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【新文速递】2024年4月6日复合材料SCI期刊最新文章

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今日更新:Composite Structures 8 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 3 篇,Composites Science and Technology 2 篇

Composite Structures

Deep learning uncertainty quantification for ultrasonic damage identification in composite structures

Houyu Lu, Sergio Cantero Chinchilla, Xin Yang, Konstantinos Gryllias, Dimitrios Chronopoulos

doi:10.1016/j.compstruct.2024.118087

复合材料结构超声波损伤识别的深度学习不确定性量化

In this paper, three state-of-the-art deep learning uncertainty quantification (UQ) methods —Flipout probabilistic convolutional neural network (CNN), deep ensemble probabilistic CNN, and Bayesian probabilistic CNN—based on the Visual Geometry Group 13 architecture are proposed. They are compared with a traditional Bayesian inference approach for localizing delamination damage in composite. The law of conditional covariance is used to separate and quantify the predictive variance of the three networks into aleatoric and epistemic uncertainty. The network models’ performance is enhanced through hyperparameter optimization using Hyperband and warm-up optimization algorithms. The performance of the three networks in measuring the uncertainty is assessed on an out-of-distribution (OOD) dataset and validated on an in-distribution (ID) dataset for localization of composite delamination damage. Results indicate high accuracy in predicting damage locations for all methods on the ID dataset. On the OOD dataset, the Flipout and deep ensemble network have better performance, stably measuring aleatoric uncertainty in both trained and untrained areas, while the Bayesian network’s aleatoric uncertainty shows a discernible change across both areas. All three networks effectively measure epistemic uncertainty. Overall in both ID and OOD datasets, the Flipout network provides an optimal balance among training efficiency, UQ effectiveness and accuracy in predicting damage locations.

本文基于 Visual Geometry Group 13 架构,提出了三种最先进的深度学习不确定性量化(UQ)方法--Flipout 概率卷积神经网络(CNN)、深度集 合概率 CNN 和贝叶斯概率 CNN。它们与传统的贝叶斯推理方法进行了比较,以定位复合材料中的分层损伤。利用条件协方差定律将这三种网络的预测方差分为不确定性和认识不确定性,并对其进行量化。通过使用 Hyperband 和预热优化算法进行超参数优化,提高了网络模型的性能。在一个分布外(OOD)数据集上评估了三个网络在测量不确定性方面的性能,并在一个分布内(ID)数据集上验证了复合材料分层损伤定位的性能。结果表明,在 ID 数据集上,所有方法预测损伤位置的准确性都很高。在 OOD 数据集上,Flipout 和深度集 合网络具有更好的性能,可以稳定地测量训练区域和未训练区域的不确定性,而贝叶斯网络的不确定性在两个区域都有明显的变化。这三个网络都能有效测量认识不确定性。总体而言,在 ID 和 OOD 数据集中,Flipout 网络在训练效率、UQ 效果和预测损坏位置的准确性之间实现了最佳平衡。


An experimental and parametrical study on repair of cracked titanium airframe structures with single-side bonded carbon fiber-reinforced polymer prepreg patches

Junshan Hu, Ruihao Kang, Jinrong Fang, Shizhan Chen, Shanyong Xuan, Jian Zhou, Wei Tian

doi:10.1016/j.compstruct.2024.118102

使用单面粘接碳纤维增强聚合物预浸料修补剂修复开裂钛机身结构的实验和参数研究

The present research aims to investigate efficient repair techniques of cracked Ti-alloy aircraft structures with adhesively bonded carbon fiber-reinforced polymer prepreg patches. The repaired specimens in the configuration of a Ti-alloy butt joint with one-side bonded composite patch were prepared under multiple repair factors including patch thickness, patch length, adhesive thickness, cure pressure, patch layup and surface treatment. The repair efficiency was evaluated by loading behavior, bonded interface microstructure and failure mode. The results reveals that the geometric factors affect the loading performance and alter failure modes by adjusting stress distribution in the repair system, whereas the cure pressure and surface treatment act on the bondline and change interfacial properties. A sensitivity-optimization model based on analysis of variance was established for parametrical study to quantify the contribution of repair factors and obtain optimal values. The optimum parameters were validated by repaired central-cracked specimens via static and fatigue tests, which proved that the repaired structure could restore 90.7% loading capacity of intact ones and endure more than 106 fatigue cycles of 25% ultimate failure load level of center-cracked ones. The proposed experimental and parametrical study possessed good efficacy in refurbishing strength and stiffness of cracked metallic structures.

本研究旨在探讨使用粘合碳纤维增强聚合物预浸料补片对开裂的钛合金飞机结构进行高效修复的技术。在多种修复因素(包括贴片厚度、贴片长度、粘合剂厚度、固化压力、贴片铺设和表面处理)的作用下,制备了钛合金对接接头与单面粘合复合材料贴片的修复试样。通过加载行为、粘接界面微观结构和失效模式对修复效率进行了评估。结果表明,几何因素通过调整修复系统中的应力分布影响加载性能并改变破坏模式,而固化压力和表面处理则作用于粘合线并改变界面特性。在参数研究中建立了基于方差分析的敏感性优化模型,以量化修复因素的贡献并获得最优值。修复后的中心裂纹试样通过静态和疲劳试验验证了最佳参数,证明修复后的结构可恢复完整试样 90.7% 的承载能力,并可承受中心裂纹试样 25% 极限破坏载荷水平的 106 次以上疲劳循环。所提出的实验和参数研究在修复开裂金属结构的强度和刚度方面具有良好的效果。


Study on the performance of aluminum matrix ceramic ball composite materials plate for hypervelocity impact protection based on FE-SPH adaptive method

YJ. Deng, YF. Ren, X. Liu, L. Li, M. Qin

doi:10.1016/j.compstruct.2024.118103

基于 FE-SPH 自适应方法的超高速冲击防护铝基陶瓷球复合材料板性能研究

Space debris is a major threat to the safety of spacecraft in orbit, and advanced protective materials with lightweight and high impact resistance are effective passive protection solutions. In order to investigate the hypervelocity impact protection performance of aluminum matrix ceramic ball composite materials plate, this paper has carried out the hypervelocity impact test of aluminum matrix ceramic ball composite materials plate, and verified the accuracy of the numerical model based on the FE-SPH adaptive method, and then carried out a comparative study on the hypervelocity impact protection performance of aluminum plate and aluminum matrix ceramic ball composite materials plate with the same area density. The results show that: compared with the aluminum plate conditions, the composite materials target has a better ability to broken the projectile. Compared with the aluminum target, the kinetic energy absorbed by the composite target is increased by 37.04%, and the kinetic energy of the generated debris cloud decreased by 69.57. The proportion of the internal energy dissipation of the composite materials impact system reaches up to 72.03%. The secondary pollution generated by the composite target is less and the hazardous debris have less threat to the rear wall. The research in this paper can provide reference for the selection of hypervelocity impact protection materials.

