今日更新:Composite Structures 4 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 4 篇,Composites Science and Technology 1 篇
Effective modulus of 3D-printable curvilinear fiber reinforced composites
Tengyuan Hao, Javid Mustafa, Garrett Gray, Zubaer Hossain
doi:10.1016/j.compstruct.2023.117811
三维打印曲线纤维增强复合材料的有效模量
This paper presents the coupling between curvilinearity and effective modulus for a set of mathematically admissible high-symmetry and low-symmetry fiber architectures. The contour of the fiber is decomposed into a series of unidirectional short segments and effective modulus is determined using an integration scheme that combines theoretical analysis and finite element simulations. Results show that the modulus of low-symmetry sinusoidal and hyperbolic tangent fibers varies nonlinearly with orientation and controlled by the segments forming the smallest direction cosine with the loading direction. Both the orientation of the midline and amplitude of the fibers strongly influence the effective behavior. For unidirectional fiber reinforced composites, results reveal the existence of a critical fiber-orientation angle of 60° where the modulus is minimum. Fibers are the majority stress carrier below 60°, and above this angle, the matrix carries the load. The approach is applicable to fiber-based composites of arbitrary fiber geometries, and the findings are expected to advance the design of additively manufactured complex composite structures.
本文介绍了一组数学上可接受的高对称性和低对称性光纤结构的曲线性和有效模量之间的耦合。纤维的轮廓被分解成一系列单向短段,并采用理论分析和有限元模拟相结合的积分方案确定有效模量。结果表明,低对称性正弦和双曲切线纤维的模量随取向呈非线性变化,并受与加载方向形成最小余弦方向的纤维段控制。纤维中线的取向和振幅都对有效行为有很大影响。对于单向纤维增强复合材料,结果显示存在一个临界纤维取向角,即模量最小的 60°。在 60° 以下,纤维是主要的应力载体,而在该角度以上,基体则承担载荷。该方法适用于任意纤维几何形状的纤维基复合材料,研究结果有望推动添加式制造复杂复合材料结构的设计。
Quasi-3D free and forced vibrations of poroelastic microplates in the framework of modified couple stress theory
Behrouz Karami, Mergen H. Ghayesh, Nicholas Fantuzzi
doi:10.1016/j.compstruct.2023.117840
修正耦合应力理论框架下孔弹性微板的准三维自由振动和受迫振动
In this study, a comprehensive study on the vibration behaviour of functionally graded thick microplates with material imperfections is presented for free and forced vibrations within a quasi-3D model and the modified couple stress (MCS) theory. Axial, transverse, rotation, and stretching motions are considered for modelling the thick microplate in the framework of the modified power-law scheme and quasi-3D and MCS theories. The microplate deformation is assumed to be infinitesimal and is modelled using the linear strain–displacement relationships. Using a virtual work method, the governing motion equations are derived. For fourfold coupled (axial-transverse-rotation-stretching) characteristics, the partial differential equations components are discretised via trigonometric expressions and the corresponding natural frequencies and time histories (time-dependent deflections) are determined numerically. The methodology and model are initially validated through a comparative analysis between the natural frequencies of the macrolevel simplified structure and those obtained using finite element software. Additionally, the simulation is compared, for validation purposes, with other simplified versions from the literature. Once model's validity is confirmed, an investigation into the quasi-3D free and forced vibrations of the structure is conducted for the new model. The results demonstrate the considerable effect of thickness stretching and material imperfection on the vibration characteristics of the poroelastic thick microplates.
