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【新文速递】2024年8月16日复合材料SCI期刊最新文章

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今日更新:Composite Structures 2 篇,Composites Part A: Applied Science and Manufacturing 4 篇,Composites Part B: Engineering 1 篇,Composites Science and Technology 2 篇

Composite Structures

Comprehensive FRP-concrete bond behavior: Impact of test methods and the innovative UBoT

Faisal Mukhtar

doi:10.1016/j.compstruct.2024.118475

综合frp -混凝土粘结性能:测试方法的影响和创新的UBoT

The lack of a standardized bond test method for fiber-reinforced polymer (FRP)-concrete interfaces leads to variations in forms of the popular single-lap shear, double-lap shear, beam, mixed-mode, and pull-off tests. Recognizing the limitations of each bond test technique and the importance of analyzing all results as complementary, a detailed evaluation of these variations is essential for accurate bond behavior assessment prior to design and field deployment, to avoid subjective decisions and predictions. This study pioneers the evaluation of FRP-concrete bond test methods, offering the industry a consistent dataset for informed decision-making. Single- and double-lap shear tests yield trilinear bond-slip responses; however, the single-lap test’s lack of symmetry reduces bond strength by 15% compared to the double-lap test. The beam test, unsuitable for bond-slip modeling, shows comparable average bond strength to the single- and double-lap tests. The mixed-mode test better simulates field applications, while the pull-off test provides the most consistent results. Given that each test method reflects only one field scenario, the Universal Bond Tester (UBoT) was developed. This device can convert to all FRP-concrete bond test types. It also addresses the modified double-lap shear test’s limitations (e.g., inapplicability to pultruded laminate and FRP rupture in wet layup systems) and present a modified ASTM D7958 beam and mixed-mode tests cost-effectively. The UBoT captures full bond behavior and variabilities, overcoming the limitations of existing methods which fail to capture all failure modes in bond-critical applications. It reduces specimen sizes, weight, and data acquisition needs by half for most tests. This study allows test laboratories to use any preferred testing method with the UBoT. Link to video demonstrations for all tested specimens are provided in the supplementary material.

纤维增强聚合物(FRP)-混凝土界面缺乏标准化的粘结试验方法,导致流行的单搭接剪切、双搭接剪切、梁、混合模式和拉脱试验形式各异。认识到每种胶结测试技术的局限性以及分析所有结果作为补充的重要性,在设计和现场部署之前,对这些变化进行详细评估对于准确评估胶结行为至关重要,以避免主观决策和预测。这项研究开创了frp -混凝土粘结测试方法的评估,为行业提供了一个一致的数据集,以进行明智的决策。单搭接和双搭接剪切试验产生三线性粘结滑移响应;然而,与双搭接测试相比,单搭接测试缺乏对称性,使粘合强度降低了15%。不适合粘结滑移模型的梁试验显示出与单搭接和双搭接试验相当的平均粘结强度。混合模式测试更好地模拟了现场应用,而下拉测试提供了最一致的结果。鉴于每种测试方法只能反映一个现场场景,因此开发了通用粘结测试仪(UBoT)。该设备可转换为所有frp -混凝土粘结试验类型。它还解决了改进的双搭剪试验的局限性(例如,不适用于湿铺层系统中的拉挤层压和FRP断裂),并提出了一种改进的ASTM D7958梁和混合模式试验,具有成本效益。UBoT捕获了完整的键行为和变化,克服了现有方法在键关键应用中无法捕获所有失效模式的局限性。它将大多数测试的样品尺寸、重量和数据采集需求减少了一半。这项研究允许测试实验室使用任何首选的测试方法与UBoT。在补充材料中提供了所有测试样本的视频演示链接。


Nature-inspired 3D printing-based double-graded aerospace negative Poisson’s ratio metastructure: Design, Fabrication, Investigation, optimization

Yuze Nian, Shui Wan, Mehmet Avcar, Xiao Wang, Ru Hong, Ru Yue, Mo Li

doi:10.1016/j.compstruct.2024.118482

 

