首页/文章/ 详情

【新文速递】2025年4月18日复合材料SCI期刊最新文章

3小时前浏览0
 
   

今日更新:Composite Structures 2 篇,Composites Part A: Applied Science and Manufacturing 4 篇,Composites Part B: Engineering 3 篇,Composites Science and Technology 1 篇

Composite Structures

Ultra-high temperature mechanical behavior and microstructural evolution of needle-punched carbon/carbon composites under time-varying thermo-mechanical coupling conditions

Boyi Wang, Songhe Meng, Bo Gao, Kunjie Wang, Chenghai Xu

doi:10.1016/j.compstruct.2025.119192

时变热-力耦合条件下针 刺碳/碳复合材料的超高温力学行为及显微组织演化

Carbon/carbon (C/C) composites are extensively employed in the thermal protection systems of hypersonic vehicles, and the precise acquisition of critical process information is vital for the reliable design of such vehicles. Consequently, this research introduces a high-temperature repeated loading testing protocol for needle-punched C/C composites, aimed at characterizing the mechanical behavior of re-entry vehicles in intricate thermal–mechanical coupling environments. Initially, an ultra-high-temperature speckle pattern was prepared using plasma spraying and laser etching techniques, which is suitable for the temperature range of this study (room temperature to 2000 °C). Subsequently, under time-varying temperature and load conditions, the local strain field and tensile properties were investigated. In the single-loading test, at 1500 °C, the stress–strain curve slope decreased by up to 58 %. In the cyclic loading test, at 2000 °C, the slope increased by up to 46 % with the number of cycles, while the specimen strength decreased by up to 27.1 % compared to the standard test. By examining fracture morphology and internal structure at both macroscopic and microscopic scales, the study elucidated how interfacial performance and the level of graphitization contribute to the tensile behavior. The results indicate that as the number of loading cycles increases, the stress–strain curve slope is primarily influenced by interfacial properties and carbon fiber graphitization, with each playing a dominant role at different loading stages. Additionally, tensile strength decreases with the rise in loading cycles, positively correlating with interfacial performance and inversely with carbon fiber graphitization.

碳/碳(C/C)复合材料广泛应用于高超声速飞行器的热防护系统中,关键工艺信息的精确获取对于高超声速飞行器的可靠设计至关重要。因此,本研究引入了针刺C/C复合材料的高温重复加载测试方案,旨在表征再入飞行器在复杂热-力学耦合环境中的力学行为。首先,采用等离子喷涂和激光刻蚀技术制备了超高温散斑图,该散斑图适用于本研究的温度范围(室温至2000 °C)。然后,在时变的温度和载荷条件下,研究了局部应变场和拉伸性能。在单加载试验中,在1500 °C时,应力-应变曲线斜率下降高达58 %。在2000 °C循环加载试验中,与标准试验相比,随着循环次数的增加,边坡增加高达46 %,而试件强度下降高达27.1 %。通过在宏观和微观尺度上检查断裂形态和内部结构,该研究阐明了界面性能和石墨化水平如何影响拉伸行为。结果表明:随着加载循环次数的增加,应力-应变曲线斜率主要受界面性能和碳纤维石墨化程度的影响,且在不同加载阶段,界面性能和碳纤维石墨化程度分别起主导作用;拉伸强度随加载次数的增加而降低,与界面性能呈正相关,与碳纤维石墨化成反比。


Multi-body dynamic transfer matrix modeling and validation for full-scale wind turbine blades in biaxial fatigue testing systems

Yi Ma, Aiguo Zhou, Yutian Zhu, Jinlei Shi, Shiwen Zhao, Jianzhong Wu

doi:10.1016/j.compstruct.2025.119205

全尺寸风电叶片双轴疲劳试验系统多体动态传递矩阵建模与验证

Continuous advancements in wind turbine technology, driven by the pursuit of increased power generation and extended blade dimensions, have heightened the demand for reliable biaxial fatigue testing of full-scale blades. Such testing is critical for evaluating long-term structural integrity under realistic loading conditions. This study presents a novel multi-body dynamic transfer matrix methodology to address the modeling and analysis challenges inherent in full-scale biaxial testing systems for large wind turbine blades. The proposed approach discretizes the heterogeneous blade structure into beam elements and employs transfer matrix theory to derive system matrices encompassing spatial beam dynamics, mass distribution, damping characteristics, and elastic properties. Through the systematic formulation of the dynamic transfer equations and subsequent numerical solutions of the characteristic equations, this method enables comprehensive vibration analysis of the multi-body test system. Comparative validation through finite element simulations and experimental measurements demonstrates that the equivalent model achieves prediction discrepancies below 7% across multiple blade configurations. The developed framework provides an effective multibody transfer matrix model for investigating vibration characteristics and bending moment distributions in blade fatigue testing systems, establishing theoretical foundations for dynamic characterization and optimized design of full-scale biaxial fatigue testing platforms.