在本研究中,针对准三维模型和修正耦合应力(MCS)理论中的自由振动和受迫振动,对具有材料缺陷的功能分级厚微板的振动行为进行了全面研究。在修正幂律方案、准三维和 MCS 理论的框架内,考虑了厚微板建模时的轴向、横向、旋转和拉伸运动。微板变形被假定为无限小,并使用线性应变-位移关系建模。利用虚功方法推导出支配运动方程。对于四重耦合(轴向-横向-旋转-拉伸)特性,通过三角函数表达式对偏微分方程成分进行离散化,并通过数值确定相应的固有频率和时间历程(随时间变化的挠度)。通过对宏观简化结构的固有频率和使用有限元软件获得的固有频率进行比较分析,初步验证了该方法和模型。此外,还将模拟结果与文献中的其他简化版本进行比较,以进行验证。一旦模型的有效性得到确认,就会针对新模型对结构的准三维自由振动和受迫振动进行研究。结果表明,厚度拉伸和材料缺陷对孔弹性厚微板的振动特性有相当大的影响。
Experimental and simulation study on surface material stripping of Glass Fiber Reinforced Composites by baking soda abrasive Jetting Technology
Jiale Xu, Zhouyu Jiang, Mingzhu Yang, Xiaowen Zhang, Mingliang Wang
doi:10.1016/j.compstruct.2023.117842
小苏打喷射技术对玻璃纤维增强复合材料表面材料剥离的实验和模拟研究
Glass fiber reinforced composites (GFRP) working in a specific environment require regular inspection and maintenance. It is necessary to remove the surface material of fiber reinforced composites to check the fracture of fibers and the damage to matrix that binds fibers in this process. In this paper, the baking soda abrasive jetting was utilized to strip the surface material of glass fiber reinforced epoxy resin (GFREP). The stripping effects of baking soda abrasive jetting technology under different jetting parameters (fiber orientation, jet angle, jet pressure) were explored, and the optimum stripping conditions were determined as parallel to the fiber, 30°, 0.4MPa. Compared with the chemical stripping method (phenol-dichloromethane), baking soda abrasive jetting can better retain epoxy resin between glass fibers. The LS-DYNA was applied to simulate the erosion process of a single abrasive particle under the optimum stripping condition. The plastic deformation of the matrix and the slight bending deformation of the glass fiber under abrasive impact were observed.
在特定环境中工作的玻璃纤维增强复合材料(GFRP)需要定期检查和维护。在此过程中,有必要去除纤维增强复合材料的表面材料,以检查纤维的断裂情况以及粘结纤维的基体的损坏情况。本文利用小苏打磨料喷射来剥离玻璃纤维增强环氧树脂(GFREP)的表面材料。探讨了小苏打磨料喷射技术在不同喷射参数(纤维方向、喷射角度、喷射压力)下的剥离效果,确定了最佳剥离条件为平行于纤维、30°、0.4MPa。与化学剥离法(苯酚-二氯甲烷)相比,小苏打磨料喷射法能更好地保留玻璃纤维间的环氧树脂。应用 LS-DYNA 模拟了在最佳剥离条件下单个磨料颗粒的侵蚀过程。在磨料冲击下,基体发生了塑性变形,玻璃纤维也发生了轻微的弯曲变形。
A viscoelastic-plastic model for the temperature-dependent creep and recovery behavior during dry fiber fabric compaction
Yanpeng Si, Lishuai Sun, Junzhen Chen, Zhiyong Zhao, Jianjun Jiang, Yujun Li
doi:10.1016/j.compstruct.2023.117843
干纤维织物压实过程中随温度变化的蠕变和恢复行为的粘弹性塑料模型
The preforming process of dry fiber fabric usually involves compaction under constant pressure and specific temperature during fiber-reinforced composite manufacturing. The fabric exhibits time- and temperature-dependent considerable permanent deformation and creep/recovery behavior in compaction. A better understanding of these phenomena, combined with the ability to predict the behavior, will contribute to better control of fiber volume fraction and material composition. This study presented a universal viscoelastic-plastic model to represent the fabric’s visco-effect in compression and recovery stages. The proposed model consisted of a modified Burges element for time-dependent deformation and a plastic element for permanent deformation that occurs in all cases. It used only one set of equations and one set of parameters to characterize the cyclic loading/unloading and the compaction and relaxation phases. It could consider the material densification effect observed experimentally. The model was validated against experimental data for unidirectional (UD), plain woven, and twill woven fabrics. A reasonable match between experiments and prediction was achieved under different compression scenarios.
