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【新文速递】2024年5月13日复合材料SCI期刊最新文章

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今日更新:Composite Structures 5 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 1 篇,Composites Science and Technology 1 篇

Composite Structures

Variable angle tow-steered curvilinear fibres-based rotating arbitrarily layered composite beams- a coupled vibration of chordwise-flapwise-torsional motions by higher-order beam theory

Lingesh Balaji, Ganapathi Manickam, Olivier Polit, Mohamed Haboussi, Sachin Dineshkumar

doi:10.1016/j.compstruct.2024.118199

基于变角拖曳曲线纤维的旋转任意层状复合梁-高阶梁理论的弦向-旋向-扭向耦合振动

In the present work, variable angle tow-steered curvilinear fibres-based straight composite rotating beam is studied for its coupled vibrational behaviours from different beam planes by a higher-order beam formulation satisfying plane stress situation and combining with finite element methodology. The structural theory is extended to include all the vibrational motions including chord- and flap-wise motions, axial and torsional vibrations of beam. The centrifugal force stiffening and gyroscopic effects stemming from rotational motions are taken into the formulation. The generic differential equations of equilibrium for the proposed structural theory are evolved adopting virtual dynamic work, Hamilton’s principle and a suitable C1 continuity based elemental equations are gotten. The newly constructed finite element formulation is tested for solved problems that are known in the literature. Based on in-depth analysis, vibration features of curvilinear fibre-based rotating generally layered composite beam including coupled dynamic motions in terms of vibrational modes and their frequencies pertaining to chord- and flap-wise, axial, torsional motions are detailed presuming variable angles along the curvilinear fibre path at the centre and layer edge, short and long beams, hub-radius, beam cross-section, and high rotational speed effects.

本文采用满足平面应力情况的高阶梁公式,结合有限元方法,研究了变角拖向曲线纤维直复合旋转梁在不同梁平面上的耦合振动特性。将结构理论扩展到包括梁的弦振和扑翼振、轴振和扭振在内的所有振动运动。公式中考虑了由旋转运动引起的离心力加强和陀螺效应。采用虚动力功、Hamilton原理和合适的C1连续性元素方程,推导了该结构理论的一般平衡微分方程。新构建的有限元公式对已知文献中已解决的问题进行了测试。在深入分析的基础上,详细分析了基于曲线纤维的旋转层状复合梁的振动特征,包括沿曲线纤维路径中心和层边缘、短梁和长梁、轴向、轴向、扭转等角度的振动模式和频率耦合动力运动,以及高转速效应。


Temperature-dependent debonding behavior of adhesively bonded CFRP-UHPC interface

Wei Zhang, Jinwei Lin, Yiqun Huang, Benqing Lin, Shuaiwen Kang

doi:10.1016/j.compstruct.2024.118200

CFRP-UHPC界面温度相关脱粘行为研究

The adhesively bonded structure, comprising carbon fiber-reinforced polymer (CFRP) and ultra-high-performance concrete (UHPC), enhances structural strength while reducing brittleness and strain softening behavior. However, the adhesively bonded structure is inevitably influenced by temperature variations throughout its service life. When the adhesive layer's temperature surpasses the glass transition temperature (Tg), significant damage occurs to the bond layer joint. To investigate the debonding behavior of the CFRP-UHPC interface at various temperatures, a series of three-point-bending tests were conducted at room temperature, 120%Tg, 150%Tg, and 160%Tg. This study introduced a temperature degradation factor, employing a proposed maximum load capacity prediction formula to adjust both the test results and data from other researchers. By adjusting the cohesion parameters with the temperature degradation factor, a temperature-dependent mixed-mode cohesive zone model (CZM) was developed. The model's validity was confirmed through finite element (FE) analysis, considering two distinct experimental scenarios. The paper concludes that the proposed model effectively simulates interface debonding behavior across varying temperatures.

由碳纤维增强聚合物(CFRP)和超高性能混凝土(UHPC)组成的粘接结构可增强结构强度,同时降低脆性和应变软化行为。然而,粘接结构在整个使用寿命期间不可避免地会受到温度变化的影响。当粘合层的温度超过玻璃化转变温度(Tg)时,粘合层接缝就会发生严重破坏。为了研究 CFRP-UHPC 界面在不同温度下的脱粘行为,分别在室温、120%Tg、150%Tg 和 160%Tg 下进行了一系列三点弯曲试验。这项研究引入了温度退化因子,并采用了建议的最大承载能力预测公式来调整试验结果和其他研究人员的数据。通过用温度退化因子调整内聚力参数,建立了与温度相关的混合模式内聚带模型(CZM)。考虑到两种不同的实验情况,通过有限元(FE)分析证实了该模型的有效性。本文的结论是,所提出的模型能有效模拟不同温度下的界面脱粘行为。


In-Plane crushing performance of bionic glass Sponge-Type honeycomb structures

Yuyang Wang, Guoxing Lu, Ngoc San Ha, Li Wang

doi:10.1016/j.compstruct.2024.118201

仿生玻璃海绵型蜂窝结构的面内破碎性能

Honeycomb structures are commonly adopted due to their superior energy absorption capacity. In this study, a new bionic glass sponge–type honeycomb structure (BSH) with a quadrilateral octagonal mesh microstructure inspired by the sea sponge structure was proposed. The in-plane crushing performance of the BSH with different geometrical parameters under different crushing speeds was investigated by ABAQUS/Explicit. The numerical findings suggested that the BSH displayed stronger energy absorption in contrast to the square, hexagonal and hierarchical honeycombs at both quasi-static and dynamic crushing conditions. More plastic hinges and more unit walls involved in deformation resulted in a high energy absorption capacity. In addition, three typical deformation modes of the BSH under different loading speeds were discussed, and the empirical model to predict the plateau stress of the BSH was established based on the shock wave theory. Finally, the effect of boundary segmentation parameter m on crushing performance was also illustrated. The energy absorption capacity reaches a maximum at m = 3 for quasi–static loading, whereas at m = 5 for dynamic loading. These findings provide valuable insights into the optimization of bionic honeycombs.

