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【新文速递】2024年4月20日复合材料SCI期刊最新文章

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今日更新:Composite Structures 2 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 3 篇,Composites Science and Technology 3 篇

Composite Structures

Failures of laminates under nonpenetrative impacts

Junchen Zhou, Zheng-Ming Huang

doi:10.1016/j.compstruct.2024.118096

 

非穿透性冲击下层压板的失效

Various failures of laminates under low-velocity impacts without penetration are simulated systematically with a limited number of inputs, all measurable following existing standards without any data calibration. No iteration is required to determine any of the failures investigated in this work. Any two adjacent lamina (primary) layers are inserted with a matrix (secondary) layer, whose stresses are modified through two modification coefficients (MCs). The MCs are determined through peak loads of double cantilever beam and end-notched flexure tests on unidirectional laminates, and their weak sensitivity to sample dimensions is shown. Delamination is reproduced by deleting failed secondary-layer elements. The homogenized stresses of fiber and matrix obtained by Bridging Model are converted into true values through the author’s true stress theory to estimate constituent-induced intralaminar failures, such as fiber breakage, matrix crack and interface debonding, against the monolithic fiber or matrix strengths measured independently. Primary- layer elements attaining a fatal failure (fiber breakage or matrix crack accompanied with a critical strain condition) are deleted before an impact termination corresponding to separation of the impactor from target. The predicted delamination areas and impact force, displacement and energy histories for the laminates of three lamination angles under different impact energies agree well with our measured counterparts, validating the efficiency of the simulation.

本文系统地模拟了层压板在低速冲击下无穿透的各种失效,输入数量有限,所有失效均可按照现有标准测量,无需任何数据校准。不需要迭代来确定本工作中调查的任何故障。任意两个相邻的层(主)层插入基质(次)层,基质(次)层的应力通过两个修正系数(mc)进行修正。通过双悬臂梁峰值荷载和单向层合板端缺口挠曲试验确定了MCs,表明MCs对试样尺寸的敏感性较弱。通过删除失败的第二层元素来重现分层。通过作者提出的真应力理论,将桥接模型得到的纤维和基体的均质应力转换为真值,根据独立测量的整体纤维或基体强度,估计由成分引起的纤维断裂、基体裂纹和界面脱粘等层内破坏。达到致命破坏(纤维断裂或伴随临界应变条件的基体裂纹)的初级层单元在撞击终止前被删除,对应于撞击器与目标的分离。在不同冲击能量下,三种层合角度层合材料的分层面积、冲击力、位移和能量历史与实测数据吻合较好,验证了仿真的有效性。


Verification and Validation of finite element models for laminated timber structures using solid, solid-beam and solid-shell approaches

Jeanne Paroissien, Marc Oudjene, Pascal Lardeur

doi:10.1016/j.compstruct.2024.118083

 

采用实心、实心梁和实心壳方法的层合木结构有限元模型的验证与验证

This paper presents a numerical approach to assess efficiently the vibration performance of adhesive-free engineered wood products assembled through compressed wood dowels. Predictive finite element models are obtained by applying the Verification and Validation methodology. The models are first developed using solid elements. Then, solid-beam and solid-shell approaches based on standard solid elements are developed with first-order or higher-order theories. Beam or shell kinematic assumptions are applied throughout the cross-section of the dowels and through the thickness of the layers. From a numerical point of view, a modification of the system of algebraic equations, based on the concept of independent and dependent nodes, is developed. Dependent nodes are eliminated, resulting in a significant reduction in the number of degrees of freedom and floating-point operations. The methodology is evaluated for the calculation of frequencies and mode shapes of adhesive-free laminated timber beams and timber panels with a mix of solid elements, solid-shell and solid-beam approaches. The study highlights the efficiency of the proposed modelling approach in terms of quality of results and model size reduction.

本文提出了一种通过压缩木钉装配无胶粘剂工程木制品的振动性能的数值评估方法。应用验证和验证方法得到预测有限元模型。这些模型首先是使用实体元素开发的。然后,基于一阶或高阶理论,发展了基于标准实体单元的固体梁和固体壳方法。梁或壳的运动学假设应用于整个销子的横截面和层的厚度。从数值角度出发,基于独立节点和相依节点的概念,对代数方程组进行了改进。消除了相关节点,从而大大减少了自由度和浮点操作的数量。该方法用于计算无胶粘剂层压木梁和木板的频率和模态振型,采用固体单元、固体壳和固体梁的混合方法。该研究强调了所提出的建模方法在结果质量和模型尺寸减小方面的效率。


Composites Part A: Applied Science and Manufacturing

A new method for obtaining the in situ interfacial shear strength of the 3D woven composite

Qingsong Zong, Jinzhao Huang, Ruijian Sun, Junfeng Ding, Tao Zheng, Kai Huang, Licheng Guo

doi:10.1016/j.compositesa.2024.108215

 

三维编织复合材料原位界面抗剪强度的一种新方法

The interfacial strengths have significant effects on the accuracy of numerical simulations for the 3D woven composite (3DWC). However, obtaining the in situ interfacial strengths of the 3DWC currently presents substantial challenges. Furthermore, it remains questionable whether the interlaminar strength of laminate composites can represent the interfacial strength of the 3DWC. This paper proposes an in situ experiment-simulation (ISES) method to determine the shear strength of the interface within the 3DWC. For this purpose, several novel off-axis tensile specimens were designed with a simplified and continuous interface structure. A corresponding full-scale finite element (FE) model based on the mesoscale structure of the specimen was established, employing the cohesive zone model to describe the interface mechanical behavior. The in situ interfacial shear strength of the 3DWC was then obtained using the proposed ISES method.

