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【新文速递】2023年11月17日固体力学SCI期刊最新文章

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今日更新:International Journal of Solids and Structures 3 篇,Journal of the Mechanics and Physics of Solids 1 篇,Mechanics of Materials 1 篇,International Journal of Plasticity 2 篇,Thin-Walled Structures 2 篇

International Journal of Solids and Structures

Uniqueness of Finite Element Limit Analysis solutions based on weak form lower and upper bound methods

Poulsen Peter Noe, Olesen John Forbes

doi:10.1016/j.ijsolstr.2023.112532

基于弱形式下限和上限方法的有限元极限分析解的唯一性

Finite Element Limit Analysis (FELA) is increasingly used for calculating the ultimate bearing capacity of structures made of ductile materials. Within FELA for reinforced concrete structures the elements have been based on rigorous lower bound or boundary mixed formulations. The lower bound element formulation may be overly constrained for certain meshes and the dual displacement interpretation may contain spurious modes, moreover the boundary mixed element formulation has an internal equilibrium node with no associated displacement field. Here a consistent and general weak formulation based on virtual work is presented specifically for both the lower and the upper bound problem, and it is shown that they are each others dual ensuring uniqueness of the optimal solution. As a consequence there is no difference between the solutions based on the weak upper and lower bound methods. Here a plane element is presented, with a linear stress variation and a quadratic displacement field, optionally including a concentrated bar element with a linear variation of the normal force. These elements are applied in a verification example and two reinforced concrete examples where they show very good results for both load level, stress distribution and collapse mechanism even for coarse meshes.

有限元极限分析(FELA)越来越多地用于计算韧性材料结构的极限承载力。在钢筋混凝土结构的有限元极限分析中,元素一直基于严格的下限或边界混合公式。对于某些网格来说,下限元素公式可能会限制过多,而且双重位移解释可能包含虚假模式,此外,边界混合元素公式有一个内部平衡节点,但没有相关的位移场。这里提出了一种基于虚拟工作的一致且通用的弱公式,特别适用于下边界问题和上边界问题,并证明它们互为对偶,确保了最优解的唯一性。因此,基于弱上界法和弱下界法的求解没有区别。这里介绍的是一种平面元素,具有线性应力变化和二次位移场,也可选择包含法向力线性变化的集中杆元素。这些元素被应用于一个验证实例和两个钢筋混凝土实例中,即使在粗网格中,它们也能在载荷水平、应力分布和坍塌机制方面显示出非常好的结果。


Modelling deformation effects in multiple collisions using Collisional-SPH

Vyas Dhairya R., Cummins Sharen J., Delaney Gary W., Rudman Murray, Khakhar Devang V.

doi:10.1016/j.ijsolstr.2023.112578

利用碰撞-SPH 模拟多重碰撞的变形效应

Multiple collisions of granules on a substrate are encountered in a wide range of applications. In this work, such multiple collisions are analysed using Collisional Smooth Particle Hydrodynamics (CSPH) to understand how deformation caused by an impact influences the collision dynamics of subsequent impacts. It is found that the collision dynamics depends on the location of the impact and the deformation of the substrate caused by the preceding impacts. The predictions of three theoretical models are also compared with CSPH to assess the accuracy of the assumptions made by the models. The theoretical model predictions are only found to be useful when the granule repeatedly impacts the same location. Since these models do not simulate the shape change during the substrate deformation they fail to accurately model the cases where multiple impacts occur at different locations.

在各种应用中都会遇到颗粒在基底上发生多次碰撞的情况。在这项工作中,我们使用碰撞平滑粒子流体力学(CSPH)对这种多次碰撞进行了分析,以了解撞击造成的变形如何影响后续撞击的碰撞动力学。研究发现,碰撞动力学取决于撞击的位置和之前撞击造成的基体变形。还将三个理论模型的预测结果与 CSPH 进行了比较,以评估模型假设的准确性。结果发现,理论模型的预测只有在颗粒反复撞击同一位置时才有用。由于这些模型没有模拟基底变形过程中的形状变化,因此无法准确模拟在不同位置发生多次撞击的情况。


Effect of the crack layer theory parameters on the discontinuous slow crack growth of high density polyethylene under fatigue loading

Almomani Abdulla, Mourad Abdel-Hamid I., Deveci Suleyman

doi:10.1016/j.ijsolstr.2023.112579

裂纹层理论参数对疲劳载荷下高密度聚乙烯不连续慢速裂纹生长的影响

For engineering thermoplastics, particularly high density polyethylene (HDPE), the crack layer (CL) theory is an effective proposition for modeling slow crack growth and predicting their lifetime. Nevertheless, the associated excessive input parameters needed in its implementation sets a difficulty for its use. Therefore, an understanding of the role of each parameter and how they affect the CL growth is needed. The effect of the parameters has been studied in the past, however, under creep conditions only. Their effects under other loading conditions, e.g., fatigue, and geometries, e.g., compact tension (CT) specimen, is still unclear. For instance, increasing the natural drawing ratio λ was found to non-linearly reduce failure time tf, whereas a rise in the drawing stress σdr increased tf which correlates logarithmically with the loading frequency f. Furthermore, tf was found to increase with the transformation energy γtr, specimen thickness B, plane stain elastic modulus E′, drawing stress σdr, characteristic time t∗, and the specific fracture energy γ0. Therefore, outcomes of this work extend the applicability of the CL theory in the design and lifetime prediction of various industrial products within oil and gas, nuclear, automotive, and aerospace.