蜂窝状结构由于具有较好的吸能能力而被普遍采用。在本研究中,受海绵结构的启发,提出了一种具有四边形八边形网状结构的仿生玻璃海绵型蜂窝结构(BSH)。采用ABAQUS/Explicit软件,对不同几何参数的BSH在不同破碎速度下的面内破碎性能进行了研究。数值结果表明,在准静态和动态破碎条件下,BSH比正方形、六边形和分层蜂窝具有更强的能量吸收。更多的塑性铰链和更多的单元壁参与变形导致了高的能量吸收能力。此外,讨论了不同加载速度下BSH的三种典型变形模式,建立了基于激波理论的BSH平台应力预测经验模型。最后,分析了边界分割参数m对破碎性能的影响。准静态加载时,吸能能力在m = 3处达到最大值,动加载时,吸能能力在m = 5处达到最大值。这些发现为仿生蜂窝的优化提供了有价值的见解。


Nanocomposite fracture analysis: Aligned Fe3O4-GNP nanoplatelets’ effects on KIC, GIC, CTODc, and fracture mechanisms in epoxy matrices

Anupam Tiwari

doi:10.1016/j.compstruct.2024.118208

纳米复合材料断裂分析: 排列整齐的 Fe3O4-GNP 纳米颗粒对环氧树脂基质中 KIC、GIC、CTODc 和断裂机制的影响

Epoxy nanocomposites are crucial in aerospace, enhancing structural performance, reducing weight, and improving fuel efficiency across various applications. They ensure safety, reliability, and optimal performance in critical aerospace systems. Optimizing fracture properties like crack growth resistance (KIC), critical stress intensity factor (GIC), and critical crack tip opening displacement (CTODc), is vital for safety, durability, and innovation, especially in epoxy nanocomposites under extreme conditions. This study examines how random Graphene Nanoplatelets (GNP) and aligned Fe3O4-GNP nanoplatelets impact the fracture resistance of epoxy nanocomposites. It analyzes various fracture properties and crack propagation mechanisms following ASTM D5045-99 standards for CT specimen toughness tests using a COD gauge, focusing on nanoparticle alignment and wt% loading effects. Neat epoxy has a KIC of 0.94 MPa m1/2, increasing to 1.20 with 0.600 wt% GNP. Aligned Fe3O4-GNP peaks at 1.49. the baseline GIC starts at 209 J/m2 and rises to 301 J/m2 with 0.600 wt% GNP, and notably to 419J/m2 with aligned Fe3O4-GNP. Aligned Fe3O4-GNP significantly enhances fracture properties by modifying stress distribution at primary crack fronts through mechanisms such as deflection, branching, and twisting. These findings offer crucial insights for improving epoxy nanocomposites in aerospace, ensuring increased safety, reliability, and performance in critical components.

环氧纳米复合材料在航空航天领域至关重要,它能在各种应用中增强结构性能、减轻重量并提高燃料效率。它们可确保关键航空航天系统的安全性、可靠性和最佳性能。优化裂纹生长阻力(KIC)、临界应力强度因子(GIC)和临界裂纹尖端张开位移(CTODc)等断裂性能对于安全性、耐用性和创新性至关重要,尤其是在极端条件下的环氧纳米复合材料。本研究探讨了随机石墨烯纳米片(GNP)和排列的 Fe3O4-GNP 纳米片如何影响环氧纳米复合材料的抗断裂性。该研究按照 ASTM D5045-99 标准,使用 COD 仪进行 CT 试样韧性测试,分析了各种断裂特性和裂纹扩展机制,重点关注纳米颗粒排列和 wt% 负载的影响。纯环氧树脂的 KIC 值为 0.94 MPa m1/2,当 GNP 含量为 0.600 wt%时,KIC 值增至 1.20。对齐的 Fe3O4-GNP 的峰值为 1.49。基线 GIC 从 209 J/m2 开始,在 GNP 含量为 0.600 wt% 时上升到 301 J/m2,而在对齐的 Fe3O4-GNP 中则明显上升到 419 J/m2。对齐的 Fe3O4-GNP 通过偏转、分支和扭曲等机制改变了原生裂纹前沿的应力分布,从而显著提高了断裂性能。这些发现为改进航空航天领域的环氧纳米复合材料,确保提高关键部件的安全性、可靠性和性能提供了重要启示。


Exploring in-plane shear characteristics of multilayer biaxial weft knitted fabrics through a micro-scale virtual fiber modeling

Liwei Wu, Kanghui Zhou, Feng Zhao, Shengkai Liu, Junbo Xie, Liangsen Liu, Peng Cao, Youhong Tang, Qian Jiang

doi:10.1016/j.compstruct.2024.118209

通过微尺度虚拟纤维建模,探索多层双轴纬针织物的面内剪切特性

The multilayer biaxial weft knitted (MBWK) fabrics and their composites have been widely applied in fields of complex structural products due to their flexible curved deformability. The existence of stitch in MBWK complicates the deformation behavior under the in-plane shear loading. However, it has not been well explored and understood. In this study, a numerical micro-scale virtual fiber modeling was built to investigate the in-plane shear performance of MBWK by considering the micro geometric features and fiber property that are difficult to be characterized solely by experiment. The strain conditions of the stitch that determine the fabric shear behavior are discussed. The deformation behavior leads to local deformation and morphological locking of the stitch. In the early stage of the shearing, the deformability of stitch provides enough space to accommodate the rearrangement of axial yarns. In the shear locking stage, the restriction of stitch and compression within axial yarns at high shear angles restricts the axial yarns from movement in the loading direction. When the theoretical shear angle is 20°, the shear angle located in different shear regions varies. The maximum shear angle near the loading area is 19.1°, while the minimum shear angle near the fixed area is approximately 17°. The results illustrate the deformation mechanism of MBWK under in-plane shearing and provide an excellent guidance for the design of large deformation fabrics, especially for curved surfaces, thus realize the effective utilization of fabrics in engineering applications.

