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【新文速递】2024年6月13日复合材料SCI期刊最新文章

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今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 7 篇,Composites Science and Technology 2 篇

Composite Structures

Optimal interply angle of bio-inspired composite curved panels with helicoidal fiber architecture

Pattama Khotjanta, Sontipee Aimmanee

doi:10.1016/j.compstruct.2024.118269

螺旋纤维结构仿生复合曲面板的最佳夹角

The exoskeleton structure of mantis shrimp’s dactyl clubs presents an extraordinary helicoidal reinforcement pattern, holding immense potential for revolutionizing fiber-reinforced composite materials. While extensive investigations have shed light on its unique advantages, the inherent nature of curved Bouligand structures remains incompletely comprehended. To elucidate these unexplored characteristics, the present study introduces a novel analytical model to efficiently calculate the interlaminar shear and normal stresses in helicoidal laminated curved beams under transverse loading. The analytical model systematically determines the optimal uniform fiber interply (pitch) angle for bio-inspired structures with arbitrary numbers of layers. The computational analysis revealed that achieving minimum interlaminar stresses always requires the precise orientation of π or 2π helicoids along the laminate thickness when the number of layers exceeds two. This theoretical discovery is remarkably identical to the study of stacked chitin fibrils in arthropod clubs reported in the literature. For a 37-ply composite, the flat and shallow-curved beam configurations primarily resulted in a 5° optimal pitch angle, while the deep-curved configuration yielded a 10° optimal angle. To validate the model, three-point bending testing were performed. Four fiber pitch angles were thoroughly examined, including the optimal and quad angles. The digital image correlation (DIC) technique was employed to analyze the structural responses and detect the onset of delamination. The numerical and experimental results demonstrated good consistency, exhibiting significant enhancement in the delamination resistance with the optimal angle of up to 30 percent.

螳螂虾的dactyl棒的外骨骼结构呈现出非凡的螺旋增强模式,具有巨大的潜力革命性的纤维增强复合材料。虽然广泛的研究揭示了其独特的优势,但弯曲的布利甘结构的内在本质仍然不完全被理解。为了阐明这些未被探索的特性,本研究引入了一种新的解析模型来有效地计算螺旋螺旋层合弯曲梁在横向荷载作用下的层间剪切和正应力。该分析模型系统地确定了具有任意层数的仿生结构的最佳均匀纤维间距角。计算分析表明,当层数超过两层时,要实现层间应力最小,总是需要π或2π螺旋沿层厚精确定向。这一理论发现与文献报道的节肢动物俱乐部中堆积的几丁质原纤维的研究非常一致。对于37层复合材料,平坦和浅弯曲的梁配置主要产生5°的最佳俯仰角,而深弯曲的梁配置产生10°的最佳角度。为了验证该模型,进行了三点弯曲试验。研究了四种纤维节角,包括最佳节角和四节角。采用数字图像相关(DIC)技术分析结构响应并检测分层的发生。数值与实验结果均显示出良好的一致性,当最佳角度达到30%时,抗分层能力显著增强。


Composites Part A: Applied Science and Manufacturing

Carbon fiber/epoxy composite property enhancement through incorporation of carbon nanotubes at the fiber–matrix interphase − direct observations of the fiber–matrix interphase by SEM and TEM

Toshiya Kamae, Lawrence T. Drzal

doi:10.1016/j.compositesa.2024.108306

碳纤维/环氧复合材料性能的增强——通过扫描电镜和透射电镜直接观察纤维-基质间相

A new method to fabricate carbon fiber reinforced plastics (CFRPs) with multiwalled carbon nanotubes (MWNTs) as a secondary reinforcement has been developed. In this method, a uniform coating of MWNTs onto CFs was achieved by simply applying a CNT-containing sizing coating with the assistance of cationic polymers. It was found that the 0˚ tensile strength of the MWNT reinforced CFRPs was improved by 89 % with the incorporation of only 0.39 wt% MWNTs. The SEM and TEM observations of smooth surface and thin cross sections prepared by a tilted microtoming technique revealed that the CFRPs have a thin MWNT/epoxy resin layer of 100–––200 nm thickness at the fiber–matrix interphase. The results indicate that the MWNT reinforced fiber–matrix interphase, which has a high modulus and strength, increases the stress transfer and energy absorption resulting in a higher 0˚ tensile strength than the CFRPs without MWNTs.

提出了一种以多壁碳纳米管作为二次增强材料制备碳纤维增强塑料(cfrp)的新方法。在这种方法中,通过在阳离子聚合物的帮助下简单地应用含有碳纳米管的施胶涂层,可以在碳纳米管表面均匀地涂覆碳纳米管。结果表明,加入0.39 wt% MWNT后,MWNT增强cfrp的0˚拉伸强度提高了89 %。通过倾斜微切分技术制备的光滑表面和薄截面的SEM和TEM观察表明,cfrp在纤维-基体界面具有100—200 nm厚度的MWNT/环氧树脂薄层。结果表明:MWNT增强纤维-基体界面相具有较高的模量和强度,增加了应力传递和能量吸收,使cfrp的0˚拉伸强度高于未添加MWNT的cfrp;


Composites Part B: Engineering

A macromolecular flame retardant for polyamide 6 and its filaments with enhanced fire safety, tensile and UV-blocking performance

Yanlu Sun, Xilin Pei, Zhengqi Wang, Dequn Wu, Xueli Wang, Jianyong Yu, Ruchao Yuan, Faxue Li

doi:10.1016/j.compositesb.2024.111631

 

一种用于聚酰胺6及其长丝的高分子阻燃剂,具有增强的防火、拉伸和防紫外线性能

In the pursuit of enhancing the fire safety of polyamide 6 (PA6), the addition of flame retardants generally leads to hydrogen bond dissociation, which results in detrimental effects on the mechanical properties of PA6 composites and impedes processing and application in the textile field. In this study, a macromolecular flame retardant, PPB, designed with hydrogen bond donor-acceptor spacing aligned with PA6, was synthesized to increase the number of hydrogen bonds. The addition of 10 wt% PPB to the PA6 matrix (PA6/PPB10) endowed the composite with the limiting oxygen index (LOI) increased to 31.6% and V-0 rating in the vertical burning (UL-94) test. PA6/PPB10 also exhibited significant enhancement in tensile strength by 12.6% compared to pure PA6 and demonstrated a superior ultraviolet protection factor (UPF) value of 573, greatly exceeding the value of 3 for PA6. The quenching effect, diluting effect in the gas phase, and hydrogen bond interactions between PPB and PA6 backbones imparted PA6/PPB composites with satisfactory flame retardancy and mechanical properties. As a representative example, PA6/PPB10 was melt-spun into filaments with a pleasing tenacity of 3.6 cN/dtex and self-extinguishing capability within 5 sec after ignition, confirming the sustained comprehensive properties after spinning and drawing into filaments.

