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【新文速递】2024年6月16日复合材料SCI期刊最新文章

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今日更新:Composite Structures 5 篇,Composites Part A: Applied Science and Manufacturing 5 篇,Composites Part B: Engineering 1 篇,Composites Science and Technology 3 篇

Composite Structures

Geometrically nonlinear transient analyses of rotating structures through high-fidelity models

R. Azzara, M. Filippi, E. Carrera

doi:10.1016/j.compstruct.2024.118265

通过高保真模型对旋转结构进行几何非线性瞬态分析

This work presents geometrically nonlinear transient analyses of various rotating blades. The structures are discretized through refined beams or multi-dimensional finite element models, which are generated using the Carrera Unified Formulation (CUF). The CUF offers a procedure to develop low- and high-fidelity one-dimensional, two-dimensional, and three-dimensional finite element models hierarchically and automatically. Various beam models were developed using different kinematics models based on Taylor or Lagrange expansion functions. Multi-dimensional models were obtained by merging beam and solid elements, exploiting the unique feature of Lagrange polynomials to have only pure displacements as unknowns. This property allows beam and solid elements to be coupled at the node level without requiring complicated mathematical formulations. By utilizing the Finite Element Method in conjunction with the CUF, the governing equations are written by including all rotation effects, namely the Coriolis term, spin-softening, and geometrical stiffening. In a total Lagrangian scenario, the Hilbert-Hughes-Taylor-α method and the iterative Newton-Raphson scheme are employed to solve the equations of motion. The proposed methodology has been applied to evaluate different blade configurations, comparing the solution obtained using linear, linearized, and nonlinear approaches. The results have been verified and validated by comparing them with existing solutions present in the literature.

本研究对各种旋转叶片进行了几何非线性瞬态分析。通过使用 Carrera Unified Formulation(CUF)生成的细化梁或多维有限元模型对结构进行离散化。CUF 提供了一种程序,可分层自动开发低保真和高保真的一维、二维和三维有限元模型。使用基于泰勒或拉格朗日扩展函数的不同运动学模型开发了各种梁模型。利用拉格朗日多项式只有纯位移作为未知数的独特特征,通过合并梁和实体元素获得了多维模型。这一特性使梁和实体元素可以在节点级耦合,而无需复杂的数学公式。通过将有限元法与 CUF 结合使用,可以写出包括所有旋转效应(即科里奥利项、自旋软化和几何刚化)在内的控制方程。在总拉格朗日方案中,采用希尔伯特-休斯-泰勒-α 法和迭代牛顿-拉斐森方案来求解运动方程。所提出的方法已被用于评估不同的叶片配置,并对使用线性、线性化和非线性方法获得的解决方案进行了比较。通过与文献中的现有解决方案进行比较,对结果进行了验证和确认。


A constitutive model for rate-dependency analysis of open hole woven composites under compression loading

J.M. Rodríguez Sereno, J. Pernas-Sánchez, J.A. Artero-Guerrero, J. López Puente

doi:10.1016/j.compstruct.2024.118274

用于分析压缩荷载下开孔编织复合材料速率依赖性的构成模型

The mechanical performance of composite materials under impact phenomena is of interest for several industries. Although the effect of the strain rate on composites significantly affects the behaviour of these materials, most studies describe the mechanical behaviour of CFRP laminates neglecting the strain rate dependence. This work presents a new constitutive model to numerically implement the change of in-plane properties of an plain weave CFRP (AGP193) over a wide range of strain rates (up to 500 s−1). Open hole compression tests are used to validate the model under quasi-static and dynamic loading. The importance of implementing the influence of strain rate on mechanical properties is illustrated by the maximum strength plot and the stress–strain history, both of which would be underestimated without the inclusion of strain rate in the model. The strain rates at the edge of the hole greatly exceed the average values in the sample, leading to an underestimation of the apparent strength up to 100% if the strain rate effect is not taken into account.

复合材料在冲击现象下的机械性能受到多个行业的关注。虽然应变率对复合材料的影响很大,但大多数研究在描述 CFRP 层压材料的机械性能时都忽略了应变率的相关性。本研究提出了一种新的构成模型,用于数值计算平织 CFRP(AGP193)在各种应变速率(最高 500 s-1)下的面内特性变化。开孔压缩试验用于验证准静态和动态加载下的模型。最大强度图和应力-应变历史记录说明了实施应变率对机械性能影响的重要性,如果不将应变率纳入模型,这两项指标都会被低估。孔边缘的应变率大大超过了样品的平均值,如果不考虑应变率的影响,表观强度会被低估达 100%。


Mechanical analysis of a stitched sandwich structure and its SiO2f/SiO2 panels: Experimental and numerical investigation on compression and shear performances

Duoqi Shi, Bo Zhang, Shuangqi Lv, Changqi Liu, Zhen Cheng, Xiaoguang Yang

doi:10.1016/j.compstruct.2024.118277

缝合夹层结构及其 SiO2f/SiO2 面板的力学分析:压缩和剪切性能的实验和数值研究

The compression and shear performances of the stitched sandwich thermal protection structure (SSTPS) was systematically investigated through experimental and simulation methods in this study. Compression and shear testing methods were designed, and macroscopic performance data for SiO2f/SiO2 thin panels and SSTPS were successfully obtained, thereby validating the rationality of the experimental approach. By establishing mechanical experimental methods, the correlation between microscopic structural features and macroscopic mechanical performance was revealed, and mechanical modeling and analysis work was conducted. The experimental and numerical results indicate that compression and shear failure of thin panels mainly occur at the intersections of fiber bundles, exhibiting non-brittle failure. The delamination of sandwich materials or the buckling deformation of panels is identified as the primary cause of the nonlinear response in SSTPS. Elevated temperatures induce an increase in the modulus and strength of SSTPS and a decrease in toughness, correlated with the high-temperature densification of the matrix structure. Finite element simulations reveal the critical role of component and interface damage in macroscopic nonlinear mechanical responses. The research demonstrates that, the compressive and shear failure mechanisms of SiO2f/SiO2 thin panels and SSTPS were successfully elucidated through the implementation of an innovative experimental methodology.