对于工程热塑性塑料,尤其是高密度聚乙烯(HDPE),裂纹层(CL)理论是模拟缓慢裂纹生长和预测其寿命的有效方法。然而,在实施过程中所需的相关输入参数过多,给其使用带来了困难。因此,需要了解每个参数的作用及其对 CL 生长的影响。过去对参数影响的研究仅限于蠕变条件下。它们在其他加载条件(如疲劳)和几何形状(如紧密拉伸 (CT) 试样)下的影响仍不清楚。例如,研究发现增加自然拉伸比 λ 会非线性地缩短破坏时间 tf,而拉伸应力 σdr 的增加会延长 tf,tf 与加载频率 f 成对数关系。此外,研究还发现 tf 会随着转化能 γtr、试样厚度 B、平面沾污弹性模量 E′、拉伸应力 σdr、特征时间 t∗ 和比断裂能 γ0 的增加而增加。因此,这项工作的成果扩展了 CL 理论在油气、核能、汽车和航空航天领域各种工业产品的设计和寿命预测中的适用性。


Journal of the Mechanics and Physics of Solids

Dynamic high-order buckling and spontaneous recovery of active epithelial tissues

Wang Huan, Liu Yong-Quan, Hang Jiu-Tao, Xu Guang-Kui, Feng Xi-Qiao

doi:10.1016/j.jmps.2023.105496

活性上皮组织的动态高阶屈曲和自发恢复

Active epithelial tissues can adapt to quasi-static compressive forces through buckling instability, but their responses to dynamic forces at shorter timescales remain elusive. We firstly establish a cytoarchitectural model that can accurately capture the experimentally observed high-order buckling and postbuckling (e.g., spontaneous flattening and stress recovery) behaviors of epithelia under fast compression. It is found that the stress evolution of epithelia can be divided into three stages: loading, phase transition, and stress recovery. In the loading stage, we observe the high-order instability with a buckling mode highly correlated with the strain rate, and derive its analytical relation, showing that the rate-dependent buckling mode is quantitatively determined by the viscoelastic and geometrical characteristics of epithelia. In the phase transition and stress recovery stages, we demonstrate that the postbuckling process is governed by the active tension generated by the actomyosin network. Furthermore, by proposing a minimal model, we obtain the explicit solutions of the flattening time and stress recovery extent as functions of the applied strain or strain rate, which are in quantitative agreement with our simulations and relevant experiments. In addition, depending on the stress evolution route, we construct a universal phase diagram for the morphology evolution of the epithelia in a wide range of strain and strain rate. This study elucidates the dominative roles of the activity and rheological characteristics of active soft materials in their dynamic mechanical behaviors, offering an approach for studying the complex morphology evolution.

活跃的上皮组织可以通过屈曲不稳定性来适应准静态压缩力,但它们对较短时标的动态力的反应仍然难以捉摸。我们首先建立了一个细胞结构模型,该模型能准确捕捉实验观察到的上皮组织在快速压缩下的高阶屈曲和屈曲后行为(如自发扁平化和应力恢复)。研究发现,上皮的应力演变可分为三个阶段:加载、相变和应力恢复。在加载阶段,我们观察到了与应变速率高度相关的屈曲模式的高阶不稳定性,并推导出了其分析关系,表明与速率相关的屈曲模式是由上皮的粘弹性和几何特性定量决定的。在相变和应力恢复阶段,我们证明了屈曲后过程是由肌动蛋白网络产生的主动张力控制的。此外,通过提出一个最小模型,我们得到了扁平化时间和应力恢复程度作为施加应变或应变率函数的显式解,这与我们的模拟和相关实验在数量上是一致的。此外,根据应力演化路径,我们还构建了一个通用相图,用于描述上皮在宽应变和应变率范围内的形态演化。这项研究阐明了活性软材料的活性和流变特性在其动态力学行为中的主导作用,为研究复杂的形态演变提供了一种方法。


Mechanics of Materials

A multi-scale approach to predict shrinkage and creep of cementitious composite in a hygro-thermo-chemo-mechanical framework-theoretical formulation and numerical validation

Pal Biswajit, Ramaswamy Ananth

doi:10.1016/j.mechmat.2023.104866

在湿热-化学-力学框架下预测水泥基复合材料收缩和蠕变的多尺度方法--理论表述和数值验证

Prediction of time-dependent deformation such as shrinkage and creep are of utmost interest in terms of long-term serviceability of a concrete structure. However, owing to highly heterogeneous nature of concrete, existing macroscopic prediction models lack in terms of its general applicability. Hence, in this study, a multi-scale description is used to simulate the shrinkage and creep of concrete where the heterogeneity and associated physical-chemical processes are modeled in a mathematical framework. A hierarchical homogenisation technique is used to link across different scales. Model predicated shrinkage and creep are then validated with the corresponding experimental data. Model prediction is also compared with few national codes and popular macroscopic models to highlights the associated gaps in these models that can be overcome with the present developed multi-scale approach.