在纤维增强复合材料制造过程中,干纤维织物的预成型工艺通常包括在恒定压力和特定温度下进行压实。在压实过程中,纤维织物会表现出与时间和温度相关的相当大的永久变形和蠕变/恢复行为。更好地理解这些现象,并结合预测这些行为的能力,将有助于更好地控制纤维体积分数和材料成分。本研究提出了一种通用的粘弹性塑料模型,用于表示织物在压缩和恢复阶段的粘弹性效应。所提议的模型包括一个用于表示随时间变化的变形的改良伯格斯元素和一个用于表示在所有情况下都会发生的永久变形的塑性元素。该模型仅使用一组方程和一组参数来描述循环加载/卸载以及压实和松弛阶段。它可以考虑实验观察到的材料致密化效应。该模型根据单向(UD)、平纹和斜纹机织物的实验数据进行了验证。在不同的压缩情况下,实验与预测之间实现了合理的匹配。
Fluorinated interface engineering targeting high-performance multifunctional composites of BN/aramid nanofibers
Haoou Ruan, Xiang Yu, Yunpeng Liu, Yixiao Zhang, Sidi Fan, Fangcheng Lv
doi:10.1016/j.compositesa.2023.107975
以 BN/芳纶纳米纤维高性能多功能复合材料为目标的氟化界面工程学
Aramid nanofibers (ANFs)-based composites have attracted considerable interest in electronic and electrical engineering due to their exceptional thermal stability, high strength, and superior insulating properties. However, the performance of ANFs-based composites is severely confined by interfacial issues. Accordingly, a novel strategy of fluorinated interface engineering is proposed herein, by which the fillers are grafted by the fluorine-containing functional groups. The introduction of interfacial fluorination yields a dense and compact composite structure which stems from the improved compatibility at the matrix-filler interfaces. The tensile strength and thermal conductivity are increased by 30% and 50%, respectively. Additionally, the band structure variation is observed in the fluorinated BNNs, where the electron trap states are formed at the interface. With the deepened deep trap depth and increased density, the breakdown strength is enhanced by 50%. The breakdown phase field simulations also indicate the high discharge energy consumption by the fluorination effect.
芳纶纳米纤维(ANFs)基复合材料因其卓越的热稳定性、高强度和优异的绝缘性能,在电子和电气工程领域引起了广泛关注。然而,ANFs 基复合材料的性能受到界面问题的严重限制。因此,本文提出了一种新颖的氟化界面工程策略,通过含氟官能团接枝填料。通过引入界面氟化,基体与填料界面的相容性得到了改善,从而产生了致密、紧凑的复合结构。拉伸强度和热导率分别提高了 30% 和 50%。此外,在氟化 BNN 中还观察到带状结构的变化,即在界面处形成了电子阱态。随着陷阱深度的加深和密度的增加,击穿强度提高了 50%。击穿相场模拟还表明,氟化效应会消耗大量放电能量。
Electrospun photocrosslinkable hydrogel fibrous membrane with metal ion trapping capability as an artificial periosteum to promote bone regeneration
Xi He, Ruideng Wang, Li Wang, Xinbo Wei, Moyan Zhou, Jiarui Tang, Xin Che, Ruichen Wang, Fang Zhou, Haifeng Liu
doi:10.1016/j.compositesb.2023.111147
具有金属离子捕获能力的电纺丝光交联水凝胶纤维膜作为人工骨膜促进骨再生
The periosteum plays a crucial role in both bone development and the healing process of bone fractures. However, few studies have focused on developing artificial periosteum due to the complexity of its construction and the biological risks for clinical practice. To address this issue, we proposed a strategy for the fabrication of a photocrosslinkable natural hydrogel nanofibrous membrane (SFMA-Lap@AcBP) based on methacrylated silk fibroin (SFMA), photoinitiator (Lap), acrylate bisphosphonate (AcBP) through combining electrospinning technology with hydrogel, mimicking the structure and function of periosteum to promote bone regeneration. AcBP were covalently attached to the SFMA hydrogel nanofibrous membrane via conjugation. With the degradation of SFMA-Lap@AcBP hydrogel nanofibrous membrane, the released BP-grafted derivates could promote bone regeneration. Moreover, SFMA-Lap@AcBP