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【新文速递】2024年5月9日固体力学SCI期刊最新文章

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今日更新:International Journal of Solids and Structures 1 篇,Journal of the Mechanics and Physics of Solids 1 篇,Mechanics of Materials 1 篇,Thin-Walled Structures 4 篇

International Journal of Solids and Structures

Effect of an edge dislocation on hydride growth in zirconium: Elastic complex potential study

C.Y. Liu, L.N. Li, C. Xie

doi:10.1016/j.ijsolstr.2024.112870

边缘位错对锆中氢化物生长的影响:弹性络合电位研究

The formation of hydrides can significantly decrease the mechanical reliability of Zr servicing in the nuclear reactor. This study investigates the effect of the local stress field resulting from the hydride eigenstrain and dislocations on hydrogen transport and explores the hydride growth regulation. The stress functions, which can be extended and further applied to the realistic crystal structure and servicing status, are derived using the dislocation-based strain nucleus model and elastic complex potential method. The nonhomogeneous equation of hydrogen transport governed by diffusion and hydrostatic stress gradient is analytically solved. The results show that: (1) In the absence of dislocations, the hydride grows toward 112¯0 direction under the hydrostatic stress gradient resulting from the hydride eigenstrain. (2) The lower the temperature is, the higher the hydrogen concentration gradient in the adjacent area of the hydride is. The higher hydrogen fraction can also accelerate the growth rate. (3) Dislocation defects are capable of inducing triangle-shaped and asymmetric growth tendencies and providing new nucleation loci for hydrides. Based on the significant hydrostatic stress gradient led by dislocation singularity, this study analytically explains the autocatalysis and new-nucleation-locus effects raised by the in-situ observations.

氢化物的形成会大大降低核反应堆中锆材料的机械可靠性。本研究调查了氢化物特征应变和位错产生的局部应力场对氢传输的影响,并探讨了氢化物生长的调节。利用基于位错的应变核模型和弹性复势方法,推导出了应力函数,该函数可扩展并进一步应用于现实的晶体结构和维修状态。分析求解了受扩散和静水应力梯度支配的氢传输非均质方程。结果表明 (1) 在没有位错的情况下,氢化物在氢化物特征应变产生的静应力梯度作用下向 112¯0 方向生长。(2) 温度越低,氢化物邻近区域的氢浓度梯度越高。较高的氢分量也会加快生长速度。(3) 位错缺陷能够诱发三角形和不对称生长倾向,并为氢化物提供新的成核位置。本研究基于位错奇异性导致的显著静水应力梯度,分析解释了原位观测所提出的自催化和新成核点效应。


Journal of the Mechanics and Physics of Solids

A micromechanical scheme with nonlinear concentration functions by physics-guided neural network

Ce Chen, Liujun Wu, Jiaqi Fu, Chenyang Xin, Wenbin Liu, Huiling Duan

doi:10.1016/j.jmps.2024.105681

基于物理导向神经网络的非线性集中函数微力学方案

The mechanical behavior of heterogeneous materials has been reported to be significantly influenced by the nonlinear properties of both the matrix and interface. However, the micromechanical homogenization methods for predicting the effective properties are challenged in nonlinear problems due to the difficulties in solving the analytical form of the concentration tensors. In this study, we develop a nonlinear micromechanical scheme for heterogeneous materials with complex interfacial behaviors, where the key component, namely nonlinear concentration functions, is determined by the devised physics-guided neural network. In particular, the nonlinear Mori–Tanaka method (NMT) implemented within this new micromechanical scheme yields accurate solutions to axisymmetric nonlinear homogenization problems considering the effects of finite deformation, loading conditions, volume fraction, etc. Furthermore, the NMT is equivalent to the linear Mori–Tanaka method in the condition of the small deformation. Notably, this neural-network-based micromechanical scheme shows good generalization for different types of nonlinear interfaces, while the corresponding approach for generating training data via the finite element method (FEM) is cost-effective. This theoretical framework introduces a novel approach to nonlinear physical modeling, namely, not by the direct regression from the dataset but by deeply embedding neural networks in physical laws.