风力涡轮机技术的不断进步,在追求更大的发电量和更大的叶片尺寸的驱动下,提高了对全尺寸叶片可靠的双轴疲劳测试的需求。这种测试对于评估实际荷载条件下的长期结构完整性至关重要。本研究提出了一种新的多体动态传递矩阵方法,以解决大型风力涡轮机叶片全尺寸双轴测试系统固有的建模和分析挑战。该方法将非均匀叶片结构离散为梁单元,并利用传递矩阵理论推导出包含梁空间动力学、质量分布、阻尼特性和弹性特性的系统矩阵。该方法通过系统地建立动力传递方程和随后的特征方程数值解,实现了对多体试验系统的全面振动分析。通过有限元模拟和实验测量的对比验证表明,等效模型在多种叶片配置下的预测误差低于7%。该框架为研究叶片疲劳试验系统的振动特性和弯矩分布提供了有效的多体传递矩阵模型,为全尺寸双轴疲劳试验平台的动态表征和优化设计奠定了理论基础。


Composites Part A: Applied Science and Manufacturing

In-plane compression behaviors of cedarwood-inspired cores and composite sandwich structures

Zhi Sun, Xin Zhou, Ruishuang Li, Yawen Zhang, Shanshan Shi

doi:10.1016/j.compositesa.2025.108933

杉木芯材与复合材料夹层结构的面内压缩特性

The microstructures of biological tissues can effectively guide the design of composite honeycomb sandwich structures. In this study, a cedarwood-inspired honeycomb core was proposed. In-plane compression tests were conducted on honeycomb cores and sandwich specimens to analyze the deformation and failure mechanisms of the cedarwood-inspired core and to examine their effects on the mechanical properties and failure modes of the sandwich structures. The cedarwood-inspired microstructure altered the load-transfer mechanism within the core, converting concentrated loads into distributed loads and restricting the expansion of unit cell deformations in the core. Experimental results indicated that the deformation and failure modes of the cores and sandwich specimens were modified, and the mechanical properties were significantly improved using the proposed cedarwood-inspired honeycomb cores. Specifically, the peak load of the cedarwood-inspired sandwich is 31.52% higher. Additionally, a theoretical prediction model was developed to determine Young’s modulus and peak load of the cedarwood-inspired core, offering valuable guidance for the design of future honeycomb cores.

生物组织的微观结构可以有效地指导复合材料蜂窝夹层结构的设计。在本研究中,提出了一种以雪松木为灵感的蜂窝芯。通过对蜂窝芯和夹层试件进行面内压缩试验,分析雪松木芯的变形破坏机理,研究其对夹层结构力学性能和破坏模式的影响。杉木结构改变了岩心内的荷载传递机制,将集中荷载转化为分布荷载,限制了岩心内单胞变形的扩展。实验结果表明,采用雪松木蜂窝岩心可以改变岩心和夹层试件的变形破坏模式,并显著改善其力学性能。具体来说,以雪松木为灵感的三明治的峰值负荷高出31.52%。此外,建立了一个理论预测模型来确定雪松木蜂窝芯的杨氏模量和峰值荷载,为未来蜂窝芯的设计提供了有价值的指导。


Low-velocity impact response of carbon/epoxy laminates with interlaminar hybrid toughening via core–shell-rubber particles and non-woven thermoplastic fibre veils

Mehmet Çağatay Akbolat, Sheng Wang, Kali Babu Katnam, Prasad Potluri, Constantinos Soutis

doi:10.1016/j.compositesa.2025.108944

核-壳-橡胶复合增韧碳/环氧复合材料与热塑性无纺布纤维膜的低速冲击响应

Advanced composites (e.g. carbon fibre-reinforced epoxies) have been increasingly used in lightweight, critical applications such as aerospace, renewable energy and defence industries due to their excellent mechanical properties including high specific strength, stiffness and fatigue properties. However, the inherent brittleness of polymer composites makes them vulnerable to low-velocity out-of-plane impact loading, threatening their structural integrity. In this context, enhancing the low-velocity impact resistance of composite laminates is crucial for maintaining their structural integrity and reliability throughout their service life. Therefore, this study explores the low-velocity out-of-plane impact resistance of composite laminates (i.e. consisting of the unidirectional non-crimp carbon fibre fabrics and low-viscous two-part epoxy resin) toughened with core–shell rubber (CSR) particles and thermoplastic veils. The CSR particles varying from 0.1 to 3µm and Polyphenylene Sulfide (PPS) fibre veils with a fibre diameter of 9 µm were used to achieve non-hybrid and hybrid toughening. The impact response of the composite laminates, manufactured with vacuum-assisted resin infusion and out-of-autoclave curing, were characterised with drop-weight low-velocity impact testing in two energy ranges: near the delamination threshold (i.e. 2 J, 3 J, 4 J) and over a broader range (i.e. 2.5 J, 5 J, 7.5 J, 10 J). The results show that the toughening mechanisms derived from the hybrid use of PPS veils and CSR particles effectively enhance the impact resistance of composite laminates up to the delamination threshold. Additionally, the hybrid approach significantly reduces the projected damage area. However, beyond the delamination threshold, the influence of these toughening mechanisms on the impact properties is found to be limited.

