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【新文速递】2025年2月20日复合材料SCI期刊最新文章

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今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 17 篇,Composites Science and Technology 1 篇

Composite Structures

Dynamic and static behaviour of geopolymer concrete for sustainable infrastructure development: Prospects, challenges, and performance review

Amer Hassan, Chunwei Zhang

doi:10.1016/j.compstruct.2025.118984

用于可持续基础设施发展的地聚合物混凝土的动态和静态行为:前景、挑战和绩效回顾

Geopolymer concrete (GPC) is increasingly recognized as a sustainable and environmental option to conventional concrete due to its utilization of industrial byproducts. This paper thoroughly investigates the dynamic and static behaviour of GPC, focusing on its mechanical properties, durability, and resistance to impact and seismic loads. Also, this article compares the experimental results reported in previous studies with a predicted model to justify the results obtained by experiments. According to the evaluation and review of previous studies, it could be summarised that no individual factor influences the structural properties of GPC. Additionally, efforts should be made to determine the interrelationship between various factors in order to facilitate the creation of a GPC that is both cost-effective and sustainable for the environment. Further, emphasis is placed on fibre reinforcement, which enhances the material’s dynamic performance. Also, the dynamic behaviour of GPC, including impact and seismic resistance, is still uncertain due to the lack of studies on this subject, and more investigation on this matter must be undertaken to generate a comprehensive picture of the dynamic behaviour of these materials before introducing them to the industry.

地聚合物混凝土(GPC)越来越被认为是传统混凝土的可持续和环保选择,因为它利用了工业副产品。本文深入研究了GPC的动态和静态性能,重点研究了它的机械性能、耐久性以及对冲击和地震载荷的抵抗力。并将以往研究的实验结果与预测模型进行对比,验证实验结果。通过对以往研究的评价和回顾,可以总结出,没有单个因素影响GPC的结构性能。此外,应努力确定各种因素之间的相互关系,以便促进建立既具有成本效益又对环境具有可持续性的全球可持续发展方案。此外,重点放在纤维增强,这提高了材料的动态性能。此外,由于缺乏对这一主题的研究,GPC的动态性能,包括冲击和抗震性能,仍然是不确定的,在将这些材料引入工业之前,必须进行更多的调查,以产生这些材料的动态性能的全面图景。


Composites Part A: Applied Science and Manufacturing

Deterioration behaviors of phenolic amine/epoxy-based GFRP laminates exposed to aggressive environments

Yinlong Cao, Guanghui Gao, Wenhuan Wang, Genjin Liu, Jiuwen Bao, Yifei Cui, Ying Li

doi:10.1016/j.compositesa.2025.108788

酚醛胺/环氧基GFRP层压板在恶劣环境下的劣化行为

The advanced resin systems are crucial for the application of GFRP in the practical marine engineering. Besides, the reliable performance data on GFRP exposed to marine environment are still lacking. This study aims to comprehensively evaluate the durability-related performance of the GFRP laminates made up of the modified resin. In this experiment, the resin and GFRP laminate specimens were exposed to deionized water (DW), real seawater (RSW), simulated pore solutions of seawater sea sand concrete (SSCSPS) and real marine environment (RME). The results showed that the moisture absorption of GFRP laminates in SSCSPS was higher than that in DW and RSW due to the destruction of GFRP multiphase structures. The tensile strength of the resin exposed to RSW and RME after 90 days was improved due to its post-curing, while that of GFRP laminates decreased by 8–9 %. Besides, it was remarkable that the tensile strength retention of the resin and GFRP laminates immersed in SSCSPS after 90 days was decreased by more than 30 %. The modified prediction model was developed by considering the resin factor on tensile strength of GFRP laminates exposed to various environments. Furthermore, the deterioration mechanisms of GFRP laminates were discussed by morphology characterization.

先进的树脂体系对玻璃钢在实际海洋工程中的应用至关重要。此外,GFRP在海洋环境下的可靠性能数据仍然缺乏。本研究旨在综合评价改性树脂构成的玻璃钢复合材料的耐久性相关性能。在本实验中,树脂和GFRP层压试件分别暴露于去离子水(DW)、真实海水(RSW)、模拟海水海砂混凝土孔隙溶液(SSCSPS)和真实海洋环境(RME)中。结果表明,由于GFRP多相结构的破坏,SSCSPS中GFRP复合材料的吸湿率高于DW和RSW。经RSW和RME处理90 天后,树脂的抗拉强度因其后固化而提高,而GFRP层压板的抗拉强度下降了8-9 %。此外,在SSCSPS中浸泡90 天后,树脂和GFRP层压板的抗拉强度保持率下降了30 %以上。考虑树脂因素对玻璃钢复合材料在不同环境下拉伸强度的影响,建立了改进的预测模型。此外,从形貌表征方面探讨了玻璃钢复合材料的劣化机理。


Role of glass fiber surface treatment on hydrothermal aging at the interface between polybutylene terephthalate and glass fiber

Hideyuki Uematsu, Shunya Yorikane, Ayaka Yamaguchi, Shinji Sugihara, Fumihiro Nishimura, Masachika Yamane, Shuichi Tanoue

doi:10.1016/j.compositesa.2025.108811

玻璃纤维表面处理对聚对苯二甲酸丁二酯与玻璃纤维界面水热老化的影响

The objective of this study is to characterize the role of glass fiber (GF) surface treatment in hydrothermal aging at polybutylene terephthalate (PBT) and GF interfaces from X-ray photoelectron spectroscopy analysis of the fracture surface. The mechanical properties of PBT/GF were investigated using four types of GFs treated with aminosilane and epoxy. The surface treatment containing epoxy contributed to the suppression of GF fracture during molding process and improved the interfacial strength with PBT, resulting in higher tensile strength of the PBT/GF before hydrothermal treatment. After hydrothermal treatment, the tensile strength of the epoxy-treated GF and PBT composites reduced owing to moisture absorption, and that of the aminosilane-treated GF and PBT composites decreased by hydrolysis at the interphase. Nevertheless, in the PBT/GF treated with epoxy and aminosilane together, the interfacial hydrolysis and moisture absorption during the hydrothermal treatment were suppressed, resulting in the highest tensile strength of PBT/GF.

本研究的目的是通过对断口表面的x射线光电子能谱分析来表征玻璃纤维(GF)表面处理在聚对苯二甲酸丁二酯(PBT)和GF界面水热老化中的作用。采用氨基硅烷和环氧树脂对四种GFs进行处理,研究了PBT/GF的力学性能。含环氧树脂的表面处理有助于抑制成型过程中GF的断裂,提高与PBT的界面强度,使水热处理前PBT/GF的拉伸强度更高。水热处理后,环氧树脂处理的GF和PBT复合材料的抗拉强度因吸湿而降低,氨基硅烷处理的GF和PBT复合材料的抗拉强度因界面水解而降低。而环氧树脂和氨基硅烷共同处理的PBT/GF,水热处理过程中的界面水解和吸湿被抑制,从而使PBT/GF的拉伸强度最高。


Composites Part B: Engineering

W-shaped broadband attenuation of longitudinal waves through composite elastic metamaterial

Brahim Lemkalli, Krzysztof K. Dudek, Muamer Kadic, Qingxiang Ji, Sébastien Guenneau, Abdellah Mir, Younes Achaoui

doi:10.1016/j.compositesb.2025.112250

复合弹性超材料对纵波w型宽带衰减的影响

We investigate a composite elastic meta-slab with exceptional transmission properties, particularly the presence of a W-shaped bandgap. A comprehensive study, utilizing experimental measurements, the finite element method, and an analytical approach, identifies this specific bandgap. The meta-slab design involves cutting an array of composite materials arranged in parallel with strategically placed incisions. This configuration ensures that the materials between the slits act as plate-like waveguides within the surrounding medium. The incorporation of steel into ABS-based Fabry–Perot cavities induces a notable coupling effect between longitudinal waves and localized modes traversing the structure, leading to the formation of two distinct Fabry–Perot resonators. These coupling effects generate a series of resonances and antiresonances, ultimately producing the W-band gap through the interaction of two symmetric Fano resonances.

我们研究了一种具有特殊透射特性的复合弹性元板,特别是w形带隙的存在。综合研究,利用实验测量,有限元方法和分析方法,确定了这一特定的带隙。meta-slab设计包括切割一系列平行排列的复合材料,并有策略地放置切口。这种结构确保了狭缝之间的材料在周围介质中充当板状波导。将钢加入abs基法布里-珀罗腔中,在纵波和穿过结构的局域模式之间产生了显著的耦合效应,从而形成了两个不同的法布里-珀罗谐振腔。这些耦合效应产生一系列共振和反 共振,最终通过两个对称的Fano共振相互作用产生w带隙。


Enhancing Bone Healing through Immunological Microenvironment Modulation via a Smart-Responsive Multifunctional Therapeutic System

Yu Wang, Huaiyuan Zhang, Tinglin Zhang, Kuo Xia, Wenyu Qiao, Longhai Du, Xueneng Hu, Xuan Zhou, Huifen Qiang, Meigui Li, Jun Meng, Feiyan Chen, Jie Gao, Zuochong Yu

doi:10.1016/j.compositesb.2025.112252

 

通过免疫微环境调节通过智能反应多功能治疗系统促进骨愈合

The clinical repair of bone defects is still a significant challenge because of unfavorable immunological microenvironments, limited blood supply, and weak osteogenic differentiation potential. Therefore, a hydroxyapatite-based (HAp) nanocomposite (HPDD), consisting of polydopamine (PDA)-adhered deferoxamine (DFO), was designed and incorporated into an F127DA hydrogel. The HPDD nanocomposite acted as a photosensitizer, endowing the F127DA/HPDD hydrogel with the ability to spatiotemporally and intelligently release DFO and Ca2+ in response to near-infrared (NIR)/pH stimulation. This mild photothermal therapy induced by NIR irradiation achieves the clearance of reactive oxygen species (ROS), the polarization of M1 macrophages toward the M2 phenotype, and the promotion of angiogenesis and bone repair. Furthermore, by fostering an anti-inflammatory immunological microenvironment, the F127DA/HPDD hydrogel sustained release system promoted the secretion of functional factors, which are beneficial for angiogenesis and bone repair. Transcriptomic analysis was employed to investigate how M2 macrophage polarization enhances angiogenesis and osteogenic differentiation. In vivo experiments further confirmed that the F127DA/HPDD hydrogel system, under NIR/pH stimulation, promoted angiogenesis and osteogenic differentiation by inhibiting inflammation. In summary, this intelligent responsive hydrogel system provides a novel approach for reshaping an anti-inflammatory immunological microenvironment to accelerate bone repair.