在追求提高聚酰胺6 (PA6)防火安全性的过程中,阻燃剂的加入通常会导致氢键解离,从而对PA6复合材料的力学性能产生不利影响,阻碍其在纺织领域的加工和应用。本研究合成了一种高分子阻燃剂PPB,其氢键给受体间距与PA6对齐,以增加氢键的数量。在PA6/PPB10基体中添加10 wt%的PPB,复合材料的极限氧指数(LOI)提高到31.6%,垂直燃烧(UL-94)试验的V-0等级提高。与纯PA6相比,PA6/PPB10的抗拉强度提高了12.6%,紫外线防护系数(UPF)为573,大大超过了PA6的3。PA6/PPB复合材料的淬火效应、气相稀释效应以及与PA6骨架之间的氢键相互作用使其具有良好的阻燃性能和力学性能。以PA6/PPB10为代表,熔融纺丝后得到了令人满意的强度为3.6 cN/dtex的长丝,并在着火后5秒内具有自熄能力,证实了纺丝和拉丝后综合性能的持续性。


Fracture mechanical and ablation behaviors of C/SiC–Cu3Si–Cu interpenetrating composites and their dependence on metal addition and interface thickness

Yue Wu, Bin Liang, Rida Zhao, Shengyang Pang, Bohui Sun, Chenglong Hu, Jian Li, Sufang Tang

doi:10.1016/j.compositesb.2024.111632

C/ SiC-Cu3Si-Cu互穿复合材料的断裂力学和烧蚀行为及其与金属添加量和界面厚度的关系

The C/SiC–Cu3Si–Cu interpenetrating composites were prepared by the ceramization and metallization of carbon fiber reinforced carbon aerogel (C/CA) preforms. Fracture mechanical and ablation behaviors as well as their dependence on metal addition and PyC interface thickness were investigated. With the presence of metallic components, the C/SiC–Cu3Si–Cu composites show pseudo-plastic fracture, typical brittle-plastic mixed fracture, and then ladder-like fracture with the PyC interface thickness increasing due to the co-existence of ductile and brittle components, obviously different from the fracture of conventional ceramic matrix composites. The composite with 3.0 μm-thick interface has the highest flexural strength of 292.8 MPa due to the proper interfacial bond strength and residual compressive stress. The composite with 1.9 μm-thick interface has the highest work of fracture but relatively low fracture toughness due to the abundant modes of crack propagation. The anti-ablation property is deteriorated with increased PyC thickness due to the weakened transpiration cooling effect and reduced oxide scale quality. The composite with 0.9 μm-thick interface exhibits lower mass and linear ablation rates of 0.054 mg cm−2 s−1 and 0.018 μm s−1 after ablation at 2200 °C for 600 s, respectively. This work provides vital insights into the control of the overall performance of carbon fiber reinforced ceramic-metal matrix composites.

采用碳纤维增强碳气凝胶(C/CA)预制体的陶瓷化和金属化工艺制备了C/ SiC-Cu3Si-Cu互穿复合材料。研究了材料的断裂力学和烧蚀行为及其与金属添加量和PyC界面厚度的关系。在金属成分存在的情况下,C/ SiC-Cu3Si-Cu复合材料表现为伪塑性断裂、典型的脆塑性混合断裂,并随着PyC界面厚度的增加,由于韧性和脆性成分并存,呈现阶梯状断裂,明显不同于常规陶瓷基复合材料的断裂。当界面厚度为3.0 μm时,由于界面结合强度和残余压应力合适,复合材料的抗折强度最高,达到292.8 MPa。当界面厚度为1.9 μm时,由于裂纹扩展模式丰富,复合材料的断裂功最高,但断裂韧性相对较低。随着PyC厚度的增加,由于蒸腾冷却效果减弱,氧化皮质量降低,抗烧蚀性能下降。界面厚度为0.9 μm的复合材料在2200℃下烧蚀600 s后,质量和线性烧蚀率分别为0.054 mg cm−2 s−1和0.018 μ s−1。这项工作为控制碳纤维增强陶瓷-金属基复合材料的整体性能提供了重要的见解。


NMR investigations on Cl− and Na+ ion binding during the early hydration process of C3S, C3A and cement paste: A combined modelling and experimental study

Yanliang Ji, Xiaoxiao Zhang, Leo Pel, Zhenping Sun

doi:10.1016/j.compositesb.2024.111624

C3S、C3A和水泥浆体水化初期Cl−和Na+离子结合的核磁共振研究:模型与实验相结合的研究

Using materials containing sodium chloride(e.g., seawater) to make concrete is sometimes unavoidable. However, the associated ion binding mechanisms and structural evolution during the early hydration process are not fully understood. This study investigated Cl− and Na + binding behaviour and microstructure of C3S, C3A and cement paste within the first 48h using a high-field NMR setup. Results show that during hydration, KOH can reduce Cl− binding but enhance Na + ion binding in C3S paste, while increasing gypsum dosage in C3A paste retards both Cl− and Na+ binding. Retarders reduce Cl− and Na+ binding, while accelerators slightly promote Cl− binding but reduce Na+ binding in cement paste. It is also found that boundary nucleation and growth(BNG) modelling is the most suitable for fitting the ion binding. Finally, the microstructure assessed by the T1 relaxation rate is related to ion binding in various ranges, indicating that hydrates during hydration have various binding efficiencies.

使用含有氯化钠的材料(如:(海水)来制造混凝土有时是不可避免的。然而,早期水化过程中相关的离子结合机制和结构演化尚不完全清楚。本研究使用高场核磁共振装置研究了C3S, C3A和水泥浆在前48小时内的Cl -和Na +结合行为和微观结构。结果表明:在水化过程中,KOH能降低C3S膏体中Cl -的结合,但能增强C3A膏体中Na+的结合,而增加C3A膏体中石膏的用量会减缓Cl -和Na+的结合。缓凝剂降低Cl -和Na+的结合,而促进剂略微促进Cl -的结合,但降低Na+的结合。边界成核与生长(BNG)模型最适合于离子结合的拟合。最后,通过T1弛豫率评价的微观结构与不同范围的离子结合有关,表明水化过程中水合物具有不同的结合效率。


Drop-weight impact and compressive properties of repeatable self-healing carbon fiber reinforced composites

Zhen Wang, Yan Li

doi:10.1016/j.compositesb.2024.111626

 

可重复自愈碳纤维增强复合材料的落锤冲击和压缩性能

Herein, repeated self-healing of impact damage in carbon fiber reinforced composites is successfully achieved by using hollow glass fibers containing self-healing resin and two types of microcapsules (HGFs-Ms). The HGFs-Ms and microcapsules containing hardener were incorporated to fabricate repeatable self-healing carbon fiber reinforced polymer composite laminates (RSH-CFRPs). Low-velocity drop-weight impact tests and compression tests were performed to investigate the impact resistance, energy absorption, residual compressive strength and repeated self-healing performances of the RSH-CFRPs. The results revealed that the energy absorption capacity of the RSH-CFRPs could be repeatedly recovered and the barely visible impact damage (BVID) zone was almost fully healed after every healing process. Moreover, the RSH-CFRPs successfully minimized the reduction in compressive strength after repeated drop-weight impact tests due to their efficient repeated self-healing ability in impact induced damage.

本文采用含自愈树脂的中空玻璃纤维和两种微胶囊(HGFs-Ms)成功实现了碳纤维增强复合材料冲击损伤的反复自愈。将hfs - ms和含有固化剂的微胶囊结合在一起,制备了可重复自修复的碳纤维增强聚合物复合材料层合板(RSH-CFRPs)。通过低速落重冲击试验和压缩试验,研究了rsh - cfrp的抗冲击性能、吸能性能、残余抗压强度和反复自愈性能。结果表明,RSH-CFRPs的能量吸收能力可以反复恢复,每次愈合后几乎完全愈合了几乎不可见的冲击损伤区。此外,RSH-CFRPs由于在冲击损伤中具有有效的重复自愈能力,成功地将反复落重冲击试验后抗压强度的降低降至最低。


A Quick and Effective Modification Method to Improve the Patency and Endothelialization of Cryopreserved Allogenic Blood Vessels

Jingai Zhang, Yamin Liu, Ye Wan, Shanshan Kang, Quhan Cheng, Xin Kong, Ting Wang, Lei Cao, Xiaofeng Li, Shafiq Muhammad, Xianhui Liang, Pei Wang, Deling Kong, Kai Wang

doi:10.1016/j.compositesb.2024.111628

 