先进复合材料(如碳纤维增强环氧树脂)由于其优异的机械性能,包括高比强度,刚度和疲劳性能,已越来越多地用于轻量化,关键应用,如航空航天,可再生能源和国防工业。然而,聚合物复合材料固有的脆性使其容易受到低速面外冲击载荷的影响,威胁其结构完整性。在这种情况下,增强复合材料层压板的抗低速冲击能力对于在其整个使用寿命中保持其结构完整性和可靠性至关重要。因此,本研究探讨了用核壳橡胶(CSR)颗粒和热塑性薄膜增韧复合层压板(即由单向无卷曲碳纤维织物和低粘性双组分环氧树脂组成)的低速抗面外冲击性能。采用0.1 ~ 3µm的CSR颗粒和直径为9µm的聚苯硫醚(PPS)纤维膜实现非杂化增韧和杂化增韧。采用真空辅助树脂注入和非高压釜固化制造的复合材料层合板的冲击响应,通过两种能量范围的落锤低速冲击测试进行了表征:在脱层阈值附近(即2 J、3 J、4 J)和更宽的范围(即2.5 J、5 J、7.5 J、10 J)。结果表明,PPS膜和CSR颗粒混合使用的增韧机制有效地提高了复合材料层合板的抗冲击能力,直至脱层阈值。此外,混合方法大大减少了预计的损伤面积。然而,在脱层阈值之外,这些增韧机制对冲击性能的影响是有限的。


Enhancing interlaminar fracture toughness in CFRP composites using ethanolamine-coated CNT sheets

Manoj Sehrawat, Mamta Rani, Karishma Jain, Sonu Rani, Sony Bharadwaj, Bhanu Pratap Singh, Raj Ladani, Brian G. Falzon

doi:10.1016/j.compositesa.2025.108958

乙醇胺涂层碳纳米管增强CFRP复合材料层间断裂韧性

Traditional interleaving of carbon nanotube (CNT) sheets in CFRP composites often leads to poor resin infiltration, resulting in lower interlaminar fracture toughness. This study proposes a novel strategy to modify CNT sheets with non-covalent amine groups to enhance their interaction with the polar epoxy matrix, thereby improving wettability and infiltration. CFRP composites containing amine-modified CNT sheets exhibited a remarkable 206% increase in Mode I fracture toughness due to stronger interlaminar interactions and enhanced fibre bridging. The use of these amine-modified CNT sheets induced the transfer of nanotubes onto the carbon fibre (CF) surface, resulting in nanomodified CFs with increased active sites for matrix bonding, resulting in increased fibre bridging between the delaminated plies. The mode II fracture toughness values show a slight reduction (8.2%) with the use of ethanolamine coated CNT (EACNT) interleaves, as the toughened interlayer does not allow the crack to traverse through it, resulting in a shorter crack path. Nonetheless, this strategy offers a promising advancement towards the use of CNT sheet interleaves for the effective enhancement of CFRP composite fracture toughness.

CFRP复合材料中传统的碳纳米管(CNT)片间交错排列往往导致树脂渗透性差,导致层间断裂韧性较低。本研究提出了一种用非共价胺基修饰碳纳米管片的新策略,以增强其与极性环氧基的相互作用,从而提高润湿性和渗透性。含有胺改性碳纳米管片的CFRP复合材料由于层间相互作用增强和纤维桥接增强,其I型断裂韧性提高了206%。使用这些胺改性碳纳米管片诱导纳米管转移到碳纤维(CF)表面,导致纳米改性碳纤维具有增加的基质键合活性位点,从而增加了分层层之间的纤维桥接。使用乙醇胺涂层碳纳米管(EACNT)交织层,II型断裂韧性值略有降低(8.2%),因为增韧的夹层不允许裂纹穿过它,导致更短的裂纹路径。尽管如此,该策略为使用碳纳米管片交错层有效增强CFRP复合材料断裂韧性提供了一个有希望的进展。


Enhanced interfacial strength in carbon-nanotubes-reinforced Al matrix composites via an interface substitution strategy

Weiwei Zhou, Zhenxing Zhou, Mingqi Dong, Yuchi Fan, Keiichi Shirasu, Go Yamamoto, Naoyuki Nomura

doi:10.1016/j.compositesa.2025.108955

 

通过界面取代策略提高碳纳米管增强Al基复合材料的界面强度

The foremost concern when fabricating carbon nanotube (CNTs)-reinforced Al matrix composites is achieving appropriate interfacial bonding while avoiding intrinsic structural damage. In this study, an interface substitution strategy was developed for replacing the CNT-Al interface with a sandwiched CNT-ceramic-Al interface, thereby enhancing interfacial connections. A uniform, continuous SiO2 layer was deposited on the CNT surface via a sol–gel process, followed by powder metallurgy routines to fabricate SiO2@CNTs/Al composites, in which the CNTs exhibited minimal structural damage and remained well-dispersed without interfacial reactions. An in situ pullout test demonstrated a high interfacial strength of 32.5 MPa for the SiO2@CNT-Al interface, attributed to the enhanced residual compressive stress and interfacial wettability. Consequently, the composite strength was significantly enhanced with CNTs addition, aligning well with predictions from the shear lag model. This interface substitution strategy underscored the feasibility of tuning the CNT-metal interfacial states and highlighted the potential for designing advanced nanocarbon/Al composites.

