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【新文速递】2024年7月10日固体力学SCI期刊最新文章

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今日更新:International Journal of Solids and Structures 1 篇,Mechanics of Materials 1 篇,Thin-Walled Structures 3 篇

International Journal of Solids and Structures

Compliant frame geometry for DEMES-based gripper and flapping wing actuators: A comprehensive design study

Aman Khurana, M.M. Joglekar, Paul Motzki, Stefan Seelecke

doi:10.1016/j.ijsolstr.2024.112969

基于 DEMES 的抓手和拍翼致动器的顺应性框架几何结构:综合设计研究

Dielectric elastomer minimum energy structures (DEMES) have attracted significant attention in the recent past because of their ability to switch between multiple equilibrium states. The DEMES is formed when a pre-stretched elastomer film adheres to an inextensible frame and is further allowed to attain an equilibrium configuration as a result of energy minimization. While several researchers have investigated; both theoretically and experimentally, the underlying mechanics of DEMES, a majority of them deploy simplistic boundary frames (square/rectangular/circular) to obtain the requisite minimum energy configuration. In this paper, we demonstrate that this seemingly restrictive choice of using simplistic frame-geometries can be given away with by designing more complex-shaped compliant frames capable of producing useful modes of deformation. To demonstrate this idea, two prototypes; namely, the four-arm gripper actuator and the flapping-wing actuator, are studied numerically and experimentally. In both cases, a single compliant frame is used to realize the respective configuration, thus circumventing the need to assemble multiple MES on a common platform. In tandem, we investigate the role of reinforcements in (a) controlling the warping in MES and (b) maximizing actuation in the desired mode of deformation. Finite element analyses are carried out using the ABAQUS to determine the equilibrium configuration of the actuators, and subsequently their electromechanical behavior. Experimental investigations involve the utilization of the commercially available VHB-4910 acrylic tape in conjunction with PET frames and 3D printed reinforcements. Excellent qualitative agreement is achieved between the numerical predictions and the experimental observations. Finally, we allude to a few innovative frame architectures leading the MES of engineering interest.

近年来,介电弹性体最小能量结构(DEMES)因其能够在多种平衡状态之间切换而备受关注。当预先拉伸的弹性体薄膜附着在一个不可拉伸的框架上,并在能量最小化的作用下进一步达到平衡构型时,就形成了介电弹性体最小能量结构。虽然一些研究人员已经从理论和实验两方面对 DEMES 的基本力学原理进行了研究,但他们大多采用简单的边界框架(方形/矩形/圆形)来获得所需的最小能量配置。在本文中,我们证明了可以通过设计形状更复杂、能够产生有用变形模式的顺应性框架来放弃这种看似限制性的简单框架几何结构选择。为了证明这一想法,我们对两个原型,即四臂抓手致动器和拍翼致动器进行了数值和实验研究。在这两种情况下,我们都使用单个顺应框架来实现各自的配置,从而避免了在通用平台上组装多个 MES 的需要。同时,我们还研究了加强筋在以下方面的作用:(a) 控制 MES 中的翘曲;(b) 在所需的变形模式中最大限度地发挥致动作用。我们使用 ABAQUS 进行了有限元分析,以确定致动器的平衡配置以及随后的机电行为。实验研究使用了市售的 VHB-4910 丙烯酸胶带、PET 框架和 3D 打印加固材料。数值预测与实验观察之间取得了极好的定性一致。最后,我们简要介绍了几种创新的框架结构,这些框架结构引领着工程领域的 MES。


Mechanics of Materials

On the effect of strain rate during the cyclic compressive loading of liquid crystal elastomers and their 3D printed lattices

Bo Song, Dylan Landry, Thomas Martinez, Christopher N. Chung, Kevin N. Long, Kai Yu, Christopher M. Yakacki