非均相材料的力学行为受到基体和界面非线性特性的显著影响。然而,由于难以求解浓度张量的解析形式,用于预测有效性质的微力学均匀化方法在非线性问题中受到挑战。在这项研究中,我们开发了具有复杂界面行为的非均质材料的非线性微力学方案,其中关键成分,即非线性浓度函数,由设计的物理引导神经网络确定。特别是,在这种新的微力学方案中实现的非线性Mori-Tanaka方法(NMT)可以精确地解决考虑有限变形,加载条件,体积分数等影响的轴对称非线性均匀化问题。此外,在小变形条件下,NMT与线性Mori-Tanaka方法等效。值得注意的是,这种基于神经网络的微力学方案对不同类型的非线性界面具有良好的泛化性,而通过有限元方法生成训练数据的相应方法具有成本效益。该理论框架引入了一种新的非线性物理建模方法,即不是通过数据集的直接回归,而是通过将神经网络深度嵌入物理定律。


Mechanics of Materials

Hydrogen diffusion behavior within microstructures near crack tip: A crystal plasticity study

Kaidi Li, Bin Tang, Mengqi Zhang, Jinhua Dai, Xichuan Cao, Bangqi Yin, Zhenshun Zhang, Jiangkun Fan, Jinshan Li

doi:10.1016/j.mechmat.2024.105032

裂纹尖端附近微结构中氢的扩散行为:晶体塑性研究

The hydrogen diffusion and damage characteristics within the microstructure at the crack tip are direct factors determining hydrogen embrittlement (HE) phenomena, yet research in this area from a mesoscale perspective is still insufficient. This study employs a non-local crystal plasticity constitutive model coupled with a hydrogen diffusion model that considers grain boundary (GB) characteristics and incorporates fracture initiation parameter accounting for the HELP+HEDE mechanisms. The research investigates hydrogen diffusion behavior at the crack tip in pure nickel and provide a detailed exploration of the mechanism underlying hydrogen-assisted crack propagation. The results indicate that the non-local model exhibits advantages in simulating the hydrogen diffusion process. Hydrogen induces intragranular cracks to propagate along slip planes with a high dislocation density. High-energy GBs and triple junctions are more susceptible to hydrogen accumulation, and under the influence of the HEDE mechanisms, they represent the primary sites for crack initiation. The entire fracture process involves the continuous coalescence of primary cracks with secondary cracks. Moreover, the HE resistance is better in equiaxed microstructures compared to rolled microstructures, particularly when the crack plane is parallel to the TD direction.

裂纹尖端微观组织内氢的扩散和损伤特征是决定氢脆现象的直接因素,但从中尺度角度对氢脆现象的研究尚显不足。本研究采用非局部晶体塑性本构模型与氢扩散模型耦合,该模型考虑了晶界(GB)特征,并纳入了HELP+HEDE机制的断裂起裂参数。研究了纯镍中氢在裂纹尖端的扩散行为,并对氢辅助裂纹扩展的机制进行了详细的探索。结果表明,非局部模型在模拟氢气扩散过程中具有优势。氢诱导晶内裂纹沿滑移面扩展,位错密度高。高能GBs和三重结更容易发生氢气积聚,在HEDE机制的影响下,它们是裂纹起裂的主要部位。整个断裂过程是原生裂缝与次生裂缝的连续贯通过程。此外,等轴组织的HE抗力优于轧制组织,特别是当裂纹平面平行于TD方向时。


Thin-Walled Structures

Mechanical issues of lithium-ion batteries in road traffic conditions: a review

Yue Liu, Yongjun Pan, Huacui Wang, Honggang Li, Huanhuan Bao, Zhiwei Zhao, Binghe Liu

doi:10.1016/j.tws.2024.111985

道路交通条件下锂离子电池的力学问题综述

The escalating challenges of the energy crisis and environmental pollution have propelled the development of the lithium-ion battery (LIB) industry as a response to the demand for low-carbon solutions. Known for its high energy density, extended lifespan, and robust stability, LIB has become the preferred power source for electric vehicles, with safety concerns demanding significant attention. Mechanical abuse stands out as a significant contributor to battery fire and explosion incidents, prompting the establishment of safety standards and heightened concerns in this regard. According to the road traffic conditions, mechanical abuse is categorized into three forms: vibration, mechanical shock, and crash in this review. Each is individually discussed, covering corresponding real traffic scenarios, relevant safety standards, and experimental methodologies. The review then delves into the failure behaviors including mechanical, electrochemical and thermal performance, and the associated observation methods. Finally, existing mechanical modeling methods and their applications are summarized. The paper aims to comprehensively explore the mechanical abuse behaviors and research methodologies applicable to LIBs in traffic scenarios, ultimately providing engineering guidance to enhance the safety performance of LIBs.