收缩和徐变等随时间变化的变形预测对混凝土结构的长期适用性至关重要。然而,由于混凝土具有高度异质性,现有的宏观预测模型缺乏普遍适用性。因此,本研究采用多尺度描述来模拟混凝土的收缩和徐变,并在数学框架内对异质性和相关的物理化学过程进行建模。分层均质化技术用于连接不同尺度。然后用相应的实验数据对模型预测的收缩和徐变进行验证。此外,还将模型预测与一些国家规范和流行的宏观模型进行了比较,以突出这些模型中的相关差距,而目前开发的多尺度方法可以克服这些差距。


International Journal of Plasticity

Heterogeneous metallic glass composites with a unique combination of strength, plasticity and conductivity

Bao Weizong, Bao Longke, Chen Jie, Li Junzhi, Xiang Tao, Yu Bohua, Cai Zeyun, Xie Guoqiang

doi:10.1016/j.ijplas.2023.103810

集强度、塑性和导电性于一身的异质金属玻璃复合材料

Metallic glass-reinforced Cu-based composites offer a promising avenue for overcoming the trade-off between high strength and high electrical conductivity in materials. In this investigation, heterogeneous CuZrAl metallic glass-reinforced CuCrZr alloy composites are prepared through spark plasma sintering and a one-step hot pressing. The microstructural evolution of the composites during the preparation process and its correlation with mechanical and electrical properties are revealed. Grain refinement and dislocation accumulation in the CuCrZr alloy matrix resulted in strength gain and a trade-off in electrical conductivity. However, precipitation of the Cr-rich phase compensates for the loss of conductivity. Directional strengthening and toughening of the composites are achieved by inducing deformation of the CuZrAl metallic glass reinforcement in the undercooled liquid region to attain its ordered arrangement. Furthermore, the electrical and mechanical properties of the crystalline phase Cu10Zr7 at the edge of metallic glass are predicted and investigated using first-principles calculations, with a focus on its impact on the performance of composites. A novel Cu-based metallic glass composites fabricated using an efficient processing approach offers valuable insights into material selection for electrical conductor applications.

金属玻璃增强铜基复合材料为克服材料中高强度和高导电性之间的权衡问题提供了一种前景广阔的途径。本研究通过火花等离子烧结和一步热压制备了异质 CuZrAl 金属玻璃增强 CuCrZr 合金复合材料。研究揭示了复合材料在制备过程中的微观结构演变及其与机械和电气性能的相关性。CuCrZr 合金基体中的晶粒细化和位错累积导致了强度的提高和导电性能的折衷。然而,富铬相的析出弥补了导电性的损失。通过在过冷液体区域诱导 CuZrAl 金属玻璃增强体变形,使其达到有序排列,从而实现了复合材料的定向增强和增韧。此外,还利用第一原理计算方法预测和研究了金属玻璃边缘结晶相 Cu10Zr7 的电气和机械特性,重点关注其对复合材料性能的影响。采用高效加工方法制造的新型铜基金属玻璃复合材料为电导体应用的材料选择提供了宝贵的见解。


From mechanical behavior and elastocaloric effect to microscopic mechanisms of gradient-structured NiTi alloy: A phase-field study

Zhang Qi, Chen Junyu, Fang Gang

doi:10.1016/j.ijplas.2023.103809

从梯度结构镍钛合金的机械行为和弹性效应到微观机制:相场研究

The introduction of gradient structure has been recently reported as a practical way to tailor the mechanical behavior of NiTi while improving its elastocaloric effect simultaneously. In this research, a thermo-mechanically weakly coupled phase-field model considering crystal plasticity is employed to investigate the microscopic mechanisms of the elastocaloric effect related to the gradient structure, especially from the point of view of the two-way interaction between stress and martensite variants. A set of polycrystalline systems are established to accomplish the gradual transition from a fine-grained specimen to a coarse-grained one by the grain-size gradient. The gradually changed mechanical response and transformation characteristics during the superelastic simulations embody the effectiveness of the grain structure as a regulator of the material properties. The Brayton cycle simulations conducted next revolve around further validation of the proposed model and variant-related interpretation of the effects of the grain structure. Predictions relevant to histories of stress and temperature agree well with the experimental results, and more remarkably, the linear stress-temperature relationship observed during the stress drop of the first hold in the Brayton cycle conforms perfectly to the classical Clausius–Clapeyron relation. Together with martensite reorientation, the propagating martensite phases, where the increasing non-major variants are necessary complements to the major one preferentially aligned with the external stress, are largely responsible for this stress drop. Regarding the elastocaloric effect, the gradient structures achieve very similar cooling capacity but higher cooling efficiency compared to the coarse-grain one, taking advantage of more martensite, particularly the major variant, produced if provided with the same transformable area (excluding the grain boundaries). Besides, a steeper gradient in structures is prone to alter the composition of martensite variants and more non-major variants are demanded to alleviate the developing deformation mismatch among layers with different grain sizes.

最近有报道称,引入梯度结构是调整镍钛机械行为并同时改善其弹性效应的一种实用方法。本研究采用考虑晶体塑性的热-机械弱耦合相场模型来研究与梯度结构相关的弹性效应的微观机制,特别是从应力和马氏体变体之间的双向相互作用的角度进行研究。建立了一组多晶系统,通过晶粒尺寸梯度完成从细粒试样到粗粒试样的渐变。超弹性模拟过程中逐渐变化的机械响应和转变特性体现了晶粒结构作为材料特性调节器的有效性。接下来进行的布雷顿循环模拟围绕着进一步验证所提出的模型以及对晶粒结构影响的变异相关解释展开。与应力和温度历史相关的预测与实验结果非常吻合,更值得注意的是,在布雷顿循环第一次保持应力下降期间观察到的线性应力-温度关系完全符合经典的克劳修斯-克拉皮隆关系。与马氏体重新取向一起,传播马氏体相(其中不断增加的非大变体是与外部应力优先对齐的大变体的必要补充)在很大程度上造成了这种应力下降。在弹性热效应方面,梯度结构与粗晶粒结构相比,冷却能力非常接近,但冷却效率更高,因为如果提供相同的可转变区域(不包括晶界),会产生更多的马氏体,尤其是主要变体。此外,较陡的梯度结构容易改变马氏体变体的组成,需要更多的非主要变体来缓解不同晶粒尺寸层之间正在形成的变形不匹配。