doi:10.1016/j.mechmat.2024.105086

液晶弹性体及其 3D 打印晶格循环压缩加载过程中应变率的影响

Nematic liquid crystal elastomers (LCEs) are a unique class of network polymers with the potential for enhanced mechanical energy absorption and dissipation capacity over conventional network polymers because they exhibit both conventional viscoelastic behavior and soft-elastic behavior (nematic director changes under shear loading). This additional inelastic mechanism makes them appealing as candidate damping materials in a variety of applications from vibration to impact. The lattice structures made from the LCEs provide further mechanical energy absorption and dissipation capacity associated with packing out the porosity under compressive loading.Understanding the extent of mechanical energy absorption, which is the work per unit mass (or volume) absorbed during loading, versus dissipation, which is the work per unit mass (or volume) dissipated during a loading cycle, requires measurement of both loading an unloading. In this study, a bench-top linear actuator was employed to characterize the loading-unloading compressive response of polydomain and monodomain LCE polymers and polydomain LCE lattice structures with two different porosities (nominally, 62% and 85%) at both low and intermediate strain rates at room temperature. As a reference material, a bisphenol-A (BPA) polymer with a similar glass transition temperature (9°C) as the nematic LCE (4°C) was also characterized at the same conditions for comparing to the LCE polymers. Based on the loading-unloading stress-strain curves, the energy absorption and dissipation for each material at different strain rates (0.001, 0.1, 1, 10 and 90 s-1) were calculated with considerations of maximum stress and material mass/density. The strain-rate effect on the mechanical response and energy absorption and dissipation behaviors was determined. The energy dissipation ratio was also calculated from the resultant loading and unloading stress-strain curves. All five materials showed significant but different strain rate effects on energy dissipation ratio. The solid LCE and BPA materials showed greater energy dissipation capabilities at both low (0.001 s-1) and high (above 1 s-1) strain rates, but not at the strain rates in between. The polydomain LCE lattice structure showed superior energy dissipation performance compared with the solid polymers especially at high strain rates.

向列液晶弹性体(LCE)是一类独特的网络聚合物,与传统的网络聚合物相比,具有增强机械能吸收和耗散能力的潜力,因为它们既表现出传统的粘弹性行为,又表现出软弹性行为(剪切加载下的向列方向变化)。这种额外的非弹性机制使它们成为从振动到冲击等各种应用中的理想阻尼材料。由 LCE 制成的晶格结构还能进一步吸收机械能,并在压缩载荷作用下通过填充孔隙率来消散能量。机械能吸收是指加载过程中单位质量(或体积)所吸收的功,而耗散是指加载周期中单位质量(或体积)所耗散的功,要了解机械能吸收和耗散的程度,需要对加载和卸载进行测量。在这项研究中,我们使用了台式线性致动器来表征多域和单域 LCE 聚合物以及具有两种不同孔隙率(名义上分别为 62% 和 85%)的多域 LCE 晶格结构在室温下的低应变率和中应变率条件下的加载-卸载压缩响应。作为参考材料,双酚 A (BPA) 聚合物的玻璃化转变温度(9°C)与向列 LCE 相似(4°C),也在相同条件下进行了表征,以便与 LCE 聚合物进行比较。根据加载-卸载应力-应变曲线,考虑到最大应力和材料质量/密度,计算了每种材料在不同应变速率(0.001、0.1、1、10 和 90 s-1)下的能量吸收和耗散。确定了应变速率对机械响应以及能量吸收和耗散行为的影响。还根据加载和卸载应力应变曲线计算了能量耗散率。所有五种材料对能量耗散比的应变率影响都很明显,但又各不相同。固体 LCE 和双酚 A 材料在低应变速率(0.001 s-1)和高应变速率(高于 1 s-1)下都表现出更强的能量耗散能力,但在两者之间的应变速率下则没有。与固体聚合物相比,多域 LCE 晶格结构显示出更优越的能量耗散性能,尤其是在高应变速率下。


Thin-Walled Structures

Prediction of Aerodynamic Forces at the Tip of the Compressor Blades Based on Multi-scale 1DCNN Combined with CBAM

Minghui Yao, Shaohua Wu, Yan Niu, Qiliang Wu, Renduo Song, Bin Bai

doi:10.1016/j.tws.2024.112190

基于多尺度 1DCNN 和 CBAM 的压缩机叶片顶端空气动力预测

The compressor is a crucial component of aircraft engines, and the blades are the critical factor affecting the performance of the compressor. Based on multi-scale one-dimensional convolution neural network (1DCNN) with Convolutional Block Attention Module (CBAM), a data-driven model is proposed for predicting the aerodynamic characteristics of the blade tips. The model is trained using the Adam with decoupled weight decay (AdamW) optimizer and a staged learning rate scheduling strategy. Due to the distinct aerodynamic pressure distributions on the suction and pressure sides, separate models are constructed in order to reveal the aerodynamic performance of the blade tips accurately. During the model validation, Root Mean Square Error (RMSE) and the coefficient of determination (R2) are taking as evaluation criterions, where high reliability is demonstrated compared to Computational Fluid Dynamics (CFD) results.