多层双轴纬编织物及其复合材料由于具有柔性弯曲变形能力,在复杂结构产品领域得到了广泛的应用。缝的存在使MBWK在面内剪切荷载作用下的变形行为复杂化。然而,它还没有被很好地探索和理解。为了研究MBWK的面内剪切性能,考虑到MBWK的微观几何特征和纤维性能难以通过实验表征的特点,建立了数值微尺度虚拟纤维模型。讨论了决定织物剪切性能的针脚应变条件。这种变形行为导致针脚局部变形和形态锁紧。在剪切初期,针段的变形性为轴向纱线的重新排列提供了足够的空间。在剪切锁紧阶段,大剪切角时轴向纱内的针距和压缩受到限制,限制了轴向纱在加载方向上的运动。当理论剪切角为20°时,位于不同剪切区的剪切角是不同的。加载区附近最大剪切角为19.1°,固定区附近最小剪切角约为17°。研究结果阐明了MBWK在面内剪切作用下的变形机理,为大变形织物特别是曲面织物的设计提供了良好的指导,从而实现了织物在工程应用中的有效利用。


Composites Part A: Applied Science and Manufacturing

The moisture absorption of 3D printed short carbon fibre reinforced polyamide

Y. Hou

doi:10.1016/j.compositesa.2024.108266

3D打印短碳纤维增强聚酰胺的吸湿性能

Polymer composites are commonly exposed to humid conditions and undergo reductions in mechanical properties. It is challenging to describe the moisture absorption dynamics of 3D printed parts due to manufacture-induced microstructures. This work investigates the moisture absorption of 3D printed short carbon fibre reinforced polyamide with varied microstructures and resulting influence on mechanical properties. The printed composites have inferior microstructures compared to the polyamide and diffusivity increases with the number of interlayer interfaces by up to 119 % (three times that of compression moulded composite). The microstructure is permanently aggravated by moisture resulting in more significant and irreversible reductions in yield stress (39 to 59 %) and tensile modulus (65 to 79 %) compared to injection moulded samples. Additionally, the shear modulus of printed polyamide and composites decrease by up to 63 % and 74 %, respectively. The results are helpful for prediction, evaluation, and maintenance of 3D printed applications subject to moisture environment.

聚合物复合材料通常暴露在潮湿条件下,机械性能会降低。由于制造诱导的微结构,描述3D打印部件的吸湿动力学具有挑战性。本研究研究了3D打印不同微观结构的短碳纤维增强聚酰胺的吸湿性及其对力学性能的影响。与聚酰胺相比,打印的复合材料具有较差的微观结构,扩散率随着层间界面数量的增加而增加高达119% %(是压缩成型复合材料的三倍)。与注射成型样品相比,受潮会导致微观结构永久性恶化,从而导致屈服应力(39%至59% %)和拉伸模量(65%至79% %)更显著且不可逆的降低。此外,打印聚酰胺和复合材料的剪切模量分别降低了63 %和74 %。研究结果有助于潮湿环境下3D打印应用的预测、评估和维护。


Composites Part B: Engineering

Highly sensitive and selective flexible anisotropic strain sensor based on liquid metal/conductive ink for wearable applications

Chao Ma, Kai Wang, Dayong Gao, Gang Zhao

doi:10.1016/j.compositesb.2024.111538

 

基于可穿戴应用的液态金属/导电油墨的高灵敏度和选择性柔性各向异性应变传感器

Although many high-performance wearable strain sensors have been developed, they are limited to uniaxial strain monitoring, which makes it challenging to meet the monitoring needs of complex multidimensional motion in practical applications. This study effectively constructed an anisotropic strain sensor by combining two materials that exhibit different responses to external stimuli (strain): liquid metal and conductive ink. In particular, the maximum gauge factors of this anisotropic strain sensor in conductive ink direction and liquid metal direction are 158.9 and 1.9, respectively. Both directions display outstanding dynamic stability, frequency independence, and durability over 3000 cycles. Furthermore, the integrated sensor formed by the orthogonal stack of two anisotropic strain sensors can distinguish the strain magnitude and direction (an outstanding selectivity of 3.7). The mechanism of the sensor's selective sensing ability is analyzed, and the broad application of the sensor in complex motion monitoring, human-computer interaction, and multi-component control is demonstrated. This research discovery provides new ideas and methods for constructing anisotropic wearable strain sensors. It creates conditions for the development and practical application of multifunctional wearable devices.