由于免疫微环境不利、血供有限、成骨分化潜力弱,骨缺损的临床修复仍是一个重大挑战。因此,设计了一种由聚多巴胺(PDA)粘附去铁胺(DFO)组成的羟基磷灰石基(HAp)纳米复合材料(HPDD),并将其掺入F127DA水凝胶中。HPDD纳米复合材料作为光敏剂,使F127DA/HPDD水凝胶在近红外(NIR)/pH刺激下具有时空和智能释放DFO和Ca2+的能力。这种由近红外照射诱导的轻度光热疗法可以清除活性氧(ROS),使M1巨噬细胞向M2表型极化,促进血管生成和骨修复。此外,通过培养抗炎免疫微环境,F127DA/HPDD水凝胶缓释系统促进了有利于血管生成和骨修复的功能因子的分泌。利用转录组学分析研究M2巨噬细胞极化如何促进血管生成和成骨分化。体内实验进一步证实了F127DA/HPDD水凝胶体系在近红外/pH刺激下,通过抑制炎症促进血管生成和成骨分化。总之,这种智能反应水凝胶系统为重塑抗炎免疫微环境以加速骨修复提供了一种新的方法。


Nanoarchitected graphene/ceramic composites

Jie Li, Bin Liu, Qingtan Ren, Jingjie Cheng, Jinhao Tan, Jie Sheng, Changsheng Xing, Yunzhong Wu, Lidong Wang, Weidong Fei

doi:10.1016/j.compositesb.2025.112296

纳米石墨烯/陶瓷复合材料

The sintering and densification of graphene/ceramic composites pose significant challenges owing to the high melting point of graphene and ceramic phases. Here we address these challenges by using boron, silicon, and graphene as raw materials to prepare graphene/ceramic composites via spark plasma sintering (SPS) at 1600 °C. Boron and silicon significantly reduce the sintering temperature and improve the relative density of the composites. The abundant Y-type carbon structures effectively inhibit the sliding between graphene layers, improving the shear strength of few-layer graphene. Additionally, the strong Si-C and B-C interfacial bonding synergistically reinforce the composites, leading to exceptional mechanical strength, with the flexural strength of 561 MPa, the compressive strength up to 2.17 GPa, and the microscale compressive strength reaching 11.3 GPa (700 nm in diameter). Meanwhile, the composite exhibits impressive fracture toughness of 7.5 MPa·m1/2. Molecular dynamics simulations indicate that Y-type carbon structures allow for plastic deformation. The graphene/ceramic composites not only demonstrate superior strengths but are also easy to prepare, making them particularly advantageous for wear-resistant components, ballistic armor and aerospace materials.

由于石墨烯和陶瓷相的高熔点,石墨烯/陶瓷复合材料的烧结和致密化面临着巨大的挑战。本研究以硼、硅和石墨烯为原料,在1600℃下通过火花等离子烧结(SPS)制备石墨烯/陶瓷复合材料,解决了这些挑战。硼和硅显著降低了烧结温度,提高了复合材料的相对密度。丰富的y型碳结构有效抑制了石墨烯层间的滑动,提高了少层石墨烯的抗剪强度。此外,Si-C和B-C界面的强结合协同增强了复合材料的机械强度,其抗折强度达到561 MPa,抗压强度达到2.17 GPa,微尺度抗压强度达到11.3 GPa(直径700 nm)。同时,复合材料的断裂韧性达到了7.5 MPa·m1/2。分子动力学模拟表明,y型碳结构允许塑性变形。石墨烯/陶瓷复合材料不仅表现出优越的强度,而且易于制备,使其在耐磨部件,弹道装甲和航空航天材料方面特别有利。


Disassembly of Laminated CFRP using Direct Pulsed Discharge

Keita Sato, Taketoshi Koita, Manabu Inutsuka, Koji Yamaguchi, Masao Kimura, Chiharu Tokoro

doi:10.1016/j.compositesb.2025.112301

用直接脉冲放电法拆卸叠层CFRP

To promote the sustainable use of carbon fiber-reinforced polymers (CFRPs), the efficient recovery and recycling of carbon fibers (CFs) from used CFRP products is required. In this study, a direct pulsed discharge with high voltage was applied to CFRP samples for quick, low-cost dismantling and CF separation. It was found that direct pulsed discharge results in the effective destruction of CFRP, particularly in regions where the CFs are aligned parallel to the applied current. This implies that pulsed discharge is a promising method for the coarse dismantling of laminated CFRP. High-speed video camera observations, X-ray computed tomography, and electric field simulations revealed that Joule heat generated from the large current through the CFs rapidly gasifies the surrounding resin, resulting in the destruction of the CFRP.

为了促进碳纤维增强聚合物(CFRP)的可持续利用,需要从使用过的CFRP产品中有效地回收和再循环碳纤维(CFRP)。在本研究中,采用高压直接脉冲放电对CFRP样品进行快速、低成本的拆解和分离。研究发现,直接脉冲放电可以有效地破坏碳纤维布,特别是在碳纤维布与施加电流平行排列的区域。这表明脉冲放电是一种很有前途的粗解复合材料的方法。高速摄像机观察、x射线计算机断层扫描和电场模拟显示,通过CFRP的大电流产生的焦耳热迅速使周围的树脂气化,导致CFRP的破坏。


Bioactive nanocapsules based on lychee-like bilayer structure for synovitis treatment

Wenwen Chai, Pengfei Tian, Mengke Fan, Xiaochen Chen, Liyan Zhang, Muyan Qin, Yingbo Wang, Yansong Wang, Wei Chen, Qiang Yang, Honglong Li, Xu Cui, Deping Wang, Haobo Pan

doi:10.1016/j.compositesb.2025.112303

基于荔枝类双层结构的生物活性纳米胶囊治疗滑膜炎

Osteoarthritis (OA), as a degenerative disease, often necessitates intra-articular administration to alleviate pain. Synovial inflammation represents an important pathological factor in the development of OA. ZIF-8 (a type of Zeolitic imidazolate frameworks), a newly developed drug carrier, has garnered significant attention due to its high drug loading capacity and favorable biocompatibility. However, pH-sensitive burst drug release in inflammatory environments hampered its clinical application. To overcome this limitation, we have engineered a novel lychee-like double-layered bioactive nanocapsule, with ZIF-8 serving as the core and a bioactive amorphous sol as the outer shell, facilitated by Zn ion and Si-O coordination. The amorphous sol not only inhibits the rapid degradation of ZIF-8 in inflammatory conditions, preventing quick drug release, but also enhances the immunomodulatory capabilities of the functional carrier. Remarkably, our studies reveal that, in addition to sustained drug release, the synergistic effect of the functional carrier and anti-inflammatory drugs can regulate inflammation-induced lymphatic abnormalities. This is manifested by the suppression of macrophage secretion of excessive VEGF-C and iNOS, thereby modulating lymphatic density and restoring normal lymphatic rhythmic function. These findings indicate that such pathology-adaptive functional carriers possess superior drug release control and immunomodulatory potential compared to traditional carriers, presenting a promising innovative material for synovitis treatment.

骨关节炎(OA)作为一种退行性疾病,通常需要关节内给药来减轻疼痛。滑膜炎症是骨性关节炎发展的重要病理因素。ZIF-8(一种沸石咪唑盐框架)是一种新开发的药物载体,因其高载药量和良好的生物相容性而受到广泛关注。然而,在炎症环境中ph敏感的药物爆发释放阻碍了其临床应用。为了克服这一限制,我们设计了一种新型的荔枝状双层生物活性纳米胶囊,以ZIF-8为核心,以生物活性无定形溶胶为外壳,通过Zn离子和Si-O配位促进。无定形溶胶不仅可以抑制炎症条件下ZIF-8的快速降解,防止药物快速释放,还可以增强功能载体的免疫调节能力。值得注意的是,我们的研究表明,除了持续的药物释放外,功能载体和抗炎药物的协同作用可以调节炎症诱导的淋巴异常。这表现为抑制巨噬细胞分泌过多的VEGF-C和iNOS,从而调节淋巴密度,恢复正常淋巴节律功能。这些发现表明,与传统载体相比,这种病理适应性功能载体具有更好的药物释放控制和免疫调节潜力,是治疗滑膜炎的一种有前景的创新材料。


Robust multi-scale bionic ANF/PMSQ aerogel featuring impact protection, thermal insulation and anti-icing functions

Zhihao Hu, Sheng Wang, Jianpeng Wu, Zimu Li, Shuai Liu, Yue Yao, Shilong Duan, Guilin Mei, Xinglong Gong

doi:10.1016/j.compositesb.2025.112304

 

坚固的多尺度仿生ANF/PMSQ气凝胶,具有防冲击、隔热和防冰功能

To address the complex threats in extreme surroundings, it is urgent to develop novel safeguarding devices with multiple defensive properties. Traditional bionic structures typically exhibit only single defense function, making comprehensive protection against diversified threats strenuous. In this study, a novel aerogel material is developed by growing polymethylsesquisiloxane (PMSQ) in situ on the honeycomb skeleton of aramid nanofibers (ANF) to form multi-scale pomelo-peel/honeycomb bionic porous structures. ANF-PMSQ (ANFP) aerogel exhibits superb mechanical strength, which can support 10370 times its own weight. More importantly, ANFP effectively dissipates the impact force from 6.30 kN to 0.19 kN. Besides, mesoporous PMSQ inhibits heat convection within the directional skeleton pores, markedly reducing the thermal conductivity to 64.6 mW/(m·K), and providing outstanding thermal insulation over a wide range from -188 °C to 400 °C. In addition, the rough surface structure and large number of hydrophobic groups endow ANFP with hydrophobic and anti-icing properties. At -10 °C, the freezing time of water droplet on the ANFP surface is extended to an impressive 4547 s, significantly delaying the freezing process. Finally, ANFP provides mechanical-thermal coupling defense and anti-icing properties for outdoor pipelines and batteries in complex conditions. Thus, this work develops a multifunctional protective ANFP material for further engineering applications.

