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【新文速递】2024年12月16日复合材料SCI期刊最新文章

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今日更新:Composite Structures 8 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 1 篇,Composites Science and Technology 2 篇

Composite Structures

Compressibility and meso-mechanical behavior of polymer bonded explosives with different crystal qualities during pressing process

Yuchen Guo, Pengwan Chen,  RuiLiu,  ZhijianYang, Feng Zhang, Liyang Feng, Kezhen Lv, Bo Zhou, Gaoyang Hu

doi:10.1016/j.compstruct.2024.118784

不同结晶质量聚合物粘结炸药在压制过程中的压缩性和细观力学行为

As the predominant component in polymer bonded explosives (PBX), explosive crystals is an important factor affecting the compressibility of PBX powder. To obtain the effects of crystal quality on the mechanical properties and meso-mechanical behavior of PBX powder during die pressing, the compaction density, Brazilian strength, as well as crack propagation and energy dissipation mechanisms were systematically studied based on experiments and Discrete Element Method (DEM) simulations. The experimental results revealed that, under identical pressure, PBX parts composed of 1,3,5,7-tetranitro-1,3,5,7-tetraazecycloctane (HMX) crystals with more internal defects and lower strength will exhibit higher density and Brazilian strength. The simulation results demonstrated that crystal fragmentation occurs throughout the pressing process. The increased Brazilian strength of PBX containing low quality crystals may be attributed to more defects and larger specific surface area of the crystals. Crystal fragmentation can effectively promote particle rearrangement, resulting in higher strain of the PBX powder. During the compression process, the lower the crystal quality, the greater their susceptibility to fracture and the reduced conversion of external work into elastic potential energy. Consequently, the increase in PBX size caused by the release of elastic potential energy after unloading is therefore minimized, resulting in improved compressibility of the PBX.

炸药晶体作为聚合物粘结炸药的主要成分,是影响聚合物粘结炸药粉末可压缩性的重要因素。为了获得晶体质量对PBX粉末在模压过程中力学性能和细观力学行为的影响,基于实验和离散元法(DEM)模拟,系统研究了压实密度、巴西强度、裂纹扩展和能量耗散机制。实验结果表明,在相同压力下,由内部缺陷较多、强度较低的1,3,5,7-四氮杂环辛烷(HMX)晶体组成的PBX部件具有较高的密度和巴西强度。模拟结果表明,在挤压过程中,晶体破碎现象不断发生。含有低质量晶体的PBX的巴西强度增加可能是由于晶体的缺陷较多,比表面积较大。晶体破碎可以有效地促进颗粒重排,从而提高PBX粉末的应变。在压缩过程中,晶体质量越低,其断裂易感性越大,外部功转化为弹性势能的量也越少。因此,卸荷后因释放弹性势能而导致的PBX尺寸增加被最小化,从而提高了PBX的可压缩性。


Experimental study on GFRP spiral-confined concrete under eccentric compression

X.B. Hu, X.F. Nie, J.J. Wang, T. Yu, S.S. Zhang

doi:10.1016/j.compstruct.2024.118793

GFRP螺旋约束混凝土偏心受压试验研究

Fiber-reinforced polymer (FRP) composites are increasingly being employed as internal reinforcement in concrete structures due to their superior mechanical properties and excellent durability. The use of FRP spirals as internal shear reinforcement in compressive concrete members can also provide significant confinement to concrete and thus improve the compressive performance of the concrete members. Compared with studies on the behavior of FRP spiral-confined concrete (FSCC) under concentric compression, the existing studies on FSCC under eccentric compression have been very limited. In the present study, therefore, an experimental program containing 30 specimens was designed and conducted to investigate the compressive behavior of glass FRP (GFRP) spiral-confined concrete (GSCC) under eccentric compression, with the main examined parameters including the FRP spiral pitch and the load eccentricity-to-diameter ratio. The test results revealed that load eccentricity could largely influence the behavior of GSCC in terms of compressive strength, stiffness, ultimate axial deformation and ultimate section curvature. On the other hand, the decrease in the FRP spiral pitch can to some extent compensate for the influence of load eccentricity. The present study sets a solid experimental basis for the future numerical and theoretical studies on the behavior of GSCC under eccentric compression.

纤维增强聚合物(FRP)复合材料由于其优异的力学性能和耐久性,越来越多地被用于混凝土结构的内部加固。在受压混凝土构件中使用FRP螺旋作为内剪钢筋也可以对混凝土提供显著的约束,从而提高混凝土构件的抗压性能。与对FRP螺旋约束混凝土(FSCC)在同心压缩下的性能研究相比,现有的FSCC在偏心压缩下的研究非常有限。为此,设计了包含30个试件的试验方案,研究了玻璃玻璃钢(GFRP)螺旋约束混凝土(GSCC)在偏心受压下的抗压性能,主要考察参数包括玻璃钢螺旋节距和荷载偏心径比。试验结果表明,载荷偏心对GSCC的抗压强度、刚度、极限轴向变形和极限截面曲率的影响较大。另一方面,FRP螺旋节距的减小可以在一定程度上补偿载荷偏心的影响。本文的研究为今后GSCC偏心受压特性的数值和理论研究奠定了坚实的实验基础。


Broadband sound absorption of micro-perforated sandwich panels with hierarchical honeycomb core at high sound pressure levels

Xindong Zhou, Weitao Zhang, Xiangfei Geng, Fengxian Xin

doi:10.1016/j.compstruct.2024.118794

高声压级蜂窝芯微孔夹层板宽带吸声特性研究

This paper investigates the effects of high sound pressure level (SPL) on the sound absorption of micro-perforated sandwich panels with hierarchical honeycomb core. Based on the nonlinear sound absorption theory of micro-perforated plates, a theoretical model is established to study the absorption performance of the structure at high SPLs, which is verified by numerical simulations. The results show that under high SPL conditions, the acoustic resistance of the structure is greatly increased and the acoustic reactance of the structure is slightly decreased, resulting in the decrease of the absorption peak values and the increase of the peak frequencies of the structure. The high SPLs can greatly enhance the motion of the air particles in and around the micro-perforation, leading to vortex generation and shedding from the end of the perforation hole. In order to improve the absorption performance of the structure at high SPLs, an optimization algorithm is introduced in the design of the absorber. It is shown that the structure designed with large perforation holes and deep air cavities can achieve good broadband absorption performance at both low and high SPLs. Experimental tests are also carried out to validate the broadband absorption potential of the structure. This work provides guidance for the design and optimization of sound absorbing structures under high sound pressure level conditions.