基于自然灵感的3D打印双级航天负泊松比元结构:设计,制造,调查,优化

The advanced metamaterials concept has been widely explored and utilized in many industries, ranging from automotive applications to medicine, and has great potential in the aerospace field. Novel nature-inspired 3D printed double-graded aluminum foam-filled negative Poisson’s ratio metamaterials (DGAT) were designed, fabricated, and investigated. Their mechanical properties were examined by the finite element method and experiments. The geometrical parameters and combination types show different effects on the mechanical properties of DGAT metastructures. Under axial compressive loading, the DGAT structure has a lower peak force and higher specific energy absorption. Then, parametric analysis shows that several design parameters (e.g. m, T, θ, tmin, tmax) have a very strong effects on the mechanical performance. Finally, multi-objective optimization is performed to maximize specific energy absorption while reducing maximum impact force. Optimization results show that the novel graded metamaterials have stronger energy absorption capacity than the ordinary counterparts. Especially, the specific energy absorption can be increased to 80% with 15% peak loading force rising. Due to their unique structural design and excellent mechanical properties, the DGAT metastructures have great potential applications in the fields of transportation protection, military protection engineering, manned spacecraft cushioning and energy-absorbing boxes.

先进的超材料概念已被广泛探索和应用于许多行业,从汽车应用到医学,并在航空航天领域具有巨大的潜力。设计、制造和研究了一种新颖的受自然启发的3D打印双层泡沫铝填充负泊松比超材料(DGAT)。采用有限元法和实验对其力学性能进行了检验。几何参数和组合类型对DGAT元组织的力学性能有不同的影响。在轴向压缩载荷作用下,DGAT结构具有较低的峰值力和较高的比能吸收。然后,参数化分析表明,若干设计参数(如m, T, θ, tmin, tmax)对机械性能有很强的影响。最后进行多目标优化,使比能吸收最大化,同时减小最大冲击力。优化结果表明,新型梯度超材料比普通材料具有更强的能量吸收能力。其中,峰值载荷力上升15%,比能吸收提高到80%。由于其独特的结构设计和优异的力学性能,DGAT元结构在交通防护、军事防护工程、载人飞船缓冲和吸能箱等领域具有巨大的应用潜力。


Composites Part A: Applied Science and Manufacturing

Hyperelastic and multifunctional SiC/SiO2 composite aerogels with excellent mechanical, thermal insulation and electromagnetic wave absorbing properties

Mingyuan Yan, Yuelei Pan, Pan He, Lunlun Gong, Yangyang Fu, Xudong Cheng

doi:10.1016/j.compositesa.2024.108408

 

超弹性多功能SiC/SiO2复合气凝胶具有优异的机械、隔热和电磁波吸收性能

SiC (silicon carbide) aerogels have attracted extensive attention due to their excellent thermal stability and large porosity. But at present, the serious challenge of SiC aerogel application is still poor mechanical properties. To address the above challenge, here we report SiC/SiO2 composite aerogels (SSCAs) with a mutually supported dual-network structure. SiO2 nanoporous networks are introduced into SiC networks to achieve the multifunctional properties, including mechanics, thermal insulation and electromagnetic wave absorption properties. Benefiting from the dual-network structure, the maximum compressive stress of the SSCAs is increased to 2551 kPa. In addition, SSCAs can withstand a large elastic strain of up to 60 %. Furthermore, the SSCAs exhibit an ultra-low thermal conductivity of 0.023 W·m−1 K−1 at room temperature. More importantly, SiC/SiO2 heterointerface structure optimizes impedance matching, resulting in an effective absorption bandwidth of 6.5 GHz. This work provides new ideas and insights for the preparation of multifunctional ceramic aerogels.