虽然目前已经开发出许多高性能的可穿戴应变传感器,但它们都局限于单轴应变监测,难以满足实际应用中复杂多维运动的监测需求。本研究通过结合液态金属和导电油墨这两种对外部刺 激(应变)表现出不同反应的材料,有效地构建了一种各向异性应变传感器。特别是,该各向异性应变传感器在导电油墨方向和液态金属方向的最大测量系数分别为158.9和1.9。两个方向都显示出出色的动态稳定性,频率无关性和超过3000次循环的耐久性。此外,由两个各向异性应变传感器正交堆叠而成的集成传感器可以区分应变的大小和方向(选择性为3.7)。分析了传感器选择性感知能力的机理,论证了传感器在复杂运动监测、人机交互、多组分控制等方面的广泛应用。这一研究发现为构建各向异性可穿戴应变传感器提供了新的思路和方法。为多功能可穿戴设备的发展和实际应用创造了条件。


Composites Science and Technology

A physics-guided deep learning model for predicting the magneto-induced mechanical properties of magnetorheological elastomer: small experimental data-driven

Hang Ren, Dan Zhao, Liqiang Dong, Shaogang Liu, Jinshui Yang

doi:10.1016/j.compscitech.2024.110653

 

用于预测磁流变弹性体磁致力学性能的物理指导深度学习模型:小型实验数据驱动

Magnetorheological elastomer (MRE) is a novel intelligent material, which shows excellent potential in vibration control applications. Previous researches have fully demonstrated that the magneto-induced shear storage modulus of MRE largely determines the vibration control effect. However, both existing theoretical and experimental ways to measure the magneto-induced shear storage modulus of MRE face their own shortage. Therefore, a novel physics-guided deep learning model is proposed to efficient predict the magneto-induced mechanical properties of MRE based on Magnetic Dipole theory and data-driven methods. A small database is built by collecting the magneto-induced shear storage modulus of MRE with different material ratios tested on a special shear rheometer. The proposed model trained with small training samples and its prediction results fit well with experimental values (average R2 of 0.99) which is superior to existing constitutive models. The training only takes 25 seconds, which significantly shortens the time compared to the experiment. Furthermore, the proposed model effectively predicts the magneto-induced storage modulus of MRE and has good generalization and superior transfer performance.

磁流变弹性体(MRE)是一种新型的智能材料,在振动控制方面具有良好的应用潜力。以往的研究充分表明,磁致剪切存储模量在很大程度上决定了磁致剪切存储模量的减振效果。然而,现有的磁致剪切存储模量的理论和实验测量方法都存在各自的不足。为此,提出了一种基于磁偶极子理论和数据驱动方法的物理引导深度学习模型,以有效预测磁致机械性能。通过在专用剪切流变仪上采集不同材料配比的磁致剪切存储模量,建立了一个小型数据库。该模型采用小样本训练,预测结果与实验值拟合良好(平均R2为0.99),优于现有的本构模型。训练只需要25秒,与实验相比,这大大缩短了时间。此外,该模型能有效地预测MRE的磁致存储模量,具有良好的泛化性和优异的传输性能。



来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemHPCInspireAbaqus振动断裂复合材料航空航天裂纹理论材料仿生控制试验曲面
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【新文速递】2024年5月18日复合材料SCI期刊最新文章