Thin-Walled Structures

Net section tension capacity of high strength steel single shear bolted connections

Lin Xue-Mei, Yam Michael C.H., Song Yuchen, Chung Kwok-Fai, Ho Ho-Cheung, Han Yawei

doi:10.1016/j.tws.2023.111371

高强度钢单剪切螺栓连接的净截面拉伸能力

Single shear bolted connections under tension usually exhibit out-of-plane deformation due to the inherent load eccentricity, resulting in significant stress concentration around the bolt holes and a stress gradient through the plate thickness. This effect is particularly pronounced in high-strength steel (HSS) connections due to the relatively lower ductility and tensile-to-yield strength ratio of HSS. However, it remains unclear whether this issue can lead to premature fracture in high strain regions before effective stress redistribution develops across the net section, subsequently reducing the ultimate load capacity of the HSS connections. To examine the above design issue, an experimental and numerical study on single shear bolted connections was conducted and reported in this paper. A total of 25 connections were tested, among which 17 were made of HSS (Q690 and Q960), and 8 were made of Q345 mild steel (MS). Based on a validated finite element (FE) model, a comprehensive numerical analysis was carried out to interpret the structural behaviour of the specimens and explore the influence of various design parameters on the ultimate tension capacity of single shear bolted connections. The findings revealed that, despite the existence of out-of-plane deformation in the steel plate, all connections (either MS or HSS) investigated in this study reached the theoretical net section resistance (the product of the net section area and the ultimate tensile strength). This is because (1) the relatively low ductility and tensile-to-yield strengths ratio of HSS materials are still sufficient to allow an effective stress redistribution across both the transverse net section and the plate thickness, and (2) the biaxial stress state around the bolt holes enhances the tension capacity of the net section. Finally, a statistical evaluation of the combined test and numerical data showed that the existing design equations for predicting the net section tension capacity of HSS (specified in EN 1993-1-12:2007 and prEN 1993-1-1:2020) can be safely applied to the design of HSS single shear bolted connections, even in scenarios where the tensile-to-yield strengths ratio of HSS is as low as 1.06.

拉伸状态下的单剪切螺栓连接通常会因固有的负载偏心而产生平面外变形,从而导致螺栓孔周围出现明显的应力集中和板厚的应力梯度。由于高强度钢(HSS)的延展性和拉伸与屈服强度比相对较低,因此这种效应在高强度钢(HSS)连接中尤为明显。然而,目前仍不清楚这一问题是否会导致在净截面上形成有效的应力再分布之前,高应变区域过早断裂,从而降低高速钢连接的极限承载能力。为研究上述设计问题,本文对单剪切螺栓连接进行了实验和数值研究,并在文中进行了报告。共测试了 25 个连接件,其中 17 个由高速钢(Q690 和 Q960)制成,8 个由 Q345 低碳钢(MS)制成。在经过验证的有限元(FE)模型的基础上,进行了全面的数值分析,以解释试样的结构行为,并探讨各种设计参数对单剪切螺栓连接的极限拉伸能力的影响。研究结果表明,尽管钢板存在平面外变形,但本研究中的所有连接(MS 或 HSS)都达到了理论净截面阻力(净截面面积与极限抗拉强度的乘积)。这是因为:(1) 高速钢材料的延展性和抗拉强度与屈服强度之比相对较低,但仍足以在横向净截面和钢板厚度上实现有效的应力再分布;(2) 螺栓孔周围的双轴应力状态增强了净截面的抗拉能力。最后,对综合测试和数值数据的统计评估表明,现有的预测高速钢净截面拉伸能力的设计方程(EN 1993-1-12:2007 和 prEN 1993-1-1:2020)可以安全地应用于高速钢单剪切螺栓连接的设计,即使在高速钢的拉伸强度与屈服强度比低至 1.06 的情况下也是如此。


Energy absorption of a bio-inspired cylindrical sandwich structure

Ha Ngoc San, Lee Ting-Uei, Ma Jiaming, Li Jie, Xie Yi Min

doi:10.1016/j.tws.2023.111378

受生物启发的圆柱形夹层结构的能量吸收

This research investigates the energy absorption capability of a new bio-inspired cylindrical sandwich structure (BCSS). The sandwich core of the BCSS is designed to mimic the skeletal system of deep-sea glass sponge, which has a square lattice architecture reinforced by diagonal bracings. In this study, energy absorption characteristics are numerically evaluated, with results compared to those of conventional cylindrical sandwich structures with typical lattice and foam cores. It is found that the BCSS has significantly higher energy absorption capacity. In detail, the specific energy absorption of the BCSS is 31.2%, 18.1% and 24.4% higher than those of conventional cylindrical sandwich structures with the kagome, square and foam cores, respectively. Furthermore, a parametric study is performed which reveals that the cell number and the wall thickness of both the core and the skins are key factors determining the energy absorption capacity of the BCSS. Finally, a theoretical derivation is developed to conveniently predict the mean crushing force of the BCSS. This research sheds light on using biomimetic approaches to design an advanced composite structure with high energy absorption efficiency.