界面强度对三维编织复合材料(3DWC)的数值模拟精度有重要影响。然而,获得3DWC的原位界面强度目前面临着巨大的挑战。此外,层压复合材料的层间强度能否代表3DWC的界面强度还有待商榷。本文提出了一种原位实验模拟(ISES)方法来确定3DWC内界面的抗剪强度。为此,设计了几种具有简化连续界面结构的新型离轴拉伸试件。基于试件的细观结构,建立了相应的全尺寸有限元模型,采用内聚区模型描述界面力学行为。然后使用提出的ISES方法获得了3DWC的原位界面抗剪强度。


Correlation between interfacial bond strength and degree of healing in overprinting PAEK on CF/PAEK composites

Nan Yi, Yu Chen, Jiajia Shen, Richard Davies, Oana Ghita

doi:10.1016/j.compositesa.2024.108217

CF/PAEK复合材料套印PAEK时界面结合强度与愈合程度的关系

Overprinting is a new emerging hybrid manufacturing process that combines composite manufacturing and additive manufacturing, offering the dual advantages of cost-effectiveness and design freedom. This study presents the first endeavour of overprinting high temperature polymers. The joint strength was measured by the rib-on-plate test. A modified non-isothermal healing model was developed to predict the interfacial bond strength, based on thermal history at the interface during overprinting. The model captures how crystallisation impedes interfacial diffusion. The degree of intimate contact was employed to evaluate the true interfacial strength. A positive linear correlation was identified between the interfacial bond strength and the final degree of healing. This study reveals the critical effect of crystallisation on diffusion when the processing temperature is above the glass transition temperature, offering a more comprehensive understanding of the bonding mechanism of high temperature semi-crystalline polymers.

套印是一种新兴的混合制造工艺,它结合了复合材料制造和增材制造,具有成本效益和设计自由的双重优势。本研究是高温聚合物套印的首次尝试。采用肋板试验测量接头强度。建立了一种改进的非等温愈合模型,基于叠印过程中界面的热历史来预测界面结合强度。该模型捕捉到了结晶如何阻碍界面扩散。用亲密接触度来评价界面的真实强度。界面结合强度与最终愈合程度呈线性正相关关系。本研究揭示了当加工温度高于玻璃化转变温度时结晶对扩散的关键影响,为更全面地理解高温半晶聚合物的键合机制提供了依据。


Composites Part B: Engineering

Room-temperature plasticity of metallic glass composites: A review

Quan Dong, Jun Tan, Caiju Li, Baran Sarac, Jürgen Eckert

doi:10.1016/j.compositesb.2024.111453

 

金属玻璃复合材料的室温塑性研究进展

The remarkable mechanical, chemical, and physical characteristics exhibited by metallic glasses (MGs), arising from their disordered atomic arrangement, present substantial application prospects in the aerospace industry, consumer electronics, biomedical implants and devices, sporting goods, etc. However, the brittleness introduced by highly localized shear bands poses a limitation to broader applications. A promising approach to overcome this limitation involves the development of metallic glass composites (MGCs) via introducing a second phase (or multiple phases) to impede shear band propagation, effectively enhancing MGs' plasticity. This review aims to provide a comprehensive overview of the advancements in methods and mechanisms for improving the plasticity of MGCs. It is divided into two main sections: one detailing the impact of in-situ second phases, such as glassy, quasi-crystal, and crystalline phases (nano- and micro-particles, dendrites, B2 phases, ceramic phases, etc.), on the plasticity of MGCs at different scales. The other section explores the influence of ex-situ second phases on the plasticity of MGCs, encompassing particles, fibers, interpenetrating phases, as well as laminated structures like nano-laminated architecture, coatings, and shrink-fit metal sleeves. Additionally, the review outlines challenges and future prospects in the quest for high plasticity MGCs at room temperature.

金属玻璃由于其无序的原子排列而表现出非凡的机械、化学和物理特性,在航空航天工业、消费电子、生物医学植入物和设备、体育用品等方面具有巨大的应用前景。然而,高度局部化剪切带带来的脆性限制了其更广泛的应用。克服这一限制的一个有希望的方法是通过引入第二相(或多相)来阻止剪切带传播,从而有效提高金属玻璃复合材料(MGCs)的塑性。本文综述了提高MGCs塑性的方法和机制的研究进展。它分为两个主要部分:一部分详细介绍了原位第二相,如玻璃相、准晶相和结晶相(纳米和微粒、枝晶、B2相、陶瓷相等)对不同尺度MGCs塑性的影响。另一部分探讨了非原位第二相对MGCs塑性的影响,包括颗粒、纤维、互穿相以及层压结构,如纳米层压结构、涂层和收缩金属套管。此外,综述概述了在室温下追求高塑性MGCs的挑战和未来前景。


Fatigue response of multiscale extrusion-based additively manufactured acrylonitrile butadiene styrene-graphene nanoplatelets composites

Soran Hassanifard, Kamran Behdinan

doi:10.1016/j.compositesb.2024.111464

多尺度挤压增材制备丙烯腈-丁二烯-石墨烯纳米片复合材料的疲劳响应

This study investigates the effect of varying concentrations of graphene nanoplatelets (GNPs) on the mechanical and fatigue characteristics of acrylonitrile butadiene styrene (ABS)/GNPs nanocomposites, both in filament form and as 3D-printed parts with different raster orientations. Quasi-static and cyclic loading tests were performed on specimens containing 0.1 wt.%, 0.5 wt.%, 1.0 wt.%, and 2.0 wt.% GNPs. The results indicated that the addition of 0.1 wt.% GNPs to the ABS polymer matrix increased the ultimate tensile strength (UTS) of the filament by 18%. Addition of 1.0 wt.% and 2.0 wt.% GNPs to the matrix improved the Young's modulus of the filament by up to about 35% but did not enhance the UTS. The filament containing 0.5 wt.% GNPs demonstrated the highest fatigue life, even higher than that of the standard samples fabricated through injection molding technique. This was due to its high static strength, Young's modulus, and ductility. However, when the ABS/GNPs nanocomposites were 3D-printed, the addition of GNPs had no major impact on their fatigue life, especially in the higher load levels. Inadequate adhesion and reduced interlayer bonding strength resulted in a detrimental impact on fatigue life of 3D-printed objects. The extrudate-swell phenomenon seems to significantly affect this reduction in fatigue life. To address this, larger nozzle diameter (0.6 mm) was used in fabricating 3D-printed samples. Results indicated that samples with less distortion and smaller extrudate-swell had higher fatigue life. It highlights the importance of considering GNP concentration and printing parameters for optimal fatigue properties in ABS/GNPs composites.