一种快速有效的改善同种异体低温保存血管通畅和内皮化的修饰方法

Cryopreserved allogeneic blood vessels have received considerable attention for vascular reconstruction owing to their easy availability and excellent anti-infective property. However, current cryopreservation methods cause significant endothelium loss alongside directly exposing smooth muscle cells and extracellular matrix components to the circulating blood, which can induce thrombosis and/or restenosis. We covalently coupled PEGylated phospholipids (DMPE-PEG) with anti-coagulant bivalirudin (abbreviated as DPB) and endothelial progenitor cell (EPC)-capturing TPSLEQRTVYAK (TPS) (abbreviated as DPT), respectively. Both DPT and DPB were co-modified onto the lumen surface of cryopreserved allogeneic vessels through hydrophobic interaction between DMPE-PEG and the phospholipid bilayer of surviving cells. Cy7-labled DMPE-PEG was used to investigate the saturation concentration and incubation time on the lumen surface of cryopreserved vessels. DPB and DPT co-modified cryopreserved vessels were characterized through different assays, including tissue viability and gene expression, hemocompatibility, and EPC capture in vitro and an artery implantation model in vivo. Co-modification of DPB and DPT attained luminal saturation as earlier as 10 min while preserving the viability of the residual cells on the cryopreserved vessels. The optimally co-modified cryopreserved allogeneic vessels showed that the DPB can improve the hemocompatibility by reducing fibrinogen adsorption and platelets adhesion alongside protecting the EPCs-capturing function of the DPT via inhibiting the masking by blood components, which altogether promoted the patency and endothelialization. This work provided a quick, biocompatible and an effective approach to functionalize tissue-engineered constructs containing alive cells.

低温保存的异体血管由于其易于获得和良好的抗感染特性而受到血管重建的广泛关注。然而,目前的冷冻保存方法 会导致严重的内皮细胞损失,同时将平滑肌细胞和细胞外基质成分直接暴露于循环血液中,这可能导致血栓形成和/或再狭窄。我们将聚乙二醇化磷脂(DMPE-PEG)分别与抗凝剂比伐鲁定(简称DPB)和内皮祖细胞(EPC)捕获TPSLEQRTVYAK(简称DPT)共价偶联。DPT和DPB通过DMPE-PEG与存活细胞磷脂双分子层的疏水相互作用,共同修饰在低温保存的异体血管的管腔表面。采用cy7标记的DMPE-PEG观察其在低温保存血管管腔表面的饱和浓度和孵育时间。通过体外组织活力和基因表达、血液相容性、EPC捕获和体内动脉植入模型等不同的实验对DPB和DPT共修饰的冷冻保存血管进行了表征。DPB和DPT的共修饰早在10分钟内达到腔内饱和,同时保留了冷冻保存血管上残留细胞的活力。结果表明,DPT可通过减少纤维蛋白原吸附和血小板粘附来改善血液相容性,同时通过抑制血液成分的掩盖来保护DPT的epcs捕获功能,从而促进血管通畅和内皮化。这项工作提供了一种快速、生物相容性和有效的方法来功能化含有活细胞的组织工程构建体。


Effects of carbon-fibre Z-pins on the through-thickness tensile strength of curved composite laminates under four-point bending

Mudan Chen, Bing Zhang, Giuliano Allegri, Stephen R. Hallett

doi:10.1016/j.compositesb.2024.111629

碳纤维z销对四点弯曲弯曲复合材料层合板全厚度抗拉强度的影响

This study investigates the influence of discrete through-thickness reinforcement, i.e. Z-pins, on the through-thickness tensile strength (TTS) of curved laminates through four-point bending experiments. Three types of samples are considered: unpinned, and Z-pinned with 0.27 % and 0.54 % areal densities. HexPly® IM7/8552 carbon/epoxy unidirectional prepreg with 0/±45 layup and 0.28 mm diameter T300/BMI pins were employed to manufacture the specimens. The Z-pinned laminates have comparable TTS with the unpinned samples in terms of the first observable load-drop. However, the TTS corresponding to the ultimate load-drop for low-density and high-density Z-pinned samples are 29 % and 38 % lower than for the unpinned ones, respectively. Z-pinned samples show less scatter than unpinned ones in terms of the ultimate TTS values. All specimens failed suddenly, i.e. with no evident damage progression. This implies that Z-pins were not able to form a progressive bridging zone to dissipate mechanical energy. Through a detailed meso-scale finite element analysis (FEA), it was found that the high through-thickness tensile residual stress in the Z-pin neighbourhood generated from the cool-down stage of cure is an important factor in causing the reduction in TTS of Z-pinned laminates. CT scan images of tested Z-pinned specimens show that the carbon-fibre pins experience fracture inside the laminates.

通过四点弯曲实验,研究了离散贯厚钢筋(z销)对弯曲层合板贯厚抗拉强度的影响。考虑了三种类型的样品:未钉住的,z钉住的,面积密度分别为0.27%和0.54%。采用HexPly®IM7/8552碳/环氧单向预浸料,铺层0/±45层,直径0.28 mm的T300/BMI引脚制作样品。在第一个可观察到的负载下降方面,z -钉住层压板具有与未钉住样品相当的TTS。然而,低密度和高密度z -钉住试样的TTS对应的极限载荷降分别比未钉住试样低29%和38%。就最终TTS值而言,z -钉住的样品比未钉住的样品具有更小的散射。所有的标本都是突然失效的,即没有明显的损伤进展。这意味着z销不能形成一个渐进的桥接区来耗散机械能。通过详细的细观有限元分析(FEA)发现,固化冷却阶段产生的高贯穿厚度的z销邻近拉伸残余应力是导致z销层合板TTS降低的重要因素。测试z -钉试样的CT扫描图像显示碳纤维钉在层合板内部发生断裂。


Further understanding of the improved mechanical properties for SiCf/BN/SiC composites prepared by CVI+PIP hybrid technique: application of micro-mechanical methods

Lu Li, Xiali Zhen, Ruixiao Zheng, Chaoli Ma, Cuiyun Liu

doi:10.1016/j.compositesb.2024.111633

进一步了解CVI+PIP复合制备SiCf/BN/SiC复合材料力学性能的改善:微力学方法的应用

In this work, a chemical vapor infiltration (CVI) combined with polymer impregnation and pyrolysis (PIP) technique was used to prepare high-performance SiCf/BN/SiC composites. Compared with the SiCf/BN/SiC composite fabricated by conventional PIP technique, the SiCf/BN/SiC composite fabricated by CVI+PIP hybrid technique showed the significantly improved flexural strength and toughness. The microstructures, macro-mechanical and micro-mechanical properties were systematically investigated and compared. By applying various micro-mechanical tests (fiber push-in, micropillar compression and micropillar splitting), the in-situ mechanical parameters of different micro-zones for SiCf/BN/SiC composites were obtained accurately. Based on the characterization results of microstructures and micro-mechanical properties, the corresponding toughening process was analyzed in combination of the classical He-Hutchinson criterion. The results indicate that the micro-mechanical test methods can provide accurate and effective data for the analysis of toughening and fracture process, presenting great potentials in the further understanding of the improvement in mechanical properties of ceramic matrix composites.