空间碎片是在轨航天器安全的主要威胁,轻质高抗冲击的先进防护材料是有效的被动防护解决方案。为了研究铝基陶瓷球复合材料板的超高速撞击防护性能,本文进行了铝基陶瓷球复合材料板的超高速撞击试验,验证了基于FE-SPH自适应方法的数值模型的准确性,进而对相同面积密度的铝板和铝基陶瓷球复合材料板的超高速撞击防护性能进行了对比研究。结果表明:与铝板条件相比,复合材料靶具有更好的破射能力。与铝靶相比,复合材料靶吸收的动能增加了 37.04%,产生的碎片云动能减少了 69.57。复合材料冲击系统的内能耗散比例高达 72.03%。复合材料靶材产生的二次污染较少,有害碎片对后壁的威胁较小。本文的研究可为超高速撞击防护材料的选择提供参考。


A new guided mode so-called minimum group velocity in viscoelastic sandwich plates: A parametric numerical study

Souhail Dahmen, Cherif Othmani, Sebastian Merchel, M. Ercan Altinsoy, Abir Rouis, Jian Xiong, Farid Takali

doi:10.1016/j.compstruct.2024.118106

粘弹性夹层板中所谓最小群速度的新引导模式:参数数值研究

Zero-Group-Velocity (ZGV) guided mode has recently received particular attention because of its highly sensitive to structural changes, such as defects. Parallel to ZGV, in the present work, we introduce a new guided mode so-called Minimum-Group-Velocity (MGV) that is a remarkable phenomenon in defect detection applications. Strictly speaking, when any two phase-velocity dispersion curves of Lamb modes approach each other without overlapping, we observe this new mode in group-velocity dispersion curves. It is worth noting that this MGV mode has never been addressed in literature. We compute the Lamb-like modes in asymmetric viscoelastic sandwich plates using the Stiffness Matrix Method (SMM). We show that the change in properties of this sandwich can dramatically affect frequency ranges associated with ZGV and MGV modes. However, a linear correlation between phase velocities and this change on viscoelastic properties is discussed, where we observed an interconnection phenomenon in the dispersion curves. This interconnection happens between specific points on the dispersion curves, each corresponding to a ZGV- or MGV-mode. On the other hand, we verify that the detection of changes in level of viscoelastic properties or variations in the thickness of the buffer viscoelastic layer is possible within a limited segment of the damped mode curve.

零群速度(ZGV)制导模式因其对结构变化(如缺陷)的高度敏感性最近受到了特别关注。与 ZGV 同时,我们在本研究中引入了一种新的导波模式,即最小群速度(MGV),它在缺陷检测应用中是一种显著现象。严格来说,当任何两个 Lamb 模式的相位速度频散曲线相互接近而不重叠时,我们就能在群速度频散曲线中观察到这种新模式。值得注意的是,这种 MGV 模式从未在文献中出现过。我们使用刚度矩阵法(SMM)计算了非对称粘弹性夹层板中的类 Lamb 模式。结果表明,夹层性质的改变会极大地影响与 ZGV 和 MGV 模式相关的频率范围。然而,我们讨论了相位速度与粘弹特性变化之间的线性相关关系,并观察到频散曲线中的互连现象。这种相互连接发生在频散曲线上的特定点之间,每个点都对应一个 ZGV 或 MGV 模式。另一方面,我们验证了在阻尼模式曲线的有限段落内检测粘弹性特性水平的变化或缓冲粘弹性层厚度的变化是可能的。


A coupled 3D morphological reconstruction method for point microcrack defects in Si3N4 ceramic bearing rollers

Dahai Liao, Jianfei Yang, Xianqi Liao, Weiwen Hu, Jiao Li, Nanxing Wu

doi:10.1016/j.compstruct.2024.118107

Si3N4 陶瓷轴承滚子点状微裂纹缺陷的耦合三维形态重建方法

The features of shallow depth and gradual blurring are characterized by the point microcrack defects in Si3N4 ceramic bearing rollers. Point clouds accuracy and mesh correctness of 3D morphological reconstruction are affected. A coupled method is proposed for reconstructing the 3D morphology, based on small-scale structure from motion and nonlinear image clustering vision. The fine-tuning motion supply system is designed based on the shallow depth characteristics of point microcrack defects. The sparse point clouds of point microcrack defects are obtained. The gradually blurring of the point microcrack defects is analyzed. Thus, the nonlinear image clustering and convergence functions are established. The dense point clouds and texture mesh of point microcrack defects are reconstructed. The experimental results show the diameter of the circular region containing the point microcrack defects is 17.798 μm. The maximum local longitudinal span of the point microcrack defects is 239 nm. The number of sparse point clouds vertex, dense point clouds vertex and texture mesh face is 535, 13206, 21086, respectively. The reconstructed results are in well agreement with the raw image segmentation results. The theoretical basis for the research on the mechanism of point microcrack defects propagation and the prediction of bearing life is provided.

Si3N4 陶瓷轴承滚子的点状微裂纹缺陷具有深度浅、逐渐模糊的特征。三维形态重建的点云精度和网格正确性受到影响。本文提出了一种基于运动小尺度结构和非线性图像聚类视觉的三维形态重建耦合方法。根据点状微裂纹缺陷的浅深度特征,设计了微调运动供给系统。获得了点状微裂纹缺陷的稀疏点云。分析了点状微裂纹缺陷的逐渐模糊现象。从而建立了非线性图像聚类和收敛函数。重建了点状微裂纹缺陷的稠密点云和纹理网格。实验结果表明,包含点状微裂纹缺陷的圆形区域直径为 17.798 μm。点状微裂纹缺陷的最大局部纵向跨度为 239 nm。稀疏点云顶点、密集点云顶点和纹理网格面的数量分别为 535、13206 和 21086。重建结果与原始图像分割结果完全一致。为研究点状微裂纹缺陷传播机理和预测轴承寿命提供了理论依据。


Meso-FE modelling for homogenization of the nonlinear orthotropic behavior of PTFE-coated fabric based on virtual fiber method

Junhao Xu, Yan Zhang, Yingying Zhang, Wei Song, Hao Xu, Yushuai Zhao

doi:10.1016/j.compstruct.2024.118093

基于虚拟纤维法的用于 PTFE 涂层织物非线性各向同性行为均质化的 Meso-FE 模型

Compared to traditional textile composites, the coated fabric used in fabric membrane structures is much more flexible. Its macroscopic mechanical behavior is highly nonlinear, anisotropic, and shows stress ratio dependence during the loading process. The main reason is that the yarns within the coated fabric are not completely solidified, and there is a significant crimp interchange process in the yarns under load. This paper proposes a novel mesoscopic finite element (FE) model to predict the nonlinear orthotropic mechanical behavior of PTFE-coated fabric using the virtual fiber method (VFM). By comparing with experimental data, it is shown that the virtual fiber defined by the truss element can visually and effectively simulate the mechanical behavior of the internal fibers and reflect the crimp interchange process between two-way yarns. Combined with PBCs, it can effectively predict the uniaxial and biaxial tensile behaviors of the PTFE-coated fabric. Moreover, a new multi-scale model suitable for structural scale analysis of fabric membrane structures has been attempted by combining the direct FE2 (D-FE2) method with the proposed mesoscopic FE model. Local deformation mechanisms and macro response of fabric membrane structures can be observed simultaneously from these analyses, which provide a better understanding of the mechanical behavior of the fabric membrane structures.