为了应对极端环境下的复杂威胁,迫切需要开发具有多种防御性能的新型防护装置。传统的仿生结构通常只有单一的防御功能,难以对多种威胁进行综合防护。在本研究中,通过在芳纶纳米纤维(ANF)的蜂窝骨架上原位生长聚甲基倍半硅氧烷(PMSQ),制备了一种新型气凝胶材料,形成了多尺度的蜜柚皮/蜂窝仿生多孔结构。ANF-PMSQ (ANFP)气凝胶具有优异的机械强度,可承受自身重量的10370倍。更重要的是,ANFP有效地将6.30 kN的冲击力分散到0.19 kN。此外,介孔PMSQ抑制定向骨架孔隙内的热对流,显著降低导热系数至64.6 mW/(m·K),并在-188°C至400°C的范围内提供出色的隔热性能。此外,粗糙的表面结构和大量的疏水基团赋予了ANFP疏水和防冰性能。在-10℃时,水滴在ANFP表面的冻结时间延长至4547 s,显著延缓了冻结过程。最后,ANFP为复杂条件下的室外管道和电池提供机械-热耦合防御和防冰性能。因此,这项工作为进一步的工程应用开发了一种多功能保护ANFP材料。


Revitalizing osteoporotic bone repair via multilevel ROS scavenging and osteoimmune regulating hydrogel

Yiran Zhang, Qingcheng Song, Shuai Yang, Jiheng Xiao, Fengkun Wang, Chunxu Fu, Xin Xing, Jianhua Wu, Shuo Zhang, Yanbin Zhu, Yingze Zhang

doi:10.1016/j.compositesb.2025.112305

 

通过多水平活性氧清除和骨免疫调节水凝胶恢复骨质疏松的骨修复

Osteoporotic bone defects (OBDs) pose significant clinical challenges due to impaired tissue regeneration and osteogenic differentiation. Conventional combination therapies using systemic anti-osteoporosis drugs and graft fillings have yielded unsatisfactory results. Excessive reactive oxygen species (ROS) are a hallmark of OBDs, leading to abnormal inflammatory responses and a hostile osteoimmune microenvironment that impedes repair. In this study, we developed a multifunctional injectable hydrogel, termed PTSr@CP, composed of a strontium (Sr) and tannic acid (TA)-based metal–phenolic network core coated with polydopamine (PDA), integrated into a matrix of carboxymethyl chitosan and poly (γ-glutamic acid). The PTSr@CP hydrogel can be easily injected into bone defect sites, where it undergoes rapid in situ crosslinking and exhibits exceptional ROS-scavenging capabilities. Additionally, the hydrogel mediates mild photothermal therapy (MPTT), promoting local tissue repair. Both in vitro and in vivo studies demonstrated its excellent biosafety and confirmed synergistic bone regeneration through enhanced osteogenesis, angiogenesis, and osteoimmunomodulation. This work offers a compelling strategy for OBD treatment by combining mild hyperthermia-enhanced in situ bone repair with sustained delivery of bioactive agents to improve the osteoimmune microenvironment.

骨质疏松性骨缺损(OBDs)由于组织再生和成骨分化受损,给临床带来了重大挑战。常规的联合治疗采用全身抗骨质疏松药物和移植物填充物产生不满意的结果。过多的活性氧(ROS)是obd的一个标志,导致异常的炎症反应和不利的骨免疫微环境,阻碍修复。在这项研究中,我们开发了一种多功能可注射水凝胶,称为PTSr@CP,由一个基于锶(Sr)和单宁酸(TA)的金属酚网络核心包被聚多巴胺(PDA)组成,整合到羧甲基壳聚糖和聚γ-谷氨酸的基质中。PTSr@CP水凝胶可以很容易地注射到骨缺损部位,在那里它经历了快速的原位交联,并表现出优异的ros清除能力。此外,水凝胶介导轻度光热疗法(MPTT),促进局部组织修复。体外和体内研究都证明了其良好的生物安全性,并证实了其通过增强成骨、血管生成和骨免疫调节来促进骨再生的协同作用。这项工作提供了一种令人信服的OBD治疗策略,通过结合轻度高温增强的原位骨修复和持续递送生物活性药物来改善骨免疫微环境。


Benzene Ring Structural Design Strategy toward Well-balanced Thermal and Electrical Properties in Epoxy Dielectric Polymers

Jie Li, Boya Zhang, Xiao Yuan, Xuanjie Zhang, Yixuan Li, Weidong Cao, Xingwen Li

doi:10.1016/j.compositesb.2025.112308

环氧介质聚合物热电性能平衡的苯环结构设计策略

The increasing demand for high power density and compact size devices in modern electrical and electronic systems requires polymer materials with excellent high-temperature electrical properties. However, electrical properties and thermal stability are often mutually exclusive in current polymer dielectric materials. Here, we report a strategy to achieve a well balance between thermal and dielectric properties by tailoring the molecular structure of epoxy resin (EP) curing agents. With the rigid benzene ring providing high thermal stability, the carrier density is controlled by modulating the non-localized electron density through substitution with strong electron-withdrawing groups and aliphatic structures, while the intermolecular charge conjugation transport is blocked by altering the conformation between molecular chains through grafting of side chain groups. By synergistically combining the two strategies within the same curing agent, the resultant polymer exhibits a volume resistance of 3.76 × 1013 Ω m and a direct current breakdown strength of 243.23 kV mm-1 at 120 °C. It also demonstrates potential applications in DC transmission systems and power electronics packaging, providing a new direction for the development of next-generation insulating polymers for harsh environments.

现代电气和电子系统对高功率密度和小尺寸器件的需求日益增长,要求聚合物材料具有优异的高温电性能。然而,在目前的聚合物介电材料中,电性能和热稳定性往往是相互排斥的。在这里,我们报告了一种通过调整环氧树脂(EP)固化剂的分子结构来实现热和介电性能之间良好平衡的策略。刚性苯环具有较高的热稳定性,通过引入强吸电子基团和脂肪族结构来调节非定域电子密度来控制载流子密度,通过侧链基团接枝改变分子链之间的构象来阻断分子间电荷共轭输运。通过在同一固化剂中协同结合两种策略,所得聚合物在120°C下的体积电阻为3.76 × 1013 Ω m,直流击穿强度为243.23 kV mm-1。它还展示了在直流传输系统和电力电子封装中的潜在应用,为恶劣环境下下一代绝缘聚合物的开发提供了新的方向。


A novel hierarchical structure of in-situ copper matrix composites reinforced with micro-clusters of TiB2 particles and nano-precipitates of B24Cu particles

Hao Shi, Yihui Jiang, Pengtao Li, Jie Cui, Fei Cao, Yanfang Wang, Shuhua Liang

doi:10.1016/j.compositesb.2025.112311

TiB2颗粒微团簇和B24Cu颗粒纳米沉淀增强原位铜基复合材料的新型分层结构

Copper-based materials strengthened by a second phase are widely used in electrical industrial devices due to their high strength and high electrical conductivity. However, traditional uniformly dispersed materials have inherent limitations, which restrict their overall performance. Here, we develop a new hierarchical structure strategy to overcome this issue in copper-based materials by combining in-situ synthesized copper matrix composite powders with routine powder metallurgy processes. Based on the rapidly solidified microstructure of the composite powder, the submicron TiB2 particles with a high volume fraction formed by a liquid state in-situ reaction distribute as micro-clusters, while the nano-precipitates of B24Cu particles with high thermal stability precipitates during the sintering stage and is dispersive and homogeneously distributed. This novel hierarchical structure exhibits extraordinary work hardening capability and forms a network of low electrical resistance regions, thus leading to copper matrix composites with an ultimate tensile strength of 926 MPa and electrical conductivity as high as 79.8% International Annealed Copper Standard, which is superior to numerous copper-based materials reinforced with ceramic second phases. The results will provide fundamental insights for the structural design of second phase strengthened copper-based materials.

第二相强化铜基材料因其高强度和高导电性而广泛应用于电气工业器件中。然而,传统的均匀分散材料具有固有的局限性,这限制了它们的整体性能。本文通过将原位合成的铜基复合粉末与常规粉末冶金工艺相结合,开发了一种新的分层结构策略来克服铜基材料中的这一问题。从复合粉末的快速凝固微观结构来看,液相原位反应形成的高体积分数的亚微米TiB2颗粒呈微团簇状分布,而具有高热稳定性的B24Cu颗粒的纳米析出物在烧结阶段析出,分散且分布均匀。这种新颖的分层结构表现出非凡的加工硬化能力,并形成低电阻区域网络,从而使铜基复合材料的极限抗拉强度达到926 MPa,电导率高达79.8%,优于许多用陶瓷第二相增强的铜基材料。研究结果将为第二相强化铜基材料的结构设计提供基础见解。


Numerical characterization of the geometric shape of coral sand by particle shaping and study on the properties of graded composite coral fine aggregate

Aiguo Wang, Zhijie Xu, Yingjie Chu, Jian-Guo Dai, Qiong Xu, Kaiwei Liu, Yi Ding, Daosheng Sun

doi:10.1016/j.compositesb.2025.112313

珊瑚砂颗粒成形几何形状的数值表征及分级复合珊瑚细骨料性能研究

High porosity and complex morphological characteristics of coral coarse aggregates typically lead to low strength, poor durability, and significant variability in coral concrete properties. This study examined the diverse properties of coral sand produced by jaw crushing and mechanical ball milling respectively. The geometric characteristics of the coral sand were quantitatively analyzed, and the effects of two processing methods on the morphology and porosity of coral sand were explored. Coral sands produced by each method were combined into coral fine aggregates with varying gradations, and the intrinsic relationship between the characteristics of coral fine aggregate and its concrete properties and porosity was explored. The results demonstrated that jaw crushing or ball milling significantly improved particle morphology and reduced porosity of the coral aggregates. Jaw crushing coral sand predominantly exhibited transverse fractures, while mechanical ball milling coral sand often exhibited longitudinal fractures. Under equivalent grading conditions, ball-milled coral sand achieved higher packing density and apparent density, alongside lower void ratios and water absorption rates. The study further demonstrated that the porosity, morphology, and gradation of the fine aggregates are crucial determinants of coral concrete's performance. B-II2.7 coral fine aggregate was tightly packed and the morphology of coral sand was good. The fluidity and 7-day compressive strength of CB-II2.7 had increased by 24.2% and 27.7% respectively compared to these of CJ-I3.4, and its porosity had decreased by 29.8%.