压气机是飞机发动机的重要组成部分,而叶片是影响压气机性能的关键因素。基于带有卷积块注意模块(CBAM)的多尺度一维卷积神经网络(1DCNN),提出了一种数据驱动模型,用于预测叶尖的空气动力学特性。该模型采用带解耦权值衰减(AdamW)优化器和分阶段学习率调度策略进行训练。由于吸气侧和压力侧的气动压力分布不同,为了准确揭示叶尖的气动性能,分别构建了不同的模型。在模型验证过程中,以均方根误差(RMSE)和判定系数(R2)作为评价标准,与计算流体动力学(CFD)结果相比,显示出较高的可靠性。


Machine learning-based active control for lightweight antenna with force density method and nested genetic algorithm

Runzhi Lu, Huizhong Zhang, Qian Zhang, Honghu Jiang, Jian Feng, Marco Meloni, Jianguo Cai

doi:10.1016/j.tws.2024.112212

基于机器学习的轻型天线主动控制与力密度法和嵌套遗传算法

This work proposes the integration of a tensegrity structure composed of struts and cables into an antenna, thus achieving a lightweight and optimized design for the large-scale system. Active control is introduced to ensure the deformation accuracy of the cable-strut antenna, while a shape sensing method based on force density information is adopted to obtain the deformation field of actual wind cases from monitoring the cable forces. Numerical simulations are performed to verify the accuracy of the method, and a multi-objective optimization framework is employed to determine the optimal positions and control of actuators for active control. A machine learning-based framework is proposed to achieve rapid response of the active control system under actual wind cases. The framework is composed of a two-stage control system that combines the shape sensing method with the multi-objective optimization approach. The machine learning framework establishes a quick response system that monitors changes in the cable forces, thus ensuring structural accuracy control under wind load without structural analysis.

本研究提出将支柱和缆索组成的张弦结构集成到天线中,从而实现大型系统的轻量化和优化设计。为确保缆索-支柱天线的变形精度,引入了主动控制,同时采用了基于力密度信息的形状传感方法,通过监测缆索力获得实际风况下的变形场。通过数值模拟验证了该方法的准确性,并采用多目标优化框架确定了主动控制的最佳位置和致动器控制。提出了一个基于机器学习的框架,以实现主动控制系统在实际风况下的快速响应。该框架由两阶段控制系统组成,结合了形状感应方法和多目标优化方法。机器学习框架建立了一个快速响应系统,可监测拉索力的变化,从而确保在风荷载下的结构精度控制,而无需进行结构分析。


Bending behaviour of surface corroded and perforated corroded steel tubes repaired by laser cladding additive manufacturing

Lan Kang, Peng Song

doi:10.1016/j.tws.2024.112213

通过激光熔覆快速成型技术修复的表面腐蚀和穿孔腐蚀钢管的弯曲性能

In recent years, laser cladding (LC) technology has been increasingly applied and investigated for repairing damaged surface on metal structural components. However, there are limited experimental studies on the bending behaviour of the LC repaired steel components. And an effective repair method for the perforated corroded steel components is still lacking, therefore, this paper introduces a novel LC repair method for such steel tube. Four-point bending tests were conducted on four specimens, including one intact steel tube (IT), one surface corroded steel tube (SCT), one surface corroded steel tube repaired by LC (SRT), and one perforated corroded steel tube repaired by LC (PRT) to verify the effectiveness of the LC repair methods by evaluating their structural performance in terms of bending capacity, rotational stiffness, and ductility. The experimental results showed that the bending strength and rotational stiffness of the SRT and PRT can be fully restored and even slightly higher than those of the IT. The strain analysis indicated that the LC repair method can significantly reduce stress/strain concentration caused by surface corrosion and perforation corrosion. The experiments were replicated numerically by means of finite element (FE) analysis and parametric studies were performed to investigate the effect of different factors on the bending behaviour of the PRT and SRT. Furthermore, design formula for predicting the elastic bending capacity of the LC repaired steel tube was developed.