与传统的纺织复合材料相比,织物膜结构中使用的涂层织物要柔韧得多。它的宏观机械行为高度非线性、各向异性,并在加载过程中表现出应力比依赖性。其主要原因是涂层织物中的纱线没有完全凝固,在加载过程中纱线存在明显的卷曲交换过程。本文提出了一种新型介观有限元(FE)模型,利用虚拟纤维法(VFM)预测 PTFE 涂层织物的非线性各向同性力学行为。通过与实验数据的比较,表明由桁架元素定义的虚拟纤维能直观有效地模拟内部纤维的力学行为,并反映双向纱线之间的卷曲交换过程。结合 PBC,它能有效预测 PTFE 涂层织物的单轴和双轴拉伸行为。此外,通过将直接 FE2(D-FE2)方法与所提出的介观 FE 模型相结合,尝试了一种适用于织物膜结构尺度分析的新型多尺度模型。通过这些分析,可以同时观察到织物膜结构的局部变形机制和宏观响应,从而更好地理解织物膜结构的力学行为。


Hybridization of face sheet in sandwich composites to mitigate low temperature and low velocity impact damage

Jason P. Mack, Faizan Mirza, Arnob Banik, M.H. Khan, K.T. Tan

doi:10.1016/j.compstruct.2024.118101

夹层复合材料中的面片杂化可减轻低温和低速冲击损伤

In this study, the impact response and damage mechanisms of carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) hybrid face sheet sandwich composites are investigated with the aim to provide an understanding and solution to mitigate the coupling effects of low temperature and low velocity impact damage. Hybridization of face sheet is achieved by stacking CFRP and GFRP in different thickness configurations. Samples are subjected to low-velocity impact at 23 °C and −70 °C to compare and understand the effect of cold temperature in the Arctic environment. Results show that hybridization improves the impact performance at −70 °C. CFRP layers and foam core become extremely brittle at low temperature, but GFRP layers maintain a certain extent of ductility and enhanced laminate strength at low temperature. Moreover, different damage modes (delamination, fiber breakage, core crushing, core shear, face sheet debonding, back face fiber splitting) are observed and characterized by X-ray micro-computed tomography. The additions of GFRP layers to CFRP face sheet mitigated the increased brittle fiber failure observed at low temperatures, however the impact characteristics and damage size was found to be dependent on the hybridization configuration.

本研究对碳纤维增强聚合物(CFRP)和玻璃纤维增强聚合物(GFRP)混合面片夹层复合材料的冲击响应和损伤机理进行了研究,旨在为减轻低温和低速冲击损伤的耦合效应提供一种理解和解决方案。通过以不同厚度配置堆叠 CFRP 和 GFRP,实现了面片的混合。样品在 23 °C 和 -70 °C 下受到低速冲击,以比较和了解北极环境中低温的影响。结果表明,杂化提高了-70 °C时的冲击性能。CFRP 层和泡沫芯材在低温下变得极脆,但 GFRP 层在低温下保持了一定的延展性并增强了层压强度。此外,X 射线微观计算机断层扫描还观察到不同的破坏模式(分层、纤维断裂、芯材挤压、芯材剪切、面片脱粘和背面纤维分裂),并对其进行了表征。在 CFRP 面板上添加 GFRP 层可减轻低温下观察到的纤维脆性破坏的增加,但发现冲击特性和破坏大小取决于杂化配置。


Shape memory behaviors of three-dimensional five-directional braided composites with different axial yarns arrangements

Yingying Qi, Shuwei Huang, Haoxuan Zhang, Bohong Gu, Baozhong Sun, Wei Zhang

doi:10.1016/j.compstruct.2024.118105

不同轴向纱排列的三维五向编织复合材料的形状记忆行为

The effect of braided structure on shape memory behaviors of 3D braided composites is critical to design the responses of the composite under external fields. Here we report the effect of axial yarn on shape memory behaviors of three-dimensional five-directional (3D5d) braided shape memory polymer composites (SMPCs) under bending. It was found that the axial yarns will improve bending stiffness and electro-thermal behaviors significantly. The thermomechanical deformation and shape memory effect of SMPCs are influenced by the braiding structural parameters. Specifically, the 3D5d SMPCs exhibits a 53.6% increase in bending recovery force and a faster shape recovery speed than those of 3D four-directional SMPCs. We found from finite element analyses (FEA) that the axial yarns positions influence the inner stress distribution and shape memory behaviors of SMPCs. The axial yarns distributed on both sides of SMPC influence the shape memory behaviors more than those of the middle layer.

编织结构对三维编织复合材料形状记忆行为的影响对于设计复合材料在外力作用下的响应至关重要。在此,我们报告了轴向纱线对三维五向(3D5d)编织形状记忆聚合物复合材料(SMPC)在弯曲下的形状记忆行为的影响。研究发现,轴向纱线能显著改善弯曲刚度和电热行为。SMPC 的热机械变形和形状记忆效应受编织结构参数的影响。具体而言,与三维四向 SMPC 相比,三维五向 SMPC 的弯曲恢复力增加了 53.6%,形状恢复速度更快。我们通过有限元分析(FEA)发现,轴向纱线的位置会影响 SMPC 的内部应力分布和形状记忆行为。分布在 SMPC 两侧的轴向纱线比中间层的纱线对形状记忆行为的影响更大。


Composites Part A: Applied Science and Manufacturing

Improving the thermal conductivity of an epoxy composite with chemically boron nitride-grafted carbon fiber

Wonyoung Yang, Jihoon Kim, Pei-Chen Su, Jooheon Kim

doi:10.1016/j.compositesa.2024.108192

 

用化学氮化硼接枝碳纤维改善环氧树脂复合材料的导热性能

The rapid progress of electronic devices like electric vehicles, smartphones, and IoT systems has fueled the demand for compact, high-performance batteries. However, a critical challenge arises from heat accumulation within these devices, leading to malfunctions and reduced efficiency. To address this, efficient heat dissipation is crucial, with thermal interface materials (TIMs) widely used for heat transfer. While polymers are favored for TIMs due to their ease of processing and electrical insulation, their low thermal conductivity poses limitations. In this study, a solution is proposed by chemically grafting boron nitride (BN), a ceramic-based filler, onto carbon fiber (CF) surfaces. This BN-g-CF hybrid filler, formed through a reaction between acyl chlorides and amine groups, exhibits superior compatibility with polymer matrix. Characterization confirms successful treatment, and thermal conductivity measurements show a remarkable enhancement, positioning the BN-g-CF/epoxy resin composite as a promising solution for efficient thermal management in various electronic industries.