碳化硅气凝胶以其优异的热稳定性和大孔隙率而受到广泛关注。但目前,SiC气凝胶应用面临的严峻挑战仍然是力学性能差。为了解决上述挑战,本文报道了具有相互支持双网络结构的SiC/SiO2复合气凝胶(ssca)。将二氧化硅纳米孔网络引入到碳化硅网络中,实现了包括力学、隔热和电磁波吸收性能在内的多功能性能。得益于双网络结构,ssca的最大压应力提高到2551 kPa。此外,ssca可以承受高达60% %的大弹性应变。此外,ssca在室温下表现出0.023 W·m−1 K−1的超低导热系数。更重要的是,SiC/SiO2异质界面结构优化了阻抗匹配,使有效吸收带宽达到6.5 GHz。本研究为多功能陶瓷气凝胶的制备提供了新的思路和见解。


Investigation of MXene@APP/FDS/AgNPs@EG system for preparing multifunctional thermoplastic polyurethane composites with flame retardancy and electromagnetic shielding performance

Minghao Li, Chunhui Chen, Wenqing Hai, Ziyang Jiang, Qian Meng, Enquan Hao, Hongjie Li, Huiqi Shao, Guangwei Shao, Jinhua Jiang, Nanliang Chen, Siyi Bi

doi:10.1016/j.compositesa.2024.108409

MXene@APP/FDS/AgNPs@EG体系制备阻燃、电磁屏蔽多功能热塑性聚氨酯复合材料的研究

In order to comply with the requirement of flame retardancy and electromagnetic interference (EMI) shielding for encapsulant applied to electronic devices, multifunctional thermoplastic polyurethane (TPU) composites are prepared with the construction of an intumescent flame retardant (IFR) system comprising internal conductive network. In this work, ammonium polyphosphate wrapped with MXene (MXene@APP) is attained by microencapsulation, and expandible graphite decorated with Ag nanoparticles (AgNPs@EG) is prepared by the reducibility of silk sericin. The IFR system with conductivity is established by the introduction of MXene@APP, AgNPs@EG and furfural-derived Schiff base (FDS). The as-prepared TPU/MXene@APP/FDS/AgNPs@EG composites are able to attain significant elevation in flame retardancy, exhibiting V-0 rating and a LOI value of 33.1 %. Furthermore, TPU composites are integrated with warp-knitted metal mesh (WMM) to fabricate TPU@WMM coated fabric, displaying strengthened electromagnetic interference (EMI) shielding effectiveness (SE) of 37.53 dB within X band. This work provides a potential method for application in encapsulant with flame retardancy and electromagnetic protection.

为满足电子封装材料对阻燃性能和电磁干扰屏蔽性能的要求,构建了由内部导电网络构成的膨胀型阻燃体系,制备了多功能热塑性聚氨酯(TPU)复合材料。本研究采用微胶囊化的方法制备了MXene包裹的聚磷酸铵(MXene@APP),并利用丝胶蛋白的还原性制备了Ag纳米颗粒修饰的可膨胀石墨(AgNPs@EG)。通过引入MXene@APP、AgNPs@EG和糠醛衍生希夫碱(FDS),建立了具有导电性的IFR体系。制备的TPU/MXene@APP/FDS/AgNPs@EG复合材料的阻燃性能显著提高,阻燃系数为V-0, LOI值为33.1% %。此外,将TPU复合材料与经编金属网(WMM)相结合制备TPU@WMM涂层织物,在 X 波段内显示出37.53 dB的增强电磁干扰(EMI)屏蔽效果。本研究为阻燃和电磁防护封装材料的应用提供了一种潜在的方法。


MoSe2 nanosheets implanting on 3D hollow carbon sphere for high-efficiency electromagnetic wave absorption

Xiaonan Yang, Zhuguang Nie, Yang Feng, Xiaoli Guo, Zhiyue Zhao, Mingyu Jiang, Guiyu Chu, Shuhua Qi, Panbo Liu

doi:10.1016/j.compositesa.2024.108411

 

三维中空碳球上MoSe2纳米片的高效电磁波吸收

Carbon-based electromagnetic wave absorption (EMA) materials are extensively studied due to their unique advantages. Nevertheless, impedance matching issues was still constraining their further research. Consequently, we successfully synthesized MoSe2 nanosheets implanting on 3D hollow carbon sphere (HCS@MoSe2) composites with core–shell structure. The complex core–shell structure high-entropy composites provided multiple dissipation mechanisms for efficient dissipation of incident electromagnetic wave energy. The implanting MoSe2 nanosheets optimized the dielectric constant of the composites, thus ensuring optimal impedance matching. The HCS@MoSe2-1 composites exhibit excellent EMA properties and a significant minimum reflection loss (RLmin) of −56.19 dB. And HCS@MoSe2-1 had an ultra-wide effective absorption bandwidth (EAB) of 7.43 GHz. The significant EMA capability attributed to the synergistic effects of conductive loss, polarization loss, and optimized impedance matching. This work paved a new path for synthesizing transition metal selenide-modified carbon-based composite materials, offering great potential as high-performance materials for EMA applications.