近年来,用于修复金属结构件受损表面的激光熔覆(LC)技术得到了越来越多的应用和研究。然而,对经 LC 修复的钢构件的弯曲性能的实验研究还很有限。因此,本文介绍了一种针对此类钢管的新型 LC 修复方法。本文对四种试样进行了四点弯曲试验,包括一种完整钢管(IT)、一种表面腐蚀钢管(SCT)、一种经 LC 修复的表面腐蚀钢管(SRT)和一种经 LC 修复的穿孔腐蚀钢管(PRT),通过评估它们在弯曲能力、旋转刚度和延展性方面的结构性能来验证 LC 修复方法的有效性。实验结果表明,SRT 和 PRT 的弯曲强度和旋转刚度可以完全恢复,甚至略高于 IT。应变分析表明,LC 修复方法能显著减少表面腐蚀和穿孔腐蚀引起的应力/应变集中。通过有限元(FE)分析对实验进行了数值复 制,并进行了参数研究,以探讨不同因素对 PRT 和 SRT 弯曲行为的影响。此外,还开发了用于预测 LC 修复钢管弹性弯曲能力的设计公式。




来源:复合材料力学仿真Composites FEM
ACTMechanicalAdditiveSystemMarc振动通用理论材料多尺度控制试验
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首次发布时间:2024-11-21
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【新文速递】2024年7月12日复合材料SCI期刊最新文章

