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【新文速递】2024年1月27日固体力学SCI期刊最新文章

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今日更新:Journal of the Mechanics and Physics of Solids 2 篇,Mechanics of Materials 1 篇,International Journal of Plasticity 1 篇,Thin-Walled Structures 1 篇

Journal of the Mechanics and Physics of Solids

Combined influence of shallowness and geometric imperfection on the buckling of clamped spherical shells

Kanghyun Ki, Jeongrak Lee, Anna Lee

doi:10.1016/j.jmps.2024.105554

浅度和几何缺陷对夹紧球壳屈曲的综合影响

We investigate the combined influence of shallowness and geometric imperfection on the pressure-induced buckling behavior of clamped spherical shells. The buckling phenomenon in spherical shells has gained significant interest in diverse fields, such as soft robotics and biomechanics, due to its distinct and drastic shape morphing characteristics. However, a notable discrepancy between analytic solutions and experimental results persists, necessitating further research to comprehend the buckling behavior of spherical shells with varying shallowness and geometric imperfection. To address this gap, we experimentally investigate the buckling of clamped spherical shells under uniform pressure while controlling the shell shallowness over a wide range. The experimental results validate finite element simulations, enabling analysis of the variation in buckling pressure and behaviors by manipulating the shell shallowness and geometric imperfection. Our analysis reveals decaying oscillatory variations in the buckling strength versus the shallowness curves, eventually converging to stable buckling strength for sufficiently deep shells. Moreover, these curves exhibit changes in level and shape with varying geometric imperfection. We also observe non-axisymmetric buckling modes in shells with small geometric imperfection and specific shallowness ranges. Through parametric studies, we identify the geometric conditions influencing the buckling behavior, particularly the non-snap-through criteria and non-axisymmetric buckling modes. This comprehensive investigation sheds light on the interplay between shallowness and geometric imperfection affecting the buckling behavior of clamped spherical shells. The findings contribute to a deeper understanding of shell buckling phenomena and have implications for various shell design applications.

我们研究了浅度和几何缺陷对夹紧球壳的压力诱导屈曲行为的综合影响。球壳的屈曲现象由于其独特而剧烈的形状变形特征,在软机器人和生物力学等多个领域引起了人们的极大兴趣。然而,解析解与实验结果之间仍然存在显著差异,需要进一步研究以理解不同浅度和几何缺陷的球壳的屈曲行为。为了解决这一差距,我们实验研究了在均匀压力下夹紧球壳的屈曲,同时在很大范围内控制壳的浅度。实验结果验证了有限元模拟,可以通过操纵壳体浅度和几何缺陷来分析屈曲压力和行为的变化。我们的分析表明,在较浅的曲线上,屈曲强度的振荡变化是衰减的,对于足够深的壳,最终收敛到稳定的屈曲强度。此外,这些曲线在不同的几何缺陷下表现出水平和形状的变化。我们还观察到具有较小几何缺陷和特定浅度范围的壳的非轴对称屈曲模式。通过参数化研究,我们确定了影响屈曲行为的几何条件,特别是非卡断准则和非轴对称屈曲模式。这项全面的研究揭示了浅度和几何缺陷之间的相互作用,影响夹紧球壳的屈曲行为。这些发现有助于更深入地理解壳体屈曲现象,并对各种壳体设计应用具有指导意义。


A machine learning perspective on the inverse indentation problem: uniqueness, surrogate modeling, and learning elasto-plastic properties from pile-up

Quan Jiao, Yongchao Chen, Jong-hyoung Kim, Chang-Fu Han, Chia-Hua Chang, Joost J. Vlassak

doi:10.1016/j.jmps.2024.105557

反缩进问题的机器学习视角:唯一性、代理模型和从堆积中学习弹塑性特性

The inverse analysis of indentation curves, aimed at extracting the stress-strain curve of a material, has been under intense development for decades, with progress relying mainly on the use of analytical expressions derived from small data sets. Here, we take a fresh, data-driven perspective to this classic problem, leveraging machine learning techniques to advance indentation technology. Using a neural network (NN), we efficiently assess uniqueness and identify materials that have indistinguishable indentation responses without the need for complex, domain knowledge-based algorithms. We then demonstrate that inclusion of the residual imprint information resolves the non-uniqueness problem. We show that the elasto-plastic properties of a material can be learned directly from indentation pile-up. Notably, an accurate stress-strain curve can be derived using solely the applied indentation load and pile-up information, thereby eliminating the need for depth-sensing. We also present a systematic analysis of the machine learning model, covering important aspects such as prediction performance, sensitivity, feature selection, and permutation importance, providing insight for model development and evaluation. This study introduces and provides the groundwork of a machine-learning-based profilometry-informed indentation inversion (PI3) technique. It showcases the potential of machine learning as a transformative alternative when analytical solutions are difficult or impossible to obtain.