在制备碳纳米管增强铝基复合材料时,最重要的问题是在避免固有结构损伤的同时实现适当的界面结合。在本研究中,开发了一种界面替代策略,将CNT-Al界面替换为夹在cnt -陶瓷- al界面,从而增强界面连接。通过溶胶-凝胶法在碳纳米管表面沉积均匀、连续的SiO2层,然后采用粉末冶金方法制备SiO2@CNTs/Al复合材料,其中碳纳米管的结构损伤最小,并且在没有界面反应的情况下保持良好的分散。现场拉拔试验表明,由于残余压应力和界面润湿性的增强,SiO2@CNT-Al界面的界面强度高达32.5 MPa。因此,CNTs的加入显著提高了复合材料的强度,这与剪切滞后模型的预测结果一致。这种界面替代策略强调了调整碳纳米管-金属界面状态的可行性,并强调了设计先进纳米碳/铝复合材料的潜力。


Composites Part B: Engineering

An environmentally friendly superhydrophobic coating with high-temperature resistance, UV resistance, and abrasion resistance was fabricated on carbon fiber board via an aqueous phase polymer dispersion system

Qian Su, Kangli Yang, Zhiqing Yuan, Cancheng Li, Shoutong Meng, Xuyu Long, Rui He

doi:10.1016/j.compositesb.2025.112533

 

采用水相聚合物分散体系在碳纤维板上制备了一种具有耐高温、耐紫外线、耐磨损的环保型超疏水涂层

Aiming at the problems of carbon fiber board (CFB), which is not waterproof and has poor UV resistance, a superhydrophobic coating with UV resistance and high-temperature resistance was innovatively prepared on CFB using an aqueous-phase polymer dispersion system by a highly efficient spraying method. The whole preparation system is highly environmentally friendly and safe. The results showed that the superhydrophobic carbon fiber board (SKCFB) could resist UV up to 85 h, could withstand high temperatures up to 300 °C, and had a water contact angle (WCA) of 159°. In addition, the abrasion resistance of SKCFB is 140 and 180 cycles under the action of 800 grit and 1200 grit sandpaper, respectively, for a load of 100 g, and 110 cycles under the action of 600 grit sandpaper. When carrying a load of 500 g, the 600 mesh, 800 mesh, and 1200 mesh sandpaper can be used for 40, 60, and 80 cycles of abrasion resistance, respectively. Compared with other samples of the same type, this SKCFB is simpler to prepare, has a greener and safer preparation route, and has better performance, plus the ability to control the appearance color as desired. This study provides a novel green, simple, and fast strategy for preparing superhydrophobic coatings on CFBs. At the same time, it opens a new path for preparing superhydrophobic coatings and enhances their application in industry.

针对碳纤维板(CFB)不防水、抗紫外线能力差的问题,采用高效喷涂方法,采用水相聚合物分散体系在CFB上创新性地制备了一种耐紫外线、耐高温的超疏水涂层。整个制备系统非常环保和安全。结果表明,该超疏水碳纤维板(SKCFB)抗UV时间长达85 h,耐高温达300℃,水接触角(WCA)为159°。此外,在100 g载荷下,SKCFB在800砂纸和1200砂纸作用下的耐磨性分别为140次和180次,在600砂纸作用下的耐磨性为110次。承载500g载荷时,600目、800目、1200目砂纸可分别进行40、60、80次的耐磨性循环。与其他同类型样品相比,该SKCFB制备更简单,制备路线更环保,更安全,性能更好,并且可以根据需要控制外观颜色。本研究为在cfb上制备超疏水涂层提供了一种绿色、简单、快速的新方法。同时,为制备超疏水涂料开辟了新的途径,提高了超疏水涂料的工业应用。


Advancing Aerospace Maintenance: Thermochromic Liquid Crystal Coating Method for Skin-to-Core Disbond Detection in CFRP Honeycomb Structures

M. Sun, D. Wowk, P.R. Underhill, T.W. Krause

doi:10.1016/j.compositesb.2025.112516

推进航空航天维护:用于CFRP蜂窝结构表面到核心剥离检测的热致变色液晶涂层方法

A novel Non-Destructive Evaluation (NDE) method for aerospace maintenance is introduced, utilizing advanced Thermochromic Liquid Crystal (TLC) ink to detect skin-to-core disbonds in carbon fiber-reinforced polymer (CFRP) honeycomb structures subjected to low-velocity impacts, representing a state-of-the-art integration of functional materials (TLC) with essential aerospace maintenance practices. Traditional NDE methods for detecting disbonds in aerospace structures often necessitate skilled technicians and sophisticated equipment. In contrast, the current study demonstrates that the proposed TLC coating method provides a straightforward, real-time detection technique that can serve as a preliminary or substitute inspection method. The detection and characterization results using the TLC coating method are rigorously evaluated through comparison with Forward-Looking Infrared (FLIR) by employing a high-performance thermal imaging camera. Results demonstrated that the TLC coating method achieved the same detection limits as FLIR thermography, with measurements of the disbond size differing by no more than 5% between the two methods. A new heating method, Communicative Heating Thermography (CHT), was introduced for use with the TLC coating method in field applications without the need for post-processing, or expensive equipment. CHT enabled operators to dynamically adjust heat application based on real-time feedback from the TLC coating, optimizing disbond detection. This method was successfully implemented by untrained operators with an accuracy of 100%.