本文采用化学气相渗透(CVI)结合聚合物浸渍热解(PIP)技术制备高性能SiCf/BN/SiC复合材料。与传统PIP工艺制备的SiCf/BN/SiC复合材料相比,CVI+PIP复合工艺制备的SiCf/BN/SiC复合材料的抗弯强度和韧性均有显著提高。系统地研究和比较了材料的微观组织、宏观力学和微观力学性能。通过纤维推入、微柱压缩和微柱劈裂等多种微力学试验,准确获得了SiCf/BN/SiC复合材料不同微区的原位力学参数。基于微观组织和微观力学性能表征结果,结合经典He-Hutchinson准则分析了相应的增韧过程。结果表明,微力学测试方法可以为分析陶瓷基复合材料的增韧和断裂过程提供准确有效的数据,在进一步了解陶瓷基复合材料力学性能的改善方面具有很大的潜力。


Composites Science and Technology

Prediction of puncture key parameters in aramid stab-resistant fabrics based on surface damage images using artificial neural networks

Mengzhen Liu, Siyu Liu, Haotian Li, Hong Zhang, Guangyan Huang

doi:10.1016/j.compscitech.2024.110713

 

基于表面损伤图像的芳纶防刺织物穿刺关键参数人工神经网络预测

Stab-resistant clothing significantly contribute to personal protection. In the field of stab resistance, traditional methods typically use the known impact conditions to evaluate the protection performance and damage of stab-resistant materials. However, these methods are unable to backtrack impact information from known damage, which makes it difficult to determine impactor characteristics. This study introduces a novel puncture damage prediction model capable of predicting the impact kinetic energy, peak puncture force, and number of penetration layers of aramid stab-resistant fabrics solely from surface damage images under various puncture conditions. First, the different puncture damages images and their corresponding parameters are obtained through dynamic stabbing tests and image acquisition system. Second, the segmentation network (named SAN_SE model) developed in this study overcomes the complexity of the surface texture of fiber-reinforced composites and achieves precise segmentation of damage regions. The training loss is stable at 1.5x10-4. Then a classification model is constructed to establish a relationship between the images and puncture parameters, followed by the application of transfer learning to derive a regression model from the classification model. The error of this regression model is below 6%. Finally, a real-time puncture damage prediction system is constructed, applying this puncture damage prediction model to actual damage scenarios. The system achieves an accuracy of 88.57% in predicting the number of penetration layers and could execute single images within 0.025s. The puncture damage prediction model proposed in this study is applicable to real-time monitoring systems in medical and military fields, such as injury assessment and counter-surveillance.

防刺服对个人保护有很大的帮助。在抗刺伤领域,传统方法通常使用已知的冲击条件来评估抗刺伤材料的防护性能和损伤。然而,这些方法无法从已知损伤中回溯撞击信息,这使得确定撞击器特性变得困难。本文提出了一种新的穿刺损伤预测模型,该模型能够仅从不同穿刺条件下的表面损伤图像预测芳纶防刺织物的冲击动能、峰值穿刺力和穿透层数。首先,通过动态刺穿试验和图像采集系统获取不同刺穿损伤图像及其相应参数;其次,本文建立的分割网络(命名为SAN_SE模型)克服了纤维增强复合材料表面织构的复杂性,实现了损伤区域的精确分割。训练损失稳定在1.5x10-4。然后构建分类模型,建立图像与穿刺参数之间的关系,然后应用迁移学习从分类模型中导出回归模型。该回归模型的误差在6%以下。最后,构建了穿刺损伤实时预测系统,并将该模型应用于实际损伤场景。该系统预测穿透层数的准确率为88.57%,可在0.025秒内完成单幅图像的处理。本研究提出的穿刺损伤预测模型适用于损伤评估、反监视等医疗和军事领域的实时监测系统。


Flexible conductive polymer composite film with sandwich-like structure for ultra-efficient and high-stability electromagnetic interference shielding

Yabin Guo, Xin Chen, Chen Wei, Yi Luo, Jianwen Chen, Yutian Zhu

doi:10.1016/j.compscitech.2024.110717

 

具有三明治状结构的柔性导电聚合物复合薄膜,用于超高效、高稳定的电磁干扰屏蔽

Flexible electromagnetic interference (EMI) shielding films with the merits of light-weight, flexibility, and high EMI shielding performance are the essential materials for the consumer electronics and communication products. Herein, we construct a hybrid conductive network based on the electrospinning thermoplastic polyurethane (TPU) film loaded with different dimensional conductive fillers, including 0D FeCl3, 1D carbon nanotube (CNT) and 2D graphene nanosheet (GN), which fabricate a flexible, light-weight, and ultra-efficient EMI shielding composite film. In specific, the electrospinning porous TPU film is firstly anchored by CNTs assisted by ultrasound to generate the porous TPU/CNT film. Thereafter, the as-prepared porous TPU/CNT film is filtered by GN/CNT/FeCl3 solution to generate a double-layer GN/CNT/FeCl3@TPU/CNT film. Finally, another porous TPU/CNT film is sealed onto the GN/CNT/FeCl3@TPU/CNT film by hot-pressing, which fabricates a sandwiched TPU/CNT@GN/CNT/FeCl3@TPU/CNT composite film. It is interesting to note that the composite film possesses the ultrahigh EMI shielding value (56.0 dB at 10.0 GHz) in the X-band (8.2-12.4 GHz) with high flexibility, excellent mechanical properties, long-term durability (acid-base environment resistance and stability after 1000 bends), as well as high thermal conductivity (6.53 W/(m K)). This work proposes a simple but efficiency strategy to design the flexible EMI shielding film with ultra-high performance and outstanding durability.

柔性电磁干扰屏蔽膜具有重量轻、柔韧性好、屏蔽性能高等优点,是消费电子和通信产品中必不可少的材料。在此,我们构建了一个基于静电纺丝热塑性聚氨酯(TPU)薄膜的混合导电网络,该混合导电网络加载了不同尺寸的导电填料,包括0D FeCl3, 1D碳纳米管(CNT)和2D石墨烯纳米片(GN),从而制备了一种柔性,轻质,超高效的电磁干扰屏蔽复合薄膜。具体来说,电纺丝多孔TPU膜首先通过CNTs在超声辅助下锚定,生成多孔TPU/CNT膜。然后,将制备好的多孔TPU/CNT膜用GN/CNT/FeCl3溶液过滤,生成双层GN/CNT/FeCl3@TPU/CNT膜。最后,通过热压将另一多孔TPU/CNT膜密封在GN/CNT/FeCl3@TPU/CNT膜上,制成夹心TPU/CNT@GN/CNT/FeCl3@TPU/CNT复合膜。值得注意的是,复合薄膜在x波段(8.2-12.4 GHz)具有超高的电磁干扰屏蔽值(10.0 GHz时56.0 dB),具有高柔韧性,优异的机械性能,长期耐用性(耐酸碱环境和1000次弯曲后的稳定性)以及高导热系数(6.53 W/(m K))。本工作提出了一种简单而高效的策略来设计具有超高性能和优异耐用性的柔性电磁干扰屏蔽膜。




来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemInspireMAGNET断裂复合材料燃烧化学电子消费电子通信裂纹理论材料仿生控制试验纺织
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首次发布时间:2024-11-21
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【新文速递】2024年6月16日复合材料SCI期刊最新文章