能源危机和环境污染的挑战不断升级,推动了锂离子电池(LIB)行业的发展,以满足对低碳解决方案的需求。LIB以其高能量密度、长寿命和强大的稳定性而闻名,已成为电动汽车的首选电源,安全性问题需要引起高度重视。机械滥用是电池火灾和爆炸事件的重要原因,促使安全标准的建立,并引起人们对这方面的高度关注。根据道路交通状况,本文将机械滥用分为振动、机械冲击和碰撞三种形式。每个单独讨论,涵盖相应的真实交通场景,相关的安全标准和实验方法。然后,综述深入研究了失效行为,包括力学,电化学和热性能,以及相关的观察方法。最后,总结了现有的力学建模方法及其应用。本文旨在全面探索交通场景下桥架的力学滥用行为和研究方法,最终为桥架的安全性能提升提供工程指导。


A deviatoric couple stress Mindlin plate model and its degeneration

Ya-Wei Wang, Jian Chen, Xian-Fang Li

doi:10.1016/j.tws.2024.111978

偏偶应力Mindlin板模型及其退化

Based on the classical couple stress theory, the deviatoric couple stress theory (DCST), where both couple stress and curvature tensors are traceless, is developed. The deviatoric couple stress Mindlin plate is established based on a new hypothesis of the vanishing curvature of the transverse normal, and the governing equations and associated boundary conditions of the simplified size-dependent Mindlin plate are respectively derived by the principle of virtual work. In the absence of couple stresses, a simplified Mindlin plate model between the classical Kirchhoff plate model and classical Mindlin plate model is derived. To illustrate the simplified DCST-based Mindlin plate model, the static bending and free vibration of rectangular plates are studied. The dependence of the length scale parameter and curvature ratio on the deflection, rotations and natural frequency is analyzed. The numerical results show that the consideration of couple stresses and curvatures hardens the stiffness of the microstructure, resulting in a decrease in its deflection and rotation compared with that of the macroscopic structure under the same conditions, while the natural frequency increases, which is consistent with the size effect observed in experiments.

在经典耦合应力理论的基础上,提出了耦合应力和曲率张量均无迹的偏耦应力理论(DCST)。基于横法线曲率消失的新假设,建立了偏偶应力明林板,并利用虚功原理推导了简化尺寸相关明林板的控制方程和边界条件。在没有耦合应力的情况下,推导了经典Kirchhoff板模型和经典Mindlin板模型之间的简化Mindlin板模型。为了说明基于dst的简化Mindlin板模型,对矩形板的静弯曲和自由振动进行了研究。分析了长度尺度参数和曲率比对挠度、旋转和固有频率的依赖关系。数值结果表明,考虑应力和曲率的耦合作用使微结构刚度变硬,与宏观结构相比,在相同条件下微结构的挠度和旋转减小,而固有频率增加,这与实验观察到的尺寸效应一致。


Achieving excellent strength-ductility combination of Al-aided Mg-Gd-Al-Zr-Zn alloys fabricated by cold metal transfer-based wire-arc directed energy deposition via uniform equiaxed grains and multiple precipitates