电动汽车、智能手机和物联网系统等电子设备的快速发展,刺 激了对紧凑型高性能电池的需求。然而,这些设备内部的热量积累带来了严峻的挑战,导致故障和效率降低。为解决这一问题,高效散热至关重要,热界面材料(TIM)被广泛用于热传递。虽然聚合物因其易于加工和电气绝缘性能而成为热界面材料的首选,但其较低的热传导率却带来了局限性。本研究提出了一种解决方案,即通过化学方法将氮化硼(BN)这种陶瓷基填料接枝到碳纤维(CF)表面。这种 BN-g-CF 混合填料是通过酰基氯和胺基反应形成的,与聚合物基体具有极佳的兼容性。表征结果表明处理成功,热导率测量结果表明显著提高,BN-g-CF/环氧树脂复合材料有望成为各种电子工业高效热管理的解决方案。


Multi-DORGP for fast uncertainty quantification of multi-scale irregular defects in super large-scale fiber-reinforced composite

Yunguo Cheng, Timon Rabczuk, Chensen Ding

doi:10.1016/j.compositesa.2024.108196

用于快速量化超大尺度纤维增强复合材料中多尺度不规则缺陷的 Multi-DORGP

The presence of randomly distributed irregular defects in fiber-reinforced composites significantly impacts the structural response, yet traditional machine learning schemes often require an extensive number of samples, resulting in time-consuming processes. Therefore, this paper introduces a novel approach, termed the dual order-reduced Gaussian Process emulators (Multi-DORGP), aimed at efficiently quantifying the uncertainty of multi-scale irregular defects in fiber-reinforced composites. This is achieved by accurately characterizing the multi-scale irregular defects through precise geometric representations, utilizing massive discrete nodes and fine meshes to address the limitations of parameterization methods that may overlook shape and size differences of defects. Moreover, we comprehensively quantify uncertainty across micro, meso, and macro scales, considering spatially randomly distributed locations, sizes, and irregular shapes of defects. Notably, the Multi-DORGP scheme is presented to alleviate the computational burden associated with extremely high-dimensional data (e.g., up to 23.3 million variables). In which, we decouple and build the latent spaces for raw data assisted by principal component analysis, and Gaussian Process regression is built and trained by the coefficients between the latent spaces. Through illustrative examples, including a real-life application involving an airplane wing, we validate the proposed scheme's capability to accurately quantify the uncertainty of multi-scale irregular defects in large-scale fiber-reinforced composites using significantly few samples (e.g., 100).

纤维增强复合材料中随机分布的不规则缺陷会严重影响结构响应,但传统的机器学习方案往往需要大量样本,导致过程耗时。因此,本文介绍了一种新方法,即双阶还原高斯过程仿真器(Multi-DORGP),旨在有效量化纤维增强复合材料中多尺度不规则缺陷的不确定性。为此,我们通过精确的几何表征来准确描述多尺度不规则缺陷,利用大规模离散节点和精细网格来解决参数化方法可能忽略缺陷形状和尺寸差异的局限性。此外,考虑到缺陷在空间上随机分布的位置、尺寸和不规则形状,我们全面量化了微观、中观和宏观尺度上的不确定性。值得注意的是,我们提出了多 DORGP 方案,以减轻与极高维数据(如多达 2330 万个变量)相关的计算负担。在该方案中,我们通过主成分分析对原始数据进行解耦并建立潜在空间,然后通过潜在空间之间的系数建立并训练高斯过程回归。通过示例(包括涉及飞机机翼的实际应用),我们验证了所提出方案的能力,即使用极少的样本(如 100 个)就能准确量化大规模纤维增强复合材料中多尺度不规则缺陷的不确定性。


Composites Part B: Engineering

Tailor-made Co3O4@CeO2 based nanofibrous membrane with enhanced catalytic reactivity for efficient degradation of antibiotic

Dong Wang, Siping Ding, Zhenzhen He, Tonghui Zhang, Xuefen Wang

doi:10.1016/j.compositesb.2024.111424

 

基于 Co3O4@CeO2 的定制纳米纤维膜具有更强的催化反应活性,可高效降解抗生素

In this work, a novel Co3O4@CeO2 nanofibrous membrane was prepared by the combination of interfacial defect engineering strategy and coaxial electrospinning for unusual levofloxacin degradation. Implanting active Co3O4 into CeO2 derived from Ce-UiO-66 created more oxygen vacancies and improved the interfacial interaction (electron transfer and specific surface area). In addition, accelerated redox recycling occurred on the catalyst surface because of the cooperation of Co sites and Ce sites. As a result, the optimal Co3O4@CeO2 nanocomposite showed an unexpectedly improved degradation efficiency of levofloxacin with a rate constant higher than 6.9 times (CeO2) and 2.6 times (Co3O4), superior elimination (>98%) of antibiotic (norfloxacin, tetracycline and doxycycline hydrochloride) and dyes (methylene blue, rhodamine b, methyl orange and crystal violet). Moreover, C-type hollow structure nanofibers with increased reaction area were prepared by coaxial electrospinning to support nanoparticles for consecutive wastewater treatment. The prepared nanofibrous membrane with loading 50 wt% Co3O4@CeO2 (PC50 NFMs) exhibited loose structure, resulting in 168.2 ± 12 L m−2 h−1 of permeability driven by gravity, while 164.2 L·m−2 of levofloxacin was efficiently treated. Besides, the PC50 NFMs had satisfactory reusability and stability in real water bodies. This work paved a new avenue to control water pollution through the design of membranous catalysts.

本研究结合界面缺陷工程策略和同轴电纺丝技术,制备了一种新型 Co3O4@CeO2 纳米纤维膜,用于不寻常的左氧氟沙星降解。将活性 Co3O4 植入 Ce-UiO-66 制备的 CeO2 中,可产生更多的氧空位,改善界面相互作用(电子传递和比表面积)。此外,由于 Co 位点和 Ce 位点的合作,催化剂表面的氧化还原循环加快。因此,最佳的 Co3O4@CeO2 纳米复合材料出乎意料地提高了左氧氟沙星的降解效率,其速率常数高于 6.9 倍(CeO2)和 2.6 倍(Co3O4),对抗生素(诺氟沙星、四环素和盐酸多西环素)和染料(亚甲基蓝、罗丹明 b、甲基橙和结晶紫)的消除效果也很好(大于 98%)。此外,还利用同轴电纺丝技术制备了具有更大反应面积的 C 型中空结构纳米纤维,以支持纳米颗粒连续处理废水。所制备的负载量为 50 wt% Co3O4@CeO2 的纳米纤维膜(PC50 NFMs)结构疏松,在重力作用下的渗透率为 168.2 ± 12 L m-2 h-1,可有效处理 164.2 L-m-2 的左氧氟沙星。此外,PC50 NFM 在实际水体中的重复使用性和稳定性也令人满意。这项工作为通过设计膜催化剂来控制水污染开辟了一条新途径。


Electromagnetic wave absorption of polymer derived ceramic composites tuned by multi-component oxide solid solution

Yujun Jia, Xiaopeng Wu, Bin Ren, Jiaying Ti, Yumeng Deng, Qian Wang, Hejun Li

doi:10.1016/j.compositesb.2024.111431

用多组分氧化物固溶体调节聚合物衍生陶瓷复合材料的电磁波吸收率

Polymer-derived ceramics (PDCs) are important ceramics for high temperature electromagnetic wave (EMW) absorption because of their tunable conductivity with the pyrolysis temperature. However, it is usually difficult to tune the dielectric properties of the PDCs by only controlling the content of absorption phase in the material system for the purpose of acquiring a wide EMW absorption band. In this work, we illustrate that the PDCs with wide-band high temperature absorption can be obtained through the synergistical tuning by multi-component oxide solid solution (MOS), nano ZrB2 and the metamaterial structure design. The PDCs were prepared by co-pyrolyzing the SiOC precursor, nano ZrB2 and MOS. The MOS helps to tune the permittivity of the PDCs without decreasing the conduction loss of the composites. The effective absorption band (lower than −10dB) of the metamaterial structure made by the prepared ceramic composites exceeds 12 GHz at the frequency range of 2–18 GHz from room temperature (RT) to 1000 °C, revealing a stable high temperature EMW absorption. The metamaterial structure shows good absorption in low frequency range at high temperatures, almost covering the entire S band from RT to 700 °C. The average EM absorption of the ceramic composites is lower than −15dB in the range of 2–18 GHz from RT to 1000 °C. The lowest reflection loss (RL) of the metamaterial is −45dB at 1000 °C. This study successfully address the challenge of simultaneously keeping impedance matching and retaining the strong attenuation of ceramic composites, greatly widening the high temperature EMW absorption band of PDC composites.