碳基电磁波吸收材料因其独特的优点而受到广泛的研究。然而,阻抗匹配问题仍然制约着他们的进一步研究。因此,我们成功地合成了MoSe2纳米片植入三维空心碳球(HCS@MoSe2)复合材料。复杂核壳结构的高熵复合材料为入射电磁波能量的有效耗散提供了多种耗散机制。MoSe2纳米片的植入优化了复合材料的介电常数,从而保证了最佳的阻抗匹配。HCS@MoSe2-1复合材料具有优异的EMA性能,最小反射损耗(RLmin)为−56.19 dB。HCS@MoSe2-1具有7.43 GHz的超宽有效吸收带宽(EAB)。显著的EMA能力归因于导电损耗、极化损耗和优化的阻抗匹配的协同效应。该研究为过渡金属硒化碳基复合材料的合成开辟了新的道路,为EMA应用提供了巨大的高性能材料潜力。


Constructing bidirectional heat flow pathways by curved alumina for enhanced thermal conductivity of epoxy composites

Jiani Tan, Zhen Xu, Fei Ding, Zongxian Yang, Fangli Yuan, Yuge Ouyang

doi:10.1016/j.compositesa.2024.108412

 

用弯曲氧化铝构筑双向热流通道以增强环氧复合材料的导热性

The polymer-based composites filled with high thermal conductive fillers have received much attention in the filed of electronic package. However, traditional Al2O3 filled polymer-based composites always hardly simultaneously achieve high thermal conductivity in both horizontal and vertical directions with a low loading. Herein, curved Al2O3 particles have been fabricated via spray assembly and high-temperature sintering and subsequently are infiltrated by epoxy (EP) to obtain Al2O3/EP composites. The formation mechanism of the curved Al2O3 is analyzed in this work. The curved Al2O3 architectures are orderly stacked in EP matrix, which achieve significantly enhanced in-plane (1.21  W/m·K) and through-plane (1.46  W/m·K) thermal conductivity with a low filler loading (19.9 vol%). Importantly, the wall structure of curved Al2O3 particle consists of continuous network structure and interconnected channels, which reduce the thermal expansion coefficient of the composites. Consequently, the design of curved Al2O3 offers a new strategy for next-generation thermal management materials.

高导热填料填充聚合物基复合材料在电子封装领域受到广泛关注。然而,传统的Al2O3填充聚合物基复合材料很难同时在水平方向和垂直方向上获得高导热性,并且具有低载荷。本文通过喷雾组装和高温烧结制备了弯曲的Al2O3颗粒,然后用环氧树脂(EP)渗透得到Al2O3/EP复合材料。分析了弯曲Al2O3的形成机理。弯曲Al2O3结构在EP基体中有序堆叠,在低填充量(19.9 vol%)的情况下,显著提高了平面内(1.21  W/m·K)和平面内(1.46  W/m·K)导热系数。重要的是,弯曲Al2O3颗粒的壁结构由连续的网络结构和相互连接的通道组成,这降低了复合材料的热膨胀系数。因此,弯曲Al2O3的设计为下一代热管理材料提供了一种新的策略。


Composites Part B: Engineering

Effect of microstructural roughness on the performance and fracture mechanism of multi-type single lap joints