珊瑚粗骨料的高孔隙率和复杂的形态特征通常导致强度低、耐久性差和珊瑚混凝土性能的显著变化。研究了分别采用颚式破碎法和机械球磨法生产的珊瑚砂的不同性能。定量分析了珊瑚砂的几何特征,探讨了两种处理方法对珊瑚砂形貌和孔隙度的影响。将每种方法生产的珊瑚砂组合成不同级配的珊瑚细骨料,探讨了珊瑚细骨料的特性与其混凝土性能和孔隙率之间的内在关系。结果表明,颚破碎或球磨可显著改善珊瑚聚集体的颗粒形态,降低孔隙率。颚式破碎珊瑚砂以横向裂缝为主,机械球磨珊瑚砂以纵向裂缝为主。在同等级配条件下,球磨珊瑚砂的充填密度和表观密度更高,孔隙率和吸水率也更低。研究进一步表明,孔隙率、形态和细集料的级配是珊瑚混凝土性能的关键决定因素。B-II2.7珊瑚细骨料排列紧密,珊瑚砂形态良好。与CJ-I3.4相比,CB-II2.7的流动性和7天抗压强度分别提高了24.2%和27.7%,孔隙率降低了29.8%。


Harnessing Nanoconfinement-Enhanced Hydrogen Bonding and Multi-Scale Structures for High-Performance Sustainable Foam Materials

Kaixiong Zhao, Kangsi Zhou, Xu Chang, Shuming Liu, Weizhao Hu, Yanbei Hou

doi:10.1016/j.compositesb.2025.112318

 
  • 利用纳米约束增强氢键和多尺度结构制备高性能可持续泡沫材料

  • Developing sustainable, high-performance materials is crucial to meet the growing demand for eco-friendly, multifunctional solutions across industries. Traditional plastic-based foams can take centuries to degrade, contributing significantly to environmental pollution. This study introduces an innovative organic-inorganic composite ink suitable for direct ink writing to fabricate high-strength, sustainable foam materials. The ink formulation is composed of gelatin, hydroxypropyl methylcellulose, and Co3O4-loaded silica nanofibers (named as CSNFs). The foam prepared from this ink is named as GC, where GC-10 represents GC containing 10 wt% CSNFs. The nanoscale dimensions and high surface area of CSNFs facilitate physical entanglement within the foam matrix. Additionally, H-bond nanoconfinement, combined with the organic-inorganic multi-scale network, significantly enhances the structural stability of GC foams. The formulated ink demonstrates excellent printability, forming a porous structure after freeze-drying. GC-10 exhibits enhanced thermal insulation (0.048 W/m•K), high mechanical performance (compression modulus of 3111.1 ± 300 kPa), and reduced smoke toxicity, with a peak CO release 72.4% lower than GC. Notably, GC foams can be recycled without any loss in performance. Additionally, CSNFs are recoverable through centrifugation, minimizing environmental impact. This closed-loop recycling strategy, incorporating water solvent recovery, addresses a critical need in sustainable materials engineering. It emphasizes the potential of organic-inorganic integration in developing high-performance, multifunctional materials.

开发可持续、高性能的材料对于满足各行各业对环保、多功能解决方案日益增长的需求至关重要。传统的塑料泡沫需要几个世纪才能降解,严重污染环境。本研究介绍一种创新的有机-无机复合墨水,适用于直接墨水书写,以制造高强度,可持续的泡沫材料。油墨配方由明胶、羟丙基甲基纤维素和负载co3o4的二氧化硅纳米纤维(称为csnf)组成。用这种油墨制备的泡沫被命名为GC,其中GC-10表示含有10% csnf的GC。CSNFs的纳米级尺寸和高表面积有利于泡沫基质内的物理纠缠。此外,氢键纳米约束与有机-无机多尺度网络相结合,显著提高了GC泡沫的结构稳定性。该配方油墨具有优异的印刷性能,在冷冻干燥后形成多孔结构。GC-10具有较高的保温性能(0.048 W/m•K)、较高的力学性能(压缩模量为3111.1±300 kPa)和较低的烟雾毒性,CO峰值释放量比GC低72.4%。值得注意的是,GC泡沫可以回收而不会损失任何性能。此外,csnf可通过离心回收,最大限度地减少对环境的影响。这种闭环回收策略,结合水溶剂回收,解决了可持续材料工程的关键需求。它强调有机-无机集成在开发高性能、多功能材料方面的潜力。


Enhanced Delamination Resistance and Through-Thickness Thermal Conductivity of Carbon Fiber Epoxy Resin Composites by In Situ Generation of Interconnected Thick Oriented Matrix-Carbon Nanotube Layer

Haoyuan Wang, Qingyuan Guo, Shekun Wang, Lihong Gao, Xuetao Shi

doi:10.1016/j.compositesb.2025.112297

原位生成互连厚取向基体-碳纳米管层提高碳纤维环氧树脂复合材料的脱层阻力和通厚导热性

Conventional carbon fiber/epoxy resin-based composites are widely used due to their high specific strength. However, typical laminated composites have poor delamination resistance as well as through-thickness thermal conductivity due to poor interfacial bonding between the polymer matrix and carbon fibers, two-dimensional structure without interlayer load-bearing phases, lack of continuous interlayer thermal conductive path. In this work, the carbon fiber cloth was firstly surface-treated with in-situ growth carbon nanotube on its surface by chemical vapor deposition, then the treated cloth was combined with the synthesized liquid crystal epoxy resin. An interconnected intrinsic thick orientation layer around the carbon fiber was formed by the orientation of liquid crystal epoxy resin molecules along the direction of the carbon nanotube layers grown on the carbon fiber surface, and was observed by X-ray diffraction as well as polarized light microscopy. The interlayer strength as well as the through-thickness thermal conductivity are enhanced by the generation of high-strength oriented layers and continuous thermal conductivity paths, resulting in an increase of 56.4% in ILSS and 70.6% in through-thickness thermal conductivity, a “brittle to ductile” transition in the failure mode of the interlayer matrix is also observed in the region of overlapping oriented layers. The ultra-thickness of such oriented layers and their in-situ generation during the curing process allows them to overlap each other to form a continuous reinforcing/toughening structure as well as a continuous thermally conductive network to provide the enhancement capabilities described above.

传统的碳纤维/环氧树脂基复合材料因其高比强度而得到广泛应用。然而,典型的层压复合材料由于聚合物基体与碳纤维之间的界面结合较差,二维结构没有层间承载相,缺乏连续的层间导热路径,具有较差的抗分层性和透厚导热性。本研究首先采用化学气相沉积法对碳纤维布表面进行原位生长碳纳米管表面处理,然后将处理后的碳纤维布与合成的液晶环氧树脂结合。通过液晶环氧树脂分子沿碳纤维表面生长的碳纳米管层方向取向,在碳纤维周围形成相互连接的本征厚取向层,并通过x射线衍射和偏振光显微镜观察。高强度取向层的生成和连续的导热路径提高了层间强度和透厚导热系数,导致层间基体的ILSS和透厚导热系数分别提高了56.4%和70.6%,在取向层重叠区域,层间基体的破坏模式也发生了“脆性到延性”的转变。这种取向层的超厚度及其在固化过程中的原位生成使它们相互重叠,形成连续的增强/增韧结构以及连续的导热网络,以提供上述增强能力。


Genetic Algorithm Designed Multilayered Si3N4 Nanowire Membranes Hybridized by Dielectric Wide-range Tunable CVD Graphene Skin for Broadband Microwave Absorption

Jie Liang, Fang Ye, Qiang Song, Yuchen Cao, Caixiang Xiao, Yiming Qin, Yunzhou Lin, Bo Huang, Xiaoshuang Wang, Chen Li

doi:10.1016/j.compositesb.2025.112298

 

遗传算法设计宽频微波吸收介质宽范围可调谐CVD石墨烯蒙皮杂化多层Si3N4纳米线膜

Nowadays, the dispersion characteristics limit the broadband performance of single-layer homogeneous absorbing materials. A multilayer impedance matching structure (MIMS) is capable of optimizing the impedance matching characteristics of the broadband electromagnetic wave (EMW), thereby broadening the effective absorption band (EAB). Consequently, the availability of a database with differentiated characteristics is a crucial prerequisite for the realization of MIMS design. Herein, graphene (Gr)-skinned Si3N4 nanowires were prepared via a chemical vapor deposition (CVD) process. Moreover, the formation of a strong interfacial polarization between Si3N4 and Gr can optimize the samples within the database. Furthermore, a wide-range of defect content (0.80 to 2.35 of ID/IG) and dielectric loss (0.03 to 1.5 of tanδ) modulation was achieved through the manipulation of the CVD deposition process. A two-layer structure with a thickness of only 5 mm was rapidly designed based on a wide-range modulation and genetic algorithm. This structure exhibited an EAB of up to 12.48 GHz according to measurement of arc method, which is a significant widening of 5.6 GHz compared to the EAB of the single-layer structure. The proposed integrated design of wide-range modulation of dielectric properties and intelligent optimization algorithm of macrostructure is expected to further broaden the EAB of dielectric absorbing materials and become a new design paradigm.