本研究探讨了一种新型生物启发圆柱夹层结构(BCSS)的能量吸收能力。BCSS 的夹层核心是模仿深海玻璃海绵的骨架系统设计的,它具有由对角支撑加固的方格结构。在这项研究中,对能量吸收特性进行了数值评估,并将结果与具有典型晶格和泡沫夹芯的传统圆柱形夹层结构进行了比较。结果发现,BCSS 的能量吸收能力明显更高。具体而言,BCSS 的比能量吸收能力分别比采用卡格姆、方形和泡沫芯材的传统圆柱形夹层结构高出 31.2%、18.1% 和 24.4%。此外,参数研究表明,芯材和表皮的单元数和壁厚是决定 BCSS 能量吸收能力的关键因素。最后,通过理论推导,可以方便地预测 BCSS 的平均压碎力。这项研究揭示了如何利用仿生方法来设计具有高能量吸收效率的先进复合材料结构。



来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemInspireDeform疲劳断裂复合材料碰撞非线性化学通用航空航天核能汽车裂纹理论材料螺栓
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【新文速递】2023年11月19日复合材料SCI期刊最新文章

今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 3 篇,Composites Part B: Engineering 2 篇,Composites Science and Technology 2 篇Composite StructuresMechanical properties and failure behaviors of T1100/5405 composite T-joint under in-plane shear load coupled with initial defect and high-temperatureLi Guowei, Cao Ertai, Jia Ben, Zhang Xuanjia, Wang Wenzhi, Huang Heyuandoi:10.1016/j.compstruct.2023.117722T1100/5405 复合材料 T 型接头在平面剪切载荷、初始缺陷和高温作用下的力学性能和失效行为The T1100/5405, a novel carbon fiber resin matrix composite, boasts superior specific strength, stiffness, and broad applicability. This study rigorously investigated the in-plane shear performance and thermally coupled damage failure mechanisms of this composite in a T-joint context under initial defects, being highly relevant for hypersonic vehicles in high-temperature environments. Experimental tests yielded mechanical property parameters and in-plane shear data for varying test temperatures (25℃, 150℃) and defect radius (0mm, 15mm). Compared to flawless samples at room temperature, the synergistic impact of high temperature and defects expedited the structural damage failure process, reducing load-bearing capabilities significantly. A numerical model was established based, on the inherent structural relationship of the cohesive zone model and the continuum damage mechanics of the composite, whose accuracy was confirmed by experimental data. Further analysis revealed that a high-temperature environment would exacerbate the damage failure process of initial defects. Specifically, as the temperature rose, the defect radius increased, thus diminishing the shear capacity of T-joint. The maximum structural ultimate load has been reduced by 67.54%, which was perfectly aligned with experimental results. Consequently, the study provides practical insights for the structural design of hypersonic vehicle composite.T1100/5405 是一种新型碳纤维树脂基复合材料,具有优异的比强度、刚度和广泛的适用性。本研究严格研究了这种复合材料在初始缺陷条件下 T 型接头的面内剪切性能和热耦合损伤失效机制,这与高温环境下的高超音速飞行器高度相关。实验测试得出了不同测试温度(25℃、150℃)和缺陷半径(0 毫米、15 毫米)下的机械性能参数和平面剪切数据。与室温下的无缺陷样品相比,高温和缺陷的协同影响加速了结构的破坏过程,大大降低了承载能力。根据内聚区模型的固有结构关系和复合材料的连续损伤力学,建立了一个数值模型,其准确性得到了实验数据的证实。进一步的分析表明,高温环境会加剧初始缺陷的损坏失效过程。具体来说,随着温度的升高,缺陷半径增大,从而降低了 T 型接头的抗剪能力。最大结构极限载荷降低了 67.54%,与实验结果完全一致。因此,该研究为高超音速飞行器复合材料的结构设计提供了实用的启示。Composites Part A: Applied Science and ManufacturingFacile fabrication of low-content surface-assembled MXene in silicone rubber foam materials with lightweight, wide-temperature mechanical flexibility, improved flame resistance and exceptional smoke suppressionChen Hai-Yang, Li Yang, Wang Peng-Huan, Qu Zhang-Hao, Qin Yu-Qing, Yang Ling, Li Jia-Yun, Gong Li-Xiu, Zhao Li, Zhang Guo-Dong, Gao Jie-Feng, Tang Long-Chengdoi:10.1016/j.compositesa.2023.107907在硅橡胶泡沫材料中轻松制造低含量表面组装 MXene,具有轻质、宽温机械柔性、更好的阻燃性和优异的抑烟性能Silicone rubber foam (SiRF) is a promising porous material that is widely applied in various fields. However, its intrinsic flammability nature remains a significant challenge. One of the simplest and most economical solutions is to incorporate high content flame-retardant fillers. Unfortunately, such approach is limited by several drawbacks, including poor filler dispersion, difficulty in processing and negative effect on mechanical flexibility. Herein, we report a green and facile strategy for surface-assembling ultralow content of MXene sheets bonded onto the pore surface of SiRF via the effective foaming reaction process. The as-prepared MSiRF-0.2 composite at 0.2 wt% MXene exhibited lightweight characteristic, wide-temperature mechanical flexibility, UL94-V0 grade, limited oxygen index of >27%, and exceptional smoke suppression (reduction by 88.24%). Furthermore, flame-retardant mechanism was discussed based on the char structure observation. This study provides a novel approach for fabricating mechanically flexible and flame-retardant SiRF via in-situ reactive assembly of low content MXene sheets.