本研究通过实验和模拟方法系统地研究了缝合夹层热保护结构(SSTPS)的压缩和剪切性能。设计了压缩和剪切测试方法,并成功获得了 SiO2f/SiO2 薄板和 SSTPS 的宏观性能数据,从而验证了实验方法的合理性。通过建立力学实验方法,揭示了微观结构特征与宏观力学性能之间的相关性,并进行了力学建模和分析工作。实验和数值结果表明,薄板的压缩和剪切破坏主要发生在纤维束的交汇处,表现为非脆性破坏。夹层材料的分层或面板的屈曲变形被认为是 SSTPS 非线性响应的主要原因。温度升高会导致 SSTPS 的模量和强度增加,而韧性降低,这与基体结构的高温致密化有关。有限元模拟揭示了组件和界面损伤在宏观非线性机械响应中的关键作用。研究表明,通过实施创新的实验方法,成功地阐明了 SiO2f/SiO2 薄面板和 SSTPS 的压缩和剪切破坏机制。


A peridynamic differential operator modeling approach for ceramic matrix composites microstructure with uniform or non-uniform discretization

Q.Z. Wang, Y.L. Hu, Yin Yu, Dan Wu, Z.Y. Yao

doi:10.1016/j.compstruct.2024.118282

均匀或非均匀离散陶瓷基复合材料微观结构的周动态微分算子建模方法

Based on the theory of peridynamic differential operator (PDDO), a novel three-dimensional (3D) peridynamic (PD) model for isotropic and orthotropic material is proposed to investigate the elastic mechanical behaviors and stress distribution of Ceramic Matrix Composites (CMC) microstructure. The non-local expressions of strain and stress tensors are derived by employing PDDO and the classical constitutive equations. The bond forces in interface region crossing two different constituent materials are obtained by converting the partial differential terms into the non-local forms. The weak form of PD equations of motion is derived by using the principle of virtual work and PDDO. The validity of this approach is verified by predicting the elastic response and stress distributions of isotropic and orthotropic materials under uniaxial tension and pure shear deformation. Finally, simulations are conducted on a CMC microstructure with fiber and matrix under periodic boundary conditions. It is demonstrated that the current approach can effectively build 3D CMC microstructure with uniform or non-uniform discretization, and accurately predict the stress fields and effective elastic properties.

基于周动态微分算子(PDDO)理论,提出了一种新颖的各向同性和正交材料的三维(3D)周动态(PD)模型,用于研究陶瓷基复合材料(CMC)微结构的弹性力学行为和应力分布。通过使用 PDDO 和经典构成方程,得出了应变和应力张量的非局部表达式。通过将偏微分项转换为非局部形式,可获得两种不同成分材料交接界面区域的结合力。利用虚功原理和 PDDO 推导出了弱形式的 PD 运动方程。通过预测各向同性和各向同性材料在单轴拉伸和纯剪切变形下的弹性响应和应力分布,验证了这种方法的有效性。最后,在周期性边界条件下对带有纤维和基体的 CMC 微结构进行了模拟。结果表明,目前的方法可以有效地建立均匀或非均匀离散的三维 CMC 微结构,并准确预测应力场和有效弹性特性。


Closed-form methodology for the structural analysis of stiffened composite plates with cutouts and non-uniform lay-up

A. Blázquez, D. Pastorino, B. López-Romano, F. París

doi:10.1016/j.compstruct.2024.118284

带切口和非均匀铺设的加劲复合板结构分析的闭式方法

Building upon the methodology developed in prior studies, which utilized the Lekhnitskii formalism to address composite plates featuring cutouts, varying thicknesses, and different stacking sequences, the present work introduces the incorporation of stiffeners. The structural configuration comprises plates and stringers, with each stringer positioned between two plate regions and subjected to both stretching and bending loads. It is important to note that no coupling between the bending and stretching responses is accounted for; therefore, lay-ups must be symmetric, and stringers must be embedded and bisymmetric. The stringers are modeled using the Euler–Bernoulli formulation with the free torsion hypothesis, while the plates are modelled using the Kirchhoff–Love formulation. Several benchmark problems are analyzed, and the results are compared with those obtained using finite element analysis (utilizing Abaqus software), demonstrating a satisfactory agreement while also showcasing competitive computational efficiency. Thus, the present methodology provides the industry with a novel tool that enables efficient parametric analysis and facilitates the most promising configurations during the initial phases of the design to be selected by engineers.

之前的研究利用 Lekhnitskii 形式主 义解决了具有切口、不同厚度和不同堆叠顺序的复合板问题,在此基础上,本研究引入了加强筋。结构配置包括板和支撑杆,每根支撑杆位于两个板区域之间,同时承受拉伸和弯曲载荷。需要注意的是,弯曲和拉伸响应之间不存在耦合;因此,层叠必须对称,纵梁必须是嵌入式和双对称的。弦杆采用带有自由扭转假设的欧拉-伯努利公式建模,而板则采用基尔霍夫-洛夫公式建模。对几个基准问题进行了分析,并将结果与使用有限元分析(利用 Abaqus 软件)获得的结果进行了比较,结果表明两者的一致性令人满意,同时也展示了极具竞争力的计算效率。因此,本方法为业界提供了一种新型工具,可实现高效的参数分析,并有助于工程师在设计的初始阶段选择最有前途的配置。


Composites Part A: Applied Science and Manufacturing

Computational study on the electrical conductivity of hybrid composites under mechanical deformation

Hyeontae An, Jinyoung Hwang

doi:10.1016/j.compositesa.2024.108317

 

机械变形条件下混合复合材料导电性的计算研究

This study explores the hybrid composite’s electrical conductivity response under uniaxial tensile strain, wherein conductive nanowires and insulating particulate fillers are integrated within a flexible polymer matrix. We develop a Monte Carlo–based computational model and analyze the significant influence of particulate fillers on the strain response of the electrical conductivity. The particulate fillers induce both the exclusive volume and nanowire bending effects, significantly contributing to determining the hybrid composites’ electrical conductivity. The exclusive volume effect mitigates conductivity changes under external deformation, decreasing the conductivity change rate as the particulate filler content increases when the exclusive volume effect is dominant. Conversely, the nanowire bending effect boosts conductivity change under external deformation, so when it predominates over the exclusive volume effect, the conductivity change rate increases with higher particulate filler content. The insights from the study aid in designing and optimizing flexible electronic materials resilient to mechanical deformation.