本研究研究了不同浓度的石墨烯纳米片(GNPs)对丙烯腈-丁二烯-苯乙烯(ABS)/GNPs纳米复合材料的机械和疲劳特性的影响,包括长丝形式和具有不同光栅取向的3d打印部件。准静态和循环加载试验对含有0.1 wt.%、0.5 wt.%、1.0 wt.%和2.0 wt.% GNPs的试样进行。结果表明,在ABS聚合物基体中添加0.1 wt.%的GNPs可使长丝的极限拉伸强度提高18%。在基体中加入1.0 wt.%和2.0 wt.%的GNPs可使长丝的杨氏模量提高约35%,但没有提高UTS。含有0.5 wt.% GNPs的长丝显示出最高的疲劳寿命,甚至高于通过注射成型技术制造的标准样品。这是由于其高静态强度,杨氏模量和延展性。然而,当ABS/GNPs纳米复合材料进行3d打印时,GNPs的添加对其疲劳寿命没有重大影响,特别是在更高的载荷水平下。粘附力不足,层间结合强度降低,对3d打印物体的疲劳寿命产生不利影响。挤压膨胀现象似乎对疲劳寿命的降低有显著影响。为了解决这个问题,在制造3d打印样品时使用了更大直径(0.6 mm)的喷嘴。结果表明,变形小、挤压膨胀小的试样具有较高的疲劳寿命。它强调了考虑GNP浓度和打印参数对ABS/GNPs复合材料最佳疲劳性能的重要性。


Silk-inspired architectured filament with enhanced stiffness and toughness for fused deposition modelling (FDM)

Li Liang, Filippo Berto, Chao Gao

doi:10.1016/j.compositesb.2024.111474

丝质启发的结构长丝,具有增强的刚度和韧性,用于熔融沉积建模(FDM)

Architectured materials, those capable of manipulating the spatial configurations of two or more material phases, have recently gained substantial attention, primarily due to their unprecedented material properties (e.g., exceptional strength-to-weight ratio and intriguing negative Poisson's ratio). Most architectured materials draw inspiration from the microstructure of natural solutions. One of fascinating examples are spider silk and cocoon silk. Their multimaterial core-shell fibrous structure exhibits remarkable mechanical properties—high stiffness, strength, and toughness. In this study, silk-inspired dual-phase Core-Shell Architectured Filament (CSAF), which combines a rigid Polylactic Acid (PLA) core with a soft Thermoplastic Polyurethane (TPU) shell, was developed as feedstock for additive manufacturing. The mechanical testing of dual-phase CASF printed samples reveal intriguing results. Notably, the optimized CASF in this study, whose volume fraction of rigid core was set as 52%, was observed a substantial improvement of the printed specimens in initial stiffness and energy absorption capacity—up to a remarkable 14-fold increase in initial stiffness and a ∼9% enhancement in energy absorption when compared to the pure TPU filament. To gain a deeper understanding of the synergistic effects arising from geometrical and material configurations on the structure’s damage mechanism, a theoretical model of this core-shell structure was developed. Computational models have been built to validate theoretical model, and the results from finite element analysis are in excellent agreement with experimental results. These discoveries offer valuable insights to enhance mechanical performance of the feedstock for additive manufacturing.

建筑材料,那些能够操纵两个或多个材料相的空间结构的材料,最近获得了大量的关注,主要是由于它们前所未有的材料特性(例如,特殊的强度重量比和有趣的负泊松比)。大多数建筑材料从自然溶液的微观结构中汲取灵感。其中一个有趣的例子是蜘蛛丝和蚕丝。它们的多材料核壳纤维结构具有显著的机械性能——高刚度、高强度和高韧性。在这项研究中,丝绸启发的双相核-壳结构长丝(CSAF),结合了刚性聚乳酸(PLA)芯和柔软的热塑性聚氨酯(TPU)壳,被开发作为增材制造的原料。双相CASF打印样品的力学测试揭示了有趣的结果。值得注意的是,本研究中优化的CASF,刚性芯的体积分数设置为52%,与纯TPU长丝相比,打印样品的初始刚度和能量吸收能力有了显著提高,初始刚度提高了14倍,能量吸收能力提高了9%。为了更深入地了解几何构型和材料构型对结构损伤机理的协同作用,建立了这种核壳结构的理论模型。建立了计算模型对理论模型进行了验证,有限元分析结果与实验结果吻合良好。这些发现为提高增材制造原料的机械性能提供了有价值的见解。


Composites Science and Technology

Automatic reconstruction of closely packed fabric composite RVEs using yarn-level micro-CT images processed by convolutional neural networks (CNNs) and based on physical characteristics

Chongrui Tang, Jianchao Zou, Yifeng Xiong, Biao Liang, Weizhao Zhang

doi:10.1016/j.compscitech.2024.110616

 

基于物理特征的纱线级微ct图像卷积神经网络(cnn)自动重建紧密堆积织物复合材料RVEs

Micro-CT scanning is an advanced technique to reconstruct inner architectures for RVEs of fabric composites. Currently, however, there exist few automatic approaches to separate closely packed yarns in the micro-CT images with economical resolution that can only identify yarns but not individual fibers. To tackle this issue, an innovative method has been developed in this work to identify cross-section area of the yarns via deep-learning-based image segmentation, and then reconstruct 3D geometry model of the composites containing local fiber orientations. The image segmentation was achieved through semantic segmentation by U-Net with validation accuracy of 87% counted by mIOU and object detection by YOLO v8 with validation accuracy of 99.5% counted by mAP50. Micro-CT slices with different morphological characteristics were divided into three groups via a ResNet50-based image classification network and selected in ratio to form the training datasets for U-Net and YOLO v8 with high representativity and efficiency. Extraction of individual cross-sections of weft and warp yarns were conducted only using the micro-CT scanning from one angle of view to reduce scanning cost and yarn-to-yarn penetration error. An algorithm considering physical constraints of the yarns was also completed to estimate local fiber orientations with maximum error of 18.065°, nearly 50% smaller than the existing method.