今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 7 篇Composite StructuresLayer jamming skin‐based bionic webbed foot soft gripper with variable stiffness and envelopmentZheng Zhang, Shilong Li, Yuting Zhou, Diyong Huang, Min Sun, Guang Zhang, Hao Chai, Shaofei Jiangdoi:10.1016/j.compstruct.2024.118215具有可变刚度和包络度的分层干扰皮肤仿生蹼足软爪Inspired by webbed feet, a bionic webbed foot soft gripper with variable stiffness was designed by integrating a pneumatic networks actuator with layer jamming skin. Layer jamming skin as the key component of bionic webbed foot soft gripper, its design and fabrication process were described. An experimental platform combining stretch/bend control was established to analyze the impact of activated negative pressure, different materials and shapes jamming units, and the number of jamming layers on the stiffness of the layer jamming skin. The layer jamming skin conforms to the characteristics of variable stiffness by evaluating the experimental and numerical results of the layer jamming skin under external loading. The curling and adaptability test demonstrated the layer jamming skin's adaptability and flexibility to various shapes and sizes of caught objects. The variable stiffness, adaptability, and gripping force of the bionic webbed foot soft gripper during object grasping were assessed through gripping experiments. This work presents an enveloping gripper with variable stiffness, high adaptability, and strong grasping force.摘要以蹼足为灵感,将气动网络作动器与层扰皮肤相结合,设计了一种变刚度的仿生蹼足软爪。介绍了作为仿生蹼足软爪关键部件的层卡皮肤的设计和制作过程。建立了拉伸/弯曲控制相结合的实验平台,分析了激活负压、不同材料和形状的干扰单元以及干扰层数对分层干扰蒙皮刚度的影响。通过对层状干扰蒙皮在外载荷作用下的实验和数值计算结果进行评价,发现层状干扰蒙皮符合变刚度特性。卷曲和适应性试验证明了层干扰蒙皮对捕获物体的各种形状和大小的适应性和灵活性。通过抓取实验,对仿生蹼足软爪在抓取物体过程中的可变刚度、适应性和抓取力进行了评估。本文提出了一种可变刚度、适应性强、抓取力强的包络夹持器。Composites Part A: Applied Science and ManufacturingNew metal-epoxy-matrix carbon-fibre hybrids to tackle stress concentrationHengli Cao, Xiaochuan Sun, Luiz F. Kawashita, Dmitry S. Ivanovdoi:10.1016/j.compositesa.2024.108272新型金属-环氧基碳纤维复合材料解决应力集中问题The paper explores the feasibility of improving the performance of composite structures with stress concentrators by local infusion of metals. The resulting material architecture presents Multi-Matrix Continuously-Reinforced Composites (MMCRC) – with shared domains of both the thermoset polymer and metal matrices with fibre-bridged interfaces between the domains. The study explores the manufacturing routes to creating such composites and assesses the resulting performance using the open-hole tensile test. It has been demonstrated that the presence of a rigid multi-matrix patch around the open hole, exhibiting minimal thickness variation, leads to a 15.0% improvement in failure load and a 16.6% improvement in failure strain for quasi-isotropic carbon fibre composite laminates. The strain history analysis of the MMCRC samples indicates the occurrence of plastic yielding within the metal matrix and strain redistribution mechanisms, leading to load sharing over the hybrid matrix area.本文探讨了局部注入金属提高应力集中剂复合材料结构性能的可行性。由此产生的材料结构呈现出多基体连续增强复合材料(MMCRC) -具有热固性聚合物和金属基体的共享域,域之间具有纤维桥接界面。该研究探索了制造这种复合材料的制造路线,并使用裸眼拉伸测试评估了所得性能。结果表明,准各向同性碳纤维复合材料层合板在裸眼周围存在刚性多基体贴片,厚度变化最小,导致失效载荷提高15.0%,失效应变提高16.6%。MMCRC试样的应变历史分析表明,金属基体内部存在塑性屈服和应变再分配机制,导致混合基体区域的载荷分担。Composites Part B: EngineeringNew strategy in light-weight and ultrastrong Ti40Nb15Mo30(NbC)15 refractory complex concentrated alloyWeihang Lu, Dong Liu, Cunyu Wang, Qi An, Robert O. Ritchie, Lujun Huang, Shenbao Jin, Naonao Gao, Liangbo Sun, Lin Gengdoi:10.1016/j.compositesb.2024.111555 轻质超强Ti40Nb15Mo30(NbC)15难熔复合浓缩合金的新策略Traditional refractory high-entropy alloys (RHEAs) generally exhibit a trade-off between high-temperature strength and light weight. In present work, a novel design strategy based on tailoring element distribution is proposed to achieve excellent high-temperature strength at a density lower than 7 g·cm-3. Specifically, a Ti40Nb15Mo30(NbC)15 composite was designed and prepared by powder metallurgy. The composite is found to be composed of two ultrafine-grained (UFG) phases including a body-centered cubic (bcc) solid-solution phase and a face-centered cubic (fcc) ceramic reinforcement phase (Ti, Nb)C. The as-sintered composite shows a uniform and UFG microstructure where two phases are interconnected. Due to this unique microstructure, the Ti40Nb15Mo30(NbC)15 composite displays superb specific yield strengths among surveyed RHEAs, complex concentrated alloys, and metal-matrix composites from 800°C (243 MPa·g-1·cm3) to 1000°C (127 MPa·g-1·cm3). The outstanding high-temperature compressive strength was found to be associated with high resistance to dislocation motion and strong dislocation interactions in both the bcc and fcc phases. The phase interface after hot compression remained semi-coherent, vindicating its high stability. The high-density of stable phase interfaces not only retards the dislocation motion due to the large image force near the phase boundary but also induces a high value of activation energy for diffusion. The high activation energy can further achieve significant microstructure stability even after a long-term annealing (36 h) at 1000°C. This work provides new perspectives for the design and application of light and ultrastrong refractory complex concentrated alloys (RCCAs) by comparison to the insufficient strength of many traditional and light RCCAs.