研究了高声压级对分层蜂窝芯微孔夹层板吸声性能的影响。基于微孔板的非线性吸声理论,建立了研究微孔板在高声压下吸声性能的理论模型,并通过数值模拟进行了验证。结果表明:在高声压级条件下,结构的声阻大大增加,结构的声抗略有降低,导致结构的吸收峰值降低,峰值频率增加;高SPLs可以极大地增强微射孔内和周围空气颗粒的运动,导致涡旋的产生和射孔末端的脱落。为了提高结构在高声压下的吸收性能,在吸波器的设计中引入了优化算法。结果表明,采用大孔洞和深空腔设计的结构在低和高SPLs下都能获得良好的宽带吸收性能。实验验证了该结构的宽带吸收电位。该工作对高声压级条件下吸声结构的设计和优化具有指导意义。


Fracture from mode I dominated to mixed mode I-II in CFRP repaired steel pipes

Huayang Li, Jiayu Wu, Feng-Chen An, Guan Lin, Jian-Fei Chen

doi:10.1016/j.compstruct.2024.118798

CFRP修复钢管断裂以I型为主,以I- ii型为主

External wrapping of carbon fiber-reinforced polymer (CFRP) for the repair of steel pipes with slot-type defects has gained increasing acceptance. Interface debonding between the CFRP and the steel pipe is a common failure mode in this repair system, yet the fracture mechanism remains poorly understood. This paper presents an experimental and theoretical study aiming to elucidate the failure mechanism. A new bonded joint was designed for the experiment, and the debonding process was monitored by the strain distribution of the CFRP using distributed optical fiber sensors (DOFS). Stick-slip fracture behavior was observed in joints bonded with high-strength structural adhesives. Based on the experimental results, theoretical models are developed to describe the debonding process in three stages: elastic stage, rapid crack propagation (RCP) stage, and steady-state crack propagation (SSCP) stage. Using a linear elastic-brittle traction-separation relation, the interface debonding during the elastic and RCP stages is characterized by mode I dominated fracture, analyzed using a cohesive zone model. Mixed mode I-II fracture during the SSCP stage is analyzed using Griffith theory of fracture, with partitioning of the total energy release rate into its mode I and mode II components. The theoretical model aligns well with the experimental results, validating the model’s accuracy.

采用碳纤维增强聚合物(CFRP)外包修复槽型缺陷的钢管已得到越来越多的认可。CFRP与钢管之间的界面剥离是该修复体系中常见的破坏模式,但其断裂机制尚不清楚。本文进行了实验和理论研究,旨在阐明其破坏机理。实验设计了一种新型粘结接头,采用分布式光纤传感器(DOFS)对CFRP的应变分布进行监测。观察了高强度结构胶粘剂粘结接头的粘滑断裂行为。基于实验结果,建立了弹性阶段、快速裂纹扩展阶段和稳态裂纹扩展阶段的理论模型。采用线性弹-脆牵引-分离关系,分析了弹性阶段和RCP阶段界面剥离的ⅰ型主导断裂特征,并采用粘聚区模型进行了分析。采用Griffith断裂理论对SSCP阶段的混合I-II型断裂进行分析,将总能量释放率划分为I型和II型分量。理论模型与实验结果吻合较好,验证了模型的准确性。


Numerical analysis on tensile behavior and damage mechanism of GLARE laminates with two interacting holes combined with DIC and AE techniques

Kejun Hu, Yingxiao Zheng, Yingming Wang

doi:10.1016/j.compstruct.2024.118789

结合DIC和声发射技术对具有两个相互作用孔的眩光复合材料的拉伸性能和损伤机理进行了数值分析

Stress concentration at the hole edges and inter-hole interference effects are the main factors affecting the mechanical properties of open-hole GLARE laminates. In this paper, a combination of experimental and numerical simulation is used to investigate the effects of the distance between two holes’ edge and fiber orientation on the tensile mechanical properties and failure mechanism of the GLARE laminate with two interacting holes. The strain field at the surface of the GLARE laminate with two interacting holes and the damage progression inside the laminate is monitored in real-time using a combination of digital image correlation and acoustic emission techniques. PCA and K-means++ algorithms are used to evaluate the tensile damage patterns and damage evolution of GLARE laminates. A 3D finite element model with Hashin failure criterion and cohesive zone model is used to predict the tensile behavior of GLARE laminates, and finally, the hole-edge stresses and inter-hole interference behavior were analyzed based on the stress concentration factor. The clustering results show the following damage patterns and corresponding peak frequencies of GLARE laminates during tension: metal /intra-laminar delamination damage [0–50 kHz], matrix cracking [100–175 kHz], fiber/matrix debonding damage [175–220 kHz], inter-laminar delamination damage [220–300 kHz], and fiber fracture [300–400 kHz]. As the distance between the two holes’ edges decreases, the stress interference becomes the main cause of the laminate failure, while the stress concentration becomes the main cause as the distance between the two holes’ edges increases. The stress concentration factor at the edge of the two holes has a higher sensitivity to the direction of fiber orientation compared to the distance between the two interacting holes, which increases significantly with increasing fiber orientation angle.

孔边缘应力集中和孔间干涉效应是影响裸眼眩光层压板力学性能的主要因素。本文采用实验与数值模拟相结合的方法,研究了双孔边缘间距和纤维取向对双孔耦合的眩光复合材料拉伸力学性能及失效机理的影响。结合数字图像相关和声发射技术,实时监测了具有两个相互作用孔的眩光层压板表面的应变场和层压板内部的损伤进展。采用PCA和k -means++算法对复合材料的拉伸损伤模式和损伤演化进行了分析。采用基于Hashin破坏准则和内聚区模型的三维有限元模型预测了眩光层合板的拉伸行为,并基于应力集中系数分析了眩光层合板的孔边应力和孔间干涉行为。聚类结果显示,在拉伸过程中,GLARE层叠板的损伤模式和相应的峰值频率为:金属/层内分层损伤[0-50 kHz]、基体开裂[100-175 kHz]、纤维/基体脱粘损伤[175-220 kHz]、层间分层损伤[220-300 kHz]和纤维断裂[300-400 kHz]。随着两孔边缘距离的减小,应力干涉成为层压破坏的主要原因,而随着两孔边缘距离的增大,应力集中成为层压破坏的主要原因。两孔边缘的应力集中系数对光纤取向方向的敏感性高于两孔之间的距离,随着光纤取向角的增加,应力集中系数显著增加。


Multi-physics field induced buckling and free vibration of annular perovskite plates

Zhe Guo, Shaoyu Zhao, Yihe Zhang, Yingyan Zhang, Jie Yang

doi:10.1016/j.compstruct.2024.118791

环形钙钛矿板的多物理场诱导屈曲和自由振动

Perovskite-based structures and devices have gained tremendous research interest in a wide range of engineering applications yet their mechanical characteristics under combined multi-physics fields remains poorly understood. This paper fills in this gap by investigating the opto-electro-thermo-mechano multi-physics field-induced buckling and free vibration of annular perovskite plates with the effects of photostriction, electrostriction, and thermal expansion properties of hybrid perovskite MAPbI3 crystals being taken into account. Governing equations of the plate are obtained within the framework of the first-order shear deformation plate theory and Lagrange equation method and are solved by employing the Chebyshev-Ritz method. A comprehensive parametric study is conducted to show the effects of light illumination, electric field, temperature change, and mechanical loading on the elastic buckling behavior and free vibration characteristics of the plate. It is found that the combined action of multi-physics fields considerably affects the stability and the fundamental frequency of the perovskite plate, indicating that it is necessary and of great significance to well understand and include the effect of opto-electro-thermo-mechano multi-physics field in structural analysis of perovskite structures for more accurate and reliable engineering design.