本研究探讨了导电纳米线和绝缘颗粒填料集成在柔性聚合物基体中的混合复合材料在单轴拉伸应变下的导电响应。我们建立了一个基于蒙特卡罗的计算模型,并分析了颗粒填料对导电率应变响应的重要影响。微粒填料会产生排他性体积效应和纳米线弯曲效应,这对混合复合材料的导电性有重要影响。排他性体积效应可减轻外部变形下的电导率变化,当排他性体积效应占主导地位时,随着颗粒填料含量的增加,电导率变化率会降低。相反,纳米线弯曲效应会促进外部形变下的电导率变化,因此当纳米线弯曲效应优于独占体积效应时,电导率变化率会随着微粒填料含量的增加而增加。这项研究的启示有助于设计和优化可承受机械变形的柔性电子材料。


A comparative study of emerging material point method and FEM for forming simulation of textile reinforcements

Amir Nazemi, Abbas S. Milani

doi:10.1016/j.compositesa.2024.108284

新兴材料点法和有限元法在纺织加固材料成型模拟中的比较研究

For forming simulations of fabric composites, nonlinear Finite Element Method/FEM has been a long-standing tool to predict and mitigate defects such as wrinkling. However, small-time step requirements in explicit FEM codes, numerical instabilities, and large computational time are among challenges reported. This study presents an alternative fast forming simulation technique through an application of the so-called Material Point Method/MPM, which enables the use of much larger time steps along with fewer numerical instabilities. As a preliminary step towards assessment of this method, both standard 2D deformation modes and 3D hemispherical forming setups were employed, using a plain fabric weave at dry condition. The MPM results were compared to the conventional FEM simulations, as well as to the physical experiments. Notably, the MPM method showed a runtime 20 times faster than its FEM counterpart (under a comparable mesh size), yet with the same reliability in forming predictions as verified by experiments.

对于织物复合材料的成型模拟,非线性有限元法/有限元一直是预测和减少起皱等缺陷的长期工具。然而,显式有限元代码中的小时间步长要求、数值不稳定性和计算时间过长等问题也是所面临的挑战之一。本研究通过应用所谓的 "材料点法/MPM",提出了另一种快速成型模拟技术,它可以使用大得多的时间步长,同时减少数值不稳定性。作为对该方法进行评估的第一步,我们采用了标准二维变形模式和三维半球成型设置,并使用了干燥状态下的平纹织物编织。MPM 的结果与传统的有限元模拟以及物理实验进行了比较。值得注意的是,MPM 方法的运行时间比 FEM 方法快 20 倍(在网格大小相当的情况下),但成形预测的可靠性与实验验证的相同。


Impact response and energy absorption mechanisms of UHMWPE fabric and composites in ballistic applications: A comprehensive review

Ashish Joshi, Ashish Mishra, Vikas Kumar Saxena

doi:10.1016/j.compositesa.2024.108314

弹道应用中超高分子量聚乙烯织物和复合材料的冲击响应和能量吸收机制:全面综述

Recently, UHMWPE fabric and composites have gained attraction in ballistics due to their impressive strength-to-weight ratio and impact resistance. This article provides a critical analysis of internal and external factors influencing the impact response of UHMWPE fabric and composites. Damage mechanisms in UHMWPE yarns, fabrics, and composites are explored, which reveals the influence of internal factors like fibre properties, resin characteristics, interphase properties, and composite architecture on impact resistance. Further, the influence of external factors such as projectile type, environmental conditions, and impact velocity are discussed. The review also discussed methods employed by researchers to enhance the energy-absorbing capacity of UHMWPE fabric and its composites, focusing on improving interphase characteristics and friction between woven fabric yarns. Concluding with insights into future research, the review underscores the necessity of advancing studies to augment UHMWPE fibre’s energy absorption resistance, expanding its applications in aerospace, automotive components, protective gear, and ballistic protection.

近来,超高分子量聚乙烯织物和复合材料因其出色的强度重量比和抗冲击性而在弹道学领域备受青睐。本文对影响超高分子量聚乙烯织物和复合材料冲击响应的内部和外部因素进行了深入分析。文章探讨了超高分子量聚乙烯纱线、织物和复合材料的损伤机制,揭示了纤维特性、树脂特性、相间特性和复合材料结构等内部因素对抗冲击性的影响。此外,还讨论了弹丸类型、环境条件和冲击速度等外部因素的影响。综述还讨论了研究人员为提高超高分子量聚乙烯织物及其复合材料的吸能能力而采用的方法,重点是改善相间特性和织物纱线之间的摩擦力。综述最后对未来研究提出了见解,强调有必要推进研究,以增强超高分子量聚乙烯纤维的能量吸收能力,扩大其在航空航天、汽车部件、防护装备和弹道防护领域的应用。


Bi-continuous interpenetrated porous composite integrating the high strength and long plateau stress stage prepared by an in situ method

Endian Liu, Yu Bai, Jiawen Li, Hai Hao

doi:10.1016/j.compositesa.2024.108315

 

用原位法制备高强度和长高原应力阶段一体化的双连续互穿多孔复合材料

In this paper, bi-continuous interpenetrated porous composites (BIPCs) were prepared with the combination of melt foaming and infiltration casting process. All BIPCs exhibited superior mechanical performance than aluminum foam (AF) and the sum of their components. Among them, 4# BIPC (with 75 struts) showed the highest specific energy absorption which is 2.70 times that of AF, and 3# BIPC (with 48 struts) presented the best improvement in terms of structural strength, while 2# BIPC (with 27 struts) exhibited the largest enhancement of energy absorption. The results indicate that the in situ interface of AF and ordered lattice structure contributes to the enhanced strength of BIPCs, while pores in AF prolongs the stress plateau stage. This research provides a novelty method to solve the trade-off between different mechanical property indicators.

本文结合熔体发泡和渗透铸造工艺制备了双连续互穿多孔复合材料(BIPC)。所有 BIPC 的机械性能均优于泡沫铝(AF)及其组分的总和。其中,4# BIPC(含 75 根支柱)的比能量吸收最高,是 AF 的 2.70 倍;3# BIPC(含 48 根支柱)的结构强度改善最好;2# BIPC(含 27 根支柱)的能量吸收增强最大。研究结果表明,AF 的原位界面和有序晶格结构有助于提高 BIPC 的强度,而 AF 中的孔隙则延长了应力高原阶段。这项研究为解决不同力学性能指标之间的权衡问题提供了一种新方法。


An emerging shellwich lattice material: Unlocking design freedom and enhancing mechanical properties

Ming Lei, Pan Wang, Shengyu Duan, Weibin Wen, Jun Liang

doi:10.1016/j.compositesa.2024.108316

 

一种新兴的贝壳晶格材料:释放设计自由度,提高机械性能

This study proposes a novel sandwich shell lattice material called “shellwich”, which offsets the shell lattice to both sides to form panels and achieves the matching of porous material core layer with shell lattice panels. The shellwich lattices (P-BCC) with Schwarz Primitive (P) shell lattice panels and a body-centered cubic (BCC) truss lattice core layer are designed and fabricated. Compression experiments are carried out to explore the mechanical responses of the P-BCC experimentally and numerically. Compared with the P shell and BCC truss lattices, the P-BCC shellwich lattice demonstrates excellent mechanical properties, including widely tailorable elasticity and enhanced energy absorption. Furthermore, the effects of structural parameters on the elastic responses and energy absorption of the P-BCC are discussed. This study provides insights into the design of sandwich structures and lattice materials with high-performance and multifunctional properties, opening up new possibilities for lightweight structures, energy-absorbing systems and other engineering applications.