介绍了一种用于航空航天维修的新型无损评估(NDE)方法,该方法利用先进的热致色液晶(TLC)墨水来检测碳纤维增强聚合物(CFRP)蜂窝结构在低速撞击下的皮肤到核心的脱落,代表了功能材料(TLC)与航空航天维修实践的最先进集成。传统的无损检测方法通常需要熟练的技术人员和复杂的设备来检测航空航天结构的剥离。相比之下,目前的研究表明,所提出的TLC涂层方法提供了一种直接、实时的检测技术,可以作为初步或替代的检测方法。采用高性能热像仪与前视红外(FLIR)进行对比,对TLC涂层法的检测和表征结果进行了严格评价。结果表明,TLC涂层法与FLIR热成像法具有相同的检出限,两种方法测量的脱粘尺寸相差不超过5%。介绍了一种新的加热方法,通信加热热成像(CHT),可与TLC涂层方法一起用于现场应用,无需后处理或昂贵的设备。CHT使作业者能够根据TLC涂层的实时反馈动态调整热应用,优化剥离检测。该方法由未经训练的操作人员成功实现,准确率为100%。


Hexagonal boron nitride (h-BN) “a miracle in white”: An emerging two-dimensional material for the advanced powered electronics and energy harvesting application

Chinmoy Kuila, Animesh Maji, Naresh Chandra Murmu, Tapas Kuila

doi:10.1016/j.compositesb.2025.112531

 

六方氮化硼(h-BN)“白色奇迹”:一种新兴的二维材料,用于先进的电力电子和能量收集应用

The growing demand for batteries or other compact electronics received considerable attention because of its high energy density and excellent power-to-mass ratio. However, obstacles such as inconsistent temperature distribution, inefficient energy storage, and sluggish release rates have emerged. Effective heat dissipation is required for optimum efficiency and durability of electrical devices. Thus, it is critical to develop thermally conductive hybrid fillers for improved heat management in such systems. Two-dimensional (2D) hexagonal boron nitride (h-BN), also known as "white graphene," encounters conceivable uses in electronics and energy devices due to the broad bandgap (∼5.5 eV), superior thermal endurance, high thermal conductivity (TC), and exceptional dielectric properties. The anisotropic conductivity of BN causes a reduction in cross-plane TC, which is a fundamental concern for its practical deployments. Therefore, developing a unique technique and structural engineering remedy for enhancing BN's cross-plane TC could be achievable. The main focus of this article is to explore the phonon-phonon scattering phenomena, mechanisms, and insights to design h-BN-based composites with good cross-plane TC and electrical insulation. The article summarizes the significance of 2D h-BN in several sectors, including electronic packaging, energy (e.g., thermal energy management and conversion), and batteries/supercapacitors. These topics highlight cutting-edge filler properties and the innovative design of 2D h-BN. Finally, the challenges and perspectives of developing potential thermal interface materials (TIMs) are highlighted. Our insights offer an initial glimpse into future studies on fabricating advanced TIMs in an appropriate filler structure configuration for optimal cooling of electronic/optoelectronic devices.

对电池或其他紧凑型电子产品日益增长的需求受到了相当大的关注,因为它具有高能量密度和优异的功率质量比。然而,诸如温度分布不一致、能量储存效率低下和释放速率缓慢等障碍已经出现。有效的散热是电气设备获得最佳效率和耐用性的必要条件。因此,开发导热混合填料以改善此类系统的热管理是至关重要的。二维(2D)六方氮化硼(h-BN),也被称为“白色石墨烯”,由于宽带隙(~ 5.5 eV),优异的热耐久性,高导热性(TC)和特殊的介电性能,在电子和能源设备中遇到了可以想象的用途。BN的各向异性电导率导致了跨平面TC的降低,这是其实际部署的一个基本问题。因此,开发一种独特的技术和结构工程补救措施来增强BN的跨平面TC是可以实现的。本文的重点是探讨声子-声子散射现象、机制以及设计具有良好跨平面TC和电绝缘的h- bn基复合材料的见解。本文总结了二维氢氮化硼在电子封装、能源(如热能管理和转换)和电池/超级电容器等几个领域的意义。这些主题突出了前沿填料的性能和2D h-BN的创新设计。最后,指出了开发潜在热界面材料的挑战和前景。我们的见解为未来在适当的填料结构配置中制造先进的TIMs以实现电子/光电器件的最佳冷却提供了初步的研究。


Composites Science and Technology

Physical crosslinking optimized high-temperature capacitive energy storage of polyetherimide nanocomposites with ultralow C60 particles

Wenjie Huang, Mengyu Xiao, Baoquan Wan, Zhonghua Xiang, Yuchao Li, Yong Chae Jung, Jun-Wei Zha

doi:10.1016/j.compscitech.2025.111194

 