基于钙钛矿的结构和器件在广泛的工程应用中获得了极大的研究兴趣,但其在多物理场联合作用下的力学特性仍然知之甚少。本文考虑了杂化钙钛矿MAPbI3晶体的光致伸缩、电致伸缩和热膨胀性能的影响,研究了光-电-热-力多物理场诱导的环形钙钛矿板的屈曲和自由振动,填补了这一空白。在一阶剪切变形板理论和拉格朗日方程法的框架下,得到了板的控制方程,并采用切比雪夫-里兹法求解。对光照、电场、温度变化和机械载荷对板的弹性屈曲行为和自由振动特性的影响进行了全面的参数化研究。研究发现,多物理场的共同作用对钙钛矿板的稳定性和基频有较大的影响,说明在钙钛矿结构分析中,充分认识并纳入光电、热和力学多物理场的影响,对提高工程设计的准确性和可靠性具有重要意义。


A finite fracture mechanics approach to assess the fatigue life of laminates exhibiting free edge effects

Mohammad Burhan, Zahur Ullah, Zafer Kazancı, Giuseppe Catalanotti

doi:10.1016/j.compstruct.2024.118797

用有限断裂力学方法评估具有自由边缘效应的层合板的疲劳寿命

This study presents the application of a 3D Finite Fracture Mechanics (FFM) criterion for predicting fatigue life estimation of laminates exhibiting free edge effects. The proposed 3D FFM fatigue criterion incorporates interface properties such as the critical interlaminar stress and the incremental energy release rate as functions of the number of cycles. Material constants calibration involves computing critical interlaminar stress using effective stress distribution over an average delamination onset width while assuming a quadratic relation between critical incremental energy release rate and nominal remote maximum stress cycle. The 3D FFM fatigue criterion system of equations consists of two inequalities solved for a unique solution by assuming homothetic crack extension and utilising a non-linear constraint optimisation. The proposed methodology predicts that lower angles of ply orientation in angle-ply laminates exhibit greater finite fatigue life for a given remote cyclic load. Predictions of fatigue life estimation align well with the experimental results from the literature.

本文提出了三维有限断裂力学(FFM)准则在自由边缘效应层合板疲劳寿命预测中的应用。提出的三维FFM疲劳准则将临界层间应力和增量能量释放率等界面特性作为循环次数的函数。材料常数校准涉及使用平均分层起始宽度上的有效应力分布计算临界层间应力,同时假设临界增量能量释放率与标称远程最大应力循环之间的二次关系。三维FFM疲劳准则方程组由两个不等式组成,通过假设裂纹齐次扩展并利用非线性约束优化来求解唯一解。提出的方法预测,在给定的远程循环载荷下,角层合板的层向角越小,其有限疲劳寿命越长。疲劳寿命估计的预测与文献中的实验结果吻合得很好。


Elastic-plastic responses of honeycomb beams under large deformation three-point bending

Xinrong Fu, Xiong Zhang

doi:10.1016/j.compstruct.2024.118807

大变形三点弯曲下蜂窝梁弹塑性响应

The force responses of thin-walled beams under three-point bending can be divided into an elastic–plastic stage and a subsequent buckling stage. An accurate theoretical analysis of the elastic–plastic responses of the beams is the first step to predict their bending responses and help design the beams with better performances. However, the linear small deformation theory is still widely applied in the analysis of beams under three-point bending, leading to significant errors in the elastic–plastic force or bending moment responses of the beams. In this work, the elastic–plastic responses of honeycomb beams are analyzed theoretically with the consideration of the influence of large deformation. A theoretical solution for the bending moment distribution along beams is first derived based on a large deformation bending model. The elastic–plastic responses of the beam are obtained based on the bending moment distribution. Some problems on the large deformation bending theory are then discussed. Finally, the accuracy of the proposed theory is demonstrated. The newly proposed large deformation bending theory predicts the elastic–plastic responses of honeycomb beams with much better accuracy than the small deformation bending theory. The maximum difference in the average bending moment between the theory and simulation drops from 11.2 % to 4.5 %.

薄壁梁在三点弯曲作用下的受力响应可分为弹塑性阶段和随后的屈曲阶段。对梁的弹塑性响应进行准确的理论分析是预测其弯曲响应和设计性能更好的梁的第一步。然而,线性小变形理论在三点弯曲梁的分析中仍然广泛应用,导致梁的弹塑性或弯矩响应存在较大误差。考虑大变形的影响,对蜂窝梁的弹塑性响应进行了理论分析。在大变形弯曲模型的基础上,推导了弯矩沿梁分布的理论解。根据弯矩分布得到了梁的弹塑性响应。讨论了大变形弯曲理论中的一些问题。最后,验证了所提理论的准确性。新提出的大变形弯曲理论对蜂窝梁弹塑性响应的预测精度远高于小变形弯曲理论。理论与模拟的最大平均弯矩差由11.2 %降至4.5 %。


Composites Part A: Applied Science and Manufacturing

Impact response analysis and Physics-Informed damage classification of sandwich composites using electrical resistance-based self-sensing

Juhyeong Jang, In Yong Lee, Young-Bin Park

doi:10.1016/j.compositesa.2024.108665

基于电阻自传感的夹层复合材料冲击响应分析和物理信息损伤分类

Sandwich composites face maintenance challenges from low-velocity impacts due to their intricate geometry. We propose a method that uses the self-sensing property of carbon fiber reinforced plastic skins to determine the health of an entire sandwich structure in real time. To reflect the hierarchical nature of impact-induced damage progression and the corresponding increase in signal response, a superposition method was proposed. This method superposes binary classifications to construct a damage index map, addressing the low sensitivity of these specimens and small number of samples. This algorithm achieved an accuracy of 81.36%, which is significantly better than the 74.58–79.69% obtained using the conventional algorithm. Moreover, the color layer yields complementary information on the classification results, instilling confidence in these results. This algorithm has potential applications in hierarchical class relationships. The findings show that self-sensing can be useful in monitoring various complex structures with blind regions.

夹层复合材料由于其复杂的几何结构,面临着低速撞击带来的维护挑战。我们提出了一种利用碳纤维增强塑料表皮的自感知特性来实时判断整个三明治结构的健康状况的方法。为了反映碰撞损伤过程的层次性和相应的信号响应增加,提出了一种叠加方法。该方法利用二元分类叠加构造损伤指数图,解决了此类样本灵敏度低、样本数量少的问题。该算法的准确率为81.36%,明显优于传统算法的74.58 ~ 79.69%。此外,颜色层在分类结果上产生补充信息,为这些结果注入信心。该算法在分层类关系中具有潜在的应用前景。研究结果表明,自传感可以用于监测各种具有盲区的复杂结构。


Composites Part B: Engineering

Development of de-icing/self-sensing structural composites via controlled Joule heating curing