微ct扫描是一种重建织物复合材料rve内部结构的先进技术。然而,目前很少有经济分辨率的自动方法从微ct图像中分离出紧密缠绕的纱线,这种方法只能识别纱线而不能识别单个纤维。为了解决这一问题,本工作开发了一种创新的方法,通过基于深度学习的图像分割来识别纱线的横截面面积,然后重建包含局部纤维取向的复合材料的三维几何模型。通过U-Net进行语义分割,mIOU计算验证准确率为87%;使用YOLO v8进行目标检测,mAP50计算验证准确率为99.5%。通过基于resnet50的图像分类网络,将不同形态特征的Micro-CT切片分成三组,按比例选择,形成具有较高代表性和效率的U-Net和YOLO v8的训练数据集。为了减少扫描成本和纱线间的穿透误差,只使用微ct扫描从一个角度提取经纱和纬纱的单个截面。提出了一种考虑纱线物理约束的局部纤维取向估计算法,最大误差为18.065°,比现有方法减小了近50%。


A comprehensive study of low-velocity impact behavior and damage evaluation of angle-ply thin woven GFRP composites under various temperatures

U.A. Khashaba

doi:10.1016/j.compscitech.2024.110608

 

不同温度下角层GFRP薄编织复合材料低速冲击性能及损伤评价的综合研究

The recent climatic changes have resulted in a significant increase in temperatures over 50°C during summer midday in certain countries. This has motivated the study of the low-velocity impact (LVI) response of angle-ply thin woven glass fiber-reinforced polymer composites under temperatures of 25°C, 50°C and 75°C. The LVI performance of the laminates was assessed by eighteen parameters. A new inexpensive image processing method is developed to accurately measure the damage diameter, area, and perimeter length, which significantly aids in analyzing the damage mechanisms under various test conditions. The damage perimeter length is a new parameter that is used to interprets the change of material behaviors with temperature. The LVI results showed that the impact bending stiffness is increased with impact energy (Ei) due to increasing strain rates, which leads to decreasing the molecular mobility of polymer chains and hence, the materials tend to behave more brittle. Delamination threshold force increased with impact energy and vice versa with temperature. Soaking the specimens for 1 h at 50°C improved post curing and thus, enhanced the cross linking density, which significantly improved most of the impact properties. The penetration energy threshold of 25.5J (85% of Ei) is observed at 30J-50°C. Relaxation of the polymer chain within the glass transition region at 75°C leads to full fracture energy threshold at 30J, which correlated with open force-deformation curve, absorbed energy of 100%, zero elastic energy, zero rebound energy, zero rebound velocity, and increase contact duration. The proposed multivariate regression models accurately predict the impact properties.

最近的气候变化导致某些国家夏季正午的气温大幅升高,超过 50°C。这促使我们对角形薄层玻璃纤维增强聚合物复合材料在 25°C、50°C 和 75°C 温度下的低速冲击(LVI)响应进行了研究。层压板的低速冲击性能由 18 个参数进行评估。开发了一种新的廉价图像处理方法来精确测量损伤直径、面积和周长,这大大有助于分析各种测试条件下的损伤机制。损伤周长是一个新参数,用于解释材料行为随温度的变化。LVI 结果表明,由于应变率的增加,冲击弯曲刚度随冲击能量(Ei)的增加而增加,这导致聚合物链的分子流动性降低,从而使材料表现得更脆。分层阈值力随冲击能量的增加而增加,反之亦然。将试样在 50°C 下浸泡 1 小时可改善后固化,从而提高交联密度,显著改善大部分冲击性能。在 30J-50°C 时,可观察到 25.5J 的穿透能阈值(Ei 的 85%)。聚合物链在 75°C 玻璃转变区内的松弛导致 30J 时达到完全断裂能阈值,这与开放的力-变形曲线、100% 的吸收能、零弹性能、零反弹能、零反弹速度和接触持续时间的增加相关。所提出的多元回归模型能准确预测冲击特性。


Torsional progressive damage mechanisms in 3-D braided carbon fiber/epoxy resin composite tubes

Limeng Xun, Yasmine Mosleh, Baozhong Sun, John-Alan Pascoe, Bohong Gu

doi:10.1016/j.compscitech.2024.110615

 

三维编织碳纤维/环氧树脂复合材料管扭转递进损伤机理

3-D braided composites are a promising material for manufacturing tubular structures. However, a thorough understanding of their damage mechanisms under torsion is required to maximize their potential applications. The present work constructed a multiscale equivalent model, integrating mesoscopic and homogeneous structures to reveal torsional behavior of 3-D braided carbon fiber/epoxy resin composite tubes. The cumulative failure process, spatial stress distribution and interface damage were calculated to illustrate stress transfer and damage initiation and propagation. It is found that stress varies on the surface and internally within the representative unit cell (RUC). The yarns experience both axial tension parallel to the direction of torsion and axial compression perpendicular to the direction of torsion. The stress difference between them leads to damage initiation and propagation. Interfacial cracking as main damage mode hinders the stress transfer between resin and fiber bundles. The results show that the braided yarn path, axial stress dispersion in two directions and localization of damage effectively impede the torsional damage propagation.

三维编织复合材料是一种很有前途的管状结构材料。然而,为了最大限度地发挥其潜在的应用潜力,需要彻底了解它们在扭转下的损伤机制。本文建立了一个多尺度等效模型,综合了细观和均相结构,揭示了三维编织碳纤维/环氧树脂复合材料管的扭转行为。计算了累积破坏过程、空间应力分布和界面损伤,说明了应力传递和损伤的发生和扩展。研究发现,应力在典型单元胞(RUC)表面和内部均有变化。纱线经历平行于扭转方向的轴向拉力和垂直于扭转方向的轴向压缩。它们之间的应力差导致了损伤的发生和扩展。界面开裂是树脂束与纤维束之间应力传递的主要破坏方式。结果表明:编织纱线的路径、轴向应力在两个方向上的分散和损伤的局部化有效地阻碍了扭转损伤的传播;


来源:复合材料力学仿真Composites FEM
ACTMechanicalAdditiveSystemInspire振动疲劳断裂复合材料化学航空航天建筑电子增材裂纹理论材料多尺度
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首次发布时间:2024-11-14
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【新文速递】2024年4月27日复合材料SCI期刊最新文章