今日更新:Composite Structures 5 篇,Composites Part A: Applied Science and Manufacturing 5 篇,Composites Part B: Engineering 1 篇,Composites Science and Technology 3 篇Composite StructuresGeometrically nonlinear transient analyses of rotating structures through high-fidelity modelsR. Azzara, M. Filippi, E. Carreradoi:10.1016/j.compstruct.2024.118265通过高保真模型对旋转结构进行几何非线性瞬态分析This work presents geometrically nonlinear transient analyses of various rotating blades. The structures are discretized through refined beams or multi-dimensional finite element models, which are generated using the Carrera Unified Formulation (CUF). The CUF offers a procedure to develop low- and high-fidelity one-dimensional, two-dimensional, and three-dimensional finite element models hierarchically and automatically. Various beam models were developed using different kinematics models based on Taylor or Lagrange expansion functions. Multi-dimensional models were obtained by merging beam and solid elements, exploiting the unique feature of Lagrange polynomials to have only pure displacements as unknowns. This property allows beam and solid elements to be coupled at the node level without requiring complicated mathematical formulations. By utilizing the Finite Element Method in conjunction with the CUF, the governing equations are written by including all rotation effects, namely the Coriolis term, spin-softening, and geometrical stiffening. In a total Lagrangian scenario, the Hilbert-Hughes-Taylor-α method and the iterative Newton-Raphson scheme are employed to solve the equations of motion. The proposed methodology has been applied to evaluate different blade configurations, comparing the solution obtained using linear, linearized, and nonlinear approaches. The results have been verified and validated by comparing them with existing solutions present in the literature.本研究对各种旋转叶片进行了几何非线性瞬态分析。通过使用 Carrera Unified Formulation(CUF)生成的细化梁或多维有限元模型对结构进行离散化。CUF 提供了一种程序,可分层自动开发低保真和高保真的一维、二维和三维有限元模型。使用基于泰勒或拉格朗日扩展函数的不同运动学模型开发了各种梁模型。利用拉格朗日多项式只有纯位移作为未知数的独特特征,通过合并梁和实体元素获得了多维模型。这一特性使梁和实体元素可以在节点级耦合,而无需复杂的数学公式。通过将有限元法与 CUF 结合使用,可以写出包括所有旋转效应(即科里奥利项、自旋软化和几何刚化)在内的控制方程。在总拉格朗日方案中,采用希尔伯特-休斯-泰勒-α 法和迭代牛顿-拉斐森方案来求解运动方程。所提出的方法已被用于评估不同的叶片配置,并对使用线性、线性化和非线性方法获得的解决方案进行了比较。通过与文献中的现有解决方案进行比较,对结果进行了验证和确认。A constitutive model for rate-dependency analysis of open hole woven composites under compression loadingJ.M. Rodríguez Sereno, J. Pernas-Sánchez, J.A. Artero-Guerrero, J. López Puentedoi:10.1016/j.compstruct.2024.118274用于分析压缩荷载下开孔编织复合材料速率依赖性的构成模型The mechanical performance of composite materials under impact phenomena is of interest for several industries. Although the effect of the strain rate on composites significantly affects the behaviour of these materials, most studies describe the mechanical behaviour of CFRP laminates neglecting the strain rate dependence. This work presents a new constitutive model to numerically implement the change of in-plane properties of an plain weave CFRP (AGP193) over a wide range of strain rates (up to 500 s−1). Open hole compression tests are used to validate the model under quasi-static and dynamic loading. The importance of implementing the influence of strain rate on mechanical properties is illustrated by the maximum strength plot and the stress–strain history, both of which would be underestimated without the inclusion of strain rate in the model. The strain rates at the edge of the hole greatly exceed the average values in the sample, leading to an underestimation of the apparent strength up to 100% if the strain rate effect is not taken into account.复合材料在冲击现象下的机械性能受到多个行业的关注。虽然应变率对复合材料的影响很大,但大多数研究在描述 CFRP 层压材料的机械性能时都忽略了应变率的相关性。本研究提出了一种新的构成模型,用于数值计算平织 CFRP(AGP193)在各种应变速率(最高 500 s-1)下的面内特性变化。开孔压缩试验用于验证准静态和动态加载下的模型。最大强度图和应力-应变历史记录说明了实施应变率对机械性能影响的重要性,如果不将应变率纳入模型,这两项指标都会被低估。孔边缘的应变率大大超过了样品的平均值,如果不考虑应变率的影响,表观强度会被低估达 100%。Mechanical analysis of a stitched sandwich structure and its SiO2f/SiO2 panels: Experimental and numerical investigation on compression and shear performancesDuoqi Shi, Bo Zhang, Shuangqi Lv, Changqi Liu, Zhen Cheng, Xiaoguang Yangdoi:10.1016/j.compstruct.2024.118277缝合夹层结构及其 SiO2f/SiO2 面板的力学分析:压缩和剪切性能的实验和数值研究The compression and shear performances of the stitched sandwich thermal protection structure (SSTPS) was systematically investigated through experimental and simulation methods in this study. Compression and shear testing methods were designed, and macroscopic performance data for SiO2f/SiO2 thin panels and SSTPS were successfully obtained, thereby validating the rationality of the experimental approach. By establishing mechanical experimental methods, the correlation between microscopic structural features and macroscopic mechanical performance was revealed, and mechanical modeling and analysis work was conducted. The experimental and numerical results indicate that compression and shear failure of thin panels mainly occur at the intersections of fiber bundles, exhibiting non-brittle failure. The delamination of sandwich materials or the buckling deformation of panels is identified as the primary cause of the nonlinear response in SSTPS. Elevated temperatures induce an increase in the modulus and strength of SSTPS and a decrease in toughness, correlated with the high-temperature densification of the matrix structure. Finite element simulations reveal the critical role of component and interface damage in macroscopic nonlinear mechanical responses. The research demonstrates that, the compressive and shear failure mechanisms of SiO2f/SiO2 thin panels and SSTPS were successfully elucidated through the implementation of an innovative experimental methodology.本研究通过实验和模拟方法系统地研究了缝合夹层热保护结构(SSTPS)的压缩和剪切性能。设计了压缩和剪切测试方法,并成功获得了 SiO2f/SiO2 薄板和 SSTPS 的宏观性能数据,从而验证了实验方法的合理性。通过建立力学实验方法,揭示了微观结构特征与宏观力学性能之间的相关性,并进行了力学建模和分析工作。实验和数值结果表明,薄板的压缩和剪切破坏主要发生在纤维束的交汇处,表现为非脆性破坏。夹层材料的分层或面板的屈曲变形被认为是 SSTPS 非线性响应的主要原因。温度升高会导致 SSTPS 的模量和强度增加,而韧性降低,这与基体结构的高温致密化有关。有限元模拟揭示了组件和界面损伤在宏观非线性机械响应中的关键作用。研究表明,通过实施创新的实验方法,成功地阐明了 SiO2f/SiO2 薄面板和 SSTPS 的压缩和剪切破坏机制。