Liberata Guadagno, Luigi Vertuccio, Francesca Aliberti, Roberto Pantani, Marialuigia Raimondo, Michelina Catauro, Raffaele Longo

doi:10.1016/j.compositesb.2024.112079

可控焦耳加热固化除冰/自感结构复合材料的研制

Joule heating curing is among the most promising strategies for obtaining cured structural components. This polymerization methodology consumes less than 1% of the energy required by traditional oven/autoclave processes. In light of the relevant impact on the environmental sustainability of manufacturing processes, several aspects related to this curing methodology have been thoroughly investigated. Structural thermoset resins filled with a percentage of 3% wt./wt. carbon nanotubes (CNTs) were produced by comparing two hardening processes: the classical thermal curing in the oven and the more recent Joule heating curing. The electrical resistance change ratio was monitored during the two curing processes to understand how the hardening reactions and the type of curing process affect the electrically conductive network in the composite. It was found that the alignment of CNTs, also previously detected for traditional curing performed under applied high electric field, mainly occurs in the fluid epoxy mixture's initial curing stage and is maintained thanks to the stiffening caused by the polymerization reactions. CNT alignment was verified through tunneling atomic force microscopy (AFM-TUNA). Furthermore, when the heating occurs in the oven, the resistance (R) of the sample increases sensitively, showing a typical positive temperature coefficient behaviour. An opposite behaviour (negative temperature coefficient) is manifested when the temperature increases via Joule heating by applying an electrical field, obtaining a strong reduction of the sample resistance. Joule heating cured glass fiber reinforced composites manifest the intrinsic coexistence of smart properties (self-heating, de-icing, and self-sensing). The peculiar anisotropic electrical properties conferred by the Joule heating to the glass fiber reinforced composites can be exploited to enhance the efficacy of the self-sensing function in the direction normal to CNTs alignment. The high gauge factor of 39 ± 4 (in the linear region between 0% and 0.33% of strain) was detected. These composites exhibit enhanced smart functions compared to traditionally hardened ones, opening up new possibilities for safety and efficient industrial applications.

焦耳加热固化是获得固化结构部件最有前途的策略之一。这种聚合方法消耗的能量不到传统烤箱/高压釜工艺所需能量的1%。鉴于对制造过程的环境可持续性的相关影响,与这种固化方法相关的几个方面已经进行了彻底的研究。结构热固性树脂填充的百分比为3% wt./wt。通过比较两种硬化工艺:经典的烤箱热固化和最新的焦耳加热固化,制备了碳纳米管(CNTs)。通过监测两种固化过程中的电阻变化率,了解硬化反应和固化工艺类型对复合材料导电网络的影响。研究发现,CNTs的排列主要发生在流体环氧混合物的初始固化阶段,并且由于聚合反应引起的硬化而得以维持,而此前在施加高电场的传统固化中也检测到了这种排列。通过隧道原子力显微镜(AFM-TUNA)验证碳纳米管排列。此外,当在烘箱中加热时,样品的电阻(R)敏感地增加,表现出典型的正温度系数行为。当施加电场通过焦耳加热使温度升高时,则表现出相反的行为(负温度系数),从而使样品电阻大幅降低。焦耳加热固化玻璃纤维增强复合材料具有自加热、除冰和自传感等智能特性。焦耳加热赋予玻璃纤维增强复合材料独特的各向异性电学性能,可以提高自传感功能在与碳纳米管垂直方向上的效率。在应变的0% ~ 0.33%的线性范围内,测得高应变系数为39±4。与传统的硬化复合材料相比,这些复合材料具有增强的智能功能,为安全和高效的工业应用开辟了新的可能性。


Composites Science and Technology

Revealing the origin of the thermal conductivity improvement of the silane@polydopamine modified graphene/epoxy nanocomposites: a multiscale study

Haolin Wang, Jihun Lee, Jae Hun Kim, Hyunseong Shin

doi:10.1016/j.compscitech.2024.111009

揭示silane@polydopamine改性石墨烯/环氧纳米复合材料导热性改善的起源:一项多尺度研究

Recently, silane@polydopamine (silane@PDA) non-covalently functionalized two-dimensional nanofillers have attracted considerable interest in the field of thermal interface materials. This is because silane@PDA effectively enhanced the thermal conductivity (TC) of the nanocomposite without damaging its surface structure. However, from a theoretical standpoint, the origin of the observed TC improvement in silane@PDA modified graphene (silane@PDA-GNP)/epoxy nanocomposites remains unclear. In this study, we propose a multiscale strategy combining molecular dynamics (MD) simulations with a two-step homogenization method to investigate the TC improvement of nanocomposites induced by the silane@PDA non-covalent functional groups. Specifically, the contribution of silane@PDA was quantified based on two aspects: the TC of the effective nanofiller and interfacial thermal transport. The two-step homogenization approach indicates that the silane@PDA functional groups enhance the TC of interphase and out-of-plane TC of silane@PDA-GNP, which are crucial for the enhancement of the nanocomposite TC. The contribution of silane@PDA to the interfacial thermal conductance (ITC) was quantified, and the thermal transport process at the interface was further described by analyzing the interfacial thermal transport mechanisms (interfacial interactions and phonon vibrational power spectra). The silane@PDA functional group excites more phonons at the interphases, which leads to more phonons being involved in the interfacial thermal transport and increased ITC. Additionally, the two-step homogenization approach predicted the effects of different types of silanes and the self-condensation of silanes on the TC of the nanocomposites. The proposed two-step homogenization approach can deepen our understanding of the interfacial thermal transport mechanism, and an efficient and fast computational strategy offers a more practical approach for optimizing thermal interface materials with a high TC.

最近,silane@polydopamine (silane@PDA)非共价功能化的二维纳米填料在热界面材料领域引起了相当大的兴趣。这是因为silane@PDA在不破坏纳米复合材料表面结构的情况下,有效地提高了纳米复合材料的导热性(TC)。然而,从理论角度来看,在silane@PDA改性石墨烯(silane@PDA-GNP)/环氧纳米复合材料中观察到的TC改善的起源尚不清楚。在这项研究中,我们提出了一种结合分子动力学(MD)模拟和两步均质化方法的多尺度策略来研究silane@PDA非共价官能团诱导的纳米复合材料的TC改善。具体来说,silane@PDA的贡献是基于两个方面来量化的:有效纳米填料的TC和界面热输运。两步均质方法表明,silane@PDA官能团增强了界面TC和silane@PDA-GNP的面外TC,这是增强纳米复合材料TC的关键。量化了silane@PDA对界面热导的贡献,并通过分析界面热传递机制(界面相互作用和声子振动功率谱)进一步描述了界面的热传递过程。silane@PDA官能团在界面激发更多的声子,导致更多的声子参与界面热输运,增加了ITC。此外,两步均化方法预测了不同类型硅烷和硅烷的自缩聚对纳米复合材料TC的影响。所提出的两步均质化方法可以加深我们对界面热传递机理的理解,并且一种高效、快速的计算策略为高TC热界面材料的优化提供了更实用的方法。


Synergistic Multiple Hydrogen Bonds and Reversible Crystallization Effect Enable Ultra-Tough, Self-Healing, and Recyclable Cellulose-Enhanced Elastomer

Mingming Yu, Mujaheed Halliru Saad, Xiangyu Lin, Fuhao Dong, Xu Fan, Xu Xu, He Liu, Zhanqian Song

doi:10.1016/j.compscitech.2024.111014

协同多氢键和可逆结晶效应使超韧,自愈和可回收的纤维素增强弹性体

Incorporating dynamic covalent bonds into polyurethane (PU) elastomers contributes to exceptional self-healing and recyclable properties. However, further applications are seriously limited due to unsatisfying mechanical characteristics. Herein, a self-healing and ultra-robust nanocomposite elastomer is presented here that consists of polyurethane matrix and cellulose nanocrystals through the synergistic gradient hydrogen bonds and strain-induced reversible crystallization effect. Multiple dynamic hydrogen bonds formed between cellulose nanocrystals (CNC) and polyurethane (PHHD) together with the strain-induced reversible crystallized physical network facilitate excellent mechanical properties while maintaining favorable self-healing ability. The introduction of cellulose nanocrystals significantly enhanced the binding energy of the nanocomposite polyurethane elastomer system, exhibiting an increase of 204.32 kJ/mol. Consequently, nanocomposite elastomers display a remarkable tensile strength (up to 50.1 MPa), ultra-high toughness (441.6 MJ/m3), and excellent fracture energy (214.5 kJ/m2) Furthermore, the result found that the introduction of cellulose nanocrystals can reduce the reaction activation energy and obtain nanocomposite elastomers with highly efficient self-healing (93.9 %). The innovative approach is expected to facilitate the development of high-strength, tough, and exceptional self-healing elastomers in academia and industry.