今日更新:Composite Structures 2 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 3 篇,Composites Science and Technology 2 篇Composite StructuresDeformation behavior and scale effects in microchannel hydroforming in ultra-thin TA1/CFRP fuel cell bipolar platesYao Wang, Jiachen Cui, Yong Li, Yanfeng Zhang, Sifa Zheng, Libin Zhao, Ning Hudoi:10.1016/j.compstruct.2024.118164超薄TA1/CFRP燃料电池双极板微通道液压成形的变形行为和尺度效应Microchannels of fuel cell bipolar plates have complex shapes and dimensions at the microscale level, posing significant challenges for manufacturing. Additionally, for traditional bipolar plate materials, mainly based on graphite composites and metals, make it difficult to meet the increasing performance requirements. As the latest fourth-generation fiber-reinforced metal composites, Ti/CFRP laminates exhibit high impact resistance and stiffness after solidification and are electrically conductive, presenting broad prospects for application in bipolar plates. In this study, the metallic layer of the traditional Ti /CFRP laminate was miniaturized to microscale, and a new method for ultra-thin TA1/CFRP laminate low-constraint hydro-microforming was proposed. By combining theoretical modeling, numerical simulation, and process experiments, the deformation behavior and scale effects of the laminate, during the microchannel hydroforming process, were investigated under different process and structural parameters. A single-channel deformation mode was used to study the forming process and examine the impact of hydraulic pressure loading paths and temperature. Additionally, multi-channel and curved channel deformation modes were employed to elucidate the influence of section inclination, channel width, ridge width, and bending angle on the forming process. By varying the laminate thickness, grain size and friction status, the geometric, grain and friction scale effects, as well as the microscale mechanisms of ultra-thin TA1/CFRP laminates in microchannel forming, were explored. This study explores new avenues for the precise microforming of lightweight laminate structures and their application in fuel cell bipolar plates. It provides a theoretical foundation to address the challenges in the microchannel forming of laminates and improve forming accuracy and performance quality.燃料电池双极板的微通道在微尺度上具有复杂的形状和尺寸,给制造带来了巨大的挑战。此外,传统的双极板材料主要以石墨复合材料和金属为主,难以满足日益提高的性能要求。Ti/CFRP层压板作为最新的第四代纤维增强金属复合材料,凝固后具有较高的抗冲击性和刚度,并具有导电性,在双极板上具有广阔的应用前景。本研究将传统Ti /CFRP层压板金属层微型化至微尺度,提出了一种超薄TA1/CFRP层压板低约束水力微成形新方法。通过理论建模、数值模拟和工艺实验相结合的方法,研究了不同工艺参数和结构参数下层压板在微通道液压成形过程中的变形行为和尺度效应。采用单通道变形模式研究了成形过程,并考察了液压加载路径和温度对成形过程的影响。此外,采用多通道和弯曲通道两种变形模式,分析了截面倾角、通道宽度、脊宽和弯曲角度对成形过程的影响。通过改变层合材料厚度、晶粒尺寸和摩擦状态,探讨了TA1/CFRP超薄层合材料在微通道形成过程中的几何效应、晶粒效应和摩擦尺度效应,以及微观尺度机制。本研究为轻质层压板结构的精确微成形及其在燃料电池双极板中的应用开辟了新的途径。为解决层压板微通道成形难题,提高成形精度和性能质量提供了理论基础。Silkworm cocoon-inspired and robust nanofibrous composite separator with gradient structure for lithium ion batteriesJiayi Li, Lu Lu, Haibo Liang, Yan Sun, Xuesong Guo, Zhenzhen Wei, Yan Zhaodoi:10.1016/j.compstruct.2024.118161 基于蚕茧的纳米纤维复合材料梯度结构锂离子电池分离器Considering electrospun nanofiber-based membranes that generally exhibit high porosity but poor mechanical property, there is a growing need to fabricate nanofibrous separators with comprehensive performance for lithium-ion batteries (LIBs). Silkworm cocoon, a source of design inspiration from nature, comprises a multilayer structure with composition change in the thickness direction, thereby endowing the cocoon with relatively high porosity and outstanding mechanical strength. Therefore, a silkworm cocoon-like structured nanofibrous separator (GPS) is fabricated in this work by initially preparing several polyacrylonitrile (PAN) nanofibrous membranes with varied content of carboxyl styrene butadiene latex (SBR) and then laminating them in a concentration gradient sequence. Compared with the pristine PAN membrane, the GPS exhibits comparable porosity, thermal stability and electrolyte wettability due to the existence of PAN nanofibers, while the tensile strength and puncture resistance of the GPS are greatly raised by 5.5 times and 1.5 times, respectively. On account of the structure design, GPS also shows better mechanical strength than PAN/SBR separators without concentration gradient, and the strengthening mechanism has been verified by the finite element analysis. Meanwhile, such gradient structure of GPS renders the battery with desirable ion transport ability and stable cycle properties. Thus, the silkworm cocoon-like structured separator could be a promising separator candidate for LIBs, and the bioinspired design in structure will play an increasingly important role in the development of high-performance battery in the future.考虑到电纺丝纳米纤维基膜孔隙率高但力学性能差的特点,制备具有综合性能的锂离子电池纳米纤维隔膜的需求日益增长。蚕茧的设计灵感来源于大自然,蚕茧由多层结构组成,其成分在厚度方向上发生变化,从而使蚕茧具有较高的孔隙率和突出的机械强度。因此,本研究首先制备了几种含有不同含量的羧基丁二烯乳胶(SBR)的聚丙烯腈(PAN)纳米纤维膜,然后按浓度梯度顺序层合,制备了蚕茧状结构纳米纤维分离器(GPS)。