本研究提出了一种名为 "shellwich "的新型夹层壳格材料,它将壳格向两侧偏移形成面板,实现了多孔材料芯层与壳格面板的匹配。我们设计并制造了具有施瓦茨基元(P)贝壳晶格面板和体心立方(BCC)桁架晶格核心层的贝壳晶格(P-BCC)。通过压缩实验,以实验和数值方法探讨了 P-BCC 的机械响应。与 P 壳和 BCC 桁架晶格相比,P-BCC 壳夹层晶格表现出优异的力学性能,包括可广泛调整的弹性和更强的能量吸收。此外,还讨论了结构参数对 P-BCC 弹性响应和能量吸收的影响。这项研究为设计具有高性能和多功能特性的夹层结构和晶格材料提供了启示,为轻质结构、吸能系统和其他工程应用开辟了新的可能性。


Composites Part B: Engineering

Bioactive hydrogels loaded with BMSC-EXOs and GDNF for synergistically spinal cord injury repairing

Hong Cheng, Hui Zhang, Yangnan Hu, Yusong Wang, Lei Tian, Yanru Qi, Lei Ren, Bin Zhang, Shasha Zheng, Xinyue Han, Xiaofeng Ma, Feika Bian, Huan Wang, Tingting Liu, Renjie Chai

doi:10.1016/j.compositesb.2024.111618

负载 BMSC-EXOs 和 GDNF 的生物活性水凝胶可协同修复脊髓损伤

Spinal cord injury (SCI) is a common lethal injury to the central nervous system (CNS), which severely affects the quality of life of SCI patients. Attempts to enhance the treatment of SCI typically tend to develop functional bioactive hydrogel scaffolds with drug encapsulation. In this work, we proposed novel RGD-functionalized bioactive hydrogel loaded with bone marrow stromal cells-derived exosomes (BMSC-EXOs) and glial cell line-derived neurotrophic factor (GDNF) to synergistically promote SCI repair. The functional hydrogel consisted of methacrylic anhydride-grafted sodium alginate and acrylated RGD, and then combined with BMSC-EXOs and GDNF by photocrosslinking to form a composite bioactive hydrogel. The hydrogel showed good drug-release properties and biocompatibility. When the bioactive hydrogel was implanted into the SCI area of the SD rats, it effectively modulated the adverse inflammatory response in the SCI area. Furthermore, the bioactive hydrogel promoted the regeneration of spinal cord neurons and axons, leading to the improvement in motor function recovery. These results indicate that the bioactive hydrogel loaded with BMSC-EXOs and GDNF has great potential as a therapeutic approach for the repair of spinal cord injuries.

脊髓损伤(SCI)是中枢神经系统(CNS)常见的致命伤,严重影响脊髓损伤患者的生活质量。试图提高 SCI 治疗效果的方法通常倾向于开发具有药物封装功能的生物活性水凝胶支架。在这项工作中,我们提出了一种新型 RGD 功能化生物活性水凝胶,其中装载了骨髓基质细胞衍生的外泌体(BMSC-EXOs)和胶质细胞系衍生的神经营养因子(GDNF),可协同促进 SCI 修复。功能性水凝胶由甲基丙烯酸酐接枝海藻酸钠和丙烯酸化RGD组成,然后通过光交联与BMSC-EXOs和GDNF结合形成复合生物活性水凝胶。该水凝胶具有良好的药物释放性能和生物相容性。将该生物活性水凝胶植入 SD 大鼠的 SCI 区域后,可有效调节 SCI 区域的不良炎症反应。此外,生物活性水凝胶还促进了脊髓神经元和轴突的再生,从而改善了运动功能的恢复。这些结果表明,负载有 BMSC-EXOs 和 GDNF 的生物活性水凝胶作为脊髓损伤修复的一种治疗方法具有巨大的潜力。


Composites Science and Technology

Synergistic Enhancing Effect for Electromagnetic Wave Absorption via Melamine Resin-Based Magnetic Core-Shell Microspheres/Multi-Walled Carbon Nanotubes

Shenyang Cao, Yu’an Huang, Zhao Xu, Tienan Dong, Yihuang Su, Jiabao Lei, Siyi Zhang, Yibing Lin, Di Hao, Yichen Cao, Kaina Yang, Zusheng Hang, Runsheng Huang

doi:10.1016/j.compscitech.2024.110709

 

三聚氰胺树脂基磁核壳微球/多壁碳纳米管对电磁波吸收的协同增强效应

Rational design of corrosion-resistant electromagnetic wave (EMW) absorbing materials with wide bandwidth, strong absorption, and low filling ratio remains a significant challenge. In this work, the melamine resin-based magnetic core-shell microspheres (MF@Fe3O4@SiO2) were synthesized via dispersion polymerization and in-situ growth method. Experimental and simulation results indicated that the content and magnetism of the magnetic shell coordinated with the MF-core could be tactfully regulated with a small amount of incorporated Ni content. Moreover, the dispersion and corrosion resistance of MF@Fe3O4 core-shell microspheres were obviously enhanced by coating SiO2. It is worth noting that after the composite of MF@Fe3O4@SiO2 with MWCNTs-20, the presence of numerous heterogeneous interfaces, the tactfully improved conductive loss, and the optimized impedance matching synergistically result in superior EMW absorption properties. When the filling amount was 30 wt.%, F9N1-S/MWCNTs-20 with a matching thickness of 1.76 mm, exhibited the maximum effective absorption bandwidth (EABmax) of 6.55 GHz, while maintaining a reflection loss (RL) of -62.94 dB at 1.53 mm. When the thickness of F9N1-S/MWCNTs-30 was increased to 3.24 mm, the RLmin at low frequencies was achieved at -67.14 dB. Besides, the simulation of radar cross section values ascertains the enormous potential of F9N1-S/MWCNTs to achieve stealth under radar detection. This study introduces a novel method for producing lightweight and efficient EMW absorbers with corrosion resistance.

