network, and excellent mech anical stability, enabling flexible electrodes with outstanding lithium storage performance. The use of such hybrid electrodes effectively increases a specific capacity (approximately 2 times greater than that of their bulk counterparts), a high-rate capability at high mass loading, good temperature adaptability, and long-term cycling stability, with ∼80% retention over 1000 cycles at a 2C-rate. This work provides a facile yet effective strategy toward high-performance LIBs with other DRS electrode innovations.
富锂无序岩盐(DRS)材料具有合适的插层电位和三维锂渗透途径,作为一种有前景的快速充电锂离子电池负极候选者受到了广泛关注。然而,目前的块状DRS结构由于导电性差和多尺度复杂的渗透网络而面临很大的挑战。在此,我们提出了通过水热反应和电氧化还原反应相结合的两步制备原位耦合CNTs和DRS-Li3V2O5纳米线复合材料。坚固的混合结构使纳米复合材料具有锂离子和电子传递途径,高度可逆的渗透网络和优异的机械稳定性,使柔性电极具有出色的锂存储性能。这种混合电极的使用有效地增加了比容量(大约是其散装电极的2倍),在高质量负载下的高速率能力,良好的温度适应性和长期循环稳定性,在2c速率下超过1000次循环具有~ 80%的保留率。这项工作为高性能lib与其他DRS电极创新提供了一种简单而有效的策略。