如今,单层均质吸波材料的分散特性限制了其宽带性能。多层阻抗匹配结构(MIMS)能够优化宽带电磁波(EMW)的阻抗匹配特性,从而拓宽有效吸收频带(EAB)。因此,拥有具有差异化特性的数据库是实现 MIMS 设计的关键前提。在此,通过化学气相沉积(CVD)工艺制备了石墨烯(Gr)包覆的 Si3N4 纳米线。此外,Si3N4 与 Gr 之间形成的强界面极化能够优化数据库中的样本。而且,通过调控 CVD 沉积工艺,实现了缺陷含量(0.80 至 2.35 的 ID/IG)和介电损耗(0.03 至 1.5 的 tanδ)的宽范围调节。基于宽范围调节和遗传算法,快速设计出了厚度仅为 5 毫米的两层结构。根据弧形法测量,这种结构的电磁波吸收带宽(EAB)高达 12.48GHz,与单层结构相比,带宽显著拓宽了 5.6GHz。所提出的介电性能宽范围调制与宏观结构智能优化算法的集成设计有望进一步拓宽介电吸收材料的电磁波吸收带宽,并成为一种新的设计范式。


Property enhancement of alternating glass/carbon fibre laminated FRP composite by glow discharge post-plasma irradiation

Dibyajyoti D. Pradhan, A.P. Chakraverty, T. Badapanda, R. Nayak, U.K. Mohanty, M.R. Das

doi:10.1016/j.compositesb.2025.112299

 

辉光放电等离子体辐照增强玻璃/碳纤维复合材料的性能

Conventional FRP composite suffers various problems due to improper curing, interfacial residual stress and environmental degradation. Such problems can be compensated by adopting partial use of carbon fibre in glass fibre based FRP composite and exposing such composite to energetic radiation for post-curing strengthening. Keeping this in mind, FRP composite samples with alternative glass and carbon fibre layers were irradiated through glow discharge plasma up to 35 mins with air and argon maintained with 10-50 Watt power. About 113 % and 135 % increase in inter laminar and flexural strengths, respectively, were found with respect to argon plasma ageing for 30 mins at 50 Watt power. At this power, about 14.7 % and 35 % increase in Tg was observed for the modified FRP with 15 mins of air plasma and 30 mins of argon plasma exposure, respectively. Maximum thermal activation energy was obtained through argon plasma irradiation. FTIR test revealed additional peaks at 1721 cm-1 and 3060 cm-1 for maximum power of argon-plasma treated FRP sample. Air and argon plasma at their optimized power and duration resulted increase in wettability with improved surface roughness. The failure modes of SEM fractographs indicated improved thermo-mechanical properties in plasma cured modified FRP.

传统的玻璃钢复合材料由于养护不当、界面残余应力和环境退化等原因存在各种问题。这些问题可以通过在玻璃纤维基FRP复合材料中部分使用碳纤维,并将这种复合材料暴露于高能辐射中进行固化后强化来弥补。考虑到这一点,将具有替代玻璃和碳纤维层的FRP复合材料样品通过辉光放电等离子体照射至35分钟,并以10-50瓦的功率保持空气和氩气。在50瓦功率下氩等离子体时效30分钟,层间强度和抗弯强度分别提高了113%和135%。在此功率下,改性玻璃钢在空气等离子体暴露15分钟和氩气等离子体暴露30分钟后,Tg分别增加约14.7%和35%。氩等离子体辐照获得了最大的热活化能。FTIR测试显示氩气等离子体处理FRP样品的最大功率在1721 cm-1和3060 cm-1处有附加峰。在优化的功率和持续时间下,空气和氩等离子体的润湿性增加,表面粗糙度改善。SEM断口破坏模式表明,等离子体固化改性玻璃钢的热力学性能得到改善。


Inhibition of Neuron and Cardiac Remodeling by Microenvironment-Responsive Injectable Hydrogels with Sympatho-Immune Regulation Properties for Myocardial Infarction Therapy

Peijin Yang, Yugen Shi, Hesheng Hu, Yu Wang, Ye Wang, Xinran Li, Lu Zhang, Yiping Wang, Lei Yu, Huitang Xia, Yan Li, Jie Yin

doi:10.1016/j.compositesb.2025.112300

具有交感免疫调节特性的微环境反应性可注射水凝胶对心肌梗死治疗中神经元和心脏重构的抑制作用

Inflammation-dominated sympathetic innervation adjacent to the infarcted region plays a pivotal role in the pathogenesis of severe ventricular arrhythmias (VAs) following myocardial infarction (MI). Thus, targeting inflammation process and sympathetic innervation represents a promising therapeutic approach to prevent VAs in clinical settings. Herein, we developed intelligent injectable hydrogels using boronic ester dynamic crosslinking as a pH- and reactive oxygen species (ROS)-responsive mechanism. We synthesized fluorophenylboronic acid-modified gelatin (GelPB) and combined it with polyvinyl alcohol (PVA) to create GelPB/PVA hydrogels (GP-gel) loaded with c-type natriuretic peptide (CNP) and Sema3A. The efficacy of this smart hydrogel was evaluated in an MI model induced by left anterior descending coronary artery ligation. The drug-loaded hydrogel demonstrated the excellent anti-inflammatory, pro-angiogenic, and anti-nerve sprouting effects. Specifically, it reduced macrophages infiltration, promoted M2 macrophage polarization in the early post-MI phase, and enhanced the expression of CD31 and a-SMA. As a result, sympathetic hyperinnervation was suppressed, arrhythmia susceptibility was reduced, and electrical conduction velocity was improved. Additionally, a notable improvement in cardiac function was observed. In conclusion, hydrogel co-loaded with CNP and Sema3A offers a promising therapeutic strategy for addressing both malignant arrhythmia and heart failure post-MI.

梗死区附近炎症主导的交感神经支配在心肌梗死(MI)后严重室性心律失常(VAs)的发病机制中起关键作用。因此,针对炎症过程和交感神经支配是一种很有前途的治疗方法,可以在临床环境中预防VAs。在此,我们利用硼酯动态交联作为pH-和活性氧(ROS)响应机制开发了智能可注射水凝胶。我们合成了氟苯硼酸修饰明胶(GelPB),并将其与聚乙烯醇(PVA)结合,制备了负载c型利钠肽(CNP)和Sema3A的GelPB/PVA水凝胶(GP-gel)。在左冠状动脉前降支结扎引起的心肌梗死模型中评估了这种智能水凝胶的疗效。载药水凝胶具有良好的抗炎、促血管生成和抗神经发芽作用。减少巨噬细胞浸润,促进心肌梗死后早期M2巨噬细胞极化,增强CD31和a-SMA的表达。结果,交感神经支配被抑制,心律失常易感性降低,电传导速度提高。此外,心功能也有显著改善。综上所述,水凝胶共负载CNP和Sema3A为治疗心肌梗死后恶性心律失常和心力衰竭提供了一种有希望的治疗策略。


Tuning Co distribution in powder feedstock for laser powder bed fusion of crack-free WC-Co cemented carbides

Jingru Ai, Ming Xing, Haibin Wang, Zhi Zhao, Hao Lu, Xuemei Liu, Xiaoyan Song

doi:10.1016/j.compositesb.2025.112312

激光粉末床熔合无裂纹WC-Co硬质合金时Co在粉末原料中的分布调整

This work presents specific one-step additive manufacturing of crack-free WC-12Co cemented carbides by the laser powder bed fusion (LPBF) technology using the mixed ultra-coarse WC and agglomerated Co powder as feedstock. The critical role of the agglomerated Co in elimination of cracks, pores and carbon-deficient phases during the LPBF fabrication and subsequent heat-treatment process was disclosed. Moreover, the agglomerated Co led to the formation of lath-shaped WC grains containing numerous Co-rich particles with sizes ranging from a few nanometers to approximately 300 nm. These in-grain Co-rich particles could accommodate plastic deformation and hinder dislocation motion within lath-shaped WC grains, but did not cause local stress concentration, thereby contributing to enhance both the toughness and strength of the resulting cemented carbides. The proposed novel strategy of tuning the distribution state of metallic phase within the feedstock holds significant potential for applications in the direct additive manufacturing of high-performance cermet materials.

本文介绍了以超粗WC和结块Co粉末混合为原料,采用激光粉末床熔合(LPBF)技术一步增材制造WC- 12co无裂纹硬质合金的具体方法。揭示了凝聚Co在LPBF制备和后续热处理过程中消除裂纹、气孔和缺碳相的关键作用。此外,Co的团聚导致形成板条状WC颗粒,其中含有大量的富Co颗粒,大小从几纳米到大约300纳米不等。这些富含co的颗粒可以容纳塑性变形,阻碍条状WC晶粒内的位错运动,但不会引起局部应力集中,从而有助于提高硬质合金的韧性和强度。提出的调整原料中金属相分布状态的新策略在高性能陶瓷材料的直接增材制造中具有重要的应用潜力。


Developments and future prospects of welding technology for carbon fiber thermoplastic composites

Jiaming Liu, Dong Quan, Gennaro Scarselli, Rene Alderliesten, Hao Wang, Guoqun Zhao

doi:10.1016/j.compositesb.2025.112314

碳纤维热塑性复合材料焊接技术的发展与展望

Carbon fiber reinforced thermoplastic composites (TPCs) attracted significant attentions from the aerospace, transportation, and defense industries, due to their high specific stiffness and specific strength, outstanding thermal stability and good damage resistance, etc. As the demand of TPCs significantly increased for aerospace applications, the development of advanced joining technologies for TPC components becomes critical to ensure the structural integrity of aviation structures. This paper provides a comprehensive review of the historical development and recent advancements in welding technologies for TPCs, including ultrasonic welding, induction welding, resistance welding, and laser welding. Special emphasis is placed on ultrasonic welding due to its growing prominence in the field. The characteristics of various types of welding technologies for TPCs have been systematically discussed. Simultaneously, the strengths of the TPC joints manufactured by different welding technologies have been summarized and compared. The future development trend and research focuses for the welding technologies of TPC components are also proposed.