Chen Ji, Kun Li, Tianbao Yang, Shengwen Bai, David Z. Zhang, Lawrence E. Murr, Bin Jiang, Fusheng Pan

doi:10.1016/j.tws.2024.111980

通过均匀的等轴晶和多析出相,采用冷金属转移为基础的线弧定向能沉积制备了al辅助Mg-Gd-Al-Zr-Zn合金,实现了优异的强度-塑性组合

Limited ductility consistently poses a challenge for high-strength Mg-RE (rare earth) structures prepared by additive manufacturing. Particularly following heat treatment, while the strength of the Mg-RE alloy experiences a substantial increase, there is a noteworthy decrease in its ductility. Herein, a novel Mg-Gd-Al-Zr-Zn thin wall was successfully fabricated by cold metal transfer-based wire-arc directed energy deposition (CMT-WA-DED) and Al alloying. The microstructural evolution and mechanical properties of deposited and heat-treatment alloys were elucidated systematically. By adding Al element, Al2Gd and Al-Zr phases with thermal stability were precipitated in the deposited alloy. During the solidification or heat treatment stage, Al2Gd and Al-Zr phases could pin grain boundaries to restrict grain growth. The as-deposited alloys exhibited fully equiaxed grains at different heights and orientations. Thus, the thin wall exhibited good isotropic performance. After the heat treatment, the grain size only slightly grew and no abnormal grain growth was observed. Various morphologies of β precipitation phases were discovered along grain boundaries and within the grains. Additionally, a high density of β' and β1 phases within the grains and β phases along the grain boundary played pivotal roles in enhancing the mechanical strength of the Mg-Gd-Al-Zr-Zn alloy. The alloys exhibited an excellent combination of strength and ductility with ultimate tensile strength of 340 ± 7 MPa, yield strength of 212 ± 5 MPa, and elongation of 12.7 ± 0.9%. This work provides theoretical and practical reference value for the Mg-RE structures obtaining an excellent combination of strength and ductility prepared by additive manufacturing.

有限的延展性一直是增材制造制备高强度Mg-RE(稀土)结构的挑战。特别是热处理后,Mg-RE合金的强度大大提高,但其延展性明显下降。在此基础上,采用冷金属转移基线弧定向能沉积(CMT-WA-DED)和铝合金化技术成功制备了新型Mg-Gd-Al-Zr-Zn薄壁材料。系统地阐述了沉积合金和热处理合金的组织演变和力学性能。通过添加Al元素,沉积合金中析出具有热稳定性的Al2Gd和Al- zr相。在凝固或热处理阶段,Al2Gd和Al-Zr相可以固定晶界,限制晶粒长大。沉积合金在不同高度和取向上均表现出完全等轴晶粒。因此,薄壁具有良好的各向同性性能。热处理后晶粒尺寸略有增大,未见异常晶粒长大。沿晶界和晶粒内部发现了不同形态的β析出相。晶粒内高密度的β′和β1相以及沿晶界的β相对Mg-Gd-Al-Zr-Zn合金机械强度的提高起着关键作用。合金的抗拉强度为340±7 MPa,屈服强度为212±5 MPa,延伸率为12.7±0.9%,具有良好的强度和延展性。该工作为增材制造制备的镁稀土合金结构获得良好的强度和延展性提供了理论和实践参考价值。


A new buckling model for thin-walled micro-beams based on modified gradient elasticity: coupling effect and size effect

Bing Zhao, Huanxin Yi, Shiren Lin, Andi Lai, Chengyun Long, Jian Chen

doi:10.1016/j.tws.2024.111983

基于修正梯度弹性的薄壁微梁屈曲新模型:耦合效应和尺寸效应

More and more thin-walled micro-beams, including the I-section thin-walled micro-beams, are applied in MEMS. The buckling of a thin-walled micro-beam exhibits some different phenomena from that of a large scale thin-walled beam, such as the size effect, and the coupling effects caused by strain gradient. To investigate the influence of the coupling effects and size effect on the buckling of thin-walled micro-beams, a new buckling model is proposed. Based on modified gradient elasticity (MGE), the governing equations and boundary conditions of the new model are derived from the variational principle. The governing equations and boundary conditions can be simplified to the classical Vlasov's theory, the MGE Bernoulli-Euler beam model, MGE Bernoulli-Euler beam model considering bi-directional flexure respectively. Solved by the feature expansion method, the size effects of the thin-walled micro-beam can be captured by the new model, that is the buckling load increases with internal length scales. Besides the classical flexural-torsional coupling effect, two new coupling effects, such as the higher-order flexure-flexure coupling and the higher-order flexural-torsional coupling, are also captured by the new model. These two new high-order coupling effects of the new model reduce the critical buckling load of thin-walled micro-beams. The higher-order flexural-flexural coupling effect is far greater than the other two coupling effects, and the higher-order flexural-flexural coupling effect is on the same order of magnitude as the effect of MGE (size effect), with the former being negative and the latter positive. The size effect and higher-order coupling effect cannot be ignored and need to be considered carefully for the buckling of thin-walled micro-beams.