物理交联优化的超低C60聚醚酰亚胺纳米复合材料高温电容储能

The extreme operating environments of film capacitors have created an urgent need for a new generation of polymer dielectric materials. Polymer-based composites are a more efficient option in terms of outstanding performance and large-scale industrialized production. Herein, C60 is selected as a functional filler to be combined with commercial polyetherimide (PEI) through electrostatic interactions to construct polymer nanocomposites (C60/PEI). Ultralow-filled C60/PEI nanocomposites achieve the comprehensive improvement of electrical, thermal and mechanical performance due to the physical cross-linking points acted by C60 particles. C60 shows a strong ability to inhibit electron transfer due to the unique zero-dimensional cage structure and high electron affinity, which reduces the conduction loss at high temperatures. Theoretical and experimental results show that the introduction of trace amounts of C60 particles into PEIs constructs stable carrier traps and significantly improves the high-temperature energy storage characteristics. The dielectric permittivity and breakdown strength are increased from 3.24 and 447 MV/m for PEI to 3.45 and 520 MV/m for the optimal C60/PEI nanocomposite at 150 °C, respectively. Consequently, the optimal C60/PEI nanocomposite achieves a discharged energy density (Ud) of 3.69 J/cm3 at 150 °C, which is higher than 2.65 J/cm3 of PEI. This provides a convenient and effective strategy to synergistically improve the comprehensive performance of polymer nanocomposite films for high-temperature energy storage applications.

薄膜电容器的极端工作环境对新一代聚合物介电材料产生了迫切的需求。聚合物基复合材料在突出的性能和大规模工业化生产方面是一个更有效的选择。本文选择C60作为功能性填料,通过静电相互作用与商用聚醚酰亚胺(PEI)结合,构建聚合物纳米复合材料(C60/PEI)。超低填充C60/PEI纳米复合材料由于C60粒子作用的物理交联点,实现了电学、热学和力学性能的全面提高。C60由于其独特的零维笼结构和高的电子亲和性,表现出很强的抑制电子转移的能力,从而降低了高温下的传导损失。理论和实验结果表明,引入微量C60粒子构建了稳定的载流子陷阱,显著改善了PEIs的高温储能特性。在150℃下,C60/PEI纳米复合材料的介电常数和击穿强度分别从PEI的3.24和447 MV/m提高到C60/PEI的3.45和520 MV/m。因此,最佳的C60/PEI纳米复合材料的放电能量密度Ud在150℃时为3.69 J/cm3,高于PEI的2.65 J/cm3。这为协同提高聚合物纳米复合薄膜的综合性能提供了一种方便有效的策略。 


来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemInspireDeform振动疲劳断裂复合材料航空航天冶金电力电子裂纹理论材料控制试验
著作权归作者所有,欢迎分享,未经许可,不得转载
首次发布时间:2025-04-24
最近编辑:3小时前
Tansu
签名征集中
获赞 9粉丝 3文章 883课程 0
点赞
收藏
作者推荐