Kai Pang, Xing-er Wang, Jianqiao Ye, Craig Carnegie, Xiaonan Hou

doi:10.1016/j.compositesb.2024.111763

显微组织粗糙度对多类型单搭接接头性能及断裂机理的影响

Surface roughness of adherends is a crucial factor in determining the performance and failure mechanism of adhesive joints. However, the research dedicated to the examination of fracture mechanism for adhesive joints influenced by surface roughness at microscale is limited. This work conducts systematic experimental and numerical investigations into the effect of microstructural roughness on the performance and fracture mechanism of multi-type adhesive single lap joints (SLJ). The adherend materials are aluminium alloy (Al) and polyphthalamide (PPA), ground into three roughness grades for the fabrication of SLJs using an epoxy adhesive. The mechanical properties of the adhesive, adherends and SLJs derived from experimental studies are utilized to calibrate the microparameters in Discrete Element Method (DEM) models for a numerical analysis. The newly developed DEM models demonstrate efficacy in predicting the performance and capturing the failure modes of multi-type SLJs realistically with distinct microroughness profiles. Finally, the influencing mechanisms of microstructural roughness on the performance of multi-type SLJs are investigated, including the microscale interfacial bonds and mechanical interlockings. The effects of microstructural roughness on the microscale failure mechanisms of multi-type SLJs are also explored and discussed, including the crack initiation, coalescence, and propagation within the adhesive and interface.

粘结剂的表面粗糙度是决定粘结接头性能和失效机理的关键因素。然而,在微观尺度上对表面粗糙度对粘接接头断裂机理的研究还很有限。本文系统地研究了显微组织粗糙度对多型胶合单搭接接头(SLJ)性能和断裂机理的影响。粘附材料是铝合金(Al)和聚苯二胺(PPA),研磨成三个粗糙度等级,用于使用环氧粘合剂制造slj。利用实验研究得到的胶粘剂、黏合剂和slj的力学性能,标定离散元法(DEM)模型中的微参数,进行数值分析。新开发的DEM模型可以有效地预测具有不同微孔分布的多类型slj的性能和捕获其失效模式。最后,研究了微观结构粗糙度对多类型slj性能的影响机制,包括微观界面键和机械互锁。探讨了微观结构粗糙度对多类型slj微尺度破坏机制的影响,包括胶粘剂和界面内的裂纹萌生、裂纹合并和裂纹扩展。


Composites Science and Technology

A parametric modeling method for 2.5D warp-reinforced woven composites considering the extruded distortion of yarns

Xiangling Zhang, Junhua Guo, Huabing Wen, Haitao Cui, Hongjian Zhang, Weidong Wen, Chun Guo, Yifan Zhang, Wantao Guo

doi:10.1016/j.compscitech.2024.110807

 

考虑纱线挤压变形的2.5维经编增强机织复合材料参数化建模方法

2.5D warp-reinforced woven composites (2.5DWRWC) are widely used in various industries, but it is currently difficult to model parametrically considering the molding effects due to their complex structure. Accordingly, two special parameters (ψ and φ) are introduced to regulate the degree of yarn extrusion, where ψ is used to characterize the extrusion degree of the binder yarn on the weft yarn in the thickness direction, and φ is used to characterize the twisting degree of the warp yarn. On this basis, a parametric modeling method for 2.5DWRWC is constructed by uniting the essential weaving parameters, and the modeling code is written in TexGen software using Python language. Subsequently, the established model is verified experimentally, and the results show that the average comparison error of the geometric parameters is only 5.07%, the maximum prediction error of the mechanical properties is only 4.78%, validating the reasonableness of the proposed modeling method. Finally, the effects of the two special parameters on the mechanical properties are emphasized, and the results show that the mechanical properties in weft direction are enhanced with the increase of ψ, and the mechanical properties in warp direction are weakened with the increase of φ. This work can provide guidance for the molding process and mechanical design of 2.5DWRWC, which has significant theoretical value and engineering significance.