A peridynamic differential operator modeling approach for ceramic matrix composites microstructure with uniform or non-uniform discretizationQ.Z. Wang, Y.L. Hu, Yin Yu, Dan Wu, Z.Y. Yaodoi:10.1016/j.compstruct.2024.118282均匀或非均匀离散陶瓷基复合材料微观结构的周动态微分算子建模方法Based on the theory of peridynamic differential operator (PDDO), a novel three-dimensional (3D) peridynamic (PD) model for isotropic and orthotropic material is proposed to investigate the elastic mechanical behaviors and stress distribution of Ceramic Matrix Composites (CMC) microstructure. The non-local expressions of strain and stress tensors are derived by employing PDDO and the classical constitutive equations. The bond forces in interface region crossing two different constituent materials are obtained by converting the partial differential terms into the non-local forms. The weak form of PD equations of motion is derived by using the principle of virtual work and PDDO. The validity of this approach is verified by predicting the elastic response and stress distributions of isotropic and orthotropic materials under uniaxial tension and pure shear deformation. Finally, simulations are conducted on a CMC microstructure with fiber and matrix under periodic boundary conditions. It is demonstrated that the current approach can effectively build 3D CMC microstructure with uniform or non-uniform discretization, and accurately predict the stress fields and effective elastic properties.基于周动态微分算子(PDDO)理论,提出了一种新颖的各向同性和正交材料的三维(3D)周动态(PD)模型,用于研究陶瓷基复合材料(CMC)微结构的弹性力学行为和应力分布。通过使用 PDDO 和经典构成方程,得出了应变和应力张量的非局部表达式。通过将偏微分项转换为非局部形式,可获得两种不同成分材料交接界面区域的结合力。利用虚功原理和 PDDO 推导出了弱形式的 PD 运动方程。通过预测各向同性和各向同性材料在单轴拉伸和纯剪切变形下的弹性响应和应力分布,验证了这种方法的有效性。最后,在周期性边界条件下对带有纤维和基体的 CMC 微结构进行了模拟。结果表明,目前的方法可以有效地建立均匀或非均匀离散的三维 CMC 微结构,并准确预测应力场和有效弹性特性。Closed-form methodology for the structural analysis of stiffened composite plates with cutouts and non-uniform lay-upA. Blázquez, D. Pastorino, B. López-Romano, F. Parísdoi:10.1016/j.compstruct.2024.118284带切口和非均匀铺设的加劲复合板结构分析的闭式方法Building upon the methodology developed in prior studies, which utilized the Lekhnitskii formalism to address composite plates featuring cutouts, varying thicknesses, and different stacking sequences, the present work introduces the incorporation of stiffeners. The structural configuration comprises plates and stringers, with each stringer positioned between two plate regions and subjected to both stretching and bending loads. It is important to note that no coupling between the bending and stretching responses is accounted for; therefore, lay-ups must be symmetric, and stringers must be embedded and bisymmetric. The stringers are modeled using the Euler–Bernoulli formulation with the free torsion hypothesis, while the plates are modelled using the Kirchhoff–Love formulation. Several benchmark problems are analyzed, and the results are compared with those obtained using finite element analysis (utilizing Abaqus software), demonstrating a satisfactory agreement while also showcasing competitive computational efficiency. Thus, the present methodology provides the industry with a novel tool that enables efficient parametric analysis and facilitates the most promising configurations during the initial phases of the design to be selected by engineers.之前的研究利用 Lekhnitskii 形式主 义解决了具有切口、不同厚度和不同堆叠顺序的复合板问题,在此基础上,本研究引入了加强筋。结构配置包括板和支撑杆,每根支撑杆位于两个板区域之间,同时承受拉伸和弯曲载荷。需要注意的是,弯曲和拉伸响应之间不存在耦合;因此,层叠必须对称,纵梁必须是嵌入式和双对称的。弦杆采用带有自由扭转假设的欧拉-伯努利公式建模,而板则采用基尔霍夫-洛夫公式建模。对几个基准问题进行了分析,并将结果与使用有限元分析(利用 Abaqus 软件)获得的结果进行了比较,结果表明两者的一致性令人满意,同时也展示了极具竞争力的计算效率。因此,本方法为业界提供了一种新型工具,可实现高效的参数分析,并有助于工程师在设计的初始阶段选择最有前途的配置。Composites Part A: Applied Science and ManufacturingComputational study on the electrical conductivity of hybrid composites under mechanical deformationHyeontae An, Jinyoung Hwangdoi:10.1016/j.compositesa.2024.108317 机械变形条件下混合复合材料导电性的计算研究This study explores the hybrid composite’s electrical conductivity response under uniaxial tensile strain, wherein conductive nanowires and insulating particulate fillers are integrated within a flexible polymer matrix. We develop a Monte Carlo–based computational model and analyze the significant influence of particulate fillers on the strain response of the electrical conductivity. The particulate fillers induce both the exclusive volume and nanowire bending effects, significantly contributing to determining the hybrid composites’ electrical conductivity. The exclusive volume effect mitigates conductivity changes under external deformation, decreasing the conductivity change rate as the particulate filler content increases when the exclusive volume effect is dominant. Conversely, the nanowire bending effect boosts conductivity change under external deformation, so when it predominates over the exclusive volume effect, the conductivity change rate increases with higher particulate filler content. The insights from the study aid in designing and optimizing flexible electronic materials resilient to mechanical deformation.本研究探讨了导电纳米线和绝缘颗粒填料集成在柔性聚合物基体中的混合复合材料在单轴拉伸应变下的导电响应。我们建立了一个基于蒙特卡罗的计算模型,并分析了颗粒填料对导电率应变响应的重要影响。微粒填料会产生排他性体积效应和纳米线弯曲效应,这对混合复合材料的导电性有重要影响。排他性体积效应可减轻外部变形下的电导率变化,当排他性体积效应占主导地位时,随着颗粒填料含量的增加,电导率变化率会降低。相反,纳米线弯曲效应会促进外部形变下的电导率变化,因此当纳米线弯曲效应优于独占体积效应时,电导率变化率会随着微粒填料含量的增加而增加。这项研究的启示有助于设计和优化可承受机械变形的柔性电子材料。A comparative study of emerging material point method and FEM for forming simulation of textile reinforcementsAmir Nazemi, Abbas S. Milanidoi:10.1016/j.compositesa.2024.108284新兴材料点法和有限元法在纺织加固材料成型模拟中的比较研究For forming simulations of fabric composites, nonlinear Finite Element Method/FEM has been a long-standing tool to predict and mitigate defects such as wrinkling. However, small-time step requirements in explicit FEM codes, numerical instabilities, and large computational time are among challenges reported. This study presents an alternative fast forming simulation technique through an application of the so-called Material Point Method/MPM, which enables the use of much larger time steps along with fewer numerical instabilities. As a preliminary step towards assessment of this method, both standard 2D deformation modes and 3D hemispherical forming setups were employed, using a plain fabric weave at dry condition. The MPM results were compared to the conventional FEM simulations, as well as to the physical experiments. Notably, the MPM method showed a runtime 20 times faster than its FEM counterpart (under a comparable mesh size), yet with the same reliability in forming predictions as verified by experiments.对于织物复合材料的成型模拟,非线性有限元法/有限元一直是预测和减少起皱等缺陷的长期工具。然而,显式有限元代码中的小时间步长要求、数值不稳定性和计算时间过长等问题也是所面临的挑战之一。本研究通过应用所谓的 "材料点法/MPM",提出了另一种快速成型模拟技术,它可以使用大得多的时间步长,同时减少数值不稳定性。作为对该方法进行评估的第一步,我们采用了标准二维变形模式和三维半球成型设置,并使用了干燥状态下的平纹织物编织。MPM 的结果与传统的有限元模拟以及物理实验进行了比较。值得注意的是,MPM 方法的运行时间比 FEM 方法快 20 倍(在网格大小相当的情况下),但成形预测的可靠性与实验验证的相同。