hydrogel membranes were found to be able to trap metal ions such as Mg2+ and Ca2+ in vivo, which might play a synergistic role in inducing complete bone regeneration. Furthermore, the hydrogel membranes had excellent cytocompatibility. They could imitate the microenvironment of the extracellular matrix, thereby offering structural and biochemical cues for the adhesion, proliferation, and differentiation of cells, without the need of exogenous cells or inductive growth factors, resulting in a facilitated osteogenesis. After implanting membranes into a cranial periosteal and bone defect in rats, both the amount and quality of new bone in the SFMA-Lap@AcBP group were found to be higher than those in the other groups. Therefore, the hydrogel membrane bionic periosteum was efficient and versatile in inducing bone regeneration, providing a potential strategy to address clinical issues.
骨膜在骨骼发育和骨折愈合过程中都起着至关重要的作用。然而,由于人工骨膜的构造复杂,且在临床实践中存在生物风险,因此很少有研究关注人工骨膜的开发。针对这一问题,我们提出了一种基于甲基丙烯酸化丝纤维素(SFMA)、光引发剂(Lap)和丙烯酸酯双膦酸盐(AcBP)的光交联天然水凝胶纳米纤维膜(SFMA-Lap@AcBP)的制备策略,将电纺丝技术与水凝胶相结合,模拟骨膜的结构和功能,促进骨再生。AcBP 通过共价键连接到 SFMA 水凝胶纳米纤维膜上。随着 SFMA-Lap@AcBP 水凝胶纳米纤维膜的降解,释放出的 BP 接枝衍生物可促进骨再生。此外,研究还发现 SFMA-Lap@AcBP 水凝胶膜能够在体内捕获 Mg2+ 和 Ca2+ 等金属离子,这可能会在诱导完全骨再生方面发挥协同作用。此外,水凝胶膜还具有良好的细胞相容性。它们可以模仿细胞外基质的微环境,从而为细胞的粘附、增殖和分化提供结构和生化线索,而无需外源细胞或诱导生长因子,从而促进骨生成。将水凝胶膜植入大鼠颅骨骨膜和骨缺损处后,发现 SFMA-Lap@AcBP 组新生骨的数量和质量均高于其他组。因此,水凝胶膜仿生骨膜在诱导骨再生方面具有高效性和多功能性,为解决临床问题提供了一种潜在的策略。
Mechanisms of CLDH seeding on hydration kinetics of slag-based geopolymer: Towards aluminosilicate cement phase engineering
Zuhua Zhang, Zhengning Zhou, Huajun Zhu, Ping Duan, Yuan Fang, Zhengwu Jiang
doi:10.1016/j.compositesb.2023.111157
CLDH 播种对矿渣基土工聚合物水化动力学的影响机制:实现铝硅酸盐水泥相工程
Geopolymer and related chemically activated materials are more sustainable aluminosilicate cementitious materials that have less natural materials consumption and CO2 emissions. An intrinsic challenge comes from the lack of sufficient crystalline phases in the binder, which leads to the suffering of volume instability and other issues for this type of cements. This study proposes phase engineering concept, for the first time, and investigates the stargate of using active crystal seeds. Calcined layered double hydroxides (CLDH) was used as a type of seed to understand the impact on hydration kinetics and microstructure of slag-based geopolymer. Through various characterization techniques, it is revealed that during the hydration process of slag, CLDH adsorbs OH− ions and other anions from the solution, leading to a rapid recrystallization and formation of hydrotalcite (Ht) phase. The generated Ht phase serves as nucleation sites, accelerating the formation of C-A-S-H amorphous gel and more Ht phase. Ht nanocrystals consistently exists in the binder, at least in the studied period, together with C-A-S-H nanocrystals and more ordered gel phases. Low modulus of silicate activator is found to enhance the nucleation effect of Ht. This research provides valuable insights into the interactions and mechanisms governing the hydration kinetics and phase evolution in geopolymer, and proves the effectiveness of phase engineering via seeding.