越来越多的薄壁微梁,包括工字截面薄壁微梁在微机电系统中的应用。薄壁微梁的屈曲表现出与大尺度薄壁梁不同的现象,如尺寸效应、应变梯度引起的耦合效应等。为了研究耦合效应和尺寸效应对薄壁微梁屈曲的影响,提出了一种新的屈曲模型。基于修正梯度弹性理论,利用变分原理推导了新模型的控制方程和边界条件。控制方程和边界条件可分别简化为经典Vlasov理论、MGE伯努利-欧拉梁模型和考虑双向挠曲的MGE伯努利-欧拉梁模型。通过特征展开法求解,新模型可以捕捉到薄壁微梁的尺寸效应,即屈曲载荷随内长度尺度的增大而增大。除了经典的弯扭耦合效应外,该模型还捕获了两种新的耦合效应,即高阶弯扭耦合和高阶弯扭耦合。新模型的这两个新的高阶耦合效应降低了薄壁微梁的临界屈曲载荷。高阶弯弯耦合效应远大于其他两种耦合效应,且高阶弯弯耦合效应与MGE效应(尺寸效应)在同一个数量级上,前者为负,后者为正。对于薄壁微梁的屈曲,尺寸效应和高阶耦合效应是不可忽视的,需要认真考虑。



来源:复合材料力学仿真Composites FEM
ACTMechanicalAdditiveSystemDeform振动断裂碰撞非线性化学汽车增材裂纹理论材料MEMS
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【新文速递】2024年5月11日复合材料SCI期刊最新文章