传统的耐火高熵合金(RHEAs)通常在高温强度和轻质之间进行权衡。在本工作中,提出了一种基于定制元素分布的新型设计策略,以在密度低于7 g·cm-3的情况下获得优异的高温强度。具体而言,采用粉末冶金方法设计并制备了Ti40Nb15Mo30(NbC)15复合材料。该复合材料由两种超细晶相(UFG)组成,即体心立方(bcc)固溶相和面心立方(fcc)陶瓷增强相(Ti, Nb)C。烧结后的复合材料具有均匀的UFG型微观结构,两相相互连接。由于这种独特的微观结构,Ti40Nb15Mo30(NbC)15复合材料在800°C (243 MPa·g-1·cm3)至1000°C (127 MPa·g-1·cm3)范围内表现出优异的比屈服强度,优于所研究的RHEAs、复杂的密集 合金和金属基复合材料。优异的高温抗压强度与bcc相和fcc相中高的位错运动阻力和强的位错相互作用有关。热压缩后的相界面保持半相干,证明了其高稳定性。稳定相界面的高密度不仅由于相边界附近的大像力而延缓了位错运动,而且引起了高的扩散活化能。即使在1000℃下长时间退火(36 h),高活化能也能进一步实现显著的微观结构稳定性。通过对许多传统和轻型耐火材料复合浓缩合金强度不足的比较,本工作为轻质和超强耐火材料复合浓缩合金(RCCAs)的设计和应用提供了新的视角。Microstructure evolution and phase interface characterization in anti-ablation (Hf1/4Zr1/4Ta1/4Ti1/4)C-coated C/C compositesJiachen Li, Junhao Zhao, Tao Li, Jingtong Li, Deyu Yang, Yanqin Fu, Junshuai Lv, Lingxiang Guo, Yulei Zhangdoi:10.1016/j.compositesb.2024.111569 抗烧蚀(Hf1/4Zr1/4Ta1/4Ti1/4)C /C复合材料的微观结构演变及相界面表征Ta and Ti elements are often used as modified components to densify the loose oxide film for HfC/ZrC coatings after long-term ablation, while the synergistic effect among their multi-phase oxides on the ablation resistance of the coatings for C/C composites is still being explored. In this work, a (Hf1/4Zr1/4Ta1/4Ti1/4)C high-entropy carbide ceramic was proposed as an advanced anti-ablation coating for C/C composites and the multicomponent synergistic effect on the ablative behavior was investigated. At the initial ablation, the O atoms first reacted with Hf and Zr elements to form m-(Hf, Zr)O2. The TiO2 was prone to decompose into TiO and then evaporated from the coating during ablation, slowing down the volatilization of Ta2O5. The remaining TiO2 and Ta2O5 diffused to m-(Hf, Zr)O2 and produced a phase transition from Ta/Ti-doped m-(Hf, Zr)O2 to o-(Hf, Zr)6Ta2O17/o-(Hf, Zr)TiO4. The formation of nanotwin between (Hf, Zr)6Ta2O17 and (Hf, Zr)TiO4 enhanced the toughness of the oxide film. Although excessive Ta2O5 broke the stability of the oxide film, the Hf-Zr-rich oxide skeleton (Ta/Ti-doped (Hf, Zr)O2, (Hf, Zr)6Ta2O17 and (Hf, Zr)TiO4)) ensured that C/C substrates were intact after ablation for 180 s, showing superior ablation resistance.长期烧蚀后,HfC/ZrC涂层常采用Ta和Ti元素作为改性组分使松散的氧化膜致密化,而其多相氧化物之间的协同作用对C/C复合材料涂层抗烧蚀性能的影响仍在探索中。本文提出了一种(Hf1/4Zr1/4Ta1/4Ti1/4)C高熵碳化物陶瓷作为C/C复合材料的高级抗烧蚀涂层,并研究了多组分协同作用对其烧蚀行为的影响。在初始烧蚀过程中,O原子首先与Hf和Zr元素反应生成m-(Hf, Zr)O2。在烧蚀过程中,TiO2容易分解成TiO并从涂层中蒸发,从而减缓了Ta2O5的挥发。剩余的TiO2和Ta2O5扩散到m-(Hf, Zr)O2,并产生了从Ta/ ti掺杂的m-(Hf, Zr)O2到o-(Hf, Zr)6Ta2O17/o-(Hf, Zr)TiO4的相变。(Hf, Zr)6Ta2O17与(Hf, Zr)TiO4之间形成纳米孪晶,增强了氧化膜的韧性。虽然过量的Ta2O5破坏了氧化膜的稳定性,但富Hf-Zr的氧化物骨架(Ta/ ti掺杂的(Hf, Zr)O2, (Hf, Zr)6Ta2O17和(Hf, Zr)TiO4))保证了C/C衬底在烧蚀180 s后完好无损,表现出优异的抗烧蚀性能。Microwave assisted black phosphorus-based core-shell composites with synergistic antibacterial and osteogenic ability for bone tissue repairYan-lei Zhan, Kai-chao Wen, Zheng-an Li, Jing Zang, Ping Sun, Feng-qian Lidoi:10.1016/j.compositesb.2024.111554 微波辅助黑磷基核壳复合材料具有协同抗菌和成骨能力的骨组织修复In clinics, repairing bone tissue with methicillin-resistant Staphylococcus aureus (MRSA) infections and bone defects remains a remarkable challenge. This study designs new core-shell composites of PMP/PVA (Fe3O4@APNs based on magnesium phosphate cement/Fe3O4@APNs-VAN-PLGA microspheres-agarose hydrogel). With Fe3O4@APNs (Phytic acid dodecasodium exfoliated BPNs (APNs) modified with Fe3O4) as an enhanced microwave (MW) sensitizer, the PMP/PVA system exhibits outstanding MW thermal performance. Under MW irradiation, the PMP/PVA exerts dual antibacterial activity through the MW thermal effect (MTE, quickly increased to 68.7±2.4 °C in 5 min at 2.45 GHz, 10 W/cm2) and MW-triggered chemotherapy (CTH, in vitro: 99.98±0.02% (MRSA), 99.43±0.73% (E. coli); in vivo: 99.98±0.02%), which possesses antibacterial ability in vitro and anti-infective effects in vivo with low toxicity and side effects. In addition, PMP/PVA possesses biodegradability with Ca2+, Mg2+, and PO43- released, which not only facilitates the proliferation and osteogenic differentiation of rat bone marrow mesenchymal stem cells (BMSC) in vitro but also promotes new bone formation for bone defect sites with chronic osteomyelitis in vivo (the implantations were gradually replaced with a large area of new bone without apparent cortical reactions). Therefore, PMP/PVA with dual antibacterial activity, osteogenic performance, and low toxicity ability can potentially repair bone tissue with MRSA infections and refractory bone defects. The proposed system is promising for bone tissue repair of chronic osteomyelitis with bone defects.