碳纤维增强热塑性复合材料(tpc)因其具有高比刚度和比强度、优异的热稳定性和良好的抗损伤性等优点而受到航空航天、交通运输和国防工业的广泛关注。随着航空航天领域对TPC的需求不断增加,开发先进的TPC连接技术对保证航空结构的完整性至关重要。本文综述了TPCs焊接技术的历史发展和最新进展,包括超声波焊接、感应焊接、电阻焊接和激光焊接。特别强调的是超声波焊接,因为它在该领域日益突出。系统地讨论了tpc各种焊接工艺的特点。同时,对不同焊接工艺制备的TPC接头的强度进行了总结和比较。提出了TPC构件焊接技术的未来发展趋势和研究重点。


Composites Science and Technology

Lightweight Metastructure with Broadband Strong Absorption through Multiscale Modulation

Kai Cui, Lei Zheng, Lili Wu, Tao Wang, Xian Wang, Rongzhou Gong

doi:10.1016/j.compscitech.2025.111110

 

基于多尺度调制的宽带强吸收轻量化元结构

Designing and fabricating an advanced metastructure absorber (MA) with lightweight, broadband, and high absorption efficiency is a promising solution to the growing electromagnetic (EM) pollution issue. Herein, the nano-graphite (NG)/polyamide 12 (PA12) composite filaments were fabricated using hot-melting processing, with the dispersion of NG particles in PA12 controlled by varying machining times. Analytical results revealed that improved dispersion of NG particles in the PA12 matrix significantly enhances the EM loss capability of the composite filaments, primarily due to increased conductive paths and interfacial contact area. Subsequently, a multilayer honeycomb structure with a bi-gradient material-structure was developed to improve the impedance matching of carbon-based composites. Simulations revealed that the proposed MA achieved a reflection loss (RL) below -10 dB in the 2 - 18 GHz with a relative bandwidth of up to 160%, and exhibited a strong RL below -20 dB in the 4.2 - 18 GHz range. Finally, the MA was fabricated using FDM 3D printing technology and demonstrated excellent agreement between the experimental RL and simulation results. Importantly, this research offers new insights into the modulation of EM property in carbon-based composite filaments and the design of MA with integrated broadband and high efficiency.

设计和制造一种轻量化、宽频带和高吸收效率的先进元结构吸波器是解决日益严重的电磁污染问题的一个有希望的解决方案。采用热熔法制备了纳米石墨(NG)/聚酰胺12 (PA12)复合长丝,通过不同的加工时间控制NG颗粒在PA12中的分散。分析结果表明,NG颗粒在PA12基体中分散的改善显著提高了复合丝的EM损耗能力,这主要是由于导电路径和界面接触面积的增加。随后,为了改善碳基复合材料的阻抗匹配,提出了一种双梯度材料结构的多层蜂窝结构。仿真结果表明,该方法在2 ~ 18 GHz频段的反射损耗(RL)低于-10 dB,相对带宽高达160%;在4.2 ~ 18 GHz频段的反射损耗(RL)低于-20 dB。最后,采用FDM 3D打印技术制作了MA,实验结果与仿真结果吻合良好。重要的是,该研究为碳基复合材料长丝的电磁特性调制以及集成宽带和高效率的MA设计提供了新的见解。




来源:复合材料力学仿真Composites FEM
ACTMechanicalAdditiveSystemMAGNET断裂复合材料化学电路航空航天冶金电力电子裂纹电场材料分子动力学
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【新文速递】2025年2月22日复合材料SCI期刊最新文章