今日更新:Composite Structures 2 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 1 篇,Composites Science and Technology 1 篇Composite StructuresCrashworthiness investigation on a Carbon Fiber Reinforced Plastic solar vehicleAlessandro Papavassiliou, Ana Pavlovic, Giangiacomo Minakdoi:10.1016/j.compstruct.2024.118147碳纤维增强塑料太阳能汽车的耐撞性研究This article presents a research study involving different simulations of crash tests by means of the finite element explicit dynamic software Ansys LS-Dyna to determine the roadworthiness of a fully composite chassis lightweight solar vehicle and its conformity to the World Solar Challenge (WSC) regulations. Furthermore, the paper describes the results of crash test simulations in conditions comparable with those of the standard homologation test, with an initial velocity of 15.5 m/s against a rigid barrier considering overlaps of 50% and 100%. The velocity measured at the base of the seat was later used in a sled test with a dummy to calculate the Head Injury Criterion (HIC), a number proportional to the probability of head injury caused by the impact. The values remained within the threshold of acceptability with overlap at 50% but exceeded the limit with the 100% overlap. With no load limiter implemented in the model, the seatbelt caused contact forces with the chest up to 14 kN against 6 kN of the typical load limiter used in road cars to limit damage to ribs and internal organs. Finally, the possibility of improving the front crash box was investigated by changing the crash box’s planar sandwich structure with corrugated ones and layup without foam between the carbon layers. Various values of semi-amplitudes (A) of the sinusoidal profile have been tested. With a value of A of 6 mm, the capacity to absorb energy from an impact at 9 m/s was close to the original configuration.本文采用有限元显式动力软件Ansys LS-Dyna进行了不同碰撞试验模拟研究,以确定全复合材料底盘轻型太阳能汽车的路适性及其符合世界太阳能挑战赛(WSC)规则。此外,本文还描述了在考虑50%和100%重叠的情况下,以15.5 m/s的初始速度撞击刚性屏障的碰撞试验模拟结果,与标准一致性试验的条件相当。在座椅底部测量的速度随后用于假人的雪橇试验,以计算头部损伤标准(HIC),该标准与撞击造成头部损伤的概率成正比。当重叠为50%时,这些值仍在可接受阈值范围内,但当重叠为100%时,这些值超过了可接受阈值。在模型中没有实施载荷限制器的情况下,安全带与胸部的接触力高达14千牛,而公路汽车中使用的典型载荷限制器为6千牛,以限制肋骨和内脏的损伤。最后,研究了将前碰撞箱的平面夹层结构改为波纹夹层结构和碳层间无泡沫叠层的可能性。对正弦剖面的各种半振幅(A)值进行了测试。当a值为6 mm时,吸收9 m/s冲击能量的能力接近于原始配置。Microstructure generation and full-field multi-scale analyses for short fiber reinforced thermoplastics: Application to PA66GF compositesFrancis Praud, Konrad Schneider, George Chatzigeorgiou, Fodil Meraghnidoi:10.1016/j.compstruct.2024.118175短纤维增强热塑性塑料的微观结构生成及现场多尺度分析:在PA66GF复合材料中的应用Short Fiber Reinfored Thermoplastics (SFRTs) like PA66GF composites are highly heterogeneous materials with a rather complex microstructure such that the characterization and the prediction of their mechanical behavior remain quite challenging. So far, most of the research efforts have employed phenomenologigal and mean-field multi-scale models to deal with SFRTs. The present contribution rather focuses on a full-field multi-scale approach that incorporates advanced techniques in terms of microstructural representation and material modeling, allowing a deep insight of the dominating deformation mechanisms occurring in PA66GF composites. The proposed approach is based on an automatic periodic mesh generation algorithm for matrix-inclusion Representative Volume Elements (RVE) with randomly positioned fibers that follow a given Orientation Distribution Function (ODF). At the microscopic scale, while the fibers are assumed to be elastic, the behavior of the thermoplastic matrix is described by a phenomenological multi-mechanism constitutive model accounting for viscoelasticity, viscoplasticity and ductile damage. It results an advanced multi-scale model that enables to visualize the local deformation and degradation mechanisms occurring at the microscopic scale while simultaneously analyzing their influence on the macroscopic response of the composite upon monotonic, persistent and cyclic loading. The potential of the proposed approach is further evaluated by comparing the predicted responses against experimental data.