土工聚合物和相关的化学活性材料是更具可持续性的铝硅酸盐胶凝材料,其天然材料消耗量和二氧化碳排放量较少。固有的挑战来自于粘结剂中缺乏足够的结晶相,这导致这类水泥存在体积不稳定等问题。本研究首次提出了相工程概念,并研究了使用活性晶体种子的可能性。煅烧层状双氢氧化物(CLDH)被用作一种种子,以了解其对矿渣基土工聚合物水化动力学和微观结构的影响。通过各种表征技术发现,在矿渣水化过程中,CLDH 会吸附溶液中的 OH- 离子和其他阴离子,导致快速再结晶并形成水滑石(Ht)相。生成的 Ht 相可作为成核点,加速 C-A-S-H 无定形凝胶和更多 Ht 相的形成。至少在研究期间,Ht 纳米晶体始终与 C-A-S-H 纳米晶体和更有序的凝胶相一起存在于粘合剂中。研究发现,硅酸盐活化剂的低模量会增强 Ht 的成核效应。这项研究为了解土工聚合物水化动力学和相演化的相互作用和机制提供了宝贵的见解,并证明了通过播种进行相工程的有效性。
Sustained delivery of chemically modified mRNA encoding amelogenin from self-assembling hydrogels for periodontal regeneration
Jie Pan, Huizhong Tian, Siming Xu, Liwei Zhang, Jiandong Ding, Huijing Wang, Lin Yu, Wei Fu, Xin Liu
doi:10.1016/j.compositesb.2023.111162
利用自组装水凝胶持续传递编码髓鞘素的化学修饰 mRNA,促进牙周再生
Periodontitis is a growing clinical problem worldwide. Despite various approaches that have been devoted to repairing periodontal defects, the clinical outcomes are still limited due to the decline in tissue regenerative potential after periodontitis. Fortunately, chemically modified mRNA (modRNA)-based therapeutics have emerged as a promising strategy to combat incurable diseases. However, the use of modRNA for treating periodontitis is rare and challenging. Herein, a novel therapeutic mRNA platform that allows for sustained delivery and targeted osteogenesis and cementogenesis was developed for periodontal regeneration by combining a self-assembling PLA-PEG-PLA hydrogel and newly synthesized modRNA encoding amelogenin (AMELX) via in vitro transcription. The thermosensitive PLA-PEG-PLA hydrogel significantly prevented modRNA degradation and prolonged the release of encapsulated modRNA by forming an in situ hydrogel depot at 37 °C, resulting in sustained and strong expression of AMELX in human periodontal ligament stem cells (PDLSCs). Moreover, the AMELX modRNA exhibited a great capacity for promoting osteogenesis and cementogenesis of PDLSCs, as evidenced by elevated alkaline phosphatase (ALP) activity, calcium nodule formation, and osteogenesis- and cementogenesis-related gene expression (e.g., ALP, BMP2, CAP, BSP, COL1A1). As a result, after a single local injection, the PLA-PEG-PLA hydrogel enabled AMELX modRNA to persist and release at the defect site, thus successfully regenerating bone and periodontal ligament tissues in periodontal defects of rats. These findings provide a new approach for treating periodontal defects using self-assembling hydrogels to enable safe and effective delivery of AMELX modRNA, thereby offering various possibilities for functional tissue reconstruction with mRNA therapeutics.