将动态共价键纳入聚氨酯(PU)弹性体有助于卓越的自我修复和可回收性能。然而,由于不令人满意的机械特性,进一步的应用受到严重限制。本文通过协同梯度氢键和应变诱导的可逆结晶效应,提出了一种由聚氨酯基体和纤维素纳米晶体组成的自修复超坚固的纳米复合弹性体。纤维素纳米晶体(CNC)和聚氨酯(PHHD)之间形成的多个动态氢键以及应变诱导的可逆结晶物理网络在保持良好的自愈能力的同时,促进了优异的力学性能。纤维素纳米晶体的引入显著提高了纳米复合聚氨酯弹性体体系的结合能,提高了204.32 kJ/mol。结果表明,纳米复合弹性体具有优异的抗拉强度(高达50.1 MPa)、超高韧性(441.6 MJ/m3)和优异的断裂能(214.5 kJ/m2)。此外,纤维素纳米晶体的引入可以降低反应活化能,获得高效自愈的纳米复合弹性体(93.9%)。这种创新的方法有望在学术界和工业界促进高强度、高韧性和卓越的自修复弹性体的发展。



来源:复合材料力学仿真Composites FEM
ACTMechanicalOpticalSystemDeform振动疲劳断裂复合材料碰撞非线性裂纹理论材料
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【新文速递】2024年12月21日复合材料SCI期刊最新文章