聚合物衍生陶瓷(PDCs)的电导率可随热解温度的变化而调整,因此是用于高温电磁波(EMW)吸收的重要陶瓷。然而,为了获得较宽的电磁波吸收带,仅通过控制材料体系中吸收相的含量通常很难调整 PDC 的介电性能。在这项工作中,我们通过多组分氧化物固溶体(MOS)、纳米 ZrB2 和超材料结构设计的协同调谐,说明了具有宽带高温吸收的 PDCs 是可以获得的。PDC 是由 SiOC 前驱体、纳米 ZrB2 和 MOS 共同热解制备的。MOS 有助于调节 PDC 的介电常数,同时不会降低复合材料的传导损耗。在室温(RT)至 1000 °C 的 2-18 GHz 频率范围内,由制备的陶瓷复合材料制成的超材料结构的有效吸收带(低于 -10dB)超过了 12 GHz,显示了稳定的高温电磁波吸收。超材料结构在高温低频范围内表现出良好的吸收性,几乎覆盖了从室温到 700 °C 的整个 S 波段。陶瓷复合材料在 2-18 GHz(从室温到 1000 °C)范围内的平均电磁吸收率低于-15dB。超材料的最低反射损耗(RL)在 1000 °C 时为 -45dB。这项研究成功地解决了同时保持阻抗匹配和陶瓷复合材料强衰减的难题,大大拓宽了 PDC 复合材料的高温电磁波吸收带。


Selective detection of norfloxacin using MIP/PEDOT modified electrode: A study on sensing performance

Yaolong Zhang, Ruxangul Jamal, Abdukeyum Abdurexit, Tursun Abdiryim, Yu Zhang, Yanqiang Zhou, Yajun Liu, Nana Fan, Zhigang Wang

doi:10.1016/j.compositesb.2024.111432

使用 MIP/PEDOT 修饰电极选择性检测诺氟沙星:传感性能研究

Developing an analytical technique for selectively detecting trace antibiotics in complex environments is essential for food safety and environmental protection. Using poly(3,4-ethylenedioxythiophene) (PEDOT) as a matrix material, we employed molecular self-assembly electropolymerization to imprint poly-o-phenylenediamine (PoPD) in the presence of norfloxacin. The study reveals that the modified GCE features a worm-like microstructure, providing a larger surface area for the construction of additional recognition sites. This modified electrode demonstrated excellent sensing performance for NOR, wide linear range (2 nmol L−1–21.11 μmol L−1), low detection limit (173 pmol L−1) (S/N = 3), and high selectivity. It effectively detected norfloxacin in different samples, yielding satisfactory results.

开发一种在复杂环境中选择性检测痕量抗生素的分析技术对于食品安全和环境保护至关重要。我们以聚(3,4-亚乙二氧基噻吩)(PEDOT)为基质材料,采用分子自组装电聚合技术,在诺氟沙星存在的情况下压印聚邻苯二胺(PoPD)。研究发现,修饰后的 GCE 具有蠕虫状的微观结构,为构建额外的识别位点提供了更大的表面积。这种改性电极对 NOR 具有优异的传感性能,线性范围宽(2 nmol L-1-21.11 μmol L-1),检测限低(173 pmol L-1)(S/N = 3),选择性高。该方法能有效检测不同样品中的诺氟沙星,结果令人满意。


Composites Science and Technology

Effect of blind-bolt repair method on vibration and compression characteristics of delaminated composite aircraft panels

Shiqing Mi, Junshan Hu, Shanyong Xuan, Jinyi Shen, Lei Xu, Wei Tian

doi:10.1016/j.compscitech.2024.110580

 

盲螺栓修复法对分层复合材料飞机面板振动和压缩特性的影响

The paper investigates the validity and reliability of the blind-bolt repair method for repairing delaminated composite aircraft panels. The delaminated specimens are prepared by inserting Teflon film during the manufacturing process to simulate interlayer damage. Subsequently, these specimens are repaired using the blind-bolt method. Modal and uniaxial compression tests are conducted to quantitatively evaluate the natural frequency, mode shape and load-bearing strength of both delaminated and bolt-repaired specimens. Digital image correlation and ultrasonic phased array techniques are employed to characterize buckling instability and damage evolution of specimens. The results reveal that the natural frequency and compressive buckling strength of delaminated specimens significantly decrease. The mode shape also changes nonlinearly with the stiffness reduction. This variation is proportional to the size and the quantity of delaminations. The blind-bolt repair method effectively restores the vibration and mechanical properties of the delaminated composite structure by reconnecting separated sub-laminates. A repair tolerance of 20 mm–60 mm is recommended for a single blind-bolt. When the delamination length is 35 mm, the repair efficiency for the critical buckling load and the ultimate load is the highest, at 58.3% and 64.4%, respectively.

本文研究了盲螺栓修复法在修复分层复合材料飞机面板方面的有效性和可靠性。分层试样是在制造过程中插入特氟龙薄膜来模拟层间损伤的。随后,使用盲孔螺栓法对这些试样进行修复。通过模态和单轴压缩试验,对分层试样和螺栓修复试样的固有频率、模态振型和承载强度进行定量评估。采用数字图像相关和超声相控阵技术来描述试样的屈曲不稳定性和损伤演变。结果表明,分层试样的固有频率和压缩屈曲强度明显降低。模态形状也随着刚度的降低而发生非线性变化。这种变化与分层的大小和数量成正比。盲螺栓修复法通过重新连接分离的子层板,有效恢复了分层复合结构的振动和机械性能。建议单个盲孔螺栓的修复公差为 20 毫米至 60 毫米。当分层长度为 35 毫米时,临界屈曲载荷和极限载荷的修复效率最高,分别为 58.3% 和 64.4%。


One-pot strategy for the preparation of nanoparticles grafted with bimodal polymers: An in-silico insight

Jinyuan Mao, Jiajia Zhou, Hong Liu

doi:10.1016/j.compscitech.2024.110583

用双峰聚合物接枝制备纳米颗粒的一锅策略:从分子内的角度看问题

Polymer nanocomposites composed of polymer-grafted nanoparticles (NPs) have garnered significant interest due to their diverse functional applications in various domains. The emerging concept of bimodal polymer brushes within the grafting-nanoparticle framework offers control over interfacial entropic and enthalpic interactions. Here, we introduce a novel one-pot strategy that integrates “grafting-to” and “grafting-from” methods to create polymer-grafted bimodal NPs. Utilizing coarse-grained molecular dynamics simulations with a stochastic reaction model, we explore the factors influencing grafting density and polydispersity in these NPs. Our findings demonstrate that this one-pot strategy achieves a polydispersity similar to the two-step “grafting-from then grafting-to” process, while attaining a moderate grafting density comparable to the “grafting-to then grafting-from” approach. Consequently, we analyze factors such as “grafting-from” reaction rates, and initial feeding ratios, step-addition techniques which collectively influence the final grafting density and polydispersity index within this one-pot strategy. This comprehensive investigation enhances our understanding of the kinetics behind synthesizing bimodal polymer-grafted NPs and offers insights for designing polymer-based nanocomposites with improved performance.