牙周炎是全世界日益严重的临床问题。尽管已经有多种方法致力于修复牙周缺陷,但由于牙周炎后组织再生潜力下降,临床效果仍然有限。幸运的是,以化学修饰 mRNA(modRNA)为基础的疗法已经成为一种很有前景的对抗不治之症的策略。然而,使用modRNA治疗牙周炎是罕见和具有挑战性的。在本文中,通过将自组装聚乳酸-聚乙二醇-聚乳酸水凝胶与通过体外转录新合成的编码amelogenin (AMELX)的modRNA结合在一起,开发出了一种新型的治疗mRNA平台,该平台可实现持续递送、靶向成骨和骨水泥生成,用于牙周再生。热敏聚乳酸-聚乙二醇-聚乳酸水凝胶可显著防止modRNA降解,并通过在37 °C下形成原位水凝胶库,延长封装modRNA的释放时间,从而使AMELX在人牙周韧带干细胞(PDLSCs)中得到持续、强有力的表达。此外,AMELX modRNA 在促进牙周韧带干细胞成骨和骨水泥形成方面表现出很强的能力,具体表现为碱性磷酸酶(ALP)活性升高、钙结形成以及成骨和骨水泥形成相关基因(如 ALP、BMP2、CAP、BSP、COL1A1)的表达。因此,在一次局部注射后,PLA-PEG-PLA 水凝胶可使 AMELX modRNA 在缺损部位持续释放,从而成功地使大鼠牙周缺损部位的骨和牙周韧带组织再生。这些发现为利用自组装水凝胶治疗牙周缺损提供了一种新方法,使 AMELX modRNA 能够安全、有效地输送,从而为 mRNA 疗法的功能性组织重建提供了多种可能性。
Degradation of mechanical properties and microstructure evolution of basalt-carbon based hybrid FRP bars in real seawater and sea-sand concrete
Xiangke Guo, Zuquan Jin, Chuansheng Xiong, Bo Pang, Dongshuai Hou, Weihua Li
doi:10.1016/j.compositesb.2023.111163
玄武岩-碳基混合玻璃钢棒材在实际海水和海砂混凝土中的力学性能退化和微观结构演变
The degradation of basalt fibre-reinforced polymer (BFRP) bars induced by alkaline environments hinders their application in seawater and sea-sand concrete (SWSC). The use of carbon fibres (CFs) to partially replace basalt fibres in the preparation of hybrid-FRP (HFRP) bars is an effective method for enhancing the durability of BFRP-bar. To evaluate the effectiveness of using CFs to replace part of the basalt fibres in preparing HFRP bars to enhance the durability of BFRP-bar in real SWSC. The tensile and interlayer interface properties of HFRP bars with different CFs hybrid contents (VCF, %) and arrangements in the SWSC were tested after exposure to seawater at different temperatures. Digital microscopy, scanning electron microscopy, X-ray computed tomography and matrix digestion analysis were used to investigate the microstructural evolution of HFRP bars and SWSC after conditioning. The results showed that the VCF increasing to 10% or 25% significantly alleviated the interlaminar shear strength (ILSS) and tensile strength (TS) losses. The maximum enhancements in the ILSS and TS retention for the SWSC-embedded BFRP bar were 19.12% and 17.55%, respectively. The hybrid CFs changed the failure model of the BFRP-bar. Compared with HFRP bars with CFs in the core, HFRP bars are more likely to deteriorate when the CFs are dispersed circumferentially. The hybrid CFs improved the environmental reduction coefficients (ERC) of TS and ILSS of the HFRP bars. Compared with the SWSC, the ERC of the HFRP bars in the normal concrete was significantly improved.