2.5维经编增强机织复合材料(2.5DWRWC)广泛应用于各个行业,但由于其结构复杂,目前难以进行考虑成型效果的参数化建模。为此,引入两个特殊参数ψ和φ来调节纱线的挤压程度,其中ψ用于表征粘结纱在纬纱粗细方向上对纬纱的挤压程度,φ用于表征经纱的加捻程度。在此基础上,通过统一基本织造参数,构建了2.5DWRWC的参数化建模方法,并使用Python语言在TexGen软件中编写了建模代码。随后,对所建立的模型进行了实验验证,结果表明,几何参数的平均比较误差仅为5.07%,力学性能的最大预测误差仅为4.78%,验证了所提出建模方法的合理性。结果表明:经向的力学性能随ψ的增大而增强,经向的力学性能随φ的增大而减弱;该工作可为2.5DWRWC的成型工艺和机械设计提供指导,具有重要的理论价值和工程意义。


Multi-Walled Carbon Nanotube-Enhanced Polyurethane Composite Materials and the Application in High-Performance 3D Printed Flexible Strain Sensors

Xinchun Luo, Hailong Cheng, Kaiqi Chen, Lin Gu, Sheng Liu, Xin Wu

doi:10.1016/j.compscitech.2024.110818

 

多壁碳纳米管增强聚氨酯复合材料及其在高性能3D打印柔性应变传感器中的应用

Flexile strain sensors hold vast potential for applications in monitoring human motion, enabling human-machine interaction, and facilitating information transfer, etc. However, the available materials and manufacturing techniques for fabricating flexible strain sensors with high sensitivity and extended sensing range still face significant challenges. By utilizing solution casting and twin-screw extrusion techniques, this study prepared high-performance thermoplastic polyurethane/multi-walled carbon nanotube (TPU/MWCNT) nanocomposite 3D printable filaments, and employed material extrusion 3D printing technology to facilely fabricate flexible strain sensors. The 1-pyrene carboxylic acid (PCA)-modified TPU/MWCNT(3wt%) nanocomposite exhibited outstanding mechanical properties, with a tensile strength of 24.3±0.5 MPa and a fracture elongation of 625.8±12.3%. The 3D printed TPU/MWCNT(3wt%)/PCA flexible strain sensors demonstrated amazing sensitivity (GFmax=10279.95) within a wide strain range (0-300% strain). The addition of PCA brings the benefits of improved dispersion of MWCNTs in the TPU composite, as well as enhanced thermal stability, and upgraded mechanical and electrical properties under different tensile strains. Meanwhile, the 3D printed samples displayed remarkable durability and reproducibility. Finally, the flexible strain sensors fabricated from this nanocomposite material could accurately perceive human motion, providing great prospects for wearable device applications.

柔性应变传感器在监测人体运动、实现人机交互、促进信息传递等方面具有巨大的应用潜力。然而,制造具有高灵敏度和大范围传感的柔性应变传感器的材料和制造技术仍然面临着重大挑战。本研究采用溶液铸造和双螺杆挤压技术,制备了高性能热塑性聚氨酯/多壁碳纳米管(TPU/MWCNT)纳米复合材料3D打印长丝,并利用材料挤压3D打印技术方便地制造柔性应变传感器。1-芘羧酸(PCA)改性TPU/MWCNT(3wt%)纳米复合材料具有优异的力学性能,抗拉强度为24.3±0.5 MPa,断裂伸长率为625.8±12.3%。3D打印的TPU/MWCNT(3wt%)/PCA柔性应变传感器在宽应变范围(0-300%应变)内表现出惊人的灵敏度(GFmax=10279.95)。PCA的加入改善了MWCNTs在TPU复合材料中的分散性,增强了材料的热稳定性,提高了材料在不同拉伸应变下的力学和电学性能。同时,3D打印的样品显示出显著的耐用性和可重复性。最后,利用该纳米复合材料制备的柔性应变传感器能够准确感知人体运动,为可穿戴设备的应用提供了广阔的前景。



来源:复合材料力学仿真Composites FEM
ACTMechanicalSystemInspireMAGNET断裂复合材料通用航空航天汽车电子离散元裂纹理论材料试验
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首次发布时间:2024-11-21
最近编辑:1月前
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【新文速递】2024年8月18日复合材料SCI期刊最新文章