今日更新:Composite Structures 3 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 4 篇,Composites Science and Technology 1 篇Composite StructuresData-Driven Mean-Field Homogenization: Enhancing the accuracy of the Mori-Tanaka methodWitold Ogiermandoi:10.1016/j.compstruct.2025.118985数据驱动的平均场均匀化:提高Mori-Tanaka方法的准确性The Mori-Tanaka method is well-known for its good predictive capabilities and excellent time efficiency. However, a significant weakness of the Mori-Tanaka method is its decreasing accuracy as the volume fraction of particles increases. Therefore, this paper focuses on developing a new approach to improve stiffness predictions for particle-reinforced composites across a wide range of particle volume fractions by using a mixed data-driven and mean-field homogenization modelling strategy. The basic idea is to modify the strain concentration tensor by fitting the results of Mori-Tanaka homogenization to data generated using numerical full-field homogenization based on the representative volume element (RVE). The modified tensor can then replace the original strain concentration tensor within the established framework of Mori-Tanaka homogenization to predict the effective stiffness. The results obtained using the proposed approach are in good agreement with those provided by full-field finite element-based homogenization. Moreover, the results obtained through Mori-Tanaka and double inclusion methods have been added for reference. The presented results demonstrate the potential of the proposed data-driven mean-field model as an efficient approach for addressing the micromechanics of particle-reinforced composites.Mori-Tanaka方法以其良好的预测能力和出色的时间效率而闻名。然而,Mori-Tanaka方法的一个显著缺点是其精度随着颗粒体积分数的增加而降低。因此,本文的重点是开发一种新的方法,通过使用混合数据驱动和平均场均匀化建模策略,提高颗粒增强复合材料在大范围颗粒体积分数下的刚度预测。其基本思想是将Mori-Tanaka均质化结果拟合到基于代表性体积元(RVE)的数值全场均质化生成的数据中,从而修正应变浓度张量。修正后的张量可以在Mori-Tanaka均质化框架内代替原有的应变浓度张量来预测有效刚度。采用该方法得到的结果与基于全场有限元的均匀化方法得到的结果吻合较好。并补充了Mori-Tanaka法和双包合法所得结果,供参考。研究结果表明,数据驱动的平均场模型是解决颗粒增强复合材料微观力学问题的有效方法。Blast resistance of sandwich structure consisting of re-entrant honeycomb reinforced by catenaryZhen Zou, Fengxiang Xu, Xiaoqiang Niu, Yifan Zhu, Zhoushun Jiangdoi:10.1016/j.compstruct.2025.118995接触网增强可入式蜂窝夹层结构的抗爆破性能In order to further improve the blast resistance of re-entrant honeycomb (RH) cored sandwich panels while ensuring manufacturability, a sandwich panel consisting of RH reinforced by catenary is proposed, and its blast resistance is evaluated through the finite element method validated by the explosion experiments of reinforced RH (RRH) cored sandwich panels. The numerical results show that the RRH core can achieve an 18.7% decline in the maximum deflection of back facesheets, and a 25.7% increase in energy absorption, compared to the classic RH core with the same relative density. When RRH and RH cores share the same thickness, the former can achieve a 76.1% decrease in the maximum deflection of back facesheets and a 10.4% improvement in energy absorption. Furthermore, the deformation behavior of sandwich panels and core units is analyzed to determine that both the formation of more plastic hinges and a larger deformation region than those observed in classic RH cores promote the better blast resistance of RRH cored sandwich panels. Additionally, a parametric analysis is carried out to suggest that increasing the core thickness and catenary height of RRH units can further improve the anti-blast performance.为了在保证可制造性的前提下进一步提高蜂窝芯夹芯板的抗爆性能,提出了一种接触网加固的蜂窝芯夹芯板,并通过加固的蜂窝芯夹芯板爆炸实验验证了该夹芯板的抗爆性能。数值计算结果表明,在相同的相对密度下,与传统的RH磁芯相比,RRH磁芯的最大后面板挠度降低了18.7%,能量吸收提高了25.7%。当RRH型芯与RH型芯厚度相同时,RRH型芯的最大背板挠度降低76.1%,吸能提高10.4%。此外,对夹层板和芯板的变形行为进行了分析,确定了与经典RH芯相比,RRH芯板形成更多的塑性铰链和更大的变形区域都促进了RRH芯板的抗爆破性能。此外,参数分析表明,增加RRH单元的核心厚度和悬链线高度可以进一步提高抗爆性能。Mechanical behaviors of glulam beam-to-column joints strengthened with fiber-reinforced polymer composites: Experimental investigation, numerical analysis and ANN prediction modelYasemin SIMSEK TURKER, Semsettin KILINCARSLAN, Mehmet AVCARdoi:10.1016/j.compstruct.2025.118983纤维增强聚合物复合材料加固胶合木梁柱节点的力学行为:试验研究、数值分析和人工神经网络预测模型Because of its respective advantages, such as high load-bearing capacity relative to their bulk, low embodied carbon and renewable properties, and sustainability, wood is becoming more popular in engineering structures. Due to several effects, some deterioration occurs in wood structures over time, and the load-bearing elements lose their properties, especially the beam-to-column joints. This study investigates the mechanical behaviors of basalt fiber-reinforced polymer (BFRP) and carbon fiber-reinforced polymer (CFRP) glulam beam-to-column joints. Beam-to-column connections are realized using three methods and are wrapped 2, 3, and 4-times. Cycle loading load–displacement experiments are performed on beam-to-column joints. Vital mechanical behaviors, including maximum load-carrying capacity, energy consumption capacity, and stiffness value, are investigated. The data obtained from the experimental study are estimated by creating a model with artificial neural networks (ANNs) and finite element (FE) analysis. The obtained findings show that the effect of reinforcement improves the rigidities, energy consumption capabilities, and load-carrying capacities of beam-to-column joints. In addition, it is observed that the load-carrying capacity of beam-to-column joints increases with the increase in the number of plies. Furthermore, it is determined that the mechanical behaviors of the beam-to-columns strengthened with CFRPs are better than those for BFRPs.由于其各自的优势,例如相对于其体积的高承载能力,低隐含碳和可再生特性以及可持续性,木材在工程结构中越来越受欢迎。由于几种影响,随着时间的推移,木结构会发生一些劣化,承重元件失去其性能,特别是梁柱节点。本文研究了玄武岩纤维增强聚合物(BFRP)和碳纤维增强聚合物(CFRP)胶合木梁柱节点的力学行为。梁柱连接使用三种方法实现,并包裹2、3和4次。对梁柱节点进行了循环荷载-位移试验。关键的力学行为,包括最大承载能力,能量消耗能力和刚度值,进行了研究。通过人工神经网络(ann)和有限元(FE)分析建立模型,对实验研究得到的数据进行了估计。结果表明,配筋的作用提高了梁柱节点的刚度、耗能能力和承载能力。此外,梁柱节点的承载能力随着层数的增加而增加。此外,还确定了cfrp加固梁柱的力学性能优于bfrp加固梁柱的力学性能。Composites Part A: Applied Science and ManufacturingHigh-density polyethylene reinforced with carbon dots for improved processing cycles and recyclability traceabilityRaul Simões, Joana Rodrigues, Žan Podvratnik, Ana Violeta Girão, Nélia Alberto, Nazanin Emami, Victor Neto, Teresa Monteiro, Gil Gonçalvesdoi:10.1016/j.compositesa.2025.108814 高密度聚乙烯增强与碳点改善加工周期和可回收性的可追溯性The sustainable utilization of polymers depends on efficient recycling and the ability to retain their critical physical properties for further processing. In this study, high-density polyethylene (HDPE) nanocomposite properties were enhanced by the integration of carbon dots (CDs), in terms of processability and optical traceability during recycling. HDPE composites with varying CD loadings were prepared to assess their effects on optical and mechanical properties over three consecutive recycling cycles. The composite containing 0.5 wt% CDs demonstrated a 17 % increase in tensile strength after recycling, with a maximum strain of 11%, significantly outperforming the neat HDPE while preserving its crystalline structure. Additionally, incorporating 0.1 wt% CDs reduced the wear rate by up to 98 %, highlighting a substantial improvement in durability. Improved processability of the recycled material was confirmed by producing 3D-printed specimens at each CD concentration. Notably, composites containing 0.1 wt% CDs exhibited excellent printability even after three recycling cycles. CDs have also been utilized as luminescence tracers. This study revealed that the quenching of the blue phosphorescence associated to the carbonyl groups of the polymer backbone was highly dependent on the CD content. Importantly, nanocomposites with 0.1 wt% CDs exhibited progressive luminescence changes corresponding to the number of recycling cycles, enabling quick and reliable traceability and sorting using standard mobile phone cameras. These findings are highly promising, paving the way for rapid, automated, and scalable HDPE recycling. This innovation offers significant potential for advancing the circular economy of HDPE and enhancing the sustainability of polymer materials.聚合物的可持续利用取决于有效的回收和为进一步加工保留其关键物理特性的能力。在这项研究中,高密度聚乙烯(HDPE)纳米复合材料的性能通过碳点(cd)的集成而得到增强,在可加工性和回收过程中的光学可追溯性方面。制备了不同CD载荷的HDPE复合材料,以评估其在连续三个循环中对光学和机械性能的影响。含有0.5 wt% CDs的复合材料在回收后的抗拉强度增加了17%,最大应变为11%,在保持其晶体结构的同时显著优于纯HDPE。此外,加入0.1 wt% cd后,磨损率降低了98%,显著提高了耐久性。通过在每种CD浓度下生产3d打印样品,证实了再生材料的可加工性得到改善。值得注意的是,含有0.1 wt% cd的复合材料即使在三次回收循环后也表现出优异的印刷性。cd也被用作发光示踪剂。该研究表明,与聚合物主链羰基相关的蓝色磷光的猝灭高度依赖于CD含量。重要的是,含有0.1 wt% CDs的纳米复合材料显示出与回收循环次数相对应的渐进发光变化,可以使用标准手机相机快速可靠地跟踪和分类。这些发现非常有希望,为快速、自动化和可扩展的HDPE回收铺平了道路。这一创新为推进HDPE的循环经济和增强聚合物材料的可持续性提供了巨大的潜力。Advanced characterization of thermal degradation mechanisms in carbon fibre-reinforced polymer composites under continuous wave laser irradiationMax Mammone, Jojibabu Panta, Richard P. Mildren, John Wang, Juan Escobedo-Diaz, Lance Mcgarva, Mathew Ibrahim, Adam Sharp, Richard Yang, Y.X. Zhangdoi:10.1016/j.compositesa.2025.108817连续波激光辐照下碳纤维增强聚合物复合材料热降解机理的深入表征This study provides a detailed and comprehensive analysis of the effects of laser power and beam diameter on the thermal damage characteristics of carbon fibre-reinforced polymer (CFRP) composites, aiming to uncover the underlying damage mechanisms using advanced characterization techniques. Continuous wave laser irradiation was performed with beam diameters of 3.18 mm and 5.70 mm at varying power levels up to 365 W to evaluate the influence of laser parameters on CFRP damage. High-resolution thermal imaging captured temperature distributions on the CFRP surfaces, revealing complex interactions between laser parameters and resulting thermal damage. Quantitative ultrasonic C-scan imaging offered detailed insights into the extent and distribution of damage, elucidating the interplay between laser parameters and CFRP integrity. Results show that for the 3.18 mm beam diameter, perforation times significantly decreased from 46 s at 215 W to 7 s at 365 W. Simultaneously, the damaged area reduced from 1204 mm2 (48.2 %) at 215 W to 372 mm2 (14.9 %) at 365 W, indicating efficient material ablation. Conversely, for the 5.7 mm beam diameter, perforation times were considerably longer, ranging from 393 s at 215 W to 269 s at 365 W, while the damage area increased from 1299 mm2 (52.0 %) to 1712 mm2 (68.5 %), reflecting a broader heat-affected zone (HAZ) and more extensive thermal damage. Mass loss trends also varied, decreasing with higher power for the smaller beam diameter but increasing for the larger beam, highlighting contrasting ablation efficiencies and thermal effects. Micro-CT imaging revealed internal structural changes in the CFRP, confirming SEM observations that detailed surface morphology alterations under varying laser conditions. Infrared micro-spectroscopy beamline (IRM) analysis further uncovered chemical modifications and compositional changes induced by laser exposure, providing insights into degradation mechanisms and residual stresses within the composite matrix. These findings significantly enhance the understanding of thermal damage mechanisms in CFRP, offering valuable implications for aerospace and high-performance composite applications.本研究详细而全面地分析了激光功率和光束直径对碳纤维增强聚合物(CFRP)复合材料热损伤特性的影响,旨在利用先进的表征技术揭示潜在的损伤机制。采用连续波激光照射,光束直径分别为3.18 mm和5.70 mm,照射功率为365 W,以评估激光参数对CFRP损伤的影响。高分辨率热成像捕获了CFRP表面的温度分布,揭示了激光参数与热损伤之间复杂的相互作用。定量超声c扫描成像提供了详细的了解损伤的程度和分布,阐明了激光参数与CFRP完整性之间的相互作用。结果表明:对于直径为3.18 mm的光束,穿孔时间由215 W时的46 s显著缩短至365 W时的7 s;同时,损伤面积从215 W时的1204 mm2(48.2%)减少到365 W时的372 mm2(14.9%),表明材料有效消融。相反,对于5.7 mm的光束直径,射孔时间明显延长,从215 W时的393 s增加到365 W时的269 s,而损伤面积从1299 mm2(52.0%)增加到1712 mm2(68.5%),反映出更宽的热影响区(HAZ)和更广泛的热损伤。