碱性环境导致玄武岩纤维增强聚合物(BFRP)棒材降解,阻碍了它们在海水和海砂混凝土(SWSC)中的应用。使用碳纤维(CFs)部分替代玄武岩纤维制备混合-FRP(HFRP)棒材是提高 BFRP 棒材耐久性的有效方法。评估使用碳纤维替代部分玄武岩纤维制备 HFRP 棒材以提高 BFRP 棒材在实际 SWSC 中的耐久性的有效性。在不同温度下暴露于海水中后,测试了不同纤维素混合含量(VCF,%)和排列方式的 HFRP 棒材在 SWSC 中的拉伸和层间界面性能。采用数字显微镜、扫描电子显微镜、X 射线计算机断层扫描和基质消解分析来研究调理后 HFRP 棒材和 SWSC 的微观结构演变。结果表明,VCF 增加到 10% 或 25% 后,层间剪切强度(ILSS)和拉伸强度(TS)的损失明显减少。嵌入 SWSC 的 BFRP 棒材的层间剪切强度(ILSS)和拉伸强度(TS)最大保持率分别提高了 19.12% 和 17.55%。混合 CF 改变了 BFRP 棒的破坏模式。与芯部含有 CF 的高频复合材料棒材相比,当 CF 在圆周上分散时,高频复合材料棒材更容易劣化。混合 CF 提高了高频复合材料棒材的 TS 和 ILSS 环境降低系数 (ERC)。与 SWSC 相比,普通混凝土中 HFRP 钢筋的 ERC 得到了显著改善。
Understanding the behaviors of ZIF-67 reinforced electrospun carbon nanofibers in the preparation and stabilization
Xiangjie Gong, Tao Yang, Yan Song, Xiaodong Tian, Zihui Ma, Zhanjun Liu
doi:10.1016/j.compscitech.2023.110403
了解 ZIF-67 增强电纺碳纳米纤维在制备和稳定过程中的行为
MOFs-reinforced electrospun carbon nanofibers offer a wide range of applications in the field of energy storage. In this study, ZIF-67 nanoparticles were produced and combined with polyacrylonitrile for electrospinning before being stabilized and carbonized to form a carbon nanofiber. BET, FT-IR, EA, DSC, and other techniques were used to investigate the stabilizing behaviors of PAN electrospun fiber with varying ZIF-67 concentrations at different temperatures. Under the same stabilizing settings, it was discovered that PAN electrospun fiber containing ZIF-67 nanoparticles could absorb more oxygen, promoting a higher degree of cyclization and crosslinking. Therefore, it was preferred to prepare carbon nanofibers at a lower stabilization temperature. Importantly, the degree of stability and disorder of the PAN/ZIF-67 stabilized fiber has been described by the FT-IR and the Raman spectra. This research deepens understanding about the formation of MOF-reinforced carbon nanofibers and expands our knowledge of the stability of PAN/MOF hybrid fibers.
MOFs 增强电纺碳纳米纤维在储能领域有着广泛的应用。在本研究中,制备了 ZIF-67 纳米粒子,并将其与聚丙烯腈结合进行电纺丝,然后经过稳定和碳化形成碳纳米纤维。利用 BET、FT-IR、EA、DSC 等技术研究了不同浓度的 ZIF-67 在不同温度下对 PAN 电纺纤维的稳定行为。结果发现,在相同的稳定条件下,含有 ZIF-67 纳米粒子的 PAN 电纺纤维能吸收更多的氧气,促进更高的环化和交联。因此,最好在较低的稳定温度下制备碳纳米纤维。重要的是,PAN/ZIF-67 稳定纤维的稳定性和无序度已通过傅立叶变换红外光谱和拉曼光谱进行了描述。这项研究加深了人们对 MOF 增强碳纳米纤维形成的理解,并拓展了我们对 PAN/MOF 混合纤维稳定性的认识。