以提取材料应力-应变曲线为目的的压痕曲线逆分析已经得到了几十年的大力发展,其进展主要依赖于使用从小数据集导出的解析表达式。在这里,我们采取了一个新的,数据驱动的角度来解决这个经典问题,利用机器学习技术来推进缩进技术。使用神经网络(NN),我们有效地评估唯一性并识别具有不可区分的压痕响应的材料,而无需复杂的基于领域知识的算法。然后,我们证明了残余印记信息的包含解决了非唯一性问题。我们证明了材料的弹塑性特性可以直接从压痕堆积中了解到。值得注意的是,仅使用施加的压痕载荷和堆积信息就可以推导出精确的应力-应变曲线,从而消除了深度传感的需要。我们还对机器学习模型进行了系统的分析,涵盖了预测性能、灵敏度、特征选择和排列重要性等重要方面,为模型开发和评估提供了见解。本研究介绍并提供了基于机器学习的轮廓信息缩进反演(PI3)技术的基础。它展示了机器学习作为一种变革性替代方案的潜力,当分析解决方案很难或不可能获得时。


Mechanics of Materials

On the flat punch hole expansion test of sheet metals: Mechanics of deformation and evaluation of anisotropic plasticity models

A. Abedini, A. Narayanan, C. Butcher

doi:10.1016/j.mechmat.2024.104931

板料平冲孔膨胀试验:变形力学及各向异性塑性模型的评价

The conventional approach to calibrating anisotropic yield functions relies upon uniaxial and biaxial tension data. Consequently, the stress state in which plane strain conditions arise is allowed to occur anywhere between uniaxial and equal-biaxial states despite growing experimental evidence suggesting that it is close to the theoretical stress state predicted by pressure-independent plasticity for steel and aluminum alloys. The objective of the study was to investigate the role of the plane strain stress state on yield surface calibration and its influence upon the mechanics of the flat punch hole expansion test. First, a parametric study was performed to determine how the plane strain stress state affects the predicted strain field in flat punch hole expansion simulations of an AA6022-T4 sheet. It is shown that the flat punch hole expansion deformation can be described as being under stress-controlled boundary conditions. The predicted location behind the hole edge where zero minor strain occurs was observed to be directly related to the yield function calibration and its accuracy evaluated from optical strain measurements. It was shown that the thinning strain distributions away from the edge could be well predicted by coupling the major strain gradient near the hole edge (geometry effect) with the normal vectors of the yield function from uniaxial-to-plane strain tension (yield function effect). The resulting best practices for plasticity characterization were then applied to a 3rd Gen 1180 steel. The global and local responses of the 3rd Gen 1180 flat punch hole expansion tests were accurately predicted by simulations using calibrations of the Yld2000 and Yld2004 anisotropic yield functions that enforced the plane strain constraint.

校准各向异性屈服函数的传统方法依赖于单轴和双轴张力数据。因此,尽管越来越多的实验证据表明,它接近由压力无关塑性预测的钢和铝合金的理论应力状态,但允许出现平面应变条件的应力状态发生在单轴和等双轴状态之间的任何地方。研究了平面应变应力状态在屈服面标定中的作用及其对平冲孔膨胀试验力学性能的影响。首先,进行了参数化研究,以确定平面应变应力状态对AA6022-T4板材平冲孔扩展模拟中预测应变场的影响。结果表明,在应力控制的边界条件下,扁冲孔的膨胀变形可以被描述为。观察到,在孔边缘后发生零小应变的预测位置与屈服函数校准及其通过光学应变测量评估的精度直接相关。结果表明,将孔边缘附近的主应变梯度(几何效应)与从单轴到平面的应变张力屈服函数法向量(屈服函数效应)耦合,可以很好地预测孔边缘以外的应变变薄分布。然后将塑性表征的最佳实践应用于第三代1180钢。通过对施加平面应变约束的Yld2000和Yld2004各向异性屈服函数的校正,模拟准确预测了第3代1180平冲孔扩展试验的整体和局部响应。