合理设计具有宽频带、强吸收和低填充比的抗腐蚀电磁波(EMW)吸收材料仍然是一项重大挑战。本研究通过分散聚合和原位生长法合成了三聚氰胺树脂基磁芯壳微球(MF@Fe3O4@SiO2)。实验和模拟结果表明,只要加入少量的镍,就能巧妙地调节与 MF 磁芯配合的磁壳的含量和磁性。此外,通过包覆二氧化硅,MF@Fe3O4 核壳微球的分散性和耐腐蚀性明显增强。值得注意的是,MF@Fe3O4@SiO2 与 MWCNTs-20 复合后,大量异质界面的存在、导电损耗的巧妙改善以及阻抗匹配的优化协同作用,使其具有优异的电磁波吸收特性。当填充量为 30 wt.% 时,匹配厚度为 1.76 mm 的 F9N1-S/MWCNTs-20 的最大有效吸收带宽(EABmax)为 6.55 GHz,同时在 1.53 mm 处的反射损耗(RL)保持在 -62.94 dB。当 F9N1-S/MWCNTs-30 的厚度增加到 3.24 mm 时,低频的 RLmin 达到了 -67.14 dB。此外,对雷达截面值的模拟确定了 F9N1-S/MWCNTs 在雷达探测下实现隐身的巨大潜力。本研究介绍了一种生产轻质、高效、耐腐蚀电磁波吸收器的新方法。


An ultrasound-assisted resin transfer molding to improve the impregnation and dual-scale flow for carbon fiber reinforced resin composites

Xinxin Xu, Kai Wei, Ming Mei, Maojun Li, Xujing Yang

doi:10.1016/j.compscitech.2024.110710

 

用超声波辅助树脂传递成型技术改善碳纤维增强树脂复合材料的浸渍和双尺度流动性

The imbalance of the dual-scale flow, i.e., microscopic intra-bundles and macroscopic inter-bundles flow, always generates voids in resin transfer molding (RTM) of composites, substantially weakening the mechanical performance. An ultrasound-assisted strategy to improve the impregnation and to balance dual-scale flow is promising to suppress the voids, while, it has still not been explored. Here, an ultrasound-assisted RTM for carbon fiber reinforced resin composites, realized by a self-developed device, is originally proposed. The influences of ultrasound vibration on the carbon fibers, resins, wettability, and impregnation process are systematically explored. Furthermore, the dual-scale flow, affected by the ultrasound vibration, is optimized. It is identified that the ultrasound vibration effectively reduces the viscosity of the resin and increases the roughness and surface activity of the fibers, hence significantly weakening the delayed impregnation in the intra-bundles, and speeding up the impregnation velocity in the inter-bundles. The reduction of the viscosity and the contact angle synergistically lowers the modified capillary number Ca*, hence balancing the dual-scale flow, while the excessively high impregnation velocity in the inter-bundles detrimentally enlarges Ca*, leading to the imbalance of the dual-scale flow. Accordingly, a critical ultrasound energy input (4 min of ultrasound vibration at the power range of 400–600 W) is figured out to achieve an optimal Ca*, providing a promising approach to suppress the flow-induced voids in composites manufacturing by RTM.

双尺度流动(即微观束内流动和宏观束间流动)的不平衡总是会在树脂传递模塑(RTM)复合材料中产生空洞,从而大大削弱其机械性能。利用超声波辅助改善浸渍并平衡双尺度流动的策略有望抑制空洞的产生,但这一方法尚未得到探索。在此,我们提出了一种超声波辅助碳纤维增强树脂复合材料的 RTM 方法,该方法是通过自主研发的设备实现的。系统地探讨了超声振动对碳纤维、树脂、润湿性和浸渍过程的影响。此外,还优化了受超声振动影响的双尺度流动。结果表明,超声振动能有效降低树脂的粘度,提高纤维的粗糙度和表面活性,从而大大减弱纤维束内的延迟浸渍,加快纤维束间的浸渍速度。粘度和接触角的降低协同降低了改良毛细管数 Ca,从而平衡了双尺度流动,而束间过高的浸渍速度则不利地扩大了 Ca,导致双尺度流动失衡。因此,我们找出了一个临界超声能量输入(在 400-600 W 功率范围内超声振动 4 分钟),以达到最佳 Ca*,从而为抑制 RTM 复合材料生产中的流动诱发空洞提供了一种可行的方法。


Nano-engineered hierarchical natural fibre composites with localised cellulose nanocrystals and tailored interphase for improved mechanical properties

Shahed Ekbatani, Yushen Wang, Shanshan Huo, Dimitrios Papageorgiou, Han Zhang

doi:10.1016/j.compscitech.2024.110719

 

具有局部纤维素纳米晶体和定制相间物的纳米工程分层天然纤维复合材料可改善机械性能

Natural fibre composites have been utilised in many applications such as automotive and buildings, thanks to their high specific properties and environmentally friendly nature. However, the incompatibility between hydrophilic natural fibres and hydrophobic polymer resins remains a longstanding issue in natural fibre composites. Inspired by nature's hierarchical structures and tailored functionalities, a nano-engineered hierarchical natural fibre composite has been developed in this study, utilising cellulose nanocrystals (CNCs) as localised nano-reinforcements at flax surfaces in a flax/bio-epoxy system. A simple and versatile spray coating technique was used to deposit CNCs on unmodified flax fibres, without using any chemical solvents. With the increased surface roughness and hence improved epoxy wetting on nano-engineered flax surfaces (3 wt.% CNC loading), mechanical properties of the hierarchical composites have been significantly improved, with a 60% increase in interlaminar shear strength, indicating an enhanced interfacial load transfer between flax and epoxy, alongside improved flexural modulus (14%) and strength (23%). This green approach without using any chemicals provides a scalable and sustainable way to develop tailored interfaces for natural fibre composites with enhanced resin wetting and mechanical properties.