由聚合物接枝纳米粒子(NPs)组成的聚合物纳米复合材料因其在不同领域的多种功能应用而备受关注。在接枝纳米颗粒框架内的双模聚合物刷这一新兴概念提供了对界面熵和焓相互作用的控制。在这里,我们介绍了一种新颖的一锅策略,该策略将 "接枝到 "和 "接枝自 "方法整合在一起,以创建聚合物接枝的双峰 NPs。利用随机反应模型进行粗粒度分子动力学模拟,我们探索了影响这些 NPs 接枝密度和多分散性的因素。我们的研究结果表明,这种一锅策略所实现的多分散性与 "先接枝-再接枝-再接枝-再接枝 "的两步法相似,而达到的适度接枝密度与 "先接枝-再接枝-再接枝-再接枝 "的方法相当。因此,我们分析了 "从接枝到接枝 "反应速率、初始进料比、步骤添加技术等因素,这些因素共同影响了这种一锅策略的最终接枝密度和多分散指数。这项全面的研究加深了我们对合成双峰聚合物接枝 NPs 动力学的理解,并为设计性能更佳的聚合物基纳米复合材料提供了启示。




来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemMAGNETDeform振动疲劳断裂复合材料非线性化学航天汽车电子裂纹参数优化BIM理论纺织
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【新文速递】2024年3月17日复合材料SCI期刊最新文章