硅橡胶泡沫(SiRF)是一种前景广阔的多孔材料,被广泛应用于各个领域。然而,其固有的易燃性仍然是一个重大挑战。最简单、最经济的解决方案之一是加入高含量阻燃填料。遗憾的是,这种方法受到几个缺点的限制,包括填料分散性差、加工困难以及对机械柔韧性的负面影响。在此,我们报告了一种绿色简便的策略,即通过有效的发泡反应过程将超低含量的 MXene 片材粘合到 SiRF 的孔隙表面进行表面组装。所制备的 MXene 含量为 0.2 wt% 的 MSiRF-0.2 复合材料具有轻质特性、宽温机械柔韧性、UL94-V0 等级、限氧指数大于 27% 以及优异的烟雾抑制性能(减少 88.24%)。此外,还根据炭结构观察探讨了阻燃机理。这项研究为通过低含量 MXene 片材的原位反应组装制造具有机械柔韧性和阻燃性的 SiRF 提供了一种新方法。Triple-shape memory polybenzoxazine resins and their compositesLuo Lan, Niu Zhihong, Hu Rongxiang, Zhang Fenghua, Liu Yanju, Leng Jinsongdoi:10.1016/j.compositesa.2023.107910三重形状记忆聚苯并恶嗪树脂及其复合材料Shape memory polymer (SMP) as a new type of smart material can be programmed into a temporary shape by external excitation. Benzoxazine is a novel thermosetting resin with excellent heat resistance, high glass transition temperature (Tg) and mechanical properties. Here, triple-shape memory polybenzoxazines with high Tg were obtained by copolymerization of phenol/polyetheramine with phenol/furanamine benzoxazines. Electrically driven composites were prepared using multi-walled carbon nanotubes, and the SMP electrically driven function was achieved by forming a complete and continuous conductive permeable network inside the composites, shape recovery can be completed in 15 s at 60v. Furthermore, at high temperatures the carbon residue rate is increased to 45 % at 800 °C, demonstrating the high performance of electrically driven shape memory polymer composites. The realization of the triple and electrically induced shape memory properties of shape memory polybenzoxazines broadens the way for their application in extreme high-temperature environments in aerospace and aviation.形状记忆聚合物(SMP)作为一种新型智能材料,可在外部激励下被编程为临时形状。苯并恶嗪是一种新型热固性树脂,具有优异的耐热性、高玻璃化转变温度(Tg)和机械性能。在这里,通过苯酚/聚醚胺与苯酚/呋喃胺苯并噁嗪的共聚,获得了具有高 Tg 的三重形状记忆聚苯并噁嗪。利用多壁碳纳米管制备了电驱动复合材料,并通过在复合材料内部形成完整连续的导电渗透网络实现了 SMP 电驱动功能,在 60v 下 15 秒内即可完成形状恢复。此外,在高温条件下,800 °C 时的碳残留率提高到 45%,证明了电驱动形状记忆聚合物复合材料的高性能。形状记忆聚苯并恶嗪的三重形状记忆特性和电致形状记忆特性的实现,为其在航空航天领域极端高温环境中的应用拓宽了道路。Flexible Multiwalled Carbon Nanotubes/cellulose nanofibers Membrane with Rapid Temperature Increasing Induced by Interface StrengtheningChen Siyao, Chen Zhiyu, Ou Yangling, Lyu Junwei, Li Junning, Liu Xiangyang, Liu Yangdoi:10.1016/j.compositesa.2023.107911通过界面强化快速升温的柔性多壁碳纳米管/纤维素纳米纤维膜Towards advanced electrical heaters with superior Joule heating property, high electrical conductivity has always been critical issue. Herein, in addition to the commonly recognized factor of electrical conductivity, we proved that the composite interface poses significant effect on temperature increasing as electrical heaters. Specifically, direct fluorination utilizing F2/N2 was applied to selectively decorate the outer walls of multiwalled carbon nanotubes (MWCNTs) while keeping the inner tube intact, which was followed by compositing it with cellulose nanofibers (CNFs) to prepare F-MWCNTs/CNFs flexible membrane. Due to the enhanced electrostatic interaction at the interface and stronger phonon vibrational coupling, interfacial phonon diffusion was significantly improved, which facilitated a higher temperature increase rate in the F-MWCNTs/CNFs membrane compared to the unmodified MWCNTs/CNFs membrane when subjected to an electric field. This unique interfacial effect holds promise for the development of high-performance electrical heaters with rapid response.为了实现具有卓越焦耳加热特性的先进电加热器,高导电率一直是一个关键问题。在本文中,除了公认的导电率因素外,我们还证明了复合界面对电热片的升温具有显著影响。具体来说,我们利用 F2/N2 直接氟化技术选择性地装饰了多壁碳纳米管(MWCNT)的外壁,同时保持内管完好无损,然后将其与纤维素纳米纤维(CNFs)复合,制备出 F-MWCNTs/CNFs 柔性膜。由于界面上的静电相互作用增强,声子振动耦合加强,界面声子扩散显著改善,与未改性的 MWCNTs/CNFs 膜相比,F-MWCNTs/CNFs 膜在电场作用下的升温速率更高。这种独特的界面效应为开发快速响应的高性能电加热器带来了希望。