International Journal of Plasticity

Characterization and unified modelling of creep and viscoplasticity deformation of titanium alloy at elevated temperature

Yong Li, Haosheng Chen, Lihua Du, Feng Yang, Ying Zhang, Dongsheng Li

doi:10.1016/j.ijplas.2024.103892

钛合金高温蠕变与粘塑性变形表征及统一建模

A unified model to characterize the mechanism transitions in a wide range of strain rates at elevated temperatures of titanium alloys has been developed and validated in this study. Models of microstructure-based backstress and strain rate dependent stress sensitivity covering both creep and viscoplasticity domains have been proposed, so as to predict different deformation behaviors concurrently for hot forming. Systematical experiments, including hot tensile, creep, stress-relaxation, and corresponding loading-unloading tests have been designed and performed, to get the different deformation behaviors, as well as the evolution of backstresses of titanium alloys at elevated temperatures. Microstructural observations, such as electron backscatter diffraction (EBSD), have also been performed to assist the mechanisms characterization. Based on the microstructural and macro properties results, the developed unified model has been calibrated and further implemented for typical cases of hot stamping - stress-relaxation forming (HS-SRF). The developed model achieved an excellent accuracy for all the tensile, creep, and stress-relaxation behaviors concurrently, with an error of only about 4.9%, and a comparative 71.8% ∼ 90.8% reduction in springback prediction error has been reported for hot forming of typical thin-walled titanium alloy components when compared with the conventional modelling strategy where a single deformation mechanism is considered. The potential of the proposed model for process design and optimizations has also been discussed.

本研究建立了一个统一的模型来表征钛合金在高温下大范围应变速率下的机制转变。基于微观组织的背应力和应变率相关的应力敏感性模型涵盖了蠕变和粘塑性两个领域,从而可以同时预测热成形的不同变形行为。设计并进行了热拉伸、蠕变、应力松弛和相应的加载-卸载试验,得到了钛合金在高温下的不同变形行为和背应力的演变规律。显微结构观察,如电子背散射衍射(EBSD),也被用于协助机制表征。基于微观组织和宏观性能的结果,对所建立的统一模型进行了标定,并对热冲压-应力松弛成形(HS-SRF)的典型案例进行了进一步的实施。与考虑单一变形机制的传统建模策略相比,所开发的模型对所有拉伸、蠕变和应力松弛行为同时具有优异的精度,误差仅为4.9%,并且在典型薄壁钛合金部件的热成形中回弹预测误差降低71.8% ~ 90.8%。本文还讨论了所提出的模型在工艺设计和优化方面的潜力。


Thin-Walled Structures

Research on Mechanical Properties of Duplex Stainless Steel S22053 at Elevated Temperature and after Fire

Tiancheng Chen, Shenggang Fan, Qingfeng Xu, Kuiyuan Xu, Jinpeng Luo, Yuxian Tang

doi:10.1016/j.tws.2024.111620

S22053双相不锈钢高温及火后力学性能研究

Stainless steel has advantages such as corrosion resistance, durability and aesthetic appearance, with extensive application prospects in the field of construction engineering. In order to investigate the mechanical properties of duplex stainless steel S22053 at elevated temperature and after fire, 58 standard coupons were fabricated, with 4 coupons for tensile tests at ambient temperature, 18 coupons for steady-state tests at elevated temperatures, and 36 coupons for tensile tests after fire. The temperatures were set at 100 °C, 200 °C, 300 °C, 400 °C, 500 °C, 600 °C, 700 °C, 800 °C and 900 °C, in total of 9 temperature levels. Two cooling methods, water cooling and air cooling, were employed for the postfire coupons. Based on the test results, the expressions of stress-strain relations for duplex stainless steel S22053 under two fire conditions were proposed, and comparisons were made with existing models. The reduction formulas for 6 major mechanical parameters (E0, σ0.05, σ0.2, σ1.0, σ2.0 and σu) of duplex stainless steel S22053 under two fire conditions were obtained through data fitting. Reliability analysis was performed on the mechanical property parameters, and corresponding standard values were proposed.