今日更新:Composite Structures 1 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Science and Technology 2 篇Composite Structures3D winding path modeling method with fiber overlap effectShuo Li, Zhuo Meng, Richen Hong, Yize Sundoi:10.1016/j.compstruct.2024.118488考虑纤维重叠效应的三维缠绕路径建模方法The fibers will repeatedly cross and stack on the liner during the continuous winding process, which poses a challenge in creating accurate local and global structure models. To address the issue, a 3D winding path modeling method is proposed to simulate the fiber overlap effect. First, the initial path is offset equidistantly along the direction of width and thickness to construct a 3D fiber model. Then, by calculating the overlap thickness, the overlapped fibers are raised to the corresponding overlap thickness to eliminate interference in the 3D fiber model. Finally, a 3D winding path with the fiber overlap effect is obtained by solving the suspended points before and after the overlapping area to describe the behavior of fibers separating from the liner surface under tension. 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It puts a big barrier for the large-scale production and application. In this work, we have a low-cost and facile approach constructing a hierarchical nano/micro-structure based on the nanosheets of MXene (Ti3C2Tx) and the gold micro-wrinkles on polydimethylsiloxane (PDMS) surface. The period micro-wrinkles can be easily controlled by the thickness of gold layer and the pre-strain on PDMS through the uniaxial stretching method. The formed hierarchical structure can endow the high sensitivity (15 kPa−1 when applied pressure less than 50 Pa), an ultra-fast response time of 15 ms, a minimum detection of 2 Pa, which can achieve the precise acoustic detection of low frequency. Moreover, the flexible sensor also can detect the large pressure about 1000 Pa, and show stable repeatability over 1500 cycles at 400 Pa.柔性和高灵敏度的声传感器已成为成功的军事探测的必要条件。这对大规模生产和应用造成了很大的障碍。在这项工作中,我们利用MXene (Ti3C2Tx)纳米片和聚二甲基硅氧烷(PDMS)表面的金微皱,构建了一种低成本、简便的层次化纳米/微结构。通过单轴拉伸的方法,可以很容易地通过金层厚度和PDMS上的预应变来控制周期微皱。所形成的层次化结构具有高灵敏度(施加压力小于50 Pa时为15 kPa−1)、超快响应时间为15 ms、最小探测2 Pa,可实现低频的精确声学探测。此外,柔性传感器还可以检测约1000 Pa的大压力,并在400 Pa下表现出超过1500次的稳定重复性。Composites Science and TechnologySimultaneous enhancement of axial/transverse compressive strength of aramid fibers by the construction of branched multi-hydrogen bonding sitesXueyong Deng, Wen Zhai, Chunlin Fan, Longbo Luo, Xiangyang Liudoi:10.1016/j.compscitech.2024.110797 支化多氢键位点的构建同时增强芳纶纤维的轴/横向抗压强度The terrible compressive strength is a prominent issue that restricts the broad application of organic fibers in multi-dimensional stress scenarios. Traditional strategies focus on enhancing the axial compressive performance of fibers, simultaneously improving the axial and transverse compressive properties of fibers still poses significant challenges. Inspired by the octopus's tentacles that can conduct stress in multiple directions, a novel strategy by constructing branched multi-hydrogen bonding sites structure in aramid fiber was conducted to solve the problem. The branched multi-hydrogen bonding sites constructed on nano-silica (SiO2-B) offer excellent dispersibility within the poly(p-phenylene-benzimidazole-terephthalamide) (PBIA) matrix. Composite fibers (PBIA-SiO2-B) co-mixed with SiO2-B and PBIA were prepared using a solution spinning technique. The results of Fourier-transform infrared spectroscopy (FTIR) and dynamic mechanical analysis (DMA) reveal that the introduction of SiO2-B significantly