今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 4 篇,Composites Part B: Engineering 2 篇,Composites Science and Technology 1 篇Composite StructuresThe role of printing parameters on the short beam strength of 3D-printed continuous carbon fibre reinforced epoxy-PETG compositesJosé Humberto S. Almeida, Siddharth Jayaprakash, Kari Kolari, Jukka Kuva, Kirsi Kukko, Jouni Partanendoi:10.1016/j.compstruct.2024.118034 打印参数对 3D 打印连续碳纤维增强环氧-PETG 复合材料短束强度的影响It is well known that printing parameters strongly affect the mechanical performance of 3D printed parts, especially for recently developed continuous fibre-reinforced composites. This work then explores the printing parameters that mainly affect the mechanical properties of 3D printed composites: i) extruder temperature, ii) print speed, and iii) layer height. The interlaminar strength of the composites exhibits variations in response to changes in these parameters. The carbon fibre-reinforced thermoset filament is printed concomitantly with polyethylene terephthalate glycol (PETG) thermoplastic filament in a single nozzle, characterising a continuous fibre co-extrusion (CFC) process. There is a significant variation in the short beam strength for composites printed with different parameters. The load–displacement curves have a similar pattern, with clear load peaks followed by a plastic zone. Optical micrographs and computed tomography (CT) scans reveal that the microstructure is dependent on the printing parameters. Image analysis elucidates the various mechanisms of void formation. Following the application of a three-way ANOVA and statistical tests to quantify the effects and interactions among variables, the analysis concludes that the extruder temperature has the highest influence, followed by print speed and layer height. When considering all possible interactions between the factors, the interaction between print speed and layer height is the most impactful.众所周知,打印参数会严重影响三维打印部件的机械性能,特别是对于最近开发的连续纤维增强复合材料。因此,这项研究探索了主要影响三维打印复合材料机械性能的打印参数:i) 挤压机温度;ii) 打印速度;iii) 层高。复合材料的层间强度随这些参数的变化而变化。碳纤维增强热固性长丝与聚对苯二甲酸乙二酯(PETG)热塑性长丝在一个喷嘴中同时打印,这是连续纤维共挤(CFC)工艺的特点。用不同参数印制的复合材料的短梁强度差异很大。载荷-位移曲线具有相似的模式,即明显的载荷峰值之后是塑性区。光学显微照片和计算机断层扫描(CT)显示,微观结构取决于印刷参数。图像分析阐明了空隙形成的各种机制。通过三方方差分析和统计检验来量化变量之间的影响和相互作用,分析得出的结论是挤出机温度的影响最大,其次是打印速度和层高。考虑到各因素之间所有可能的交互作用,打印速度和层高之间的交互作用影响最大。Composites Part A: Applied Science and ManufacturingA fatigue test based on inclined loading block concept to benchmark delamination growth considering loading history and R -curve effectI. Lecinana, J. Renart, L. Carreras, A. Turon, J. Zurbitu, B.H.A.H. Tijsdoi:10.1016/j.compositesa.2024.108128 基于倾斜加载块概念的疲劳试验,在考虑加载历史和 R 曲线效应的情况下,对分层增长进行基准测试The main objective of this paper is to present a delamination benchmark test concept for composite materials that develop non-self-similar delamination in characterization specimens. The non-self-similar delamination is induced by rotating the loading blocks. The simplicity of the test allows for analyzing the loading mode history by concatenating different loading conditions, such as static and fatigue loading, under multiple loading modes. The methodology introduced in this paper can be particularized for any given composite material set and any sequence of loading conditions. To demonstrate the capabilities of the benchmark test, a case study is presented using AS4D/PEKK-FC thermoplastic composite material, which exhibits strong R-curve behavior. A sequence of opening and shear failure modes was applied under static and fatigue loading, providing an experimental data set that is ready to be used as a part of the validation of numerical predictive delamination models. The delamination process was monitored by X-ray radiography, and the final fracture surfaces were analyzed with scanning electron microscopy (SEM), giving a physical insight into the contribution of the fracture mechanisms to the delamination process.本文的主要目的是针对在表征试样中出现非自相矛盾分层的复合材料提出一种分层基准测试概念。非自相似分层是通过旋转加载块引起的。试验的简易性允许在多种加载模式下通过串联不同的加载条件(如静态和疲劳加载)来分析加载模式历史。本文介绍的方法可针对任何给定的复合材料组和任何加载条件序列进行具体化。为了证明基准测试的能力,本文使用 AS4D/PEKK-FC 热塑性复合材料进行了案例研究,该材料具有很强的 R 曲线行为。在静态和疲劳加载条件下,采用了一系列开裂和剪切失效模式,提供的实验数据集可用于验证数值预测分层模型。分层过程由 X 射线射线照相术进行监测,最终断裂表面由扫描电子显微镜(SEM)进行分析,从而对断裂机制对分层过程的贡献有了物理上的了解。Experiments and simulations for dynamic yarn pull-out response of Kevlar® fabricsFrank D. Thomas, Julie Roark, Paul Moy, Subramani Sockalingam, Daniel J. O'Brien, Tusit Weerasooriyadoi:10.1016/j.compositesa.2024.108147Kevlar® 织物的动态纱线拉出响应实验与模拟This work presents a novel experimental method for performing dynamic yarn pull-out using a modified tensile split Hopkinson pressure bar. The pull yarn is fixed to a piezoelectric load cell, while the woven fabric specimen is displaced at pull-out velocities ranging from 22 to 32 m/s. Pull-out force, displacement, and energy absorption over time are quantified for commercially available Kevlar® KM2 + woven fabric with pull lengths L = 5 mm and 27 mm in both quasi-static (QS) and dynamic loading. Dynamic peak pull-out force increases over QS by as much as 290–460 % and 170–220 % for L = 5 mm and L = 27 mm, respectively, and overall energy absorption increases by 140–420 % and 40–140 % for L = 5 mm and L = 27 mm, respectively. In QS loading, stick–slip interactions result in forces dropping by approximately 70–80 % between oscillating peaks for L = 5 mm and 30–40 % between peaks for L = 27 mm, and displacements between peaks are typically 1.5 mm, corresponding to two yarn crossings or two spans. However, at dynamic rates, stick–slip stage force drops by 100 % after the first and all subsequent peaks due to the dynamic release of the pull yarn from the fabric, resulting in the pull yarn passing through multiple yarn crossings. To better understand the underlying mechanisms for these observations, finite element simulations of the experiments are performed. Strain rate dependent longitudinal shear stiffness of the yarn is found to significantly affect the dynamic yarn pull-out response and explain the enhanced dynamic yarn pull-out peak force and energy absorption. While the shorter yarn of L = 5 mm experiences a more uniform loading along the entire length, non-uniform loading via progressive uncrimping is observed in the longer yarn of L = 27 mm along the length.这项研究提出了一种新颖的实验方法,使用改良的拉伸分体式霍普金森压力棒进行动态纱线拉拔。拉伸纱线固定在压电称重传感器上,同时编织物试样以 22 至 32 m/s 的拉伸速度发生位移。在准静态(QS)和动态加载条件下,对拉伸长度 L = 5 毫米和 27 毫米的市售 Kevlar® KM2 + 编织物的拉伸力、位移和随时间变化的能量吸收进行了量化。L = 5 毫米和 L = 27 毫米的动态峰值拉拔力分别比 QS 增加了 290-460 % 和 170-220 %,L = 5 毫米和 L = 27 毫米的整体能量吸收分别增加了 140-420 % 和 40-140 %。在 QS 载荷中,粘滑相互作用导致 L = 5 mm 的振荡峰之间的力下降约 70-80%,L = 27 mm 的振荡峰之间的力下降 30-40%,峰之间的位移通常为 1.5 mm,相当于两个纱线交叉点或两个跨度。然而,在动态速率下,由于牵伸纱线从织物上动态释放,导致牵伸纱线通过多个纱线交叉点,粘滑阶段力在第一个峰值和所有后续峰值之后下降 100%。为了更好地理解这些观测结果的内在机制,我们对实验进行了有限元模拟。结果发现,与应变速率相关的纱线纵向剪切刚度会显著影响动态拉纱响应,并解释了动态拉纱峰值力和能量吸收增强的原因。L = 5 mm 的较短纱线在整个长度上承受的载荷更为均匀,而 L = 27 mm 的较长纱线则在整个长度上通过渐进式非卷曲承受非均匀载荷。Resin percolation and intimate contact in fast processing of thermoplastic compositesJoseph Kirchhoff, Omar Ghattas, Mehran Tehranidoi:10.1016/j.compositesa.2024.108145热塑性复合材料快速加工过程中的树脂渗透和亲密接触Fusion bonding of thermoplastic composites (TPCs) requires intimate contact before polymer interdiffusion and solidification can establish an interlaminar bond. The lack of such intimate contact results in voids or disbonds. This study showed through cross-sectional imaging and scaling analysis that percolation flow, rather than squeeze flow, of resin through fibers is the dominant mechanism to achieve intimate contact in rapid TPC processes such as automated fiber placement (AFP) and welding. A 1D intimate contact model based on resin percolation, derived from Darcy’s Law, is presented and compared to experiments. While this model proved effective in comparing processing conditions by adeptly capturing trends, it under-predicted resin content in samples processed using AFP with low pressure. The model was extended to high processing rates. In-situ high-speed imaging and ex-situ microscopy revealed void size and morphology based on AFP processing parameters. The results of this study can guide fast processing of thermoplastic composites.热塑性复合材料(TPC)的熔融粘接需要在聚合物相互扩散和凝固之前进行亲密接触,以建立层间粘接。缺乏这种亲密接触会导致空隙或脱粘。本研究通过横截面成像和缩放分析表明,在自动纤维贴装(AFP)和焊接等快速 TPC 工艺中,树脂通过纤维的渗流而非挤压流是实现亲密接触的主要机制。根据达西定律推导出了基于树脂渗流的一维亲密接触模型,并与实验进行了比较。