不锈钢具有耐腐蚀、耐用、美观等优点,在建筑工程领域具有广泛的应用前景。为了研究双相不锈钢S22053在高温和火灾后的力学性能,制作了58个标准试样,其中4个试样用于常温拉伸试验,18个试样用于高温稳态拉伸试验,36个试样用于火灾后拉伸试验。温度设置为100°C、200°C、300°C、400°C、500°C、600°C、700°C、800°C和900°C,共9个温度级别。火后汽票采用水冷却和风冷两种冷却方式。根据试验结果,提出了两种火灾条件下双相不锈钢S22053的应力应变关系式,并与已有模型进行了比较。通过数据拟合得到了两种着火条件下双相不锈钢 S22053 的 6 个主要力学参数(E0、σ0.05、σ0.2、σ1.0、σ2.0 和 σu)。对力学性能参数进行了可靠性分析,并提出了相应的标准值。



来源:复合材料力学仿真Composites FEM
ACTMechanicalOpticalSystemDeform光学建筑电子ECAD理论材料机器人控制试验
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首次发布时间:2024-11-06
最近编辑:21天前
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【新文速递】2024年1月30日复合材料SCI期刊最新文章

今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 3 篇,Composites Science and Technology 1 篇Composite StructuresAn efficient parameterized simulation framework for 3D scarf-repaired composite laminatesZhenyu Wang, Yimeng Shan, Bin Fu, Han Yan, Yinghua Liu, Xuefeng Yaodoi:10.1016/j.compstruct.2024.117934三维带状修复复合材料层合板的有效参数化仿真框架This paper proposes a parameterized simulation framework for predicting the load-bearing capacity of 3D scarf-repaired composite laminates which remarkably reduces the modeling time from several hours to just a few seconds. The specific implementation is demonstrated through a detailed step-by-step explanation. The main contribution lies in: (1) By introducing a reusable geometric partitioning method for composite layers and implementing a partitioning method-based numbering scheme for element and node, the effective management of element and node IDs of elements and nodes in such complex 3D models is greatly facilitated; (2) By ingeniously combining open-source meshing tools and text rewriting techniques, a highly efficient approach has been developed to construct complete models for such structures, showcasing the remarkable potential of these existing techniques in this field. The reliability of the efficient parameterized simulation framework proposed in this study is verified through the comparison between strength values acquired from progressive damage analysis (PDA) and experiment data reported in the existing literature.本文提出了一种参数化的三维复合材料带修复层合板承载能力预测仿真框架,将建模时间从几个小时缩短到几秒钟。通过详细的一步一步的解释来演示具体的实现。主要贡献在于:(1)通过引入可重用的复合层几何划分方法,实现基于划分方法的元素和节点编号方案,极大地方便了复杂三维模型中元素和节点的元素和节点id的有效管理;(2)通过将开源网格工具和文本重写技术巧妙地结合起来,开发了一种高效的方法来构建此类结构的完整模型,展示了这些现有技术在该领域的显着潜力。通过将渐进损伤分析(PDA)得到的强度值与已有文献报道的实验数据进行对比,验证了本文提出的高效参数化仿真框架的可靠性。Composites Part A: Applied Science and ManufacturingIn-situ consolidation deformation of composite laminate with gaps of various widthsShu Minakuchi, Pavel Simacek, Suresh G. Advanidoi:10.1016/j.compositesa.2024.108054含不同宽度缝隙的复合材料层板原位固结变形Gaps between prepreg tapes, which occur when prepreg tapes are placed automatically, cause concave deformation of the laminate during consolidation, which degrades the quality of the cured laminate. However, this in-situ concave deformation has never been measured. This study measures consolidation deformation of a cross-ply thermosetting composite laminate containing gaps of various widths at the middle layer. A unique fiber-optic-based shape sensor is used for the in-situ deformation monitoring and the deformation during autoclave pressurization and heating is presented. The results indicate that the deformation phenomenon depends on whether the upper bagging-side layer bridging the gap contacts the tool-side layer below the gap as it sinks into the gap during consolidation. The consolidation process reveals when the gap width is narrow, the fibers and the resin from the prepreg layer flow into the gap and displace upwards the sunken upper layer, partially reducing the concave deformation. One attempt to suppress gap-induced deformation is also made by using a curing condition inspired by the observation and understanding of this deformation mechanism.