今日更新:Composite Structures 2 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 3 篇Composite StructuresA piece-wise linear model for modelling the tension-stiffening effect in steel-reinforced UHPC compositesJunqing Xue, Angelo Aloisio, Alessandro Contento, Zhengxian Yang, Ni Hu, Bruno Briseghelladoi:10.1016/j.compstruct.2024.118373钢增强UHPC复合材料拉伸加劲效应的分段线性模型This study examines the tensile behaviour of Ultra-High Performance Concrete (UHPC) specimens reinforced with varying steel fibre content and rebar diameters. An experimental campaign involving 18 reinforced UHPC specimens was conducted, following individual tensile response characterizations of UHPC and reinforcing steel. These specimens were designed and fabricated with threaded welded steel cages to transfer loads to the central measurement area. Force–displacement curves were measured to derive stress–strain curves for the UHPC component, evaluating the impact of reinforcement rebar and steel fibre content on UHPC’s mechanical response. The analysis revealed that steel fibre volume content significantly influences the tensile response of UHPC reinforcement more than the steel bar diameter and yield strength. Comparing the strain in steel bars to the average strain in reinforced UHPC specimens indicated that post-cracking deformation concentrates at the crack. At the same time, the bond between reinforcement and UHPC remains intact in uncracked sections, allowing effective load transfer. UHPC specimens reinforced with 14 mm diameter steel bars displayed a significant horizontal segment in the descending phase of the stress–strain curve. In contrast, specimens with 18 mm or 22 mm diameter bars exhibit a progressive stress reduction at a nearly constant rate. Stress–strain curves of UHPC were fitted with a five-fold piecewise empirical model applicable to UHPC with a reinforcement ratio higher than 0.09%. The resulting model can be used to model the axial behaviour in UHPC, considering the effects of steel reinforcement.本研究考察了不同钢纤维含量和钢筋直径的超高性能混凝土(UHPC)试件的拉伸性能。一项涉及18个增强的UHPC试件的实验活动,在UHPC和钢筋的个体拉伸响应特性之后进行。这些试件是用螺纹焊接钢笼设计和制造的,以将载荷传递到中心测量区域。通过测量力-位移曲线,得出UHPC构件的应力-应变曲线,评估钢筋和钢纤维含量对UHPC力学响应的影响。分析表明,钢纤维体积含量对UHPC钢筋拉伸响应的影响大于钢筋直径和屈服强度。对比钢筋应变与加筋UHPC试件的平均应变,发现开裂后变形集中在裂缝处。与此同时,在未开裂的部分,钢筋和UHPC之间的结合保持完整,允许有效的荷载传递。直径为14mm钢筋的UHPC试件在应力-应变曲线下降阶段表现出明显的水平段。相比之下,直径为18 mm或22 mm的试件以几乎恒定的速率表现出渐进的应力减小。采用适用于配筋率大于0.09%的UHPC的五重分段经验模型拟合UHPC的应力应变曲线。所得到的模型可以用来模拟在考虑钢筋的影响下UHPC的轴向行为。Efficient equilibrium-based stress recovery for isogeometric laminated Euler–Bernoulli curved beamsAlessia Patton, Shirko Faroughi, Alessandro Realidoi:10.1016/j.compstruct.2024.118374等几何层合欧拉-伯努利曲线梁基于有效平衡的应力恢复Laminated curved composite parts, used, e.g., in the spar and ribs in aircraft and wind turbine blades, are typically subjected to high interlaminar stresses. This work focuses on a two-step procedure to study laminated Euler–Bernoulli curved beams discretized via Isogeometric Analysis (IGA). First, we solve a (planar) Euler–Bernoulli curved beam formulation in primal form to obtain the tangential and transverse displacements. This formulation features high-order PDEs, which we can straightforwardly approximate using either an IGA-Galerkin or an IGA-collocation approach. Starting from the obtained displacement solution, which accounts for bending-stretching coupling, we can directly compute the normal stress only, while we do not have information concerning the transverse shear stress state, typically responsible for delamination. However, by imposing equilibrium in strong form in a curvilinear framework which eases the post-processing, eliminating the need for coordinate changes, we can easily recover interlaminar transverse shear stresses at locations of interest. Such a posteriori step requires calculating the high-order displacement derivatives in the equilibrium equations and, therefore, demands once again higher-order regularity that can be easily fulfilled by exploiting the high-continuity properties of IGA. Extensive numerical tests prove the effectiveness of the proposed approach, which is also aided by the IGA’s superior geometric approximation.使用的层压弯曲复合材料部件,例如飞机和风力涡轮机叶片中的梁和肋,通常要承受高层间应力。本文主要研究了用等几何分析(IGA)离散化层合欧拉-伯努利曲线梁的两步法。首先,我们求解了(平面)欧拉-伯努利曲线梁的原始形式,得到了切向和横向位移。该公式具有高阶偏微分方程,我们可以使用IGA-Galerkin或iga -搭配方法直接近似。从得到的位移解出发,考虑了弯曲-拉伸耦合,我们可以直接计算正应力,而我们没有关于横向剪应力状态的信息,通常负责分层。