enhances the intermolecular interactions within the composite fibers, and this enhancement mechanism has been elaborately elucidated through molecular simulations. Furthermore, finite element simulations confirmed that the incorporation of branched structure exhibits enhanced stress-bearing capabilities under multi-directional stress and offers outstanding support when subjected to transverse compressive stress compared to linear molecular chains. Hence, compressive property testing revealed that the PBIA-SiO2-B composite fibers achieved axial compressive strengths and transverse compressive strengths of 714.3 MPa and 305.8 MPa, respectively, representing increases of 68.8% and 26.8% over pure PBIA fibers. Moreover, with the enhancement of transverse compressive strength, the Young’s modulus and interfacial shear strength of PBIA-SiO2-B fibers were also increased by 7.1% and 20.9%, respectively.抗压强度差是制约有机纤维在多维应力环境下广泛应用的突出问题。传统的策略侧重于提高纤维的轴向抗压性能,同时提高纤维的轴向和横向抗压性能仍然存在重大挑战。受章鱼触手可向多个方向传导应力的启发,在芳纶纤维中构建支链多氢键位点结构来解决这一问题。在纳米二氧化硅(SiO2-B)上构建的支链多氢键位点在聚(对苯-苯并咪唑-对苯二甲酸)(PBIA)基体中具有优异的分散性。采用溶液纺丝技术制备了与SiO2-B和PBIA共混的PBIA-SiO2-B复合纤维。傅里叶变换红外光谱(FTIR)和动态力学分析(DMA)结果表明,SiO2-B的引入显著增强了复合纤维内部的分子间相互作用,并通过分子模拟详细阐明了这种增强机理。此外,有限元模拟证实,与线性分子链相比,分支结构的结合在多向应力下表现出更强的应力承受能力,并且在承受横向压应力时提供出色的支撑。因此,抗压性能测试表明,PBIA- sio2 - b复合纤维的轴向抗压强度和横向抗压强度分别为714.3 MPa和305.8 MPa,比纯PBIA纤维提高了68.8%和26.8%。此外,随着横向抗压强度的提高,PBIA-SiO2-B纤维的杨氏模量和界面抗剪强度也分别提高了7.1%和20.9%。Study on interface toughening mechanism based on modified PBO fiber for CFRP/ plastic honeycomb sandwich structureHaotian Zheng, Jicai Liang, Yi Li, Ce Liangdoi:10.1016/j.compscitech.2024.110817 基于改性PBO纤维的CFRP/塑料蜂窝夹层结构界面增韧机理研究CFRP (carbon fiber reinforced composites)/honeycomb sandwich structures are widely used in aerospace, automotive, and high-speed rail industries due to their excellent mechanical properties and lightweight characteristics. This study investigates the impact of three designed toughened interfaces on the three-point bending performance of honeycomb structures. The results show that introducing a multiscale toughened interface made of poly(p-phenylene benzobisoxazole) (PBO) fibers grafted with polydopamine (PDA) and multi-walled carbon nanotubes (CNT) increases the peak load and post-peak load of the sandwich structure by 49.7 % and 51.9 %, respectively, and the absorbed energy by 92.4 %. This toughened interface adjusts the stress relationship between the panel, interface, and honeycomb, altering the deformation process and crack propagation mode of the sandwich structure. The micro-nano fibers form fiber bridging at the interface, changing the crack extension mode between the interfaces, transforming the delamination from a single debonding to the combined action of plate core debonding and honeycomb core buckling. Additionally, experimental results show that PBO fibers treated with PDA and CNT exhibit significantly improved surface roughness, Surface area per unit mass, wettability, and tensile strength, which delay and prevent crack propagation at the interface, effectively reducing panel debonding at the bonded joints.CFRP(碳纤维增强复合材料)/蜂窝夹层结构以其优异的力学性能和轻量化等特点,广泛应用于航空航天、汽车、高铁等行业。研究了设计的三种增韧界面对蜂窝结构三点弯曲性能的影响。结果表明,引入聚对苯并二苯并异恶唑(PBO)纤维接枝聚多巴胺(PDA)和多壁碳纳米管(CNT)的多尺度增韧界面,使夹层结构的峰后负荷和峰后负荷分别提高了49.7%和51.9%,吸收能量提高了92.4%。这种增韧的界面调整了面板、界面和蜂窝之间的应力关系,改变了夹层结构的变形过程和裂纹扩展模式。微纳纤维在界面处形成纤维桥接,改变了界面间的裂纹扩展方式,使分层由单一的脱粘转变为板芯脱粘和蜂窝芯屈曲的共同作用。此外,实验结果表明,经PDA和CNT处理的PBO纤维表面粗糙度、单位质量表面积、润湿性和抗拉强度显著提高,从而延缓和阻止了界面处的裂纹扩展,有效地减少了粘结接缝处的面板脱粘。来源:复合材料力学仿真Composites FEM

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