与原始PAN膜相比,由于PAN纳米纤维的存在,GPS具有相当的孔隙度、热稳定性和电解质润湿性,而GPS的抗拉强度和抗穿刺能力分别提高了5.5倍和1.5倍。由于结构设计的原因,GPS比无浓度梯度的PAN/SBR分离器具有更好的机械强度,并通过有限元分析验证了其强化机理。同时,GPS的这种梯度结构使电池具有良好的离子输运能力和稳定的循环性能。因此,蚕茧状结构隔膜可能是一种很有前途的锂离子电池隔膜候选材料,而结构上的仿生设计将在未来高性能电池的发展中发挥越来越重要的作用。Composites Part A: Applied Science and ManufacturingTemperature dependence of optical properties for thermoplastic composite prepreg during laser in-situ consolidationZehui Wang, Jinrui Ye, Kai Liu, Xiaodong Wang, Yingjie Qiaodoi:10.1016/j.compositesa.2024.108235 激光原位固结过程中热塑性复合材料光学性能的温度依赖性The optical properties of the thermoplastic prepreg play a critical role in influencing heating efficiency during the in-situ consolidation process. This study investigates the temperature-dependent reflectance of the prepreg during laser heating. A reflectance testing device is developed based on an in-situ heating system, and the reflectance of carbon fiber/PEEK prepreg is studied from 20 to 500 °C. Through a comparative analysis, the reflectance of pure PEEK films and carbon fibers are individually examined within the same temperature range. The variation in reflectance at different temperatures is explained according to the classical electromagnetic theory. Furthermore, the effect of fiber density on the reflectance of thermoplastic prepreg is explored, and the results indicate that the reflectance of the prepreg decreases from 15.65 % to 11.80 % as the temperature rises from 20 °C to 500 °C, which can be primarily attributed to the decline in carbon fiber reflectance with increasing temperature.在原位固结过程中,热塑性预浸料的光学性能对热效率的影响至关重要。研究了激光加热过程中预浸料的反射率随温度的变化规律。研制了一种基于原位加热系统的反射率测试装置,研究了碳纤维/PEEK预浸料在20 ~ 500 °C范围内的反射率。通过对比分析,分别考察了纯PEEK薄膜和碳纤维在相同温度范围内的反射率。根据经典电磁理论解释了不同温度下反射率的变化。研究了纤维密度对热塑性预浸料反射率的影响,结果表明:当温度从20 °C升高到500 °C时,预浸料反射率从15.65 %降低到11.80 %,这主要是由于温度升高导致碳纤维反射率下降。Natural coal-derived graphite as rubber filler and the influence of its progressive graphitization on reinforcement performanceHao Zhang, Yongjie Yang, Qinfu Liu, Leibo Ji, Zhiming Sun, Junmin Sun, Zhijing Han, Qianyi Ma, Hua Yang, Yubin Ke, Chul B. Park, Naisheng Jiangdoi:10.1016/j.compositesa.2024.108237 天然煤基石墨作为橡胶填料及其逐步石墨化对增强性能的影响This study introduces a reinforcing rubber filler, natural coal-derived graphite (NCDG), evaluating how its progressive structural evolution from meta-anthracite (MA), semi-graphite (SG) to cryptocrystalline graphite (CG) during the natural graphitization process affects their reinforcing performance to styrene-butadiene rubber (SBR) composites. The highly graphitized NCDG fillers exhibit good filler dispersion, more bound rubber content, and well compatibility between filler and rubber matrix when compounded with SBR, and significantly enhance the mechanical properties of SBR composite (tensile strength can reach 22.8 MPa), as well as improving the storage modulus, wet-skid resistance, wear resistance, and electrical conductivity. The formation of microcrystalline multilayer graphene and graphene nanoplatelets exfoliated by mechanical shear stress during ball grinding and rubber compound mixing plays an important role in improving the reinforcement performance of rubber composites. This research provides valuable insights into the utilization of NCDG as a cost-effective and environment-friendly reinforcing filler for rubber composites.本研究介绍了一种增强橡胶填料——天然煤衍生石墨(NCDG),评估了其在自然石墨化过程中从间无烟煤(MA)、半石墨(SG)到隐晶石墨(CG)的渐进结构演变对其增强丁苯橡胶(SBR)复合材料性能的影响。高石墨化NCDG填料与SBR复合后,填料分散性好,粘结胶含量高,填料与橡胶基体相容性好,显著提高了SBR复合材料的力学性能(抗拉强度可达22.8 MPa),提高了SBR复合材料的储存模量、抗湿滑性、耐磨性和导电性。在球磨和胶料混炼过程中,受机械剪切应力剥落形成微晶多层石墨烯和石墨烯纳米片,对提高橡胶复合材料的增强性能具有重要作用。本研究为利用NCDG作为一种经济、环保的橡胶复合材料增强填料提供了有价值的见解。Composites Part B: EngineeringDeveloping a binary composite of covalent organic framework and gold microstructures: Highly efficient dual-mode catalyst for analysis of nitrophenol isomers and their oxidative productsPonnusamy Arul, Sheng-Tung Huang, Chinnathambi Nandhini, Chi-Hsien Huang, N.S.K. Gowthamandoi:10.1016/j.compositesb.2024.111493 开发一种共价有机骨架与金微结构二元复合材料:分析硝基苯酚异构体及其氧化产物的高效双模催化剂As a key hazard, nitrophenol and its byproducts are a vital raw material in the industry and potentially released into aquatic environments, which affects the ecosystem and severely threatens living systems. It is crucial to detect nitro-hazards quantitatively and systematically. The unique structures of isomer separation and catalytic reduction are highly complex in a single system, not yet reported detection method. The present report constructed robust gold-microstructures (AuMSs) with bis-triazole-derived covalent organic framework (BTCOF) was developed to analyze the dual-mode application of electrochemical redox signals and catalytic degradation of nitrophenol isomers (NPIs) and their oxidative products. The synergistic interaction of tunable surfaces on binary materials enhanced catalytic efficiency, faster kinetic rates, and poor passivation. Based on the variance in pKa