预浸胶带自动放置时产生的间隙会导致层压板在固结过程中产生凹形变形,从而降低固化层压板的质量。然而,这种原位凹变形从未被测量过。本研究测量了在中间层含有不同宽度间隙的交叉层热固性复合材料层板的固结变形。提出了一种独特的基于光纤的形状传感器,用于现场变形监测,并提出了高压灭菌器加压和加热过程中的变形。结果表明,变形现象取决于固结过程中架起间隙的上部装袋层在下沉过程中是否与间隙下方的工具层接触。固结过程表明,当间隙宽度较窄时,预浸料层中的纤维和树脂流入间隙并向上置换下沉的上层,部分减小了凹变形。通过对这种变形机制的观察和理解,提出了一种固化条件来抑制间隙引起的变形。Composites Part B: EngineeringFabrication of room temperature self-healing, robust superhydrophobic coatings via spraying dual cross-linking supramolecular silicone polymer/SiO2 compositeJinqiu Tao, Lei Dong, Yuanlong Wu, Xudong Liu, Junhao Xie, Hao Wu, Qianping Randoi:10.1016/j.compositesb.2024.111245通过喷涂双交联超分子有机硅聚合物/SiO2复合材料制备室温自愈、坚固的超疏水涂层Endowing superhydrophobic surfaces (SHS) with self-healing capability has been considered a promising approach to prolonging the lifespan of SHS. However, the reported SHS consisted of self-healing polymers and adhesive nanoparticles are still subject to the contradictions between robustness and complicated repairing conditions. In this work, a room-temperature self-healable, robust superhydrophobic coating was fabricated by combining dual cross-linking supramolecular silicone polymer (BPDI), which contains multiple hydrogen interactions and reversible nitrogen-coordinated boroxines, and SiO2 nanoparticles via facile spraying methods. Benefiting from the synergetic dual reversible bonds and high mobility of BPDI polymer chains, the supramolecular resin exhibits excellent self-healing ability, recyclability, and high adhesive strength to the substrates. After the incorporation of SiO2 nanoparticles, the surface of composite coatings revealed lotus-leaf-like morphology with an averaged roughness of 105 nm and superhydrophobicity with a WCA of 158.6°. More importantly, the obtained coatings could repair themselves spontaneously and repeatedly at room temperature via surface reorganization when the composites suffer chemical deterioration such as plasma etching. Furthermore, the coated surface can maintain superhydrophobicity even after being exposed to repeated mechanical or chemical damages, including sandpaper abrasion, solvent immersion, water dripping, and UV aging. The facts are reasonably attributed to the excellent stability of BPDI resins and robust interfacial adhesion with the substrate. Moreover, the prepared superhydrophobic composites with room-temperature self-healing capability and mechanochemical durability have been applied for self-cleaning and antifouling aspects on diverse substrates.赋予超疏水表面(SHS)自愈能力被认为是延长SHS寿命的一种有前途的方法。然而,目前所报道的由自愈聚合物和黏附纳米颗粒组成的SHS仍然存在鲁棒性和复杂修复条件之间的矛盾。在这项工作中,通过简单的喷涂方法,将含有多个氢相互作用和可逆氮配位硼的双交联超分子有机硅聚合物(BPDI)与SiO2纳米颗粒结合,制备了一种室温自愈、坚固的超疏水涂层。得益于BPDI聚合物链的协同双可逆键和高迁移率,该超分子树脂具有优异的自愈能力、可回收性和对基体的高粘附强度。在SiO2纳米颗粒的掺入下,复合涂层表面呈现出荷叶状形貌,平均粗糙度为105 nm,超疏水性为158.6°。更重要的是,当复合材料遭受化学腐蚀(如等离子体蚀刻)时,所获得的涂层可以在室温下通过表面重组自发地重复修复。此外,涂层表面即使受到反复的机械或化学损伤,包括砂纸磨损、溶剂浸泡、滴水和紫外线老化,也能保持超疏水性。这些事实合理地归因于BPDI树脂优异的稳定性和与基材的强大界面附着力。