【新文速递】2025年3月21日固体力学SCI期刊最新文章

今日更新:Journal of the Mechanics and Physics of Solids 1 篇,Mechanics of Materials 1 篇,International Journal of Plasticity 1 篇,Thin-Walled Structures 2 篇Journal of the Mechanics and Physics of SolidsDistinguish the calibration of conventional and data-driven constitutive model: the role of state boundary surfacesZhihui Wang, Roberto Cudmani, Andrés Alfonso Peña Olartedoi:10.1016/j.jmps.2025.106122区分传统和数据驱动本构模型的校准:状态边界面的作用In conventional constitutive models for granular materials, calibration involves estimating a few parameters within known mathematical expressions. In contrast, data-driven constitutive models couple the model structure and parameters. Addressing this fundamental difference, the development of constitutive models based on Physics-encoded Neural Networks (PeNN) is guided from the perspective of conventional model development, highlighting similarities and differences. The crucial physical information that influences PeNN is explained, and the incorporation of three key state boundary surfaces in pressure–porosity space—critical state, loosest state, and densest state—via physics-informed deep learning is detailed. Physics-informed calibration is performed using the augmented Lagrangian method; then, the calibrated models undergo extensive drained and undrained simulations. Results indicate that using only physical information from state boundary surfaces, without data within these boundaries, fails to calibrate data-driven models; thus, boundary surface information represents partial physical information. While combining partial physical information with reasonably distributed data can improve model development under limited experimental data, adding more partial physical information and data does not necessarily enhance the results. The finding aims to bridge the gap between conventional and data-driven constitutive models, hopefully increasing the reliability and interpretability of data-driven models.在颗粒材料的传统本构模型中,校准涉及在已知的数学表达式中估计一些参数。相反,数据驱动的本构模型将模型结构和参数耦合在一起。为了解决这一根本差异,基于物理编码神经网络(PeNN)的本构模型的开发从传统模型开发的角度进行指导,突出异同。解释了影响PeNN的关键物理信息,并通过物理信息深度学习详细介绍了压力-孔隙度-空间临界状态、最松散状态和最密集状态下三个关键状态边界表面的结合。使用增广拉格朗日方法进行物理信息校准;然后,校准的模型进行广泛的排水和不排水模拟。结果表明,仅使用来自状态边界面的物理信息,而不使用这些边界内的数据,无法校准数据驱动的模型;因此,边界表面信息代表部分物理信息。在实验数据有限的情况下,将部分物理信息与合理分布的数据相结合可以改善模型的开发,但添加更多的部分物理信息和数据并不一定能提高结果。这一发现旨在弥合传统和数据驱动的本构模型之间的差距,有望提高数据驱动模型的可靠性和可解释性。Mechanics of MaterialsLithiation-induced stress and damage in electrode materials: effects of current variationsYong Li, Lili Dai, Wei Feng, Kai Zhang, Fuqian Yangdoi:10.1016/j.mechmat.2025.105332锂离子诱导的应力和电极材料的损伤:电流变化的影响Lithium-ion batteries likely experience different structural evolution during electrochemical charging and discharging under dynamic environments from the corresponding one under “conventional” cycling conditions. In this work, we introduce a time-dependent influx in the analysis of the evolution of stress, strain, mechanical and chemical damages under galvanostatic operation. The time-dependent term is presented in two different forms – one in the form of a set of cosine terms and the other in the form of a Gaussian pulse. For the time-dependent term in the form of a single cosine term, both the angular frequency and amplitude contribute to the evolution of stress, strain, mechanical and chemical damages. The cosine term with a larger amplitude and/or a smaller angular frequency has a larger effect on the structural integrity of the electrode materials in LIBs than the corresponding one with a smaller amplitude and/or a larger angular frequency. For the time-dependent term in the form of a Gaussian pulse, the degradation of LIBs is dependent on the energy coefficient of the Gaussian pulse. Increasing the energy coefficient of the Gaussian pulse leads to the increase of mechanical and chemical damages.锂离子电池在动态环境下的电化学充放电过程可能会经历与“常规”循环条件下不同的结构演变。在这项工作中,我们在恒流操作下的应力、应变、机械和化学损伤的演变分析中引入了时间相关的内流。时间相关项以两种不同的形式呈现-一种以余弦项的形式呈现,另一种以高斯脉冲的形式呈现。对于单一余弦项形式的时间相关项,角频率和幅值都对应力、应变、力学和化学损伤的演化有贡献。振幅较大和/或角频率较小的余弦项比振幅较小和/或角频率较大的余弦项对电极材料结构完整性的影响更大。对于高斯脉冲形式的时变项,锂离子电池的退化取决于高斯脉冲的能量系数。随着高斯脉冲能量系数的增大,材料的机械损伤和化学损伤增加。International Journal of PlasticityTailoring fracture resistance of a metastable Fe42Mn28Co10Cr15Si5 high entropy alloy by intrinsic tougheningManoj Yadav, Niraj Nayan, Krishanu Biswas, N.P. Guraodoi:10.1016/j.ijplas.2025.104315 基于本征增韧的亚稳态Fe42Mn28Co10Cr15Si5高熵合金的定制抗断裂性能Metastable high entropy alloys (HEAs) provide an exceptional combination of strength and ductility by the synergistic operation of slip, twinning, and transformation; however, their fracture behaviour remains unexplored. In the present investigation, tensile and elastic-plastic fracture toughness tests with a 2D digital image correlation setup were carried out for different microstructural states of Fe42Mn28Co10Cr15Si5 HEA. Finite element analysis (FEA) coupled with combinatorial site-specific electron backscatter diffraction helps in developing a meso and micro scale mechanistic understanding of the extrinsic and intrinsic toughening processes. The calculated J-integral and plastic zone size using FEA simulations were corroborated with experimental results. The crack growth resistance (J-R) curve was evaluated across three distinct processing conditions: hot rolled (HR), 1 h annealed at 1173 K (AN1173), and 4 h annealed at 1373 K (AN1373). The