values, both NPIs and nitrosophenols (NSPIs) could be identified, peak separated, and sensed simultaneously. A catalyst combined with NaBH4, enabled NPIs reduction within ten minutes. This proposed electrochemical method achieved a nanomolar LOD (1.82, 1.67, and 1.15 × 10-9 M for o-, m-, and p-NPs), excellent sensitivity to ultrawide linear concentrations while being selective, and reproducible. Moreover, AuMSs-BTCOF/GCE detected NPIs in the industrial effluents and biofluids samples with recovery rates between 94.70-99.95 ± 0.18% with RSD < 3%. The electrochemical result was validated by conventional method with proven statistical analysis (error < 4.0%). In the catalytic reduction of NPIs, the catalyst is more than 89.24% efficient, and durable stability. The designed system has proven to be an effective, sensitive, and accurate dual-detection tool for monitoring environmental targets and diagnosing diseases.硝基酚及其副产物作为一种关键危害物质,是工业中重要的原料,并可能释放到水生环境中,影响生态系统,严重威胁生命系统。定量、系统地检测硝基危害至关重要。异构体分离和催化还原的独特结构在单一体系中高度复杂,尚未有报道的检测方法。本文利用双三 唑衍生共价有机骨架(BTCOF)构建了稳健的金微结构(AuMSs),分析了电化学氧化还原信号的双模式应用和硝基酚异构体(NPIs)及其氧化产物的催化降解。可调表面在二元材料上的协同作用提高了催化效率、更快的动力学速率和较差的钝化。根据pKa值的变化,npi和亚硝基酚(NSPIs)可以同时被识别、分离峰和检测。与NaBH4结合的催化剂可以在10分钟内还原npi。该电化学方法获得了纳米摩尔的LOD (o-、M -和p- np分别为1.82、1.67和1.15 × 10-9 M),对超宽线性浓度具有良好的灵敏度,同时具有选择性和可重复性。此外,AuMSs-BTCOF/GCE在工业废水和生物流体样品中检测npi,回收率为94.70 ~ 99.95±0.18%,RSD < 3%。电化学分析结果与常规方法一致,误差< 4.0%。在npi的催化还原中,催化剂效率达89.24%以上,且持久稳定。该系统已被证明是一种有效、灵敏、准确的环境目标监测和疾病诊断双重检测工具。STRENGTHENING SANDWICH COMPOSITES BY LAMINATING ULTRA-THIN ORIENTED CARBON NANOTUBE SHEETS AT THE SKIN/CORE INTERFACEDongyang Cao, Tingge Xu, Mengmeng Zhang, Zhong Wang, D. Todd Griffith, Samit Roy, Ray H. Baughman, Hongbing Ludoi:10.1016/j.compositesb.2024.111496超薄定向碳纳米管片在皮芯界面强化夹层复合材料Strong, tough, and lightweight composites are increasingly needed for diverse applications, from wind turbines to cars and aircraft. These composites typically contain sheets of strong and high-modulus fibers in a matrix that are joined with other materials to resist fracture. Coupling these dissimilar materials together is challenging to enhance delamination properties at their interface. We herein investigate using a trace amount of carbon nanotube sheets to improve the coupling between composite skins and core in a composite sandwich. Ultra-thin (∼100 nm) forest-drawn multi-walled carbon nanotube (MWNT) sheets are interleaved within the skin/core interphase, with MWNTs aligned in the longitudinal direction. The mechanical behavior is characterized by end-notched flexural testing (ENF). With two MWNT sheets placed in the skin/core interphase, the following performance enhancements are achieved: 36.8% increase in flexural strength; 127.3% and 125.7% increases in mode I & II fracture toughness values, respectively; and 152.8% increase in interfacial shear strength (IFSS). These are achieved with negligible weight gain of the composite sandwich (0.084 wt% increase over the baseline sandwich without MWNT sheets). The finite element simulation results show that MWNT sheets enhance the skin/core coupling by reducing stress concentration, enabling the transition from catastrophic brittle failure to a stable ductile failure mode. The MWNT sheets interleaved sandwich composites are thus demonstrated to be stronger and tougher while providing electrical conductivity (4.3×10^4) at the skin/core interface for potential de-icing, electromagnetic interference shielding, and structural health monitoring.从风力涡轮机到汽车和飞机,越来越多的应用需要坚固、坚韧和轻质的复合材料。这些复合材料通常在基体中含有高强度和高模量的纤维片,与其他材料结合以抵抗断裂。将这些不同的材料耦合在一起,以增强其界面的分层性能是具有挑战性的。在此,我们研究了在复合材料夹层中使用微量碳纳米管片来改善复合材料外壳和核心之间的耦合。超薄(~ 100 nm)森林绘制的多壁碳纳米管(MWNT)片在皮/核间期内交错,MWNT在纵向上排列。通过端缺口弯曲试验(ENF)对其力学性能进行表征。将两片MWNT片置于表皮/芯间,可实现以下性能增强:抗弯强度提高36.8%;ⅰ型和ⅱ型断裂韧性值分别提高127.3%和125.7%;界面抗剪强度(IFSS)提高152.8%。复合材料夹层的重量增加可以忽略不计(比没有MWNT片材的基线夹层增加0.084 wt%)。有限元模拟结果表明,MWNT板通过降低应力集中,增强了皮芯耦合,使其从灾难性脆性破坏过渡到稳定的延性破坏模式。因此,MWNT片交错夹层复合材料被证明在提供电导率(4.3×10^4)的同时更强、更坚韧,用于潜在的除冰、电磁干扰屏蔽和结构健康监测。Enhanced antibacterial activity of polyphenol-bound microtopography by synergistic chemical and micro/nanomechanical effectsPei Liu, Yuzheng Wu, Kaiwei Tang, Babak Mehrjou, Jin Tao, Guomin Wang, Huaiyu Wang, Zhengwei Wu, Paul K. Chudoi:10.1016/j.compositesb.2024.111498多酚结合微形貌通过协同化学和微/纳米力学效应增强抗菌活性Initial microbial attachment on surfaces is the first step in bacteria contamination and direct intervention in the early adhesion stage by constructing an antibacterial coating is an effective strategy to prevent the attachment and proliferation of bacteria. Herein, a storable polyphenol-based coating is designed and fabricated by self-assembling the cationic template and ionic ligand. The materials containing microparticles with sticky properties inherited from tannic can be deposited on various surfaces by a simple redispersion-immersion process. The functional ligands on the outer layer of the coating can kill bacteria by combining chemical damages produced by tannic as well as mechanical disruption caused by the micro-nano topography as reflected by the elevated Young’s modulus and differentiated stiffness of the bacterial membrane. The results reveal a simple method to prepare polyphenol-based antibacterial coatings and enrich our understanding of the combined use of chemical and mechanical interventions to enhance the antibacterial activity.