此外,制备的超疏水复合材料具有室温自修复能力和机械化学耐久性,已在各种基材上应用于自清洁和防污方面。A robust anti-icing/de-icing and self-healing coating based on efficient photothermal Bi2S3/Ti3C2Tx nanofillersCuiting Du, Wei Wang, Zihao Guo, Peng Wang, Shougang Chendoi:10.1016/j.compositesb.2024.111255基于高效光热 Bi2S3/Ti3C2Tx 纳米填料的坚固防冰/除冰和自愈涂层The accumulation of ice can lead to various hazards, and currently, there is no suitable coating that can adapt to the low-temperature marine environment, providing anti-icing/de-icing and corrosion-resistant protection for metal surfaces. Here, we propose a multifunctional coating (BSPU) with Bi2S3/Ti3C2Tx as a photothermal filler and polyurethane (PU) as the matrix. Bi2S3/Ti3C2Tx exhibits a photothermal conversion efficiency of 76.13 % and excellent photothermal cycle stability. The PU matrix is composed of polydimethylsiloxane (PDMS), isophorone diisocyanate (IPDI), and Diels–Alder reaction (DA reaction) monomers, providing a smooth, hydrophobic, and self-healing surface. The BSPU coating achieves passive anti-icing and active de-icing performance. Bi2S3/Ti3C2Tx undergoes photothermal conversion to elevate the coating temperature, causing the ice layer to slip off within 300 s at −30 °C. BSPU extends the freezing time of water droplets under illumination to over 1500 s, 6.3 times longer than the freezing time on bare metal substrates. The corrosion resistance of the coating is significantly enhanced due to the "maze effect" provided by the two-dimensional filler. After soaking in a low-temperature environment for 90 d, |Z|0.01 Hz remains around 109 Ω cm2.The heat generated by Bi2S3/Ti3C2Tx promotes the occurrence of DA reversible reactions, enabling the damaged coating to self-heal within 300 s under 808nm laser irradiation. This work addresses the requirements of hydrophobicity and photothermal-dominated passive anti-icing/active de-icing and corrosion resistance, making it highly promising for applications in low-temperature marine environments.冰的积累会导致各种危害,而目前还没有一种合适的涂料能够适应低温海洋环境,为金属表面提供防冰/除冰和防腐蚀保护。在此,我们提出了一种以 Bi2S3/Ti3C2Tx 为光热填料、聚氨酯(PU)为基体的多功能涂层(BSPU)。Bi2S3/Ti3C2Tx 的光热转换效率高达 76.13 %,且光热循环稳定性极佳。聚氨酯基体由聚二甲基硅氧烷(PDMS)、异佛尔酮二异氰酸酯(IPDI)和 Diels-Alder 反应(DA 反应)单体组成,具有光滑、疏水和自修复表面。BSPU 涂层具有被动防冰和主动除冰性能。Bi2S3/Ti3C2Tx 通过光热转换来提高涂层温度,从而使冰层在零下 30 °C、300 秒内滑落。BSPU 可将水滴在光照下的冻结时间延长至 1500 秒以上,是裸金属基底冻结时间的 6.3 倍。由于二维填料提供的 "迷宫效应",涂层的耐腐蚀性能显著增强。在低温环境中浸泡 90 d 后,|Z|0.01 Hz 仍保持在 109 Ω cm2 左右。Bi2S3/Ti3C2Tx 产生的热量促进了 DA 可逆反应的发生,使受损涂层在 808nm 激光照射下可在 300 秒内自我修复。这项工作满足了疏水性和光热主导的被动防冰/主动除冰和耐腐蚀性的要求,使其在低温海洋环境中的应用前景十分广阔。Phosphorus-containing curing agents with dynamic bonds endowing epoxy resins with flame retardancy and remolding capabilityXiaohui Liu, Haojie Wang, Birong Zeng, Xindan Yi, Weiang Luo, Guorong Chen, Yiting Xu, Conghui Yuan, Lizong Daidoi:10.1016/j.compositesb.2024.111260 具有动态键的含磷固化剂,使环氧树脂具有阻燃性和重塑能力To prepare epoxy resins (EP) with flame retardancy and remolding capability, novel amine curing agents (DDPM and DDPS), which incorporate phosphonates and bis-Schiff bases, were used to replace DDM partially or completely for EP curing. Curing kinetics based on a dual-parameter autocatalytic model showed that DDPM and DDPS had higher reactivity of than DDM. EP/DDPM and EP/DDPS vitrimers demonstrated excellnt flame retardancy and remolding capability (up to 60.8 %). EP/DDPS with disulfide bonds could not effectively improve the dynamic bond exchange. The molecular weight, dynamic bond stability, and viscosity were analyzed to investigate the underlying mechanisms. This study endows the dynamic properties of EP using novel curing agents and achieves flame-retardant and sustainable epoxy thermosets.