Impact response and energy absorption mechanisms of UHMWPE fabric and composites in ballistic applications: A comprehensive reviewAshish Joshi, Ashish Mishra, Vikas Kumar Saxenadoi:10.1016/j.compositesa.2024.108314弹道应用中超高分子量聚乙烯织物和复合材料的冲击响应和能量吸收机制:全面综述Recently, UHMWPE fabric and composites have gained attraction in ballistics due to their impressive strength-to-weight ratio and impact resistance. This article provides a critical analysis of internal and external factors influencing the impact response of UHMWPE fabric and composites. Damage mechanisms in UHMWPE yarns, fabrics, and composites are explored, which reveals the influence of internal factors like fibre properties, resin characteristics, interphase properties, and composite architecture on impact resistance. Further, the influence of external factors such as projectile type, environmental conditions, and impact velocity are discussed. The review also discussed methods employed by researchers to enhance the energy-absorbing capacity of UHMWPE fabric and its composites, focusing on improving interphase characteristics and friction between woven fabric yarns. Concluding with insights into future research, the review underscores the necessity of advancing studies to augment UHMWPE fibre’s energy absorption resistance, expanding its applications in aerospace, automotive components, protective gear, and ballistic protection.近来,超高分子量聚乙烯织物和复合材料因其出色的强度重量比和抗冲击性而在弹道学领域备受青睐。本文对影响超高分子量聚乙烯织物和复合材料冲击响应的内部和外部因素进行了深入分析。文章探讨了超高分子量聚乙烯纱线、织物和复合材料的损伤机制,揭示了纤维特性、树脂特性、相间特性和复合材料结构等内部因素对抗冲击性的影响。此外,还讨论了弹丸类型、环境条件和冲击速度等外部因素的影响。综述还讨论了研究人员为提高超高分子量聚乙烯织物及其复合材料的吸能能力而采用的方法,重点是改善相间特性和织物纱线之间的摩擦力。综述最后对未来研究提出了见解,强调有必要推进研究,以增强超高分子量聚乙烯纤维的能量吸收能力,扩大其在航空航天、汽车部件、防护装备和弹道防护领域的应用。Bi-continuous interpenetrated porous composite integrating the high strength and long plateau stress stage prepared by an in situ methodEndian Liu, Yu Bai, Jiawen Li, Hai Haodoi:10.1016/j.compositesa.2024.108315 用原位法制备高强度和长高原应力阶段一体化的双连续互穿多孔复合材料In this paper, bi-continuous interpenetrated porous composites (BIPCs) were prepared with the combination of melt foaming and infiltration casting process. All BIPCs exhibited superior mechanical performance than aluminum foam (AF) and the sum of their components. Among them, 4# BIPC (with 75 struts) showed the highest specific energy absorption which is 2.70 times that of AF, and 3# BIPC (with 48 struts) presented the best improvement in terms of structural strength, while 2# BIPC (with 27 struts) exhibited the largest enhancement of energy absorption. The results indicate that the in situ interface of AF and ordered lattice structure contributes to the enhanced strength of BIPCs, while pores in AF prolongs the stress plateau stage. This research provides a novelty method to solve the trade-off between different mechanical property indicators.本文结合熔体发泡和渗透铸造工艺制备了双连续互穿多孔复合材料(BIPC)。所有 BIPC 的机械性能均优于泡沫铝(AF)及其组分的总和。其中,4# BIPC(含 75 根支柱)的比能量吸收最高,是 AF 的 2.70 倍;3# BIPC(含 48 根支柱)的结构强度改善最好;2# BIPC(含 27 根支柱)的能量吸收增强最大。研究结果表明,AF 的原位界面和有序晶格结构有助于提高 BIPC 的强度,而 AF 中的孔隙则延长了应力高原阶段。这项研究为解决不同力学性能指标之间的权衡问题提供了一种新方法。An emerging shellwich lattice material: Unlocking design freedom and enhancing mechanical propertiesMing Lei, Pan Wang, Shengyu Duan, Weibin Wen, Jun Liangdoi:10.1016/j.compositesa.2024.108316 一种新兴的贝壳晶格材料:释放设计自由度,提高机械性能This study proposes a novel sandwich shell lattice material called “shellwich”, which offsets the shell lattice to both sides to form panels and achieves the matching of porous material core layer with shell lattice panels. The shellwich lattices (P-BCC) with Schwarz Primitive (P) shell lattice panels and a body-centered cubic (BCC) truss lattice core layer are designed and fabricated. Compression experiments are carried out to explore the mechanical responses of the P-BCC experimentally and numerically. Compared with the P shell and BCC truss lattices, the P-BCC shellwich lattice demonstrates excellent mechanical properties, including widely tailorable elasticity and enhanced energy absorption. Furthermore, the effects of structural parameters on the elastic responses and energy absorption of the P-BCC are discussed. This study provides insights into the design of sandwich structures and lattice materials with high-performance and multifunctional properties, opening up new possibilities for lightweight structures, energy-absorbing systems and other engineering applications.本研究提出了一种名为 "shellwich "的新型夹层壳格材料,它将壳格向两侧偏移形成面板,实现了多孔材料芯层与壳格面板的匹配。我们设计并制造了具有施瓦茨基元(P)贝壳晶格面板和体心立方(BCC)桁架晶格核心层的贝壳晶格(P-BCC)。通过压缩实验,以实验和数值方法探讨了 P-BCC 的机械响应。与 P 壳和 BCC 桁架晶格相比,P-BCC 壳夹层晶格表现出优异的力学性能,包括可广泛调整的弹性和更强的能量吸收。此外,还讨论了结构参数对 P-BCC 弹性响应和能量吸收的影响。这项研究为设计具有高性能和多功能特性的夹层结构和晶格材料提供了启示,为轻质结构、吸能系统和其他工程应用开辟了新的可能性。Composites Part B: EngineeringBioactive hydrogels loaded with BMSC-EXOs and GDNF for synergistically spinal cord injury repairingHong Cheng, Hui Zhang, Yangnan Hu, Yusong Wang, Lei Tian, Yanru Qi, Lei Ren, Bin Zhang, Shasha Zheng, Xinyue Han, Xiaofeng Ma, Feika Bian, Huan Wang, Tingting Liu, Renjie Chaidoi:10.1016/j.compositesb.2024.111618负载 BMSC-EXOs 和 GDNF 的生物活性水凝胶可协同修复脊髓损伤Spinal cord injury (SCI) is a common lethal injury to the central nervous system (CNS), which severely affects the quality of life of SCI patients. Attempts to enhance the treatment of SCI typically tend to develop functional bioactive hydrogel scaffolds with drug encapsulation. In this work, we proposed novel RGD-functionalized bioactive hydrogel loaded with bone marrow stromal cells-derived exosomes (BMSC-EXOs) and glial cell line-derived neurotrophic factor (GDNF) to synergistically promote SCI repair. The functional hydrogel consisted of methacrylic anhydride-grafted sodium alginate and acrylated RGD, and then combined with BMSC-EXOs and GDNF by photocrosslinking to form a composite bioactive hydrogel. The hydrogel showed good drug-release properties and biocompatibility. When the bioactive hydrogel was implanted into the SCI area of the SD rats, it effectively modulated the adverse inflammatory response in the SCI area. Furthermore, the bioactive hydrogel promoted the regeneration of spinal cord neurons and axons, leading to the improvement in motor function recovery. These results indicate that the bioactive hydrogel loaded with BMSC-EXOs and GDNF has great potential as a therapeutic approach for the repair of spinal cord injuries.脊髓损伤(SCI)是中枢神经系统(CNS)常见的致命伤,严重影响脊髓损伤患者的生活质量。试图提高 SCI 治疗效果的方法通常倾向于开发具有药物封装功能的生物活性水凝胶支架。在这项工作中,我们提出了一种新型 RGD 功能化生物活性水凝胶,其中装载了骨髓基质细胞衍生的外泌体(BMSC-EXOs)和胶质细胞系衍生的神经营养因子(GDNF),可协同促进 SCI 修复。功能性水凝胶由甲基丙烯酸酐接枝海藻酸钠和丙烯酸化RGD组成,然后通过光交联与BMSC-EXOs和GDNF结合形成复合生物活性水凝胶。该水凝胶具有良好的药物释放性能和生物相容性。将该生物活性水凝胶植入 SD 大鼠的 SCI 区域后,可有效调节 SCI 区域的不良炎症反应。此外,生物活性水凝胶还促进了脊髓神经元和轴突的再生,从而改善了运动功能的恢复。这些结果表明,负载有 BMSC-EXOs 和 GDNF 的生物活性水凝胶作为脊髓损伤修复的一种治疗方法具有巨大的潜力。