天然纤维复合材料具有高特定性能和环保特性,已被广泛应用于汽车和建筑等领域。然而,亲水性天然纤维与疏水性聚合物树脂之间的不相容性仍然是天然纤维复合材料的一个长期问题。受大自然分层结构和定制功能的启发,本研究开发了一种纳米工程分层天然纤维复合材料,在亚麻/生物环氧体系中利用纤维素纳米晶体(CNC)作为亚麻表面的局部纳米增强体。在不使用任何化学溶剂的情况下,采用简单、通用的喷涂技术将 CNC 沉积在未改性的亚麻纤维上。随着表面粗糙度的增加,纳米工程亚麻表面的环氧润湿性也得到了改善(3 wt.% CNC 负载),分层复合材料的机械性能得到了显著提高,层间剪切强度提高了 60%,这表明亚麻和环氧之间的界面载荷传递得到了加强,同时弯曲模量(14%)和强度(23%)也得到了提高。这种不使用任何化学品的绿色方法为开发具有增强树脂润湿性和机械性能的天然纤维复合材料定制界面提供了一种可扩展和可持续的方法。




来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemInspireAbaqus振动复合材料非线性化学隐身通用航空航天汽车建筑理论材料控制
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【新文速递】2024年6月18日复合材料SCI期刊最新文章