为了制备具有阻燃和重塑性能的环氧树脂(EP),采用含膦酸盐和双希夫碱的新型胺类固化剂(DDPM和DDPS)部分或完全取代DDM固化EP。基于双参数自催化模型的固化动力学表明,DDPM和DDPS比DDM具有更高的反应活性。EP/DDPM和EP/DDPS聚合物表现出优异的阻燃性和重塑能力(高达60.8 %)。带二硫键的EP/DDPS不能有效改善动态键交换。对其分子量、动态键稳定性和粘度进行了分析,探讨了其机理。本研究利用新型固化剂赋予EP动态性能,实现了阻燃、可持续的环氧热固性材料。Composites Science and TechnologyMOF decorated boron nitride/natural rubber composites with heterostructure for thermal management application through dual passive cooling modes base on the improved thermal conductivity and water sorption-desorption processDong An, Hongfeng Chen, Rizheng He, Jiaqi Chen, Chunlei Liu, Zhijian Sun, Huitao Yu, Yaqing Liu, Chingping Wong, Wei Fengdoi:10.1016/j.compscitech.2024.110469 MOF修饰的异质结构氮化硼/天然橡胶复合材料通过提高导热性和水吸附-解吸双重被动冷却模式进行热管理应用Numerous researches have drawn on the polymer-based thermal conductive composites to cope with heat dissipation issue both in the integrated electronics and human body. However, the limited thermal conductivity and mono-cooling mode even in the high filler content are always restricted its further application. Currently, the use of latent heat from phase transition has aroused researchers’ appetite for the thermal management. Herein, inspired by the sweat modulating the body temperature, a passive dual thermal management strategy was proposed by taking advantage of high latent heat and the improved thermal conductivity, where the liquid-vapor phase transition of water inside the MOF coated on the polymer-based composites to form the heterogeneous composites. In the proof-of-concept test, the obtained MIL-101 (Cr) MOF as the sorbent owned the high specific surface area of 1850 cm3/g, cyclic water uptake of 1.18 g and phase change enthalpy of 1780 J/g, which promoted the well spontaneous adsorption and desorption ability of water. While sulfur surface modified boron nitride/natural rubber composites (BN-S/NR) exhibited the excellent anisotropic thermal conductivity (11.48 W m−1 K−1) in the through-plane direction at the filler loading of 70 wt%. After the MIL-101 (Cr) MOF coated composites (MOF-BN-S/NR) with heterogeneous structure, the composites with 0.07 g MOF possessed the pretty cooling performance and thermal stability to adjust temperature at a proper range both in electronics and human body because of the dual passive heat dissipation approach. Therefore, these findings provide the meaningful insight into research to fabricate composites with heterogeneous-assisted heat dissipation in thermal management.聚合物基导热复合材料在解决集成电子和人体散热问题方面得到了广泛的研究。然而,即使在高填料含量的情况下,有限的导热性和单一的冷却方式一直制约着它的进一步应用。目前,相变潜热的利用已经引起了热管理研究人员的兴趣。受汗液调节体温的启发,提出了一种被动双热管理策略,利用高潜热和提高导热性的优势,将MOF内部的水的液-气相转变包覆在聚合物基复合材料上,形成非均相复合材料。在概念验证试验中,得到的MIL-101 (Cr) MOF作为吸附剂具有1850 cm3/g的高比表面积,1.18 g的循环吸水性和1780 J/g的相变焓,促进了水的良好自发吸附和解吸能力。而硫表面改性氮化硼/天然橡胶复合材料(BN-S/NR)在填充量为70 wt%时,在通面方向上表现出良好的各向异性导热系数(11.48 W m−1 K−1)。在MIL-101 (Cr) MOF涂层复合材料(MOF- bn - s /NR)具有非均相结构之后,0.07 g MOF涂层复合材料由于采用双被动散热方式,具有良好的冷却性能和热稳定性,可在电子和人体中调节温度。因此,这些发现为研究在热管理中制造具有非均质辅助散热的复合材料提供了有意义的见解。来源:复合材料力学仿真Composites FEM

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