今日更新:Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 1 篇
Hydrogel with dual networks making reduced GO connection and orientation for a bi-directional thermal conductive film
Zhang Jianyu, Zhang Yintao, Yang Cheng, Jiang Xueliang, Tian Wensheng, Li Yanyu, Liu Runlu, Chen Zhixin, Pan Hui, Zhu Shenmin
doi:10.1016/j.compositesa.2023.107816
具有双网络的水凝胶可减少 GO 的连接和定向,从而形成双向导热膜
With the rapid development of modern electronic devices, materials having high thermal conductivities (TCs) both in in-plane and through-plane directions are specially needed for thermal management. Whereas, the construction of efficient thermal-conductive pathways in bi-directions is still a challenge. Herein, a facile gel-drying approach is developed, achieving the formation of bi-directional pathways with the assistance of a dual-network structure. During the process, cellulose nanocrystal (CNC) with a high intrinsic TC was mixed with gellable cellulose (CNF) to form CNF/2CNC dispersion which was then used as a matrix. Reduced graphene oxide (RGO) foam with a network structure was used as a filler. The RGO network was tightly wrapped by the formed CNF/2CNC cross-linking network, resulting in a hydrogel with a dual-network structure. After drying, the resultant RGO-foam-CNF/2CNC film not only has a long-range orientation path in the horizontal direction, but also maintained a connected path in the vertical direction. The resultant film with 18.5 wt % RGO exhibited high TCs of 14.06 W·m-1·K-1 and 2.47 W·m-1·K-1 simultaneous for in-plane and through-plane directions, which is 21.6 times and 9.88 times higher than those of a typical CNF film, respectively. This strategy offers a new avenue for the designs of soft, cuttable, environmentally friendly polymer composite films with high TCs in bi-directions.
随着现代电子设备的飞速发展,热管理特别需要在面内和面外都具有高导热率(TC)的材料。然而,在双向构建高效导热通道仍是一项挑战。在此,我们开发了一种简便的凝胶干燥方法,在双网络结构的辅助下形成双向导热通道。在此过程中,具有高固有热导率的纤维素纳米晶(CNC)与可凝胶纤维素(CNF)混合,形成 CNF/2CNC 分散体,然后用作基质。具有网络结构的还原氧化石墨烯(RGO)泡沫被用作填料。RGO 网络被形成的 CNF/2CNC 交联网络紧紧包裹,从而形成具有双网络结构的水凝胶。干燥后,得到的 RGO- 泡沫-CNF/2CNC 薄膜不仅在水平方向上具有长程取向路径,而且在垂直方向上也保持了连接路径。RGO 含量为 18.5 wt % 的薄膜在平面内和平面外同时表现出 14.06 W-m-1-K-1 和 2.47 W-m-1-K-1 的高 TC 值,分别是典型 CNF 薄膜的 21.6 倍和 9.88 倍。这种策略为设计具有双向高 TCs 的柔软、可切割、环保型聚合物复合薄膜提供了一条新途径。
New strategy for enhancing interfacial adhesion between carbon fiber and epoxy by using mussel-inspired polydopamine-Fe complex nanospheres
Wu Qing, Xiao Bolin, Liu Qianli, Deng Hao, Ye Ziyi, Li Yating, Yao Renjie, Zhu Jianfeng
doi:10.1016/j.compositesb.2023.111032
利用贻贝启发的聚多巴胺-铁复合纳米球增强碳纤维与环氧树脂界面粘附力的新策略
The liable interfacial delamination of carbon fiber composites is a long-lasting problem that restricts its widely application. One promising route is to hybridize fiber with nano-particles on account of their prominent mechanical properties and huge specific surface area, while trial using biobased nanoparticles are in its infancy. Mussel adhered firmly to the reef relies on its bushy byssal threads, which correlates with chelation of ferric ions with catechol-containing proteins. Inspired by this, we deposited synergistic bio-based polydopamine (PDA)-Fe complex nanospheres and silane coupling agent on carbon fiber by simply impregnation, which delivers increment of 56.4% in interfacial shear strength (IFSS) in epoxy matrix relative to untreated fiber composites. Results suggest that the improved epoxy wetting behavior that imparts full infiltration, the excellent adhesivity that eliminates weak interface layer, as well as strong but reversible PDA-Fe chelate crosslinks that advance tress transfer and energy dissipation, which are critical to IFSS growth. This work provides a new and attractive bio-nanomaterial of PDA-Fe in interfacial engineering of composites.
碳纤维复合材料易发生界面分层是一个长期存在的问题,限制了其广泛应用。由于纳米颗粒具有突出的机械性能和巨大的比表面积,将纤维与纳米颗粒杂化是一条很有前景的途径,而使用生物基纳米颗粒的试验还处于起步阶段。贻贝能牢固地附着在礁石上,靠的是其茂密的鳍丝,这与含儿茶酚的蛋白质螯合铁离子有关。受此启发,我们通过简单的浸渍法将生物基多多巴胺(PDA)-铁复合物纳米球和硅烷偶联剂协同沉积在碳纤维上,与未经处理的纤维复合材料相比,环氧基体的界面剪切强度(IFSS)提高了 56.4%。研究结果表明,环氧树脂润湿性能的改善使其能够充分浸润,出色的粘合性消除了薄弱的界面层,强韧但可逆的 PDA-Fe 螯合交联促进了应力传递和能量消耗,而这对 IFSS 的增长至关重要。这项工作为复合材料的界面工程提供了一种新的、有吸引力的 PDA-Fe 生物纳米材料。