今日更新:Composite Structures 4 篇,Composites Part A: Applied Science and Manufacturing 3 篇,Composites Part B: Engineering 4 篇,Composites Science and Technology 1 篇Composite StructuresExperimental and numerical investigation on the mechanical behavior of 3D star-shaped auxetic structureWenjie Han, Yuliang Hou, Jianwei Shi, Liang Meng, Thaneshan Sapanathandoi:10.1016/j.compstruct.2024.118803三维星形结构力学性能的实验与数值研究This study proposes a novel 3D star-shaped auxetic (3D-SAU) structure and investigates the mechanical behavior using experimental and numerical approaches. Three lattice structures have been initially additively-manufactured using 3D-SAU cell, as well as the conventional body-centered-cubic (BCC) and 3D re-entrant (3D-RE) structures. Quasi-static compressive and low-velocity impact (LVI) tests have been performed on those additively-manufactured structures, to characterize the mechanical properties. The experimental and numerical results indicate that 3D-SAU structure possesses a more stable and prolonged stress plateau stage than BCC and 3D-RE structures, demonstrating its superior protective capacity. Moreover, LVI test results reveal that the structures with auxetic effect exhibit lower peak forces and longer impact durations compared to BCC structure. Both auxetic structures are found to possess better energy-absorption capacity during high energy impact cases. Finally, a parametric study of design parameters has been performed for 3D-SAU structure through quasi-static compressive tests, to optimize its performance in protecting internal components.本文提出了一种新型的三维星形形变(3D- sau)结构,并采用实验和数值方法研究了其力学行为。三种晶格结构最初使用3D- sau单元,以及传统的体心立方(BCC)和3D重入(3D- re)结构进行增材制造。对这些增材制造结构进行了准静态压缩和低速冲击(LVI)试验,以表征其力学性能。实验和数值结果表明,3D-SAU结构比BCC和3D-RE结构具有更稳定、更持久的应力平台阶段,显示出更强的保护能力。此外,LVI试验结果表明,与BCC结构相比,具有auxetic效应的结构具有更低的峰值力和更长的冲击持续时间。在高能量冲击情况下,两种结构都具有较好的吸能能力。最后,通过准静态压缩试验对3D-SAU结构的设计参数进行了参数化研究,以优化其保护内部构件的性能。CPMOH hydrogel with high tensile properties and environmental resistance Benefits from Intermolecular hydrogen bonding for ECG monitoringTinggang Zhang, Yang Li, Huan Liu, Jiafu Song, Junyao Wang, Jianlang Shu, Zhida Li, Yuyang Huang, Yuhan Huangdoi:10.1016/j.compstruct.2024.118820具有高拉伸性能和耐环境性能的CPMOH水凝胶应用于心电监测Conductive hydrogels (CHs) have been widely used in the design of flexible strain electrodes due to their excellent physicochemical properties, such as large stretchability and high electrical conductivity. However, conductive hydrogels when aqueous solvents are used as the dispersion medium are subject to freezing and drying, which greatly limits their applications. In this study, we demonstrated an conductive hydrogel that is resistant to ambient temperature and highly stretchable by replacing part of the water in the synthesized polyacrylamide/poly(vinylpyrrolidone)/carbon nanotube hydrogel with glycerol through a simple solvent substitution strategy, which provides excellent temperature resistance and good stability without sacrificing the stretchability and conductivity. The conductive hydrogel is environmentally tolerant and is capable of effectively detecting physiological signals from the human body at both high and low temperatures.导电水凝胶(CHs)由于其优异的物理化学性能,如大拉伸性和高导电性,在柔性应变电极的设计中得到了广泛的应用。然而,当使用水性溶剂作为分散介质时,导电水凝胶会受到冷冻和干燥的影响,这极大地限制了它们的应用。在本研究中,我们通过简单的溶剂替代策略,用甘油取代合成的聚丙烯酰胺/聚(乙烯吡咯烷酮)/碳纳米管水凝胶中的部分水,展示了一种耐环境温度和高拉伸性的导电水凝胶,在不牺牲拉伸性和导电性的情况下,具有优异的耐温性和良好的稳定性。导电水凝胶具有环境耐受性,能够在高温和低温下有效检测人体生理信号。Improvement of flame retardancy and anti-dripping properties of polypropylene composites via ecofriendly borax cross-linked lignocellulosic fiberSandeep Gairola, Shishir Sinha, Inderdeep Singhdoi:10.1016/j.compstruct.2024.118822 用硼砂交联木质纤维素纤维改善聚丙烯复合材料的阻燃和防滴性能This research endeavour investigates the enhancement of flame retardancy in natural fiber-reinforced polypropylene composites through boron-based cross-linking. Jute-sisal fabric was treated with borax and subsequently incorporated into a polypropylene matrix to develop flame-retardant composites. The borax-treated fabric exhibited significantly improved flame resistance, as evidenced by a 25.28% increase in limiting oxygen index (LOI), a 60.16% reduction in peak heat release rate (pHRR), and a 3.59% decrease in average heat release rate (av-HRR) compared to the untreated fabric. Similarly, the developed composites demonstrated enhanced thermal stability and flame retardancy, with a 22.01% increase in LOI, a 22.29% reduction in pHRR, and a 22.23% decrease in av-HRR compared to composites reinforced with untreated fibers. The dimensional thermal stability (DTS) of the composites, assessed by heat deflection temperature and coefficient of thermal expansion, was also improved with the incorporation of borax-modified fibers. Chemical and morphological analysis of the char residues of the treated fibers revealed a compact fibrous structure, which likely contributes to the enhanced flame retardancy by forming a protective char layer that insulates the underlying material and hinders heat and mass transfer.本研究旨在探讨通过硼基交联增强天然纤维增强聚丙烯复合材料的阻燃性。黄麻-剑麻织物用硼砂处理,随后加入聚丙烯基体,以开发阻燃复合材料。与未处理织物相比,硼砂处理织物的极限氧指数(LOI)提高了25.28%,峰值放热率(pHRR)降低了60.16%,平均放热率(av-HRR)降低了3.59%,阻燃性能得到了显著提高。同样,与未经处理的纤维增强的复合材料相比,开发的复合材料表现出更好的热稳定性和阻燃性,LOI增加22.01%,pHRR降低22.29%,av-HRR降低22.23%。以热挠曲温度和热膨胀系数评价复合材料的尺寸热稳定性(DTS),硼砂改性纤维的掺入也提高了复合材料的尺寸热稳定性。经过处理的纤维的炭渣的化学和形态分析显示了致密的纤维结构,这可能有助于通过形成一个保护炭层来隔离底层材料并阻碍传热和传质,从而增强阻燃性。Topology optimization method for light-weight design of three-dimensional continuous fiber-reinforced polymers (CFRPs) structuresYongjia Dong, Hongling Ye, Yang Xiao, Jicheng Li, Weiwei Wangdoi:10.1016/j.compstruct.2024.118819三维连续纤维增强聚合物(cfrp)结构轻量化设计的拓扑优化方法Continuous fiber-reinforced polymers (CFRPs) exhibit excellent mechanical properties and designability, offering more opportunities for achieving better structural performance through optimization. However, the high non-convexity of the concurrent optimization model may result in a suboptimal design. In this paper, a novel topology optimization method for three-dimensional CFRP structures is proposed. The light-weight optimization model with compliance constraint is formulated and solved to obtain an optimal topology and spatial fiber orientation. A local coordinate system is established based on the vectors of principal stress and fiber orientation, the interpolation method is presented to control fiber design variables during iteration, reducing the possibility of local optima. Topology and fiber orientation design variables are updated through the method of moving asymptotes (MMA) after sensitivity analysis. Numerical examples are offered to demonstrate the applicability of proposed method. The influence of different initial fiber orientations, mesh sizes and compliance constraints on the optimization results are discussed. Furthermore, the interpolation strategy is also extended to multi-loaded problems, with effectiveness evaluated through a numerical example. The proposed method offers theoretic support for light-weight design and fiber paths planning of three-dimensional CFRP structures.连续纤维增强聚合物(CFRPs)具有优异的力学性能和可设计性,为通过优化获得更好的结构性能提供了更多的机会。然而,并行优化模型的高度非凸性可能导致次优设计。本文提出了一种新的CFRP三维结构拓扑优化方法。建立并求解了具有柔度约束的轻量化优化模型,以获得最优的拓扑结构和空间光纤方向。基于主应力矢量和纤维取向矢量建立了局部坐标系,提出了在迭代过程中控制纤维设计变量的插值方法,减少了局部最优的可能性。在灵敏度分析后,通过移动渐近线法更新拓扑和光纤方向设计变量。数值算例验证了该方法的适用性。讨论了不同初始纤维取向、网格尺寸和柔度约束对优化结果的影响。此外,还将该插值策略推广到多载荷问题,并通过数值算例对其有效性进行了评价。该方法为三维CFRP结构的轻量化设计和纤维路径规划提供了理论支持。