事实证明,该模型能有效捕捉趋势,从而有效比较加工条件,但它对使用低压 AFP 加工的样品中的树脂含量预测不足。该模型被扩展到高加工率。原位高速成像和原位显微镜显示了基于 AFP 加工参数的空隙大小和形态。该研究结果可为热塑性复合材料的快速加工提供指导。Preparation of unsaturated self-emulsifying polyester sizing agent for improving interfacial and mechanical properties of carbon fiber/vinyl ester resin compositeYizhi Geng, Xin Wang, Jiawei Yao, Kangmin Niu, Chuncai Yangdoi:10.1016/j.compositesa.2024.108148制备用于改善碳纤维/乙烯基酯树脂复合材料界面和机械性能的不饱和自乳化聚酯上浆剂In order to promote the interfacial adhesion between carbon fiber and vinyl ester matrix, a series of unsaturated self-emulsifying anionic polyester sizing agents were designed. The results indicated that the sizing agents exhibited a uniform particle size distribution at the nanometer level and demonstrated favorable thermal stability below 200 °C. As the content of double bonds of sizing agents increases, the glass transition temperature also increases, and the moisture absorption of sized carbon fiber decreases. The carbon fiber surface becomes smoother after sizing. Moreover, the interlaminar shear strength and interfacial shear strength increased by 18.8 % and 43.4 %, respectively, compared to the commercial carbon fiber. This is mainly due to the unsaturated bonds in the sizing agent react with the free radicals on the surface of the carbon fiber, which enhance the interface bonding strength between the sizing agent and the surface of the carbon fiber and the vinyl ester matrix.为了促进碳纤维与乙烯基酯基体之间的界面粘合,设计了一系列不饱和自乳化阴离子聚酯上浆剂。结果表明,这些上浆剂的粒度分布均匀,达到纳米级,并在 200 °C 以下表现出良好的热稳定性。随着上浆剂双键含量的增加,玻璃化转变温度也随之升高,上浆碳纤维的吸湿性降低。上浆后的碳纤维表面更加光滑。此外,与商用碳纤维相比,层间剪切强度和界面剪切强度分别提高了 18.8% 和 43.4%。这主要是由于上浆剂中的不饱和键与碳纤维表面的自由基发生反应,从而增强了上浆剂与碳纤维表面和乙烯基酯基体之间的界面结合强度。Composites Part B: Engineering“Subconsciousness-triggered” human body defensive strategy: Bi-stability intelligent joint with bionic kirigami structureJianyu Zhou, Mei Liu, Sheng Wang, Junshuo Zhang, Mingyang Ni, Shuai Liu, Yu Wang, Huaxia Deng, Bing Liu, Xinglong Gongdoi:10.1016/j.compositesb.2024.111368 "下意识触发 "人体防御策略:具有仿生桐神结构的双稳态智能关节Kirigami structures are increasingly popular in wearable devices due to their exceptional properties. However, their mechanical robustness and anti-impact properties during structural deformation have been overlooked. This study addresses this issue by introducing defects on the surface of composites, mimicking pangolin scales to produce negative Poisson's ratio deformation during tensile strain. Kevlar, conductive shear stiffening elastomer (c-SSE), and PET are combined (Kiri-Kevlar). When subjected to impact, the subconscious rapid response of humans leads to bending arms or curling up, causing Kiri-Kevlar assembled at joints to stretch and undergo structural deformation. The Kiri-Kevlar deformation and high energy dissipation characteristics of c-SSE effectively resist external impact. In summary, a functional-integrated wearable device is developed based on a bionic kirigami structure, realizing efficient anti-impact and providing ideas for a new generation of human-computer interactive intelligent protection devices.叽里格米结构因其优异的性能在可穿戴设备中越来越受欢迎。然而,它们在结构变形过程中的机械稳健性和抗冲击性能却一直被忽视。本研究通过在复合材料表面引入缺陷,模仿穿山甲的鳞片,在拉伸过程中产生负泊松比变形,从而解决了这一问题。将 Kevlar、导电剪切加固弹性体(c-SSE)和 PET 结合在一起(Kiri-Kevlar)。当受到冲击时,人类下意识的快速反应会导致手臂弯曲或卷曲,从而使装配在关节处的 Kiri-Kevlar 纤维拉伸并发生结构变形。c-SSE 的 Kiri-Kevlar 变形和高能量耗散特性可有效抵御外部冲击。总之,基于仿生叽里格米结构开发的功能集成可穿戴设备,实现了高效抗冲击,为新一代人机交互智能防护设备提供了思路。Enhancing mechanical and wear performances of magnesium matrix composites using low-cost squid quill ashBassiouny Saleh, Reham Fathi, Lu Zhang, Zhiwei Yu, Shenguang Liu, Liguo Zhaodoi:10.1016/j.compositesb.2024.111383利用低成本乌贼毛灰提高镁基复合材料的机械和耐磨性能The increasing demand for lightweight, cost-effective aerospace and automotive components with higher performance promotes interest in the use of naturally occurring materials, such as magnesium composites with natural and low-cost reinforcements. This research focuses on stir casting to reinforce magnesium matrix composites with squid quill ash (SQA) particles, aiming to improve their mechanical and wear performances. The results show that the mechanical and wear properties of magnesium matrix composites can be improved significantly by increasing the SQA content. Incorporating 10% SQA reinforcements in AZ91 magnesium alloy leads to a maximum increase in hardness, yield strength and ultimate tensile strength by 32.34%18.86%, and 12.34%, respectively. When compared to the matrix alloy, the wear resistance of the composites reinforced with 5 wt.% and 10 wt.% of SQA particles is improved by 14.05% and 30.81%, respectively. These findings demonstrated the feasibility of using SQA particles in the production of magnesium matrix composites. This not only reduces environmental impact by repurposing SQA, but also provides a practical method for the economical utilization of SQA particles in the fabrication of magnesium matrix composites for aerospace and automotive applications.对重量轻、成本低、性能高的航空航天和汽车零部件的需求日益增长,这促进了人们对使用天然材料的兴趣,例如使用天然低成本增强材料的镁复合材料。本研究的重点是用搅拌铸造法来增强鱿鱼毛灰(SQA)颗粒的镁基复合材料,以改善其机械和磨损性能。结果表明,镁基复合材料的机械和磨损性能可通过增加 SQA 含量得到显著改善。在 AZ91 镁合金中加入 10%的 SQA 增强材料可使硬度、屈服强度和极限拉伸强度分别最大提高 32.34%18.86% 和 12.34%。与基体合金相比,使用 5 wt.% 和 10 wt.% 的 SQA 颗粒增强的复合材料的耐磨性分别提高了 14.05% 和 30.81%。这些发现证明了在镁基复合材料生产中使用 SQA 颗粒的可行性。这不仅通过对 SQA 的再利用减少了对环境的影响,还为经济地利用 SQA 颗粒制造航空航天和汽车用镁基复合材料提供了一种实用方法。Composites Science and TechnologyEnhancing interface compatibility in high-filled coal gangue/polyethylene composites through silane coupling agent-mediated interface modificationChao Li, Hongqiang Liao, Hongyu Gao, Fangqin Chengdoi:10.1016/j.compscitech.2024.110546 通过硅烷偶联剂介导的界面改性提高高填充煤矸石/聚乙烯复合材料的界面相容性This study investigates the profound impact of surface modification using the silane coupling agent KH550 on Coal Gangue (CG)-Polyethylene (PE) composites. The aim was to enhance the properties of composites while addressing waste material accumulation concerns. Comprehensive analyses elucidated the mechanism of interface formation and the subsequent influence on composite properties. Surface modification of CG with KH550 demonstrated pronounced effects on physical, mechanical, and thermal properties of the resulting composites. Notably, the coupling agent facilitated covalent bonding with CG, preventing particle agglomeration and enhancing dispersion stability. The introduction of KH550 contributed to heterogeneous nucleation, augmenting composite crystallinity and interfacial bonding with the resin, thereby improving overall compatibility. Mechanical tests revealed substantial enhancements in tensile and bending strengths with optimal KH550 content. However, excess KH550 led to diminishing returns, highlighting the critical balance required for effective modification. Thermal stability assessments demonstrated improved properties owing to KH550 modification, validating its role in safeguarding the composite matrix from thermal degradation. Microstructural analyses, including SEM, FTIR, DSC, and XRD, provided insights into the interface morphology, chemical composition, crystalline behavior, and structure of the composites. The SEM micrographs elucidated a progressive shift from clear interface boundaries to more homogenously blended states with increasing KH550 content, indicative of enhanced interaction between CG and PE. This comprehensive study demonstrates that KH550 modification offers a strategic approach to optimize CG-PE composites, showcasing potential applications in the automotive and construction industries. Those findings underscore the significance of surface modification techniques in enhancing composite properties and utilizing waste resources efficiently.本研究探讨了使用硅烷偶联剂 KH550 对煤矸石(CG)-聚乙烯(PE)复合材料进行表面改性的深远影响。目的是提高复合材料的性能,同时解决废料堆积问题。综合分析阐明了界面形成的机理及其对复合材料性能的影响。用 KH550 对 CG 进行表面改性,对所得复合材料的物理、机械和热性能产生了明显的影响。值得注意的是,偶联剂促进了与 CG 的共价键合,防止了颗粒团聚并提高了分散稳定性。KH550 的引入促进了异质成核,提高了复合材料的结晶度以及与树脂的界面结合,从而改善了整体相容性。机械测试表明,KH550 的最佳含量可大幅提高拉伸强度和弯曲强度。然而,过量的 KH550 会导致收益递减,这突出表明了有效改性所需的关键平衡。热稳定性评估表明,KH550改性提高了性能,验证了其在防止复合材料基体热降解方面的作用。包括扫描电镜、傅立叶变换红外光谱、DSC 和 XRD 在内的微观结构分析有助于深入了解复合材料的界面形态、化学成分、结晶行为和结构。扫描电镜显微照片显示,随着 KH550 含量的增加,界面边界逐渐从清晰转变为更均匀的混合状态,这表明 CG 与 PE 之间的相互作用增强。这项综合研究表明,KH550 改性为优化 CG-PE 复合材料提供了一种战略性方法,在汽车和建筑行业具有潜在的应用前景。这些发现强调了表面改性技术在提高复合材料性能和有效利用废弃资源方面的重要意义。来源:复合材料力学仿真Composites FEM

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