Composites Part B: EngineeringSilicon carbide fiber manufacturing: Cost and technologyYilmaz Sefa, Theodore Merlin, Ozcan Soydandoi:10.1016/j.compositesb.2023.111101碳化硅纤维制造:成本与技术Significant advances have been made in the past decade concerning silicon carbide fiber manufacturing methods resulting in near-stoichiometric small-diameter fibers that meet the property requirements for most of the ceramic matrix composites (CMC) and nuclear applications. The manufacturing cost, however, remained prohibitively high, preventing the use of it in different applications requiring much lower cost. Silicon carbide (SiC) fiber reinforced CMC is dominated by the cost of SiC fiber which comprises more than 50 % of the finished part cost. This article provides insight into the SiC fiber manufacturing costs and highlights the need for an alternative SiC fiber precursor and manufacturing method. Analysis of the existing polycarbosilane (PCS)-based SiC fiber manufacturing shows that the crosslinking (curing) and raw material preparation steps are high-cost steps that need lower cost options. Alternative SiC fiber precursor should be sought for lowering the cost of SiC fibers.在过去十年中,碳化硅纤维制造方法取得了重大进展,制造出了接近碳原子计量的小直径纤维,满足了大多数陶瓷基复合材料(CMC)和核应用的性能要求。然而,其制造成本仍然过高,无法用于成本要求低得多的不同应用领域。碳化硅(SiC)纤维增强 CMC 的主要成本是碳化硅纤维的成本,占成品部件成本的 50%以上。本文深入分析了碳化硅纤维的制造成本,并强调了替代碳化硅纤维前体和制造方法的必要性。对现有基于聚碳硅烷(PCS)的碳化硅纤维制造方法的分析表明,交联(固化)和原材料制备步骤成本较高,需要成本更低的方案。为降低碳化硅纤维的成本,应寻找替代的碳化硅纤维前驱体。Interlaminar shear strength of Carbon/PEEK thermoplastic composite laminate: Effects of in-situ consolidation by automated fiber placement and autoclave re-consolidationPourahmadi Emad, Shadmehri Farjad, Ganesan Rajamohandoi:10.1016/j.compositesb.2023.111104碳/PEEK 热塑性复合材料层压板的层间剪切强度:通过自动纤维铺放和高压釜再固化进行原位固结的影响Automated manufacturing techniques, such as Automated Fiber Placement (AFP), offer an opportunity over conventional manufacturing methods, such as autoclave curing, to save time and expenses. The present research focuses on evaluating the Interlaminar Shear Strength (ILSS) of Carbon/PEEK thermoplastic composite laminates manufactured by AFP in-situ consolidation and autoclave re-consolidation using the Short-Beam Shear (SBS) test. Additionally, a methodology is proposed to capture the differences observed in ILSS using a finite element simulation. In this respect, a thermoplastic laminate was fabricated using AFP in-situ consolidation. Baseline laminate was also produced by re-consolidating another AFP-made laminate inside the autoclave. A micrographic study was conducted to investigate the void content and fiber distribution resulting from each manufacturing process. The test results showed that the AFP technique results in an ILSS of the laminate that is 37 % lower than that of the autoclave-reconsolidated laminate. The distinct mechanical behaviour in the SBS test arising from in-situ consolidation and autoclave re-consolidation was differentiated in the finite element modeling utilizing cohesive elements. This distinction was achieved by numerically finding the proper interface strength properties based on the SBS experimental results. These interface properties serve as valuable input parameters for conducting further finite element modeling and analyses of Carbon/PEEK thermoplastic composite laminates manufactured by AFP in-situ consolidation.与高压固化等传统制造方法相比,自动纤维铺放(AFP)等自动化制造技术可节省时间和费用。本研究的重点是利用短梁剪切(SBS)试验,评估通过 AFP 原位固化和高压釜再固化制造的碳/PEEK 热塑性复合材料层压板的层间剪切强度(ILSS)。此外,还提出了一种利用有限元模拟捕捉 ILSS 中观察到的差异的方法。为此,使用 AFP 原位固结法制造了一种热塑性层压板。通过在高压釜内重新固结另一种 AFP 制成的层压板,还制作了基准层压板。对每个制造过程中产生的空隙含量和纤维分布进行了显微照片研究。测试结果表明,AFP 技术使层压板的 ILSS 比高压釜再固化层压板低 37%。在 SBS 试验中,原位固结和高压釜再固结所产生的不同机械性能在利用内聚元素进行的有限元建模中得到了区分。根据 SBS 试验结果,通过数值计算找到了适当的界面强度属性,从而实现了这种区分。这些界面属性是对通过 AFP 原位固结法制造的碳/PEEK 热塑性复合材料层压板进行进一步有限元建模和分析的重要输入参数。