Composites Science and TechnologySynergistic Enhancing Effect for Electromagnetic Wave Absorption via Melamine Resin-Based Magnetic Core-Shell Microspheres/Multi-Walled Carbon NanotubesShenyang Cao, Yu’an Huang, Zhao Xu, Tienan Dong, Yihuang Su, Jiabao Lei, Siyi Zhang, Yibing Lin, Di Hao, Yichen Cao, Kaina Yang, Zusheng Hang, Runsheng Huangdoi:10.1016/j.compscitech.2024.110709 三聚氰胺树脂基磁核壳微球/多壁碳纳米管对电磁波吸收的协同增强效应Rational design of corrosion-resistant electromagnetic wave (EMW) absorbing materials with wide bandwidth, strong absorption, and low filling ratio remains a significant challenge. In this work, the melamine resin-based magnetic core-shell microspheres (MF@Fe3O4@SiO2) were synthesized via dispersion polymerization and in-situ growth method. Experimental and simulation results indicated that the content and magnetism of the magnetic shell coordinated with the MF-core could be tactfully regulated with a small amount of incorporated Ni content. Moreover, the dispersion and corrosion resistance of MF@Fe3O4 core-shell microspheres were obviously enhanced by coating SiO2. It is worth noting that after the composite of MF@Fe3O4@SiO2 with MWCNTs-20, the presence of numerous heterogeneous interfaces, the tactfully improved conductive loss, and the optimized impedance matching synergistically result in superior EMW absorption properties. When the filling amount was 30 wt.%, F9N1-S/MWCNTs-20 with a matching thickness of 1.76 mm, exhibited the maximum effective absorption bandwidth (EABmax) of 6.55 GHz, while maintaining a reflection loss (RL) of -62.94 dB at 1.53 mm. When the thickness of F9N1-S/MWCNTs-30 was increased to 3.24 mm, the RLmin at low frequencies was achieved at -67.14 dB. Besides, the simulation of radar cross section values ascertains the enormous potential of F9N1-S/MWCNTs to achieve stealth under radar detection. This study introduces a novel method for producing lightweight and efficient EMW absorbers with corrosion resistance.合理设计具有宽频带、强吸收和低填充比的抗腐蚀电磁波(EMW)吸收材料仍然是一项重大挑战。本研究通过分散聚合和原位生长法合成了三聚氰胺树脂基磁芯壳微球(MF@Fe3O4@SiO2)。实验和模拟结果表明,只要加入少量的镍,就能巧妙地调节与 MF 磁芯配合的磁壳的含量和磁性。此外,通过包覆二氧化硅,MF@Fe3O4 核壳微球的分散性和耐腐蚀性明显增强。值得注意的是,MF@Fe3O4@SiO2 与 MWCNTs-20 复合后,大量异质界面的存在、导电损耗的巧妙改善以及阻抗匹配的优化协同作用,使其具有优异的电磁波吸收特性。当填充量为 30 wt.% 时,匹配厚度为 1.76 mm 的 F9N1-S/MWCNTs-20 的最大有效吸收带宽(EABmax)为 6.55 GHz,同时在 1.53 mm 处的反射损耗(RL)保持在 -62.94 dB。当 F9N1-S/MWCNTs-30 的厚度增加到 3.24 mm 时,低频的 RLmin 达到了 -67.14 dB。此外,对雷达截面值的模拟确定了 F9N1-S/MWCNTs 在雷达探测下实现隐身的巨大潜力。本研究介绍了一种生产轻质、高效、耐腐蚀电磁波吸收器的新方法。An ultrasound-assisted resin transfer molding to improve the impregnation and dual-scale flow for carbon fiber reinforced resin compositesXinxin Xu, Kai Wei, Ming Mei, Maojun Li, Xujing Yangdoi:10.1016/j.compscitech.2024.110710 用超声波辅助树脂传递成型技术改善碳纤维增强树脂复合材料的浸渍和双尺度流动性The imbalance of the dual-scale flow, i.e., microscopic intra-bundles and macroscopic inter-bundles flow, always generates voids in resin transfer molding (RTM) of composites, substantially weakening the mechanical performance. An ultrasound-assisted strategy to improve the impregnation and to balance dual-scale flow is promising to suppress the voids, while, it has still not been explored. Here, an ultrasound-assisted RTM for carbon fiber reinforced resin composites, realized by a self-developed device, is originally proposed. The influences of ultrasound vibration on the carbon fibers, resins, wettability, and impregnation process are systematically explored. Furthermore, the dual-scale flow, affected by the ultrasound vibration, is optimized. It is identified that the ultrasound vibration effectively reduces the viscosity of the resin and increases the roughness and surface activity of the fibers, hence significantly weakening the delayed impregnation in the intra-bundles, and speeding up the impregnation velocity in the inter-bundles. The reduction of the viscosity and the contact angle synergistically lowers the modified capillary number Ca*, hence balancing the dual-scale flow, while the excessively high impregnation velocity in the inter-bundles detrimentally enlarges Ca*, leading to the imbalance of the dual-scale flow. Accordingly, a critical ultrasound energy input (4 min of ultrasound vibration at the power range of 400–600 W) is figured out to achieve an optimal Ca*, providing a promising approach to suppress the flow-induced voids in composites manufacturing by RTM.双尺度流动(即微观束内流动和宏观束间流动)的不平衡总是会在树脂传递模塑(RTM)复合材料中产生空洞,从而大大削弱其机械性能。利用超声波辅助改善浸渍并平衡双尺度流动的策略有望抑制空洞的产生,但这一方法尚未得到探索。在此,我们提出了一种超声波辅助碳纤维增强树脂复合材料的 RTM 方法,该方法是通过自主研发的设备实现的。系统地探讨了超声振动对碳纤维、树脂、润湿性和浸渍过程的影响。此外,还优化了受超声振动影响的双尺度流动。结果表明,超声振动能有效降低树脂的粘度,提高纤维的粗糙度和表面活性,从而大大减弱纤维束内的延迟浸渍,加快纤维束间的浸渍速度。粘度和接触角的降低协同降低了改良毛细管数 Ca,从而平衡了双尺度流动,而束间过高的浸渍速度则不利地扩大了 Ca,导致双尺度流动失衡。因此,我们找出了一个临界超声能量输入(在 400-600 W 功率范围内超声振动 4 分钟),以达到最佳 Ca*,从而为抑制 RTM 复合材料生产中的流动诱发空洞提供了一种可行的方法。Nano-engineered hierarchical natural fibre composites with localised cellulose nanocrystals and tailored interphase for improved mechanical propertiesShahed Ekbatani, Yushen Wang, Shanshan Huo, Dimitrios Papageorgiou, Han Zhangdoi:10.1016/j.compscitech.2024.110719 具有局部纤维素纳米晶体和定制相间物的纳米工程分层天然纤维复合材料可改善机械性能Natural fibre composites have been utilised in many applications such as automotive and buildings, thanks to their high specific properties and environmentally friendly nature. However, the incompatibility between hydrophilic natural fibres and hydrophobic polymer resins remains a longstanding issue in natural fibre composites. Inspired by nature's hierarchical structures and tailored functionalities, a nano-engineered hierarchical natural fibre composite has been developed in this study, utilising cellulose nanocrystals (CNCs) as localised nano-reinforcements at flax surfaces in a flax/bio-epoxy system. A simple and versatile spray coating technique was used to deposit CNCs on unmodified flax fibres, without using any chemical solvents. With the increased surface roughness and hence improved epoxy wetting on nano-engineered flax surfaces (3 wt.% CNC loading), mechanical properties of the hierarchical composites have been significantly improved, with a 60% increase in interlaminar shear strength, indicating an enhanced interfacial load transfer between flax and epoxy, alongside improved flexural modulus (14%) and strength (23%). This green approach without using any chemicals provides a scalable and sustainable way to develop tailored interfaces for natural fibre composites with enhanced resin wetting and mechanical properties.天然纤维复合材料具有高特定性能和环保特性,已被广泛应用于汽车和建筑等领域。然而,亲水性天然纤维与疏水性聚合物树脂之间的不相容性仍然是天然纤维复合材料的一个长期问题。受大自然分层结构和定制功能的启发,本研究开发了一种纳米工程分层天然纤维复合材料,在亚麻/生物环氧体系中利用纤维素纳米晶体(CNC)作为亚麻表面的局部纳米增强体。在不使用任何化学溶剂的情况下,采用简单、通用的喷涂技术将 CNC 沉积在未改性的亚麻纤维上。随着表面粗糙度的增加,纳米工程亚麻表面的环氧润湿性也得到了改善(3 wt.% CNC 负载),分层复合材料的机械性能得到了显著提高,层间剪切强度提高了 60%,这表明亚麻和环氧之间的界面载荷传递得到了加强,同时弯曲模量(14%)和强度(23%)也得到了提高。这种不使用任何化学品的绿色方法为开发具有增强树脂润湿性和机械性能的天然纤维复合材料定制界面提供了一种可扩展和可持续的方法。来源:复合材料力学仿真Composites FEM

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