然而,通过在曲线框架中施加强形式的平衡,简化了后处理,消除了坐标变化的需要,我们可以很容易地在感兴趣的位置恢复层间横向剪切应力。这种后检步骤需要计算平衡方程中的高阶位移导数,因此,再次需要高阶正则性,这可以通过利用IGA的高连续性特性轻松实现。大量的数值试验证明了所提出的方法的有效性,IGA的优越几何近似也有助于这种方法。Composites Part A: Applied Science and ManufacturingA hyperelastic approach for modeling the membrane behavior in finite element forming simulation of unidirectional non-crimp fabrics (UD-NCF)Bastian Schäfer, Dominik Dörr, Ruochen Zheng, Naim Naouar, Luise Kärgerdoi:10.1016/j.compositesa.2024.108359单向无卷曲织物(UD-NCF)有限元成形模拟中膜行为建模的超弹性方法Unidirectional non-crimp fabrics (UD-NCFs) are highly suitable for high-performance components due to their excellent lightweight potential. However, during forming they are prone to wrinkling and gapping compared to woven or biaxial textiles. Macroscopic simulation models can be used to efficiently predict these effects as well as the global forming behavior for complex geometries. Therefore, a new hyperelastic membrane model is proposed to describe the typical deformation of UD-NCFs based on superimposed shear, transverse tension and compression perpendicular to the fiber rovings. The model is parameterized using the forces and different ratios of superimposed strains obtained in experimental off-axis-tension-tests at bias angles of 30°, 45°and 60°. The resulting approach is validated by forming simulations of a hemisphere and tetrahedron geometry in different configurations and quantitative comparison to experimental tests. The model accurately predicts the forming behavior of UD-NCF with a good agreement of the global deformation behavior and local strains.单向无卷曲织物(ud - nfc)由于其优异的轻量化潜力,非常适合用于高性能部件。然而,在成型过程中,与机织或双轴纺织品相比,它们容易起皱和开裂。宏观模拟模型可以有效地预测这些影响以及复杂几何形状的整体成形行为。因此,提出了一种新的超弹性膜模型来描述ud - nfc的典型变形,该模型基于垂直于纤维粗纱的剪切、横向拉伸和压缩叠加。模型参数化采用离轴拉伸试验在30°、45°和60°偏置角下得到的力和不同的叠加应变比。通过不同形态的半面体和四面体的成形模拟以及与实验测试的定量比较,验证了该方法的有效性。该模型准确地预测了UD-NCF的成形行为,并能很好地反映整体变形行为和局部应变。Composites Part B: EngineeringAlkali-activated materials with organics: A critical reviewShengqian Ruan, Rongfeng Gao, Wenlin Tu, Dongming Yan, Mingzhong Zhangdoi:10.1016/j.compositesb.2024.111712有机碱活化材料:综述This paper represents a critical review on alkali-activated materials (AAM) containing organics with high homogeneity at nano-scale (<1 μm). Organics including organosilicons, surfactants, water-soluble polymers and epoxy resins can contribute to performance enhancement and tailorability of AAM based on their molecular characteristics. Hence, AAM with organics can generally possess improved characteristics between organic and inorganic components and may even exhibit emerging functional properties. According to the hybridisation modes between AAM and organics such as chemical bonding, physical adsorption, electrostatic attraction or phase crosslinking, these AAM with organics are categorised into four distinct types: organic-grafted, organic-adsorbed, phase-crosslinked and phase-separated AAM. In this paper, the hybridisation modes and reaction mechanisms of AAM with organics are summarised, for the first time, followed by a comprehensive discussion on the phase assemblage, microstructure, mechanical properties, durability and potential applications. Afterwards, the fundamental insights are gained and the remaining challenges for future research are identified and discussed.本文综述了在纳米尺度(<1 μm)上含有高均匀性有机物的碱活性材料(AAM)。有机硅、表面活性剂、水溶性聚合物和环氧树脂等有机物可以根据其分子特性提高AAM的性能和可定制性。因此,含有机物的AAM通常可以具有介于有机和无机组分之间的改进特性,甚至可能表现出新的功能特性。根据AAM与有机物的杂交方式,如化学键合、物理吸附、静电吸引或相交联,将AAM与有机物的杂交方式分为有机接枝、有机吸附、相交联和相分离四种不同的类型。本文首次综述了AAM与有机物的杂化方式和反应机理,并对其相组合、微观结构、力学性能、耐久性和潜在应用进行了全面讨论。之后,获得了基本见解,并确定和讨论了未来研究的剩余挑战。Hydrophilic Silsesquioxane Nanocages Toughened Extracellular Matrix Biomimetic Poly(γ-Glutamic Acid) Multidimensional Self-Polymerizable and Osteogenic Hybrid Hydrogel for Osteoporotic Bone RegenerationLingli Liu, Shiyuan Ma, Zhisheng Xiao, Jintao Li, Yue Wang, Zhihui Lu, Yitao Zhao, Jinshan Guodoi:10.1016/j.compositesb.2024.111713 纳米亲水性硅氧烷增韧细胞外基质仿生聚γ-谷氨酸多维自聚合成骨混合水凝胶用于骨质疏松性骨再生Rapid bone defect regeneration in osteoporotic conditions remains a significant challenge due to the fragile mechanical stability and pathological microenvironment. The absence of bone matrix is the primary characteristic of these defects, and advanced strategies for treating osteoporotic bone defects focus on remodeling the bone matrix’s spatial structure and regulating the microenvironment. While many hydrogels have been developed for