微生物在表面的初始附着是细菌污染的第一步,通过构建抗菌涂层直接干预粘附的早期阶段是防止细菌附着和增殖的有效策略。本文通过阳离子模板和离子配体的自组装,设计并制备了一种可储存的多酚基涂层。通过简单的再分散-浸渍工艺,可以在各种表面上沉积具有从单宁继承的粘性微粒的材料。涂层外层的功能配体可以通过单宁产生的化学损伤和微纳形貌引起的机械破坏来杀死细菌,这反映在细菌膜的杨氏模量升高和刚度分化上。该结果为制备多酚类抗菌涂料提供了一种简单的方法,丰富了我们对化学和机械联合干预提高抗菌活性的认识。Composites Science and TechnologyOne-dimensional KNN micro rods doping to facilitate the energy conversion performance of a KNN MRs/P(VDF-TrFE) compositeXiaofang Zhang, Weimin Xia, Jing Li, Xusheng Wang, Chengmin Hou, Zhicheng Zhangdoi:10.1016/j.compscitech.2024.110626 一维KNN微棒掺杂提高KNN MRs/P(VDF-TrFE)复合材料的能量转换性能Piezoelectric self-powered electronic devices can convert ambient mechanical vibrations into electrical energy in an environmentally friendly manner, significantly alleviating the scarcity of non-renewable sources. This work prepares an one-dimensional potassium sodium niobate micro rods (1D KNN MRs) using the molten salt - topological chemical reaction method, showing the significant advantages over 0-dimension (0D) nanoparticles due to its anisotropy. Simultaneously, KNN MRs are introduced into poly(vinylidene fluoride-trifluoroethylene) to form a KNN MRs/P(VDF-TrFE) piezoelectric composite, effectively facilitating the piezoelectric β-phase in P(VDF-TrFE) film, and contributing to a high remnant polarization (Pr ∼12.3 μC/cm2) at 125 MV/m and a high piezoelectric constant (d33=-28 pC/N). Interestingly, a piezoelectric sensor assembled by KNN MRs/P(VDF-TrFE) composite shows a considerable piezoelectric output of 17.6 V at a scene of 2.5 MPa stress, offering a novel route for designing the optimum ceramic/polymer combinations suitable for mechanical energy conversion and energy harvesting.压电自供电电子设备能以环境友好的方式将周围的机械振动转化为电能,大大缓解了不可再生资源匮乏的问题。本研究采用熔盐-拓扑化学反应法制备了一维铌酸钠钾微棒(1D KNN MRs),由于其各向异性,与 0 维(0D)纳米粒子相比具有显著优势。同时,KNN MRs 被引入聚偏氟乙烯-三氟乙烯(poly(Vinylidene fluoride-trifluoroethylene))中,形成 KNN MRs/P(VDF-TrFE) 压电复合材料,有效促进了 P(VDF-TrFE) 薄膜中的压电 β 相,并在 125 MV/m 时产生高残余极化(Pr ∼12.3 μC/cm2)和高压电常数(d33=-28 pC/N)。有趣的是,由 KNN MRs/P(VDF-TrFE) 复合材料组装的压电传感器在 2.5 兆帕应力下显示出 17.6 伏的可观压电输出,为设计适用于机械能转换和能量收集的最佳陶瓷/聚合物组合提供了一条新途径。In situ Three-roll Mill Exfoliation Approach for Fabricating Asphalt/Graphite Nanoplatelet Composites as Thermal Interface MaterialsYingfeng Wen, Chao Chen, Hongru Zhou, Xiaojing Li, Xuyang Wang, Xingping Zhou, Xiaolin Xie, Yiu-Wing Maidoi:10.1016/j.compscitech.2024.110627 制备沥青/石墨纳米板复合材料作为热界面材料的原位三辊磨剥落法Thermal interface materials (TIMs) are vital to dissipate excess heat generated by electronic components with ever-growing power density to ensure their reliability and performance. However, the limited dispersibility of nano-sized thermal conductive fillers hinders further enhancement of thermal conductivity in TIMs. It remains challenging to manufacture high-performance TIMs with simultaneous high thermal conductivity, low cost, and capability of large-scale production. Herein, a solvent-free and scalable approach was adopted to fabricate asphalt/graphite nanoplatelets (GNPs) composites by in situ exfoliating graphite in asphalt melt using a three-roll mill. During exfoliation, asphalt was adsorbed onto the surface of GNPs via π-π interaction and improved their dispersibility. Hence, GNPs formed integrated thermal conductive pathways with reduced interfacial thermal resistance, which significantly improved the thermal conductivity of asphalt/GNP composites. At 25 vol.% loading, the asphalt/GNP composite displayed a thermal conductivity of 1.95 W·m-1·K-1, showing a 114% increase compared to the asphalt/commercial GNP (c-GNP) composite prepared by conventional mechanical mixing. Moreover, the heat-resistant and mechanical properties of the asphalt/GNP composites were also enhanced due to the improved filler dispersion and filler-matrix interactions. Thus, the asphalt/GNP composites fabricated by in situ three-roll milling possessed remarkable advantages as TIMs compared with asphalt/c-GNP composites and commercial silicone rubber thermal pads.热界面材料(TIMs)对于消散功率密度不断增长的电子元件产生的多余热量,以确保其可靠性和性能至关重要。然而,纳米级导热填料的分散性有限,阻碍了TIMs导热性能的进一步提高。制造同时具有高导热性、低成本和大规模生产能力的高性能TIMs仍然是一个挑战。本文采用一种无溶剂、可扩展的方法,利用三辊磨机原位剥离沥青熔体中的石墨,制备沥青/石墨纳米片复合材料。在剥离过程中,沥青通过π-π相互作用吸附在GNPs表面,提高了GNPs的分散性。因此,GNPs形成了完整的导热路径,降低了界面热阻,显著提高了沥青/GNP复合材料的导热性。在25 vol.%的负荷下,沥青/GNP复合材料的导热系数为1.95 W·m-1·K-1,与传统机械混合制备的沥青/商用GNP (c-GNP)复合材料相比,导热系数提高了114%。此外,由于填料分散性和填料-基体相互作用的改善,沥青/GNP复合材料的耐热性和力学性能也得到了提高。因此,与沥青/c-GNP复合材料和商用硅橡胶热垫相比,原位三辊铣制得的沥青/GNP复合材料具有显著的TIMs优势。来源:复合材料力学仿真Composites FEM

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