短纤维增强热塑性塑料(SFRTs),如PA66GF复合材料是高度非均相材料,具有相当复杂的微观结构,因此其力学行为的表征和预测仍然是相当具有挑战性的。到目前为止,大多数研究都是采用现象学和平均场多尺度模型来处理sfrt。目前的贡献主要集中在一个全领域的多尺度方法,该方法结合了微观结构表示和材料建模方面的先进技术,从而深入了解PA66GF复合材料中发生的主要变形机制。该方法是基于矩阵包含代表性体积元(RVE)的自动周期性网格生成算法,其中随机定位的纤维遵循给定的方向分布函数(ODF)。在微观尺度上,假设纤维是弹性的,热塑性基体的行为由考虑粘弹性、粘塑性和延性损伤的现象学多机制本构模型来描述。建立了一种先进的多尺度模型,可以在微观尺度上可视化局部变形和降解机制,同时分析它们对复合材料在单调、持久和循环加载下的宏观响应的影响。通过将预测响应与实验数据进行比较,进一步评估了所提出方法的潜力。Composites Part A: Applied Science and ManufacturingJapanese washi-paper-based green composites: Fabrication, mechanical characterization, and evaluation of biodegradabilityLovisa Rova, Alia Gallet-Pandellé, Zhenjin Wang, Hiroki Kurita, Fumio Naritadoi:10.1016/j.compositesa.2024.108261日本纸基绿色复合材料:制造、机械特性和生物降解性评价In this study, sheets of Japanese washi-paper were layered and hot pressed with films of poly(butylene succinate) (PBS) in order to produce a fiber-reinforced composite material that can be biodegraded. Using traditional Japanese washi-paper, a thin yet remarkably strong green composite with excellent biodegradability was produced, proving the potential of washi-paper as an attractive reinforcer in green composites. The composite was biodegraded in compost, and the ultimate aerobic biodegradability as well as weight loss and loss of mechanical properties during biodegradation was evaluated. Specimens fabricated from three layers of washi-paper and two layers of PBS film had remarkable mechanical properties, including an ultimate tensile strength of 59.85 MPa. Scanning electron microscopy was used to study the cross-sectional structure of the material, which showed that the hollow washi-paper provides a structure for the polymer to settle into and surround the cellulose fibers. The large contact area between the cellulose fibers and the PBS caused a large internal friction which prevented failure by fiber pull-out, dramatically increasing the strength compared to neat washi-paper and neat PBS. Concerning biodegradability, the material reached 82 % biodegradation after 35 days. During biodegradation, the composite lost its mechanical properties fast, and was extremely fragile after 2 weeks inside the compost. After 6 weeks, the biodegradation had progressed so far that it was difficult to distinguish the material inside the compost. Due to its fast biodegradation and good mechanical strength, the washi-based composite material is potentially used in packaging, furniture, and agricultural applications such as mulch film.在这项研究中,将日本的洗衣纸分层并与聚丁二酸丁二烯(PBS)薄膜热压,以生产一种可生物降解的纤维增强复合材料。以日本传统的废纸为原料,制备了一种薄而强且具有良好生物降解性的绿色复合材料,证明了废纸作为绿色复合材料增强剂的潜力。在堆肥中对复合材料进行生物降解,并对其最终的好氧生物降解性以及生物降解过程中的重量损失和机械性能损失进行了评价。三层水洗纸和两层PBS膜制备的试样具有显著的力学性能,其极限抗拉强度为59.85 MPa。利用扫描电子显微镜对材料的横截面结构进行了研究,结果表明,中空的卫生纸为聚合物进入并包围纤维素纤维提供了一种结构。纤维素纤维与PBS之间的大接触面积产生了很大的内摩擦,防止了纤维被拉出而破坏,与干净的卫生纸和干净的PBS相比,强度大大提高。在生物降解性方面,材料在35 天后达到82% %的生物降解。在生物降解过程中,复合材料的力学性能迅速丧失,在堆肥中放置2 周后极易破碎。6 周后,生物降解已经进展到难以区分堆肥内部的物质。由于其快速的生物降解和良好的机械强度,水洗基复合材料有潜力用于包装、家具和农业应用,如地膜。Composites Part B: EngineeringRational design and controlled synthesis of metal-organic frameworks to meet the needs of electrochemical sensors with different sensing characteristics: an overviewJingcheng Huang, Haowei Dong, Lingjun Geng, Rui Xu, Mengyue Liu, Zhen Guo, Jiashuai Sun, Xia Sun, Yemin Guodoi:10.1016/j.compositesb.2024.111536 合理设计和可控合成满足不同传感特性电化学传感器需求的金属有机骨架综述It is known that porous structure of materials offers opportunities for the creation of a new range of materials with precise functions. Metal-organic frameworks (MOFs) are ordered porous materials formed by self-assembly of metal nodes and organic ligands. The study found that MOFs are ideal sensing materials. Recently, increasing attention has focused on developing MOFs-based electrochemical (EC) sensors due to their adjusted pore sizes , large surface area, and excellent physical/chemical stability. Various