今日更新:Composite Structures 4 篇,Composites Part A: Applied Science and Manufacturing 2 篇,Composites Part B: Engineering 1 篇Composite StructuresMicrostructure, mechanical properties and interaction mechanism of seawater sea-sand engineered cementitious composite (SS-ECC) with Glass Fiber Reinforced Polymer (GFRP) barJiaying Wei, Linyuwen Ke, Peng Wang, Weiwen Li, Christopher K.Y. Leungdoi:10.1016/j.compstruct.2024.118302海水海砂工程水泥基复合材料(SS-ECC)与玻璃纤维增强聚合物(GFRP)棒材的微观结构、力学性能和相互作用机理With increasing demand for sustainable and long-lasting materials, seawater sea-sand engineered cementitious composite (SS-ECC) has emerged as a promising alternative to conventional concrete in near-ocean construction projects. Glass fiber reinforced polymer (GFRP) bar with excellent corrosion resistance is an ideal choice for these applications. This study evaluated the bond performance of GFRP bars embedded in normal-strength ECC with polyvinyl alcohol (PVA) fibers and high-strength ECC with polyethylene (PE) fibers through pull-out tests. Additionally, tests were conducted on GFRP bars in pristine ECC made with freshwater and river sand for comparison. Further investigation explored the structural properties and uncovered load transfer mechanisms. Results indicate that saline content facilitates early cement hydration of normal-strength ECC, resulting in finer pore structure (10.5% lower porosity and 12.5% lower sorptivity), slightly enhanced compressive performance (1.2% higher compressive strength and 8.3% higher elastic modulus), denser microstructure at GFRP-ECC interface (13.7% lower porous transition zone thickness, 19.2% narrower transition zone and 19.7% higher Ca/Si ratio), superior bond performance (28.3% higher bonding strength and 22.6% higher fracture energy). Conversely, saline content imposes a limited impact on the mechanical properties of high-strength ECC, primarily attributed to the ultra-fine microstructure and early strength characteristics exhibited by the SF-based cementitious binder随着对可持续和长效材料的需求日益增长,海水海砂工程水泥基复合材料(SS-ECC)已成为近海建设项目中替代传统混凝土的一种前景广阔的材料。具有优异耐腐蚀性能的玻璃纤维增强聚合物(GFRP)棒材是这些应用的理想选择。本研究通过拉出试验,评估了嵌入普通强度 ECC(含聚乙烯醇(PVA)纤维)和高强度 ECC(含聚乙烯(PE)纤维)中的玻璃纤维增强聚合物棒材的粘结性能。此外,还对使用淡水和河沙制成的原始 ECC 中的 GFRP 钢筋进行了测试,以进行比较。进一步的研究探讨了结构特性并揭示了荷载传递机制。结果表明,含盐量可促进正常强度 ECC 的早期水泥水化,使孔隙结构更细(孔隙率降低 10.5%,吸水率降低 12.5%),抗压性能略有提高(抗压强度提高 1.2%,弹性模量提高 8.3% ),GFRP-ECC 界面的微观结构更致密(多孔过渡区厚度降低 13.7%,过渡区变窄 19.2%,Ca/Si 比率提高 19.7%),粘结性能更优异(粘结强度提高 28.3%,断裂能提高 22.6%)。相反,盐分含量对高强度 ECC 的机械性能影响有限,这主要归因于 SF 基水泥基粘结剂所表现出的超细微观结构和早期强度特性。Low-velocity impact analysis and multi-objective optimization of hybrid carbon/basalt fibre reinforced composite laminateWenchao Xu, Jing Chen, Xiaofan Cui, Dengfeng Wang, Yongfeng Pudoi:10.1016/j.compstruct.2024.118305碳/钴混合纤维增强复合材料层压板的低速冲击分析和多目标优化Three-dimensional in-plane progressive damage model was developed for carbon/basalt fibre interlayer hybrid composites in this study, and cohesive element model was employed to simulate interlaminar damage. Numerical simulation of low-velocity progressive impact damage of hybrid composite laminate was carried out, and its accuracy was verified by physical impact test, with the maximum error of the maximum contact force, maximum displacement and energy absorption not exceeding 7% and the maximum error in damage area size within 5%. The effects of lay-up structure and angle on the impact properties of hybrid laminate were investigated through simulation. Finally, real number coding strategy was proposed for the parametric representation of the lay-up material and angle of each layer. Multi-objective optimization of hybrid laminate based on Kriging surrogate model and hybrid algorithm composed of elitist non-dominated sorting genetic algorithm and multi-objective particle swarm algorithm was conducted. The optimal trade-off solution was selected from the Pareto solutions using grey relational analysis coupled with principal component analysis method. The coefficient of variance between peak force and maximum displacement of the optimized laminate was 49.3%, 44.9% and 31.4% lower than those of the pure CFRP laminate, pure BFRP laminate, and hybrid laminate before optimization, respectively, indicating that the balance degree of impact displacement and force has been substantially improved. The progressive impact damage simulation and parametric optimization design methodology proposed in this study provide useful guidance for the design of hybrid composite laminate.本研究针对碳/盐纤维层间混合复合材料建立了三维平面内渐进损伤模型,并采用内聚元素模型模拟层间损伤。对混合复合材料层压板的低速渐进式冲击损伤进行了数值模拟,并通过物理冲击试验验证了其准确性,最大接触力、最大位移和能量吸收的最大误差不超过 7%,损伤面积大小的最大误差在 5%以内。通过仿真研究了铺层结构和角度对混合层压板冲击性能的影响。最后,提出了实数编码策略,用于参数化表示各层的铺层材料和角度。基于 Kriging 代理模型以及由精英非支配排序遗传算法和多目标粒子群算法组成的混合算法,对混合层压板进行了多目标优化。利用灰色关系分析法和主成分分析法从帕累托解中选出了最佳权衡解。与优化前的纯 CFRP 层压板、纯 BFRP 层压板和混合层压板相比,优化后的层压板峰值力和最大位移之间的方差系数分别降低了 49.3%、44.9% 和 31.4%,表明冲击位移和力的平衡度得到了大幅提高。本研究提出的渐进式冲击损伤模拟和参数优化设计方法为混合复合材料层压板的设计提供了有益的指导。Shear response and deformation mechanism of boron nitride nanosheets reinforced aluminum matrix compositesKezhong Xu, Jinming Li, Yuqi Zhou, Yuhan Gao, Xin Lei, Fulong Zhudoi:10.1016/j.compstruct.2024.118298氮化硼纳米片增强铝基复合材料的剪切响应和变形机理Atomistic simulations are performed to study the shear response and deformation mechanism of boron nitride nanosheet (BNNS) reinforced aluminum (Al) matrix composites. In this work, stacked BNNS/Al composites and dispersed BNNS/Al composites with various BNNS layers are constructed, respectively. Our computations show that the wrinkle deformation of BNNS under shear loading does not lead to the loss of load-bearing capacity. However, the yield of the Al matrix causes it to lose load-bearing capacity. The occurrence of wrinkles in BNNS aggravates the plastic failure of the Al matrix. High BNNS volume fraction increases the shear modulus and flow stress of stacked BNNS/Al composites but decreases the shear strength. Compared with stacked BNNS/Al composites, the mechanical properties of dispersed BNNS/Al composites are remarkably improved with the increase of BNNS interface in both elastic and plastic stages. In addition, the BNNS interface is able to obstruct the propagation of dislocations and stacking faults in the Al matrix. These findings may deepen our understanding of the mechanical properties and deformation mechanisms of BNNS/Al composites.为了研究氮化硼纳米片(BNNS)增强铝(Al)基复合材料的剪切响应和变形机制,我们进行了原子模拟。在这项工作中,分别构建了叠层 BNNS/Al 复合材料和具有不同 BNNS 层的分散 BNNS/Al 复合材料。我们的计算表明,BNNS 在剪切荷载下的皱缩变形不会导致承载能力的丧失。然而,铝基体的屈服会导致其失去承载能力。BNNS 出现皱纹会加剧铝基体的塑性破坏。高 BNNS 体积分数会增加叠层 BNNS/Al 复合材料的剪切模量和流动应力,但会降低剪切强度。与叠层 BNNS/Al 复合材料相比,随着 BNNS 界面的增加,分散 BNNS/Al 复合材料在弹性和塑性阶段的力学性能都得到了显著改善。此外,BNNS 界面还能阻碍位错和堆积断层在铝基体中的传播。这些发现可加深我们对 BNNS/Al 复合材料机械性能和变形机制的理解。Experimental and numerical investigation of an additively manufactured sandwich composite bridge deck utilizing gyroid building blocksLucija Stepinac, Josip Galić, Anastasios P. Vassilopoulosdoi:10.1016/j.compstruct.2024.118304利用陀螺构件对添加式制造的三明治复合材料桥面进行实验和数值研究This work investigates the integration of Additive Manufacturing (AM) techniques with cellular metamaterials integrated into composite sandwich beam systems. The study proposes an approach that combines composite materials for the face sheets with cellular structures using a Triply Periodic Minimal Surface (TPMS) Gyroid structure for the core to achieve maximum lightweight and load-bearing capabilities. The experimental and numerical campaigns were utilized for the material testing of 3D printing polymeric material reinforced with chopped carbon fibre (CF). To validate the composite sandwich structure, three bending experiments were conducted: (a) bending of the “core only” was performed to calibrate the material for the given print parameters; (b) bending of the “sandwich beam” composite with a periodic and homogenous Gyroid core bonded with glass fibre reinforced polymer (GFRP) face sheets; (c) the “arch beam” composite with the change in outer cross-section dimension with the same periodic and homogenous Gyroid core. The FEM analysis was combined with Digital Image Correlation (DIC) results to determine the bending stiffness of the sandwich beams and to detect the failure modes. It was discovered that integrating 3D printing into load-bearing structures through the composite “sandwich beam” system resulted in seven times increase in load-bearing capacity and four times increase in stiffness compared to results obtained with the “core only” structure.