在临床上,修复骨组织与耐甲氧西林金黄色葡萄球菌(MRSA)感染和骨缺损仍然是一个巨大的挑战。本研究设计了新型 PMP/PVA 核壳复合材料(基于磷酸镁水泥的 Fe3O4@APNs/Fe3O4@APNs-VAN-PLGA 微球-琼脂糖水凝胶)。以 Fe3O4@APNs(用 Fe3O4 改性的植酸十二钠剥离 BPNs (APNs))作为增强型微波(MW)敏化剂,PMP/PVA 系统表现出卓越的 MW 热性能。在微波辐照下,PMP/PVA 通过微波热效应(MTE,在 2.45 GHz、10 W/cm2 下 5 分钟内迅速升至 68.7±2.4 ℃)和微波触发化疗(CTH,体外:99. 98±0.02%(MRSA),99.43±0.73%(大肠杆菌);体内:99.98±0.02%),具有体外抗菌能力和体内抗感染作用,且毒副作用小。此外,PMP/PVA 具有生物降解性,可释放 Ca2+、Mg2+ 和 PO43-,不仅在体外促进大鼠骨髓间充质干细胞(BMSC)的增殖和成骨分化,而且在体内促进慢性骨髓炎骨缺损部位的新骨形成(植入物逐渐被大面积新骨取代,无明显皮质反应)。因此,具有双重抗菌活性、成骨性能和低毒性的 PMP/PVA 有可能修复 MRSA 感染和难治性骨缺损的骨组织。该系统有望用于慢性骨髓炎伴骨缺损的骨组织修复。A lava-inspired design strategy based on combustion characteristics of PFRP for excellent flame retardancy via dual action mechanism at wide temperature rangeZhibiao Wei, Chao Ji, Lulu Lei, Binbin Zhao, Zefei Cheng, Tao Yu, Yan Li, Jinhong Fandoi:10.1016/j.compositesb.2024.111560 基于PFRP燃烧特性的熔岩启发设计策略,通过双作用机制在宽温度范围内获得优异的阻燃性Although plant fiber reinforced composite (PFRP) with environmental-friendly and biodegradable matches with society development requirements and carbon neutral strategy, the inherent flammability limits application in the engineering field, especially in rail transit and aerospace with strict fire standards. In this work, based on combustion behaviors of PFRP, the flame-retardant strategy inspired by the characteristics of volcanic lava in nature which could flow along rock crevices or valleys and form dense ceramic protective layer with outstanding heat insulation on the surface after cooling is designed. Compared with neat PFRP, the LOI of the PFRP/APP@PTNi20-GP10 (7.7 wt% FR contents) reaches 35.8 %, and UL-94 achieves V-0, showing excellent self-extinguishing performance. Meanwhile, the peak heat release rate (PHRR), total heat release (THR), total smoke release (TSR) and CO production (COP) decrease by 70.1 % and 51.7 %, 60.3 % and 65.5 % respectively. More importantly, the char layer formed after the combustion process retains excellent strength and compactness, which provides better protection for the undecomposed composite. Furthermore, the release of toxic volatiles including aromatic compounds, esters and carbonyl compounds in gas-phase pyrolysis products decrease significantly. The mechanism of lava-inspired flame-retardant system can be attributed to the dual action mechanism where different components play corresponding flame-retardant role under wide temperature range. And it is noted that the designed strategy endows PFRP with excellent fire resistance without deteriorating mechanical properties. This work provides a novel design idea for realizing the flame retardancy of PFRP and broadens the application field of PFRP.植物纤维增强复合材料(PFRP)具有环保性和可生物降解性,符合社会发展要求和碳中和战略,但其固有的可燃性限制了其在工程领域的应用,特别是在防火标准严格的轨道交通和航空航天领域。本文基于PFRP的燃烧特性,借鉴自然界火山熔岩沿岩石缝隙或山谷流动,冷却后在表面形成致密的陶瓷保护层,并具有良好的隔热性的特点,设计了阻燃策略。与纯PFRP相比,PFRP/APP@PTNi20-GP10 (FR含量7.7 wt%)的LOI达到35.8%,UL-94达到V-0,表现出优异的自熄性能。同时,峰值放热率(PHRR)、总放热率(THR)、总排烟率(TSR)和CO产量(COP)分别降低了70.1%、51.7%、60.3%和65.5%。更重要的是,燃烧过程后形成的炭层保持了优异的强度和致密性,为未分解的复合材料提供了更好的保护。此外,气相热解产物中芳香族化合物、酯类和羰基化合物等有毒挥发物的释放量显著减少。熔岩激发型阻燃体系的机理可归结为不同组分在较宽温度范围内发挥相应的阻燃作用的双作用机制。并指出,所设计的策略使PFRP具有优异的耐火性能,而不破坏其力学性能。本工作为实现PFRP的阻燃性提供了一种新的设计思路,拓宽了PFRP的应用领域。Wholly Bio-based, Ultra-tough, Transparent PLA Composites Reinforced with Nanocellulose and NanochitinJoong-Kwon Kim, Seung Hak Oh, Myeong-Oh Song, Seyeon Jang, Seok Ju Kang, Sang Kyu Kwak, Jungho Jindoi:10.1016/j.compositesb.2024.111563 全生物基,超坚韧,透明PLA复合材料增强纳米纤维素和纳米甲壳素We introduce a novel ‘materials/processing’ approach that enables wholly bio-based, transparent polylactic acid (PLA) composites exhibiting unprecedented mechanical toughness. We introduce an aqueous colloidal suspension of cellulose-/chitin-nanofibers (CNF/ChNF) as reinforcing nanofillers. In particular, we design a water-in-oil (W/O) emulsion-based pre-complexation step whereby the aqueous CNF/ChNF nanofillers can be directly integrated with PLA forming a solid masterbatch (MB), which can be processed with twin screw extrusion (TSE) and injection molding to produce PLA composites containing only a minute amount (2 wt%) of CNF/ChNF without any foreign additives. The resulting wholly bio-based PLA composites show unprecedentedly high levels of mechanical toughness (151.2 MJ/m3), elongation at break (377.5 %), impact strength (123 J/m), and optical transparency (∼90%). In this article, we report on the fabrication and detailed structure-processing-property relation of our green PLA composites.