pure MOFs with distinct structures and functions can be synthesized by selecting different metal centers and organic ligands, the MOFs family has been further extended through the exploration of MOFs-derived materials and MOFs composites. In this review, firstly, the classifications and synthesis methods of MOFs materials are presented. Subsequently, the relationship between structure and performance, as well as different strategies for the rational design and controlled synthesis of multifunctional MOFs materials according to the specific requirements of EC sensors are discussed in detail. Finally, it presents conclusive perspectives on the current challenges in using MOFs materials for EC sensors. This paper will offer important guidance in designing and applying MOFs materials in EC sensors.众所周知,材料的多孔结构为创造一系列具有精确功能的新材料提供了机会。金属有机骨架是由金属节点与有机配体自组装而成的有序多孔材料。研究发现mof是理想的传感材料。近年来,基于mofs的电化学(EC)传感器因其可调节孔径、大表面积和优异的物理/化学稳定性而受到越来越多的关注。通过选择不同的金属中心和有机配体,可以合成各种具有不同结构和功能的纯MOFs,通过对MOFs衍生材料和MOFs复合材料的探索,MOFs家族得到了进一步的扩展。本文首先介绍了mof材料的分类和合成方法。随后,详细讨论了结构与性能之间的关系,以及根据EC传感器的具体要求合理设计和控制合成多功能MOFs材料的不同策略。最后,它提出了结论性的观点,目前在使用mof材料的EC传感器的挑战。本文将对mof材料在电磁传感器中的设计和应用具有重要的指导意义。Composites Science and TechnologyElectrical properties of MAH-g-PP modified PP/SEBS matrix semi-conductive composite materialsXuejing Li, Tianzhen Liu, Xiaolong Chen, Yanhui Wei, Jinliang He, Guochang Lidoi:10.1016/j.compscitech.2024.110657MAH-g-PP改性PP/SEBS基半导电复合材料的电学性能Polypropylene (PP) becomes a superior candidate material for new environmental-friendly cable insulation layer with its excellent heat resistance, electrical properties and degradability. At present, most of studies focus on the insulation layer of PP cable. However, there are few studies on semi-conductive shielding layer of PP cable which match its insulation layer. In this paper, polypropylene (PP)/ styrene ethylene butylene styrene (SEBS) is adopted as matrix of PP cable semi-conductive layer to matching its insulation layer. Meanwhile, Maleic anhydride grafted polypropylene (MAH-g-PP) is used to cooperatively improve the compatibility between PP and SEBS. The physicochemical properties, space charge injection properties and compatibility of semi-conductive composites with different CB and MAH-g-PP contents is studied by combining experiment and simulation methods. The experimental results show that the surface roughness of the semi-conductive layer and the space charge inside the insulation layer decrease first and then increase with the increase of CB addition. Among them, the two parameters of 25phr CB semi-conductive layer is the lowest, respectively 13.98 nm and 2.25×10-8C. These two parameters are significantly reduced after the addition of compatibilizer MAH-g-PP, which decreased by 29.47% and 62.22%, respectively. The simulation results show that the Flory-Huggins interaction parameters (χ) of MAH-g-PP with PP and SEBS are -73.3 and -45.2, respectively, which are 236.24% and 107.34% lower than those of PP/SEBS. The χ value of MAH-g-PP/CB is 8.20, which is 33.27% and 9.59% lower than CB/PP and CB/SEBS, respectively. It shows that MAH-g-PP can effectively improve the compatibility of matrix and filler. This work has important guiding significance for the research of semi-conductive layer formulation of PP cable.聚丙烯(PP)以其优异的耐热性、电性能和可降解性成为新型环保电缆绝缘层的首选材料。目前对PP电缆绝缘层的研究大多集中在PP电缆绝缘层的研究上。然而,对于与PP电缆绝缘层相匹配的半导电屏蔽层的研究却很少。本文采用聚丙烯(PP)/苯乙烯乙烯丁烯苯乙烯(SEBS)作为PP电缆半导电层的基体,与其绝缘层相匹配。同时,用马来酸酐接枝聚丙烯(MAH-g-PP)协同改善PP与SEBS的相容性。采用实验与模拟相结合的方法,研究了不同CB含量和MAH-g-PP含量的半导电复合材料的理化性能、空间电荷注入性能和相容性。实验结果表明,随着炭黑添加量的增加,半导电层表面粗糙度和绝缘层内部空间电荷先减小后增大。其中,25phr CB半导电层的两个参数最低,分别为13.98 nm和2.25×10-8C。添加相容剂MAH-g-PP后,这两个参数分别降低了29.47%和62.22%。仿真结果表明,MAH-g-PP与PP和SEBS的Flory-Huggins相互作用参数(χ)分别为-73.3和-45.2,分别比PP/SEBS低236.24%和107.34%。MAH-g-PP/CB的χ值为8.20,分别比CB/PP和CB/SEBS低33.27%和9.59%。结果表明,MAH-g-PP能有效改善基体与填料的相容性。本工作对PP电缆半导电层配方的研究具有重要的指导意义。来源:复合材料力学仿真Composites FEM

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