HR material exhibited higher strength (yield strength = 630 ± 8 MPa), while the AN1373 demonstrated highest ductility (0.74 ± 0.04). The mode I plane strain fracture toughness was highest for the AN1373 (125.4 ± 15.8 MPa.m0.5) and lowest for the AN1173 (46.3 ± 7.4 MPa.m0.5). The Cr-rich sigma phase at grain boundaries in the HR and AN1173 led to pronounced intergranular fracture, resulting in lower fracture toughness and plasticity. The multiple variants of martensite in the AN1373 microstructural state, results in refined microstructure by interactions of transformation variants and dislocations that enhance the strength, ductility, and crack tip plasticity. The findings underscore the significant impact of intrinsic toughening on the fracture and deformation behaviour of the Fe42Mn28Co10Cr15Si5 HEA.亚稳态高熵合金(HEAs)通过滑移、孪晶和相变的协同作用,提供了强度和延展性的卓越组合;然而,它们的断裂行为仍未被研究。在本研究中,采用二维数字图像相关装置对Fe42Mn28Co10Cr15Si5 HEA的不同显微组织状态进行了拉伸和弹塑性断裂韧性测试。有限元分析(FEA)与组合位特异电子背散射衍射相结合,有助于对外在和内在增韧过程进行中观和微观的机制理解。有限元模拟计算的j积分和塑性区尺寸与实验结果相吻合。通过三种不同的加工条件:热轧(HR)、1173 K退火1 h (AN1173)和1373 K退火4 h (AN1373)来评估裂纹扩展阻力(J-R)曲线。HR材料具有较高的强度(屈服强度 = 630±8 MPa),而AN1373材料具有最高的延展性(0.74±0.04)。AN1373的I型平面应变断裂韧性最高(125.4±15.8 MPa.m0.5), AN1173的I型平面应变断裂韧性最低(46.3±7.4 MPa.m0.5)。HR和AN1173晶界处富含cr的sigma相导致明显的晶间断裂,导致断裂韧性和塑性降低。在AN1373显微组织状态下,马氏体的多种变体通过相变变体和位错的相互作用使组织细化,从而提高了强度、延展性和裂纹尖端塑性。研究结果强调了本征增韧对Fe42Mn28Co10Cr15Si5 HEA断裂和变形行为的显著影响。Thin-Walled StructuresModified consistent element-free Galerkin method applied to Reissner–Mindlin platesMarcelo Silveira Pereira, Mauricio Vicente Donadondoi:10.1016/j.tws.2025.113185 改进的一致无元素伽辽金法在Reissner-Mindlin板上的应用This study addresses the solution of static, modal, buckling and aeroelastic analyses associated with rectangular plates based on the first-order shear deformation theory (FSDT), i.e., Reissner–Mindlin plates. For this purpose, a Modified Consistent Element-Free Galerkin (MCEFG) method was applied in combination with the moving least-squares (MLS) method for the obtainment of the admissible functions. Three improvements are implemented for the application of the MCEFG method: a new weighting function that diminishes the support radius influence in the MLS method, a stable and efficient numerical integration that guarantees the consistency of the method and an imposition of essential boundary conditions that do not require the augmentation of the weak form. Comparison studies on the displacement and generalized force fields, eigenfrequencies, buckling loads and flutter velocity are performed using numerical and theoretical results that confirms the accuracy and efficiency of the proposed methodology. Finally, the study considers four boundary conditions in order to guarantee the applicability of the method in different scenarios.本研究基于一阶剪切变形理论(FSDT),即Reissner-Mindlin板,解决了与矩形板相关的静力、模态、屈曲和气动弹性分析。为此,将改进的一致无单元伽辽金法(MCEFG)与移动最小二乘法(MLS)相结合,得到了可容许函数。对mefg方法的应用进行了三个改进:一个新的加权函数,减少了MLS方法中支持半径的影响,一个稳定有效的数值积分,保证了方法的一致性,以及施加了不需要增加弱形式的基本边界条件。利用数值和理论结果对位移和广义力场、特征频率、屈曲载荷和颤振速度进行了对比研究,验证了所提方法的准确性和有效性。最后,研究考虑了四种边界条件,以保证方法在不同场景下的适用性。Geometry and Size Dependent Microstructure and Crack Formation in Rene 41 Superalloy Fabricated by Laser Powder Bed FusionSila Ece Atabay, Fatih Sikan, Mathieu Brochudoi:10.1016/j.tws.2025.113211激光粉末床熔合制备Rene 41高温合金的几何尺寸相关组织和裂纹形成This study provides a systematic investigation into the size- and geometry-dependent microstructural evolution and cracking susceptibility of LPBF-fabricated Rene 41. By coupling experimental microstructural analysis with thermal modeling, this research uniquely identifies the relationship between geometry-specific thermal histories, carbide coarsening, and liquation cracking. Four different geometries with varying thickness were fabricated with the identical process parameters. It was found that the grain size and morphology are not affected by the part size. However, the thinner parts exhibited coarser sub-grain structures compared to the thicker ones. The crack formation was observed for the parts with cross-sections smaller than 1 mm, whereas thicker parts had high density without any defects. The cracks were observed in the interdendritic regions, suggesting that liquation cracking was the active micro-crack formation mechanism. The detailed microstructural analysis combined with a thermal finite element analysis proved that the heat extraction efficiency was lower for thinner parts causing a lower cooling rate and coarser carbides, making them more susceptible to constitutional liquation. Microhardness measurements were conducted for each geometry and correlated with the observed microstructural variations. The findings highlight the critical need for geometry-specific optimization of LPBF process parameters to mitigate cracking and achieve microstructural uniformity, offering valuable insights into the fabrication of complex, high-performance aerospace components.本研究对lpbf制备的Rene 41的尺寸和几何相关的显微组织演化和开裂敏感性进行了系统的研究。通过将实验显微结构分析与热建模相结合,本研究独特地确定了几何特定热历史、碳化物粗化和液化开裂之间的关系。在相同的工艺参数下,制作了四种不同厚度的几何形状。晶粒尺寸和形貌不受零件尺寸的影响。然而,与较厚的部分相比,较薄的部分表现出更粗的亚晶粒结构。截面小于1mm的零件有裂纹形成,而较厚的零件密度高,没有缺陷。在枝晶间区观察到裂纹,表明液化裂纹是主动微裂纹形成机制。详细的显微组织分析结合热有限元分析证明,薄件的抽热效率较低,导致冷却速率较低,碳化物较粗,更容易发生本构液化。对每个几何形状进行显微硬度测量,并与观察到的显微结构变化相关联。研究结果强调了对LPBF工艺参数进行几何特定优化的迫切需要,以减轻裂纹并实现微结构均匀性,为复杂、高性能航空航天部件的制造提供了有价值的见解。来源:复合材料力学仿真Composites FEM

未登录
还没有评论
课程
培训
服务
行家
VIP会员 学习计划 福利任务
下载APP
联系我们
帮助与反馈