Composites Science and TechnologyMetal coordination in polymer drives efficient phonon transfer through self-assembled microstructuresZheng Shuxin, Mu Liwen, Zhang Suoying, Lu Xiaohua, Zhu Jiahuadoi:10.1016/j.compscitech.2023.110348 聚合物中的金属配位通过自组装微结构驱动高效声子传递Molecular interactions such as hydrogen bond, van der Waals force, covalent bond in association with heat transfer in polymeric materials have been reported, while the relationship between metal-polymer coordination and thermal conduction has not been studied yet. In this work, the molecularly-assembled microstructure of the composites produced by metal coordination with polyvinyl alcohol (PVA) reveals a qualitative correlation between microstructure and thermal conductivity (TC). The ellipsoid-shaped domain and increased coil size create stable phonon transmission channels, which are beneficial for boosting TC by lengthening the mean free path of phonon propagation. Strong coordination between the metal ions and the hydroxyl groups in the polyvinyl alcohol chains results in competition between the inter- and intra-molecular OH–OH hydrogen bonds, which eventually takes precedence. Such coordination structure creates distinctive micro-crystal domains and is discovered to be essential for TC enhancement. Moreover, the power generation value of thermal conversion using PVA-H/2.0Fe(NO3)3 film is twice that of pure PVA-H film, which has higher and faster conversion efficiency. These materials have been demonstrated as excellent candidates for improving the conversion efficiency of thermoelectric devices. In summary, this work offers a new strategy for regulating TC through metal coordination and a fundamental comprehension of the link between metal coordination, microstructure, and TC in polymer composites.氢键、范德华力、共价键等分子相互作用与高分子材料的热传导有关的研究已有报道,而金属-聚合物配位与热传导之间的关系尚未研究。在这项研究中,金属与聚乙烯醇(PVA)配位产生的复合材料的分子组装微观结构揭示了微观结构与热导率(TC)之间的定性相关性。椭圆形畴和增大的线圈尺寸形成了稳定的声子传输通道,通过延长声子传播的平均自由路径,有利于提高热导率。金属离子与聚乙烯醇链中的羟基之间的强烈配位导致分子间和分子内 OH-OH 氢键之间的竞争,最终以后者优先。这种配位结构形成了独特的微晶畴,被认为是提高热导率的关键。此外,使用 PVA-H/2.0Fe(NO3)3 薄膜进行热转换的发电值是纯 PVA-H 薄膜的两倍,转换效率更高、更快。这些材料已被证明是提高热电设备转换效率的绝佳候选材料。总之,这项工作提供了一种通过金属配位调节热电转换效率的新策略,并从根本上理解了聚合物复合材料中金属配位、微观结构和热电转换效率之间的联系。Tailoring the mechanical and combustion performance of B/HTPB composite solid fuel with covalent interfacesJiang Yue, Leem Juyoung, Robinson Ashley M., Wu Shuai, Huynh Andy H., Ka Dongwon, Zhao Ruike Renee, Xia Yan, Zheng Xiaolindoi:10.1016/j.compscitech.2023.110350 利用共价界面定制 B/HTPB 复合固体燃料的机械和燃烧性能The development of high-performing solid fuels with desired mechanical and combustion properties is critical to future air-breathing propulsion systems for space exploration and hypersonic navigation. Boron (B)/hydroxyl-terminated polybutadiene (HTPB) composite has been studied for this purpose due to the high energy density (heat of combustion) of B and the appropriate processability and mechanical properties of HTPB. However, the weak interface between B and HTPB results in weakened mechanical properties, agglomerated B particles, and slow and inefficient combustion, especially for composites with high B loading (30 wt% and above). In this study, the effect of interface between B and HTPB on the combustion and mechanical performance of high-loading B/HTPB composites was investigated by surface functionalization of B particles. Three interfacial characteristics were compared: polar (pristine B)/nonpolar (HTPB), nonpolar (hydrocarbon-functionalized B)/nonpolar (HTPB), and covalently bonded (amine-functionalized B/HTPB) interfaces. It was found that both covalently bonded and nonpolar/nonpolar interfaces effectively reduced the aggregation of B particles in the HTPB matrix, even with up to 45 wt% B loading, thus promoting the combustion efficiency and burning rate. Moreover, covalently bonded interfaces in B/HTPB composites led to strain-hardening behaviors, resulting in enhanced strength, ductility, and toughness. This work highlights the significance of interface engineering in B/HTPB composites for the efficacy and safety of future air-breathing solid-fueled propulsion devices.开发具有理想机械和燃烧特性的高性能固体燃料对于未来用于太空探索和高超音速导航的喷气推进系统至关重要。硼(B)/羟基封端聚丁二烯(HTPB)复合材料因其硼的高能量密度(燃烧热)以及 HTPB 的适当加工性和机械性能而被用于这一目的的研究。然而,硼和 HTPB 之间的弱界面会导致机械性能减弱、硼颗粒团聚、燃烧缓慢且效率低下,尤其是在硼含量较高(30 wt% 及以上)的复合材料中。本研究通过对 B 颗粒进行表面官能化处理,研究了 B 与 HTPB 之间的界面对高负载 B/HTPB 复合材料燃烧和机械性能的影响。比较了三种界面特性:极性界面(原始 B)/非极性界面(HTPB)、非极性界面(烃官能化 B)/非极性界面(HTPB)和共价键界面(胺官能化 B/HTPB)。研究发现,共价键界面和非极性/非极性界面都能有效减少 B 粒子在 HTPB 基质中的聚集,即使 B 的负载量高达 45 wt%,也能有效减少 B 粒子的聚集,从而提高燃烧效率和燃烧速率。此外,B/HTPB 复合材料中的共价键界面导致了应变硬化行为,从而提高了强度、延展性和韧性。这项研究强调了 B/HTPB 复合材料界面工程对于未来喷气式固体燃料推进装置的有效性和安全性的重要意义。来源:复合材料力学仿真Composites FEM

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