bone regeneration, their use in repairing osteoporotic bone defects is constrained by deficiencies in shape-adaptivity, weak osteogenic bioactivity, and lack of physiological mechanical support. Herein, a novel bioactive hydrophilic semi-caged NH2-T4 silsesquioxane (NH2-T4-POSS) nanocage was developed, which was used to modify γ-polyglutamic acid (γ-PGA) together with dopamine, to give an organic/inorganic hybrid hydrogel PGA-DA&T4 for osteoporotic bone regeneration. The developed PGA-DA&T4 hydrogel possesses favorable injectability, shape-adaptivity, self-healability, and strong antioxidant ability. Benefited from organic/inorganic hybridation and multidimensional molecular interacting mechanism, PGA-DA&T4 exhibites enhanced thermal stability and longer degradation period, unique self-polymerizability, high elasticity, and considerable tissue adhesion ability. In vitro experiments proved that PGA-DA&T4 is biocompatible, and is able to promote cell migration and neovascularization, and possesses favorable immunoregulatory to promote macrophage polarization towards anti-inflammatory M2 phenotype. Furthermore, PGA-DA&T4 has been demonstrated to accelerate osteogenic differentiation and inhibit osteoclastogenesis, thereby promoting the repair of osteoporotic bone defects. Our research successfully developed a novel hybrid γ-PGA hydrogel with therapeutic effects and supplied a promising biomaterial with potential clinical application for repairing osteoporotic bone defects.由于脆弱的机械稳定性和病理微环境,骨质疏松症的骨缺损快速再生仍然是一个重大挑战。骨基质的缺失是这些缺陷的主要特征,治疗骨质疏松性骨缺陷的先进策略集中在骨基质空间结构的重塑和微环境的调节上。虽然许多用于骨再生的水凝胶已经被开发出来,但它们在修复骨质疏松性骨缺损方面的应用受到形状适应性不足、成骨生物活性弱和缺乏生理机械支持的限制。本研究制备了一种新型的具有生物活性的亲水半笼型NH2-T4硅氧烷(NH2-T4- poss)纳米笼,并将其与多巴胺一起修饰γ-聚谷氨酸(γ-PGA),得到用于骨质疏松性骨再生的有机/无机杂化水凝胶PGA-DA&T4。制备的PGA-DA&T4水凝胶具有良好的可注射性、形状适应性、自愈性和较强的抗氧化能力。得益于有机/无机杂化和多维分子相互作用机制,PGA-DA&T4表现出更强的热稳定性和更长的降解期,独特的自聚合性,高弹性和可观的组织粘附能力。体外实验证明PGA-DA&T4具有生物相容性,能够促进细胞迁移和新生血管形成,并具有良好的免疫调节作用,促进巨噬细胞向抗炎M2表型极化。此外,PGA-DA&T4已被证明可以加速成骨分化,抑制破骨细胞的发生,从而促进骨质疏松性骨缺损的修复。本研究成功制备出具有良好治疗效果的新型γ-PGA杂化水凝胶,为修复骨质疏松性骨缺损提供了一种具有潜在临床应用前景的生物材料。The effect of gamma-ray irradiation on polymer-graphene nanocomposite interfacesSagar U. Patil, Josh Kemppainen, Trevor Wavrunek, Gregory M. Odegarddoi:10.1016/j.compositesb.2024.111715伽马射线辐照对聚合物-石墨烯纳米复合材料界面的影响CNT yarns are used in ultra-high strength composites for use in manned deep-space vehicles. It has been previously demonstrated through experiments that gamma-ray irradiation substantially improves the mechanical performance of these composites. It is unclear how the irradiation affects the mechanical response of the CNT yarn/polymer interface that ultimately leads to these panel-level performance improvements. Physical insight into this process could enable further improvements in the CNT yarn/polymer interface design in the future. The objective of this research is to use molecular dynamics simulation to provide physical insight into the effect of gamma-ray irradiation on the mechanical behavior (interfacial interaction energy, shear resistance, adhesive strength) of the CNT yarn/polymer interface for a range of high-performance polymer systems. The simulation results indicate that gamma-ray irradiation (simulated via inclusion of defects on the CNT surface) has a most significant effect on the shear deformation resistance of CNT yarn/polymer interfaces, which likely leads to the experimentally-observed improvements in panel-level CNT yarn composites irradiated with gamma rays. The results of this study also demonstrate the importance of computational modeling in providing physical insight into observed bulk-scale material behavior. Although the predictions cannot be validated directly via experiment, such insight can ultimately lead to efficient improvements in material design (e.g. mechanical performance) that lead to further increases in panel-level composite performance.碳纳米管纱线用于载人深空飞行器的超高强度复合材料。先前通过实验证明,伽马射线辐照大大提高了这些复合材料的机械性能。目前尚不清楚辐照如何影响CNT纱线/聚合物界面的机械响应,最终导致这些面板级性能的改善。对这一过程的物理洞察可以在未来进一步改进碳纳米管纱线/聚合物界面设计。本研究的目的是利用分子动力学模拟,为一系列高性能聚合物系统的碳纳米管纱线/聚合物界面的机械行为(界面相互作用能,剪切阻力,粘接强度)的影响提供物理见解。模拟结果表明,伽马射线辐照(通过碳纳米管表面的缺陷模拟)对碳纳米管纱线/聚合物界面的抗剪切变形能力有最显著的影响,这可能导致实验中观察到的经过伽马射线辐照的面板级碳纳米管纱线复合材料的改善。这项研究的结果也证明了计算建模在提供观察到的大块材料行为的物理洞察力方面的重要性。虽然预测不能通过实验直接验证,但这种见解最终可以导致材料设计(例如机械性能)的有效改进,从而进一步提高面板级复合材料的性能。来源:复合材料力学仿真Composites FEM

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