Composites Part A: Applied Science and ManufacturingNumerical analysis of fatigue evolution of laminated composites using cohesive zone model and extended finite element methodRong-Can Hong, Ryo Higuchi, Xin Lu, Tomohiro Yokozekidoi:10.1016/j.compositesa.2024.108653 基于黏聚区模型和扩展有限元法的层合复合材料疲劳演化数值分析A numerical method for fatigue accumulation of in laminated composites is developed in this paper. Extended finite element method (XFEM) and cohesive element are integrated into a numerical program for modelling intralaminar matrix cracking and delamination in composite laminates, respectively. A damage-mechanics-based fatigue model is also introduced into the numerical scheme. Pure modes fatigue tests are used for the identification of fatigue parameters. The simulation of open hole tensile test is then performed to investigate the fatigue behaviors of composite laminates. The numerical damage distribution aligns with prior test records, while the predicted fatigue life is consistent with the referenced data. The fast crack propagation observed in the reference is also captured. This study demonstrates that the proposed numerical method can predict the fatigue initiation and evolution of multi-cracks under mixed mode loading. This paper introduces a convenient approach to effectively simulate multiple fatigue cracks in composite laminates.本文提出了一种层合复合材料疲劳累积的数值计算方法。将扩展有限元法(XFEM)和内聚元法(cohesive element)分别集成到复合材料层合板层内基体开裂和分层的数值模拟程序中。数值方案中还引入了基于损伤力学的疲劳模型。采用纯模态疲劳试验对疲劳参数进行识别。通过模拟开孔拉伸试验研究复合材料层合板的疲劳行为。数值损伤分布与试验记录一致,疲劳寿命预测与参考数据一致。在参考文献中观察到的快速裂纹扩展也被捕获。研究表明,所提出的数值方法可以预测混合模式载荷下多裂纹的疲劳萌生和演化过程。本文介绍了一种有效模拟复合材料层合板多重疲劳裂纹的简便方法。A comparative study of 3D woven variable-thickness composite structures with reduced yarns and varied weft sizes under cantilever loadingZengfei Liu, Jingran Ge, Yang Sun, Binbin Zhang, Xiaodong Liu, Jun Liangdoi:10.1016/j.compositesa.2024.108675悬臂载荷下减少纱线和不同纬纱尺寸的三维变厚编织复合材料结构的对比研究In this paper, two types of 3D woven variable-thickness composite structures are designed by reducing yarns and varying weft sizes with the same weave patterns. The mesoscale geometric morphology of two kinds of variable-thickness composite structures is observed by the optical microscope. The cantilever loading tests of the variable-thickness composite structures combined with DIC and strain gauges were carried out, and the strain distribution was determined using finite element analysis. The differences in the mechanical properties and failure mechanisms of woven variable-thickness composite structures with different preform manufacturing processes are comparatively investigated through the surface strain field evolution process and fracture morphology analysis of the specimens. The results show that the varied weft yarn size variable-thickness structures maintain the yarn continuity compared to the reduced yarn structures, but the stiffness and strength are weaker. This study provides mechanical property data support for process design optimization of aero-engine fan blades.在相同的织型条件下,通过减少纱线和改变纬纱尺寸,设计了两种三维变厚织物结构。用光学显微镜观察了两种变厚度复合材料结构的中尺度几何形态。采用DIC和应变片对变厚复合材料结构进行了悬臂加载试验,通过有限元分析确定了应变分布。通过试样的表面应变场演化过程和断口形貌分析,比较研究了不同预制体制造工艺编织变厚度复合材料结构的力学性能差异和破坏机制。结果表明:变纬纱粗变结构与减纬纱结构相比,保持了纱线的连续性,但刚度和强度较弱;该研究为航空发动机风扇叶片的工艺设计优化提供了力学性能数据支持。Characterization of damage in non-crimp fabric glass fiber-reinforced reactive thermoplastic composites at low temperature using an in-situ digital imaging techniqueErli Shi, John Montesanodoi:10.1016/j.compositesa.2024.108674使用原位数字成像技术表征无卷曲织物玻璃纤维增强反应性热塑性复合材料在低温下的损伤An in-situ digital imaging technique was developed to characterize damage in non-crimp fabric glass fiber/reactive thermoplastic cross-ply laminates subjected to tensile loading at −50 °C. A custom algorithm was developed to automatically detect the initiation and growth of 90° tow cracks, matrix cracks, and 0° tow cracks through image stacking, shift-correction, and thresholding. The laminates exhibited four stages of deformation/damage, including linear elastic, onset/growth of 90° fiber tow cracks, onset/growth of 0° fiber tow cracks, and progressive failure of 0° fiber tows. Although at low temperature the effective laminate strength and stiffness increased by 4 % and 13 %, respectively, damage initiated sooner and propagated at a higher rate leading to a 60 % increase in crack density at saturation. The digital imaging technique proved to effectively detect local damage in the glass fiber/thermoplastic laminates, which led to a deeper understanding of their low-temperature deformation response, damage characteristics, and damage tolerance.开发了一种原位数字成像技术,用于表征非卷曲织物玻璃纤维/反应性热塑性 交叉层合板在- 50 °C拉伸载荷下的损伤。开发了一种自定义算法,通过图像叠加、位移校正和阈值化自动检测90°tow裂纹、矩阵裂纹和0°tow裂纹的起裂和扩展。层合板呈现线性弹性、90°纤维束裂纹开始/扩展、0°纤维束裂纹开始/扩展和0°纤维束逐渐破坏四个阶段的变形/损伤。虽然在低温下层合板的有效强度和刚度分别增加了4 %和13 %,但损伤开始更快,扩展速度更快,导致饱和时裂纹密度增加了60 %。事实证明,数字成像技术可以有效地检测玻璃纤维/热塑性层压板的局部损伤,从而更深入地了解其低温变形响应、损伤特性和损伤容限。Composites Part B: EngineeringExperimental study on circumferential compression behavior of large-diameter bamboo winding composite pipe (BWCP)Jin Xia, Yu Zhou, Yue Chen, Qingang Ma, Jialin Dongdoi:10.1016/j.compositesb.2024.112082大直径竹缠绕复合管周向压缩性能试验研究Bamboo winding composite pipe (BWCP) is a new type of environmentally friendly pipe material that uses bamboo as the base material. In this study, the circumferential compressive performance of large-diameter BWCP (inner diameter ≥ 1 m) was investigated under various inner diameter and wall thickness conditions through parallel plate loading tests. The results showed that the initial ring stiffness of BWCP increased with wall thickness, rising from approximately 5 kN/m2 at 42 mm thickness to 25 kN/m2 at 67 mm when the inner diameter was 1.4 m. Conversely, the ring stiffness declined as inner diameter increased. When the wall thickness was approximately 52 mm, the initial ring stiffness dropped from about 18 kN/m2 at an inner diameter of 1.0 m to around 3.3 kN/m2 at 1.6 m. This decline became more pronounced with larger diameters, with a 50% reduction from 1.2 m to 1.4 m and a 60% reduction from 1.4 m to 1.6 m. BWCP demonstrated strong toughness and resistance to deformation under external pressure, with load-displacement curves showing a distinct yield plateau and specimens exhibiting ductile failure characteristics. After unloading, the pipes retained over 95% of their original inner diameter. Due to the layered anisotropic nature of BWCP, a single elastic modulus does not accurately represent its ring stiffness. Thus, an equivalent elastic modulus calculation method based on the law of mixture was adopted, and a semi-empirical, semi-theoretical formula for predicting the initial ring stiffness of BWCP was proposed by combining mechanical theory with experimental results.竹缠绕复合管是一种以竹材为基材的新型环保管材。本研究通过平行板加载试验,研究了不同内径和壁厚条件下大直径BWCP(内径≥1 m)的周向压缩性能。结果表明:当内径为1.4 m时,BWCP的初始环刚度随壁厚的增加而增加,从42 mm时的约5 kN/m2增加到67 mm时的25 kN/m2;相反,环刚度随内径的增大而减小。当壁厚约为52 mm时,初始环刚度从内径1.0 m时的约18 kN/m2下降到1.6 m时的约3.3 kN/m2。随着直径的增大,这种下降更加明显,从1.2 m到1.4 m减少了50%,从1.4 m到1.6 m减少了60%。BWCP具有较强的韧性和抗外压变形能力,载荷-位移曲线呈现明显的屈服平台,试件表现出延性破坏特征。卸载后,管道保留了95%以上的原始内径。由于BWCP的层状各向异性,单一弹性模量不能准确表示其环刚度。因此,采用基于混合规律的等效弹性模量计算方法,结合力学理论和实验结果,提出了预测BWCP初始环刚度的半经验、半理论公式。