质量损失趋势也有所不同,当光束直径较小时,质量损失随功率增大而减小,而当光束直径较大时,质量损失随功率增大而增大,这突出了不同的烧蚀效率和热效应。微ct成像显示了CFRP的内部结构变化,证实了扫描电镜观察到的在不同激光条件下详细的表面形态变化。红外微光谱光束线(IRM)分析进一步揭示了激光照射引起的化学修饰和成分变化,为复合材料基体的降解机制和残余应力提供了见解。这些发现显著增强了对CFRP热损伤机制的理解,为航空航天和高性能复合材料的应用提供了有价值的启示。Composites Part B: EngineeringEnhancing mechanical properties, durability and multifunctionality of concrete structures via using ultra-high performance concrete layer: A reviewSufen Dong, Jinfang Gu, Xinyu Ouyang, Sung-Hwan Jang, Baoguo Handoi:10.1016/j.compositesb.2025.112329利用超高性能混凝土层提高混凝土结构的力学性能、耐久性和多功能:综述As a kind of advanced cement-based composites with superior mechanical properties and remarkable durability, ultra-high performance concrete (UHPC) shows great potential in repairing and strengthening concrete structures in the form of layers. Hence, this paper firstly conducts a systematic review on the static/dynamic mechanical properties, interfacial bond performance between UHPC layer and concrete, durability, and multifunctional/eco-friendly properties (e.g. self-sensing, self-heating, self-healing, self-cleaning, and self-liminescence capability) of UHPC layer repaired/strengthened concrete structures. Carbon polymer reinforced plastic bars reinforced UHPC layer significantly enhances the flexural ultimate load and ductility of reinforced concrete (RC) structures, and two-sided layers are economical and reasonable. Roughing interface and epoxy adhesive treatment are conducive to increasing flexural ultimate load and shear resistance of UHPC layer-strengthened RC beams. The failure mode of RC beams under impact load tends to change from shear to flexure by UHPC layer, and the gap less than 10 mm between UHPC layer and RC beam limits crack development in RC beams under single impact load. Strengthening the column-foot zone by using a UHPC jacket with the size higher than the plastic hinge zone improves their seismic performance of RC columns. The increase of NSC substrate strength, surface moisture, the using of water-based epoxy resin agent, and the proper curing can improve the interfacial bond strength between UHPC layer and RC beam. Meanwhile, it is worthwhile to note that UHPC layer is not beneficial for increasing high-temperature spalling resistance of RC structures, but can be used to develop smart and multifunctional infrastructures.超高性能混凝土(UHPC)作为一种先进的水泥基复合材料,具有优异的力学性能和显著的耐久性,在以层状形式修复和加固混凝土结构方面显示出巨大的潜力。因此,本文首先系统综述了UHPC层修复/加固混凝土结构的静/动态力学性能、UHPC层与混凝土的界面粘结性能、耐久性以及自传感、自加热、自修复、自清洁、自发光等多功能/环保性能。碳高聚物钢筋加筋层显著提高了钢筋混凝土结构的极限弯曲荷载和延性,双面加筋层经济合理。粗加工界面和环氧胶粘接处理有利于提高UHPC层加筋RC梁的极限受弯荷载和抗剪能力。在冲击荷载作用下,UHPC层使RC梁的破坏模式由剪切向弯曲转变,且UHPC层与RC梁之间小于10 mm的间隙限制了单次冲击荷载作用下RC梁裂纹的发展。采用比塑性铰区尺寸大的超高性能混凝土护套对柱脚区进行加固,提高了混凝土柱的抗震性能。提高NSC基材强度、增加表面水分、使用水性环氧树脂剂以及适当的养护可以提高UHPC层与RC梁之间的界面结合强度。同时,值得注意的是,UHPC层并不利于提高钢筋混凝土结构的耐高温剥落性,但可用于发展智能多功能基础设施。Ablation-resistant (Hf,Zr)B2-SiC composite coating with alternating lamellar architecture by one-step atmospheric plasma sprayingJunshuai Lv, Wei Li, Zhenglong Li, Yanqin Fu, Yawen Ma, Lingxiang Guo, Jiachen Li, Tao Li, Yulei Zhangdoi:10.1016/j.compositesb.2025.112302一步大气等离子喷涂抗烧蚀(Hf,Zr)B2-SiC交替层状复合涂层Inspired by the brick-and-mortar arrangement of mollusk shells, constructing an alternating lamellar architecture is an effective strategy to overcome the catastrophic damage of ablation-resistant coatings and their oxide scales in extreme environments. Here, we developed a coating dominantly composed of alternating layers of (Hf,Zr)B2 and SiC by one-step supersonic atmosphere plasma spraying for C/C composites, which improves fabrication efficiency. The coating shows “zero” ablation and cycling reliability at 2200 °C. The resulting oxide scale based on a multilayered (Hf,Zr)O2 skeleton with embedded glassy SiO2 layers is responsible for the superior ablation resistance. The refractory skeleton ensures thermal stability and the SiO2 layers inhibit the oxygen inward diffusion. Two energy dissipation mechanisms, including crack deflection and multilayered delamination, contribute to the structural integrity of the oxide scale due to numerous interfaces in the lamellar architecture. The alternating lamellar coatings enable simultaneously superior oxidation resistance and damage tolerance and have great application potential for reusable aerospace components requiring thermal protection.受软体动物壳的砖块和砂浆排列的启发,构建交替的层状结构是克服极端环境下抗烧蚀涂层及其氧化鳞片灾难性破坏的有效策略。本文采用一步超声速气氛等离子喷涂技术制备了以(Hf,Zr)B2和SiC相间层为主的C/C复合材料涂层,提高了制备效率。该涂层在2200℃下表现出“零”烧蚀和循环可靠性。由此产生的基于多层(Hf,Zr)O2骨架和嵌入玻璃状SiO2层的氧化膜具有优异的抗烧蚀性。耐火材料骨架确保热稳定性,SiO2层抑制氧向内扩散。由于层状结构中存在大量的界面,两种能量耗散机制(包括裂纹挠曲和多层分层)有助于氧化层的结构完整性。交替层状涂层同时具有优异的抗氧化性和损伤容错性,在需要热保护的可重复使用的航空航天部件上具有很大的应用潜力。A novel analytical model to characterise the monotonic and cyclic contribution of fibre bridging during Mode I fatigue delamination in (C)FRPsFrancisco Monticeli, Davide Biagini, Yasmine Mosleh, John-Alan Pascoedoi:10.1016/j.compositesb.2025.112319一种新的分析模型来表征(C) frp中I型疲劳分层过程中纤维桥接的单调和循环贡献Fibre bridging is an important phenomenon influencing the mode I delamination growth behaviour in composite materials. Accurate modelling of this phenomenon is required in order to be able to account for its effects in damage tolerance evaluation of composite structures. Therefore, this study introduces a novel physical model to isolate and quantify the contribution of fibre bridging to Mode I fatigue delamination. The model distinguishes between monotonic and cyclic components of fibre bridging stress, capturing their individual effects on the strain energy release rate (SERR) in the Paris curve. The monotonic component, based on the Sørensen model, accounts for pre-cracking effects, while the cyclic component is derived by integrating a bridging stress function over the end-opening displacement, with both components modelled by empirical exponential relationships. The model has been validated against established methods such as the Yao model and specific extrapolation techniques, demonstrating improved accuracy in fitting the Paris curve, particularly in accounting for the monotonic influence in the shift of the SERR and the cyclic contribution to the curve slope. Importantly, the model requires only one quasi-static and one fatigue test, reducing the experimental workload. In conclusion, this method provides a more accurate characterisation of fibre bridging effects, making it a robust tool for fatigue delamination analysis.纤维桥接是影响复合材料I型脱层生长行为的重要现象。为了能够解释这种现象在复合材料结构损伤容限评价中的影响,需要对这种现象进行精确的建模。因此,本研究引入了一种新的物理模型来隔离和量化纤维桥接对I型疲劳分层的贡献。该模型区分了纤维桥接应力的单调和循环分量,捕捉了它们对巴黎曲线中应变能释放率(SERR)的个别影响。基于Sørensen模型的单调分量考虑了预裂效应,而循环分量则是通过对端开口位移的桥接应力函数进行积分得出的,两个分量都采用经验指数关系建模。该模型已通过Yao模型和特定外推技术等现有方法进行了验证,证明了巴黎曲线拟合的准确性有所提高,特别是在考虑SERR移动的单调影响和曲线斜率的循环贡献方面。重要的是,该模型只需要一次准静态和一次疲劳试验,减少了实验工作量。总之,该方法提供了更准确的纤维桥接效应表征,使其成为疲劳分层分析的可靠工具。Near-Infrared Induced Photo-Thermal Synergistic Curing: Enhancing the Construction Efficiency and Curing Uniformity of Glass Fiber Reinforced CompositesJunyi Pi, Zilong Zhu, Xinxin Sang, Hongchen Ji, Ren Liudoi:10.1016/j.compositesb.2025.112320 近红外诱导光热协同固化:提高玻璃纤维增强复合材料的施工效率和固化均匀性The efficient, mild, and convenient photopolymerization technology offers a promising green fabrication method for composites and has already been successfully applied in structural repair and outdoor manufacture. In previous studies, a method was developed for producing thick glass fiber-reinforced composites (GFRPC) of up to 20 mm based on upconversion assisted near-infrared photopolymerization (UCAP). Photo-thermal dual curing can further improve both curing uniformity and efficiency. The present work fully utilized the synergistic photothermal effects of UCAP. Near-infrared induced the cleavage of Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO) to generate benzoyl radicals, while benzopinacol (BPNC) thermally decomposed into benzophenone radicals, jointly promoting acrylate matrix crosslinking. When the thickness of GFRPC reached 15 mm, the curing time was reduced to 60 s, achieving double bond conversion of 81 % and 71 % on the top and bottom surfaces, respectively. Compared to the BAPO/UCAP photoinitiated system, the BPNC/BAPO/UCAP photo-thermal synergistic system significantly enhanced both the curing efficiency and uniformity of GFRPC. The resulting GFRPC exhibited an interfacial shear strength (IFSS) of 37.15 MPa, a flexural strength of 506.85 MPa, and an increased impact toughness of 242.70 kJ/m2. The photo-thermal synergistic curing method effectively facilitated the construction of reliable GFRPC with enhanced properties, thereby bolstering the potential for rapid manufacturing of high-performance GFRPC in outdoor applications using photopolymerization techniques.高效、温和、方便的光聚合技术为复合材料的绿色制造提供了一种很有前途的方法,并已成功地应用于结构修复和户外制造。在之前的研究中,开发了一种基于上转换辅助近红外光聚合(UCAP)的方法来生产厚达20毫米的玻璃纤维增强复合材料(GFRPC)。光热双固化可以进一步提高固化的均匀性和效率。本工作充分利用了UCAP的协同光热效应。近红外诱导苯二(2,4,6-三甲基苯甲酰)氧化膦(BAPO)裂解生成苯甲酰自由基,而苯并萘酚(BPNC)热分解生成苯甲酮自由基,共同促进丙烯酸酯基质交联。当GFRPC的厚度达到15 mm时,固化时间缩短至60 s,其上、下表面的双键转化率分别达到81%和71%。与BAPO/UCAP光引发体系相比,BPNC/BAPO/UCAP光热协同体系显著提高了GFRPC的固化效率和均匀性。所得GFRPC的界面抗剪强度(IFSS)为37.15 MPa,抗折强度为506.85 MPa,冲击韧性增加242.70 kJ/m2。光热协同固化方法有效地促进了性能增强的可靠GFRPC的构建,从而增强了利用光聚合技术快速制造户外应用的高性能GFRPC的潜力。Composites Science and TechnologyDynamic polydisulfide-assisted in-situ reduction and encapsulation of nanosilver for fabricating robust photothermal antimicrobial composite textilesLeilei Wu, Yun Yuan, Xinyi Huang, Xiaoyan Liu, Bo Xu, Li Cui, Qiang Wang, Ping Wangdoi:10.1016/j.compscitech.2025.111122 动态聚二硫化物辅助原位还原和包封纳米银制备坚固的光热抗菌复合纺织品The development of textiles with efficient and long-lasting antimicrobial properties is critical for mitigating medical cross-infections and addressing the growing demands of public health. Herein, an effective approach was demonstrated to fabricate biocompatible composite textiles with robust antimicrobial properties, through dynamic polydisulfide assisted in-situ reduction and encapsulation of nanosilver. Specifically, a reductive platform was established on cotton surfaces by sequentially grafting γ-aminopropyl triethoxysilane and α-lipoic acid (ALA). Subsequently, the amino groups and the dynamically-generated sulfhydryl groups within ALA units were utilized to initiate the reduction of silver ions without the need for additional reductants, thereby forming a stable antibacterial matrix layer on the fiber surface. The resulting fabric exhibits durable antimicrobial properties, achieving a 99.99% antibacterial and antifungal efficacy even after 50 cycles of standard laundering. Notably, the deposition of silver nanoparticles endows the cotton fabric with significant photothermal conversion ability, and facilitates the generation of multiple bactericidal free radicals. These properties enable the effective eradication of bacteria and fungi on the textile surface within 10 min of irradiation with an intensity of 100 mW/cm2. Furthermore, the photothermal antimicrobial fabric retains satisfactory inherent wearability and biocompatibility. The present work provides an alternative for developing robust and durable antimicrobial textiles.开发具有高效和持久抗菌性能的纺织品对于减轻医疗交叉感染和满足日益增长的公共卫生需求至关重要。本文展示了一种有效的方法,通过动态聚二硫化物辅助原位还原和纳米银的封装来制备具有强大抗菌性能的生物相容性复合纺织品。通过γ-氨基丙基三乙氧基硅烷与α-硫辛酸(ALA)序接枝,在棉花表面建立了还原平台。随后,利用ALA单元内的氨基和动态生成的巯基来启动银离子的还原,而无需额外的还原剂,从而在纤维表面形成稳定的抗菌基质层。由此产生的织物具有持久的抗菌性能,即使经过50次标准洗涤,也能达到99.99%的抗菌和抗真菌功效。值得注意的是,纳米银粒子的沉积使棉织物具有显著的光热转化能力,并有利于多种杀菌自由基的产生。这些特性使织物表面的细菌和真菌在100毫瓦/平方厘米照射10分钟内有效根除。此外,光热抗菌织物保留令人满意的固有耐磨性和生物相容性。目前的工作为开发坚固耐用的抗菌纺织品提供了另一种选择。 来源:复合材料力学仿真Composites FEM

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