我们引入了一种新的“材料/加工”方法,使全生物基透明聚乳酸(PLA)复合材料具有前所未有的机械韧性。我们介绍了纤维素/几丁质纳米纤维(CNF/ChNF)的水性胶体悬浮液作为增强纳米填料。特别是,我们设计了一种油包水(W/O)乳化基预络合步骤,通过该步骤,含水CNF/ChNF纳米填料可以直接与PLA结合形成固体母粒(MB),该母粒可以通过双螺杆挤出(TSE)和注塑成型加工,生产出仅含有微量(2wt %) CNF/ChNF的PLA复合材料,不含任何外部添加剂。由此产生的全生物基PLA复合材料具有前所未有的高机械韧性(151.2 MJ/m3)、断裂伸长率(377.5%)、冲击强度(123 J/m)和光学透明度(~ 90%)。本文报道了绿色聚乳酸复合材料的制备和详细的结构-加工-性能关系。The role of Mg content in regulating microstructures and mechanical properties of Al-Mg-ZnO composites fabricated via in-situ reaction sinteringShuo Wang, Xiaobin Lin, Xudong Rong, Xiang Zhang, Dongdong Zhao, Chunnian He, Naiqin Zhaodoi:10.1016/j.compositesb.2024.111565Mg含量对原位反应烧结Al-Mg-ZnO复合材料组织和力学性能的调控作用Al-Mg-oxides composite system exhibits great potential for achieving aluminum matrix composites (AMCs) with exceptional mechanical properties. However, the effects of Mg element on in-situ reaction mechanism and precipitation behavior remains largely unknown. In this work, Al-Mg-ZnO composite was successfully fabricated by using segmented ball milling, reaction sintering and heat treatment, resulting in an ultimate tensile strength of ∼760 MPa and fracture elongation of ∼3.5%. The Mg content-dependent reaction pathway and precipitation evolution were systematically investigated through thermodynamic analysis and microstructural characterization. The results revealed that the relatively high Mg content promotes the in-situ generation of the hybrid reinforcements composed of MgAl2O4 and MgO. Additionally, the semi-coherent reinforcement-matrix interface facilitates interfacial precipitation by reducing the energy barrier for nucleation. Consequently, solute-rich/vacancy-rich Guinier-Preston (GP) zones are activated to form η' and T' precipitates. These high-density nano-sized secondary phases contribute to the considerable strengthening effect of the composite. The present work provides valuable theoretical insight into the effect of Mg content on the microstructure evolution of Al-Mg-ZnO composite system, which offers promising avenues for achieving AMCs with superior mechanical properties.铝镁氧化物复合体系在制备具有优异力学性能的铝基复合材料(AMCs)方面显示出巨大的潜力。然而,Mg元素对原位反应机理和沉淀行为的影响尚不清楚。本文通过球磨、反应烧结和热处理制备了Al-Mg-ZnO复合材料,其抗拉强度为~ 760 MPa,断裂伸长率为~ 3.5%。通过热力学分析和微观结构表征,系统地研究了Mg含量依赖性反应途径和沉淀演化。结果表明,较高的Mg含量促进了MgAl2O4和MgO复合增强材料的原位生成。此外,半相干增强-基体界面通过降低成核能垒促进界面析出。因此,富溶质/富空位的ginier - preston (GP)区被激活形成η′和T′相。这些高密度的纳米级二次相使复合材料具有显著的强化效果。本研究为Mg含量对Al-Mg-ZnO复合体系微观结构演变的影响提供了有价值的理论见解,为实现具有优异力学性能的AMCs提供了有希望的途径。Compositional regulation in additive manufacturing of precipitation-hardening (CoCrNi)94Ti3Al3 medium-entropy superalloy: cellular structure stabilization and strength enhancementJianying Wang, Hailin Yang, Zhilin Liu, Lei Fan, Wentao Yan, Qiu Dong, M.W. Fudoi:10.1016/j.compositesb.2024.111570 沉淀硬化(CoCrNi)94Ti3Al3中熵高温合金增材制造中的成分调控:胞状组织稳定和强度增强High or medium-entropy alloys that feature high thermal stability and excellent oxidation resistance are promising candidates for elevated temperature applications. The rapid softening of monolithic high or medium-entropy alloys with single face-centered cubic structure at elevated temperatures, however, is a main weakness. In this paper, we report new high strength γ′-hardened ((CoCrNi)94Ti3Al3)98Nb2 medium-entropy alloy through laser powder-bed fusion (L-PBF) followed by ageing. In particularly, the tensile strengths of the aged ((CoCrNi)94Ti3Al3)98Nb2 alloy at 20 ºC and 700 ºC can reach up to 1.93 GPa and 1.11 GPa, respectively, 112% and 122% stronger than the as-built CoCrNi alloy tested at the same condition. A new strengthening mechanism, i.e., elemental segregation induced the cellular structure stabilization, in tandem with other hierarchical microstructure features, including ultrafine γ′ precipitates, dense twin boundaries, and other types of crystallized defects, co-contribute to the superb tensile strength at room and elevated temperatures. Such a simple alloy design and processing strategy outlines a guideline for designing novel multicomponent alloys and/or composites with superior microstructural stability and mechanical response at room and elevated temperatures.高或中熵合金具有高热稳定性和优异的抗氧化性,是高温应用的有希望的候选者。然而,具有单面心立方结构的单片高或中熵合金在高温下的快速软化是其主要缺点。本文报道了一种新型高强度γ′硬化((CoCrNi)94Ti3Al3)98Nb2中熵合金,采用激光粉末床熔炼(L-PBF)并进行时效处理。其中,时效后((CoCrNi)94Ti3Al3)98Nb2合金在20℃和700℃时的抗拉强度分别达到1.93 GPa和1.11 GPa,比同条件下的铸态CoCrNi合金提高了112%和122%。一种新的强化机制,即元素偏析诱导了细胞结构的稳定,以及其他层次组织特征,包括超细γ′沉淀、致密孪晶界和其他类型的结晶缺陷,共同促进了室温和高温下的优异拉伸强度。这种简单的合金设计和加工策略为设计具有优异显微组织稳定性和室温和高温下机械响应的新型多组分合金和/或复合材料提供了指导。来源:复合材料力学仿真Composites FEM

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