3D printing and near-net shaping of laminated Cr3C2/Cu composites: Enhanced strength, toughness, and anisotropyShuai-Shuai Li, Xiang-Yu Meng, Rui-Fen Guo, Ping Shendoi:10.1016/j.compositesb.2024.112090 Cr3C2/Cu复合材料的3D打印和近净成形:增强强度、韧性和各向异性Ceramic/metal laminates offer great potential for enhancing mechanical properties; however, traditional fabrication methods lack precise microstructural control. This study employed direct ink writing (DIW) and pressureless infiltration to create near-net-shape Cr3C2/Cu laminates with tailored properties. Adjusting the Cr3C2 content and loading orientation yielded significant improvements in strength and toughness. Notably, a composite with 26.2 vol.% Cr3C2 exhibited a flexural strength of 995 MPa and a fracture toughness (KIC) of 22.3 MPa·m1/2 when loaded parallel to the layers (S-YOZ), exceeding values reported for conventionally manufactured counterparts. The enhanced mechanical properties and anisotropic behavior result from the synergy between the alternating soft Cu and hard Cr3C2 layers, the interpenetrating microstructures, and strong interfacial bonding. In situ observations and finite element simulations confirmed toughening mechanisms, including crack deflection, ductile bridging, and multiple cracking. This DIW-based approach offers a promising route for designing high-performance ceramic/metal composites.陶瓷/金属层状复合材料在提高机械性能方面具有巨大的潜力,但传统的制备方法缺乏精确的微观结构控制。本研究采用直接墨水书写(DIW)和无压浸渍的方法,以获得具有定制性能的近净形Cr3C2/Cu层状复合材料。通过调整Cr3C2含量和加载方向,显著提高了强度和韧性。值得注意的是,当Cr3C2含量为26.2体积%时,该复合材料在平行于层的方向(S-YOZ)上的弯曲强度为995 MPa,断裂韧性(KIC)为22.3 MPa·m1/2,超过了传统制造方法的同类材料的报告值。增强的机械性能和各向异性行为源于交替的软铜和硬Cr3C2层、相互渗透的微观结构和强界面结合。在位观察和有限元模拟证实了增韧机制,包括裂纹偏转、塑性桥接和多裂纹。基于DIW的方法为设计高性能陶瓷/金属复合材料提供了有前途的途径。Adhered Web-Lapped Semi-Rigid Pultruded FRP Beam-to-Column Framing Connections: Part 2 – Spring Constant, Strength Prediction, and ApplicationsDavid Pirchio, Juan Diego Pozo, Kevin Q. Walshdoi:10.1016/j.compositesb.2024.112097粘结网搭接半刚性拉挤FRP梁-柱框架连接:第2部分-弹簧常数,强度预测和应用The herein research focused on the definition of the spring constant, developing a predictive equation for strength, and a parametric study for adhered lapped semi-rigid pultruded fiber reinforced polymers (FRP) beam-to-column connections. The research is the second part of a two-part paper in which the first part focused on the experimental testing of 51 lapped adhered semi-rigid pultruded FRP beam-to-column connections in cyclic loading. The spring constant was determined based on analytical methods to determine the initial stiffness of the semi-rigid connections, net deformation due to flexural bending, and shear acting on the connection component (i.e., the column and the beam). A predictive equation to determine the strength of the semi-rigid connection was developed using an analytical approach and compared with the connection strength determined in the first part of the work, and a strength reduction factor (i.e., ϕ-factor) was defined to grant a standard-compliant level of reliability for the application of the developed predictive equation into load and resistance factor design (LRFD) approach. Finally, the possible applications of the results within the boundaries of LRFD design of pultruded FRP framing systems were discussed via a parametric study in which the results were applied and two real-world examples.本文的研究重点是弹簧常数的定义,建立了强度预测方程,并对粘接搭接半刚性拉伸纤维增强聚合物(FRP)梁柱连接进行了参数化研究。本文的研究是两部分论文的第二部分,第一部分是对51个循环荷载下搭接粘贴半刚性拉挤FRP梁柱连接的试验测试。弹簧常数根据解析方法确定半刚性连接的初始刚度、受弯净变形和作用于连接构件(即柱和梁)的剪力。使用分析方法开发了用于确定半刚性连接强度的预测方程,并将其与第一部分工作中确定的连接强度进行了比较,并定义了强度折减因子(即,因子),以便为将开发的预测方程应用于负载和阻力因素设计(LRFD)方法提供符合标准的可靠性水平。最后,通过参数化研究和两个现实世界的例子,讨论了结果在拉挤FRP框架系统LRFD设计边界内的可能应用。Three-dimensional printing of high-performance continuous fiber-reinforced thermoplastic composites: causes and elimination of process-induced defectsWeijun Zhu, Long Fu, Xiaoyong Tian, Quan Zhi, Zhanghao Hou, Zhikun Zhang, Ning Wang, Tengfei Liu, Henglun Sun, Ryosuke Matsuzaki, Masahito Ueda, Andrei V. Malakhov, Alexander N. Polilov, Meng Luo, Dongsheng Li, Dichen Lidoi:10.1016/j.compositesb.2024.112080高性能连续纤维增强热塑性复合材料的三维打印:工艺缺陷的原因和消除Continuous fiber composite three-dimensional (3D) printing technology enables the production of lightweight, complex 3D composite parts with functional integration and other significant advantages. However, in high-end applications, scenarios such as aerospace and energy delivery the performance stability of materials in long-term service environments is critical. The poor performance and instability of the existing 3D printing of fiber composite materials, particularly fiber-reinforced thermoplastic materials, caused by the various defects introduced in the printing process, has become the main challenge. This paper focuses on high-performance continuous fiber-reinforced thermoplastic composites. It reviews various defects in the printing process and discusses their mechanisms, effects on properties and possible elimination measures. Printing defects are categorized into two types based on their primary components: polymer defects and fiber-related defects. This paper also discusses two types of defects: defects in turning zones and defects on surfaces, which are classified based on their location. In addition, this paper summarizes the existing defect elimination methods and research progress. It also suggests the direction of future development, emphasizing that understanding the mechanisms and addressing irremovable defects are crucial for advancing high-performance 3D printing technology.连续纤维复合材料三维(3D)打印技术使生产轻量化、复杂的3D复合材料部件具有功能集成等显著优势。然而,在高端应用中,如航空航天和能源输送等场景,材料在长期服务环境中的性能稳定性至关重要。现有的纤维复合材料,特别是纤维增强热塑性材料的3D打印由于在打印过程中引入的各种缺陷而导致的性能差和不稳定性成为主要挑战。本文主要研究高性能连续纤维增强热塑性复合材料。综述了印刷过程中出现的各种缺陷,讨论了缺陷产生的机理、对性能的影响以及可能的消除措施。打印缺陷根据其主要成分可分为两类:聚合物缺陷和纤维相关缺陷。本文还讨论了两类缺陷:车削区缺陷和表面缺陷,并根据它们的位置进行了分类。此外,本文还总结了现有的缺陷消除方法和研究进展。指出了未来的发展方向,强调了解机理和解决不可消除的缺陷对于推进高性能3D打印技术至关重要。Composites Science and TechnologyCharacterization of fracture behavior in adhesively bonded joints with porosity in the adhesive layer using X-ray computed tomographyWilliam E. Guin, John V. Bausano, Ashley N. Taets, Alan T. Nettles, Scott Ragasadoi:10.1016/j.compscitech.2024.111025 用x射线计算机断层扫描表征带有黏合剂层孔隙的黏合剂粘合接头的断裂行为Adhesively bonded joints with various levels of porosity in the adhesive layer are examined via X-ray computed tomography (CT) and Mode I fracture toughness testing. Bonded assemblies consisting of woven carbon fiber/epoxy composite adherends and a toughened epoxy film adhesive are considered. Porosity is induced in the adhesive layer through the use of shims during the manufacturing process. X-ray CT and accompanying image processing is used to characterize bondline thicknesses and void content in each Mode I fracture toughness specimen considered. Mode I fracture toughness tests are carried out to quantitatively assess the effects of porosity in the adhesive layer and post-test optical microscopy is used to examine the relationships between fracture toughness and fracture processes. This experimental approach is used to establish relationships among bondline thickness, void content, Mode I fracture toughness, and failure modes in an effort to correlate quantifiable physical parameters to adhesively bonded joint structural performance.通过x射线计算机断层扫描(CT)和I型断裂韧性测试,对粘接层中具有不同孔隙度的粘接接头进行了检查。考虑了由编织碳纤维/环氧复合材料粘合剂和增韧环氧薄膜粘合剂组成的粘合组件。在制造过程中,通过使用垫片在胶粘剂层中引起孔隙。x射线CT和伴随的图像处理用于表征所考虑的每个I型断裂韧性试样的结合线厚度和空洞含量。进行I型断裂韧性试验,定量评价粘接层孔隙率的影响,试验后使用光学显微镜检查断裂韧性与断裂过程的关系。该实验方法用于建立粘结线厚度、空隙含量、I型断裂韧性和破坏模式之间的关系,试图将可量化的物理参数与粘接接头的结构性能联系起来。 来源:复合材料力学仿真Composites FEM

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