这项研究探讨了将增材制造(AM)技术与蜂窝超材料集成到复合材料夹层梁系统中。研究提出了一种方法,将复合材料面片与蜂窝结构相结合,使用三周期最小面(TPMS)Gyroid 结构作为核心,以实现最大的轻质和承载能力。实验和数值计算活动用于对用切碎碳纤维(CF)增强的 3D 打印聚合物材料进行材料测试。为验证复合夹层结构,进行了三次弯曲实验:(a)对 "仅芯材 "进行弯曲,以校准给定打印参数下的材料;(b)对 "夹层梁 "复合材料进行弯曲,该复合材料具有周期性和均质的陀螺型芯材,并与玻璃纤维增强聚合物(GFRP)面片粘合;(c)对 "拱形梁 "复合材料进行弯曲,该复合材料具有相同的周期性和均质陀螺型芯材,并改变了外截面尺寸。有限元分析与数字图像关联(DIC)结果相结合,确定了夹层梁的弯曲刚度,并检测了破坏模式。研究发现,通过复合 "夹心梁 "系统将 3D 打印技术整合到承重结构中,与 "仅核心 "结构相比,承重能力提高了七倍,刚度提高了四倍。Composites Part A: Applied Science and ManufacturingA printable shear stiffening composite with enhanced fracture toughness and impact resistance for intelligent wearable applicationsChunyu Zhao, Yingfu Wang, Congcong Lou, Yu Cai, Xinglong Gongdoi:10.1016/j.compositesa.2024.108319 一种可打印的剪切加固复合材料,具有更高的断裂韧性和抗冲击性,适用于智能可穿戴应用The continuous advancement in shear stiffening materials has sparked innovation in the field of flexible wearable devices. However, conventional preparation techniques for these materials have drawbacks such as limited toughness and lack of structural design. Herein, we propose a convenient fabrication method for shear stiffening elastomer (SSE) composite using a direct-ink-writing (DIW) assisted manufacturing technique. The influence of SSE structural design strategy on the mechanical behavior of composite is comprehensively investigated using crack propagation and dynamic impact experiments. Benefiting from the mechanically complementary effect of two-phase materials, coupled with robust interfacial adhesion, the composite with a densely arranged rectangular SSE structure exhibits high fracture toughness (2776.10 J⋅m−2) and impact force dissipation (61.78 %). Further, by integrating the printable composite with deep learning-based wireless sensing modules, a wearable elbow pad with attractive man–machine interaction is developed, which verifies the broad application prospect of this composite in intelligent protection.剪切加固材料的不断进步引发了柔性可穿戴设备领域的创新。然而,这些材料的传统制备技术存在韧性有限、缺乏结构设计等缺点。在此,我们提出了一种采用直接墨水写入(DIW)辅助制造技术的剪切加固弹性体(SSE)复合材料的便捷制造方法。利用裂纹扩展和动态冲击实验全面研究了 SSE 结构设计策略对复合材料力学行为的影响。得益于两相材料的机械互补效应以及强大的界面粘附力,密集排列的矩形 SSE 结构复合材料表现出较高的断裂韧性(2776.10 J-m-2)和冲击力耗散(61.78%)。此外,通过将可打印复合材料与基于深度学习的无线传感模块相结合,开发出了一种具有人机交互吸引力的可穿戴肘垫,验证了该复合材料在智能防护领域的广阔应用前景。Discontinuous interleaving strategies for toughening, damage sensing and repair in multifunctional carbon fibre/epoxy compositesThomas D.S. Thorn, Yushen Wang, Hongxu Guo, Lichang Lu, Yi Liu, Emiliano Bilotti, Dimitrios G. Papageorgiou, Han Zhangdoi:10.1016/j.compositesa.2024.108320 用于多功能碳纤维/环氧树脂复合材料增韧、损伤传感和修复的非连续交织策略Thermoplastic interleaving is a well-established approach to toughen carbon fibre thermoset laminates, studied over the past five decades. Recently, it has been revisited to create functional smart composites with damage sensing and repair capabilities with a renewed focus on the sustainability and longevity of components. However, the introduction of thermoplastic films within the interlaminar region often lowers fibre volume fraction and performance at elevated temperature, while the addition of impermeable continuous films during manufacture may also limit compatible fabrication methods. Moreover, the incorporation of dielectric thermoplastic films inevitably reduces through-thickness electrical conductivity and prevents accurate damage sensing of delamination in carbon fibre laminates. In this study, strategies of using discontinuous interleaving to improve both fracture toughness and thermomechanical properties of carbon fibre epoxy laminates, with the ability to monitor delamination damage and restore mechanical properties after a short healing step have been explored. Both the interleaving design and the physical properties of the thermoplastic were assessed, which has not been addressed previously. Interleaving high molecular weight thermoplastic with decreasing interleaf width and distance between interleaf zones results in increased fracture toughness (+347 %), by creating a superior toughened interlaminar zone, forcing a migration of delamination into the intralaminar region. A maximum repair efficiency of 77 % was achieved when using a lower molecular weight of thermoplastic; however, the lack of thermoplastic over the entire fracture surface area affects the repairing performance universally. Damage sensing and thermomechanical properties were significantly improved compared to continuous interleaving, demonstrating that discontinuous thermoplastic interleaving strategies offer a favourable combination of toughening, thermal performance and accurate damage sensing for multifunctional high-performance composites.热塑性 交错材料是一种成熟的碳纤维热固性层压材料增韧方法,在过去的五十年中得到了广泛的研究。最近,随着人们对部件可持续性和使用寿命的重新关注,这种方法被重新用于制造具有损伤传感和修复能力的功能性智能复合材料。然而,在层间区域引入热塑性薄膜往往会降低纤维体积分数和高温下的性能,而在制造过程中添加不透气的连续薄膜也可能会限制兼容的制造方法。此外,加入电介质热塑性薄膜不可避免地会降低厚度导电性,并妨碍对碳纤维层压板分层损伤的准确检测。本研究探讨了利用不连续交错技术提高碳纤维环氧树脂层压板的断裂韧性和热机械性能的策略,这种技术能够监测分层损伤,并在短时间愈合后恢复机械性能。对交错设计和热塑性塑料的物理性能都进行了评估,这在以前从未涉及过。交织高分子量热塑性塑料,减小层间宽度和层间间距,可提高断裂韧度(+347%),因为这样可形成一个优异的增韧层间区,迫使分层迁移到层内区域。使用分子量较低的热塑性塑料时,修复效率最高可达 77%;然而,整个断裂表面区域缺乏热塑性塑料会普遍影响修复性能。与连续交错法相比,损伤传感和热力学性能有了明显改善,这表明非连续热塑性 交错法可为多功能高性能复合材料提供增韧、热性能和精确损伤传感的有利组合。Composites Part B: EngineeringMOF-derived metal oxide (Cu, Ni, Zn) gas sensors with excellent selectivity towards H2S, CO and H2 gasesCarmen Montoro, Jin-Young Kim, Ali Mirzaei, Jae-Hyoung Lee, Syreina Sayegh, Elissa Makhoul, Igor Iatsunskyi, Emerson Coy, Mikhael Bechelany, Hyoun Woo Kim, Sang Sub Kimdoi:10.1016/j.compositesb.2024.111637 MOF 衍生的金属氧化物(铜、镍、锌)气体传感器对 H2S、CO 和 H2 气体具有极佳的选择性Metal-organic framework (MOF)-derived metal oxides blend the sensing properties of metal oxides with MOF porosity, enhancing gas sensing capabilities. In this study, M-MOFs (M = Cu, Ni and Zn) were synthesized and then calcined at different temperatures to obtain their corresponding metal oxides (CuO, NiO and ZnO). The synthesis method incorporated novel approaches to enhance sensor performance, such as optimizing calcination temperatures for improved selectivity. Structural and morphological analyses confirmed the high surface area and porosity of the metal oxide materials, facilitating efficient gas adsorption and promoting enhanced sensor response. Gas sensing studies revealed significantly enhanced performance of MOF-derived metal oxides over M-MOFs, strongly influenced by calcination temperature. Moreover, CuO, NiO and ZnO MOF-derived metal oxides showed improved selectivity towards H2S, CO and H2 gases, respectively. This study demonstrates that tuning MOF and calcination parameters can tailor sensor selectivity effectively.金属有机框架(MOF)衍生的金属氧化物融合了金属氧化物的传感特性和 MOF 的多孔性,从而增强了气体传感能力。本研究合成了 M-MOF(M = Cu、Ni 和 Zn),然后在不同温度下煅烧以获得相应的金属氧化物(CuO、NiO 和 ZnO)。合成方法采用了新的方法来提高传感器的性能,如优化煅烧温度以提高选择性。结构和形态分析证实了金属氧化物材料的高比表面积和高孔隙率,有利于有效吸附气体并增强传感器响应。气体传感研究表明,MOF 衍生金属氧化物的性能明显优于 M-MOF,这与煅烧温度有很大关系。此外,CuO、NiO 和 ZnO MOF 衍生金属氧化物对 H2S、CO 和 H2 气体的选择性分别有所提高。这项研究表明,调整 MOF 和煅烧参数可以有效地定制传感器的选择性。来源:复合材料力学仿真Composites FEM

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