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一种多通道电芯原位膨胀力测试新方法

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电芯实际使用时是束缚在模组内,充放电过程中厚度的变化引起膨胀力会直接影响电芯、模组及电池包的电性能、安全及可靠性等表现。
During charge and discharge, the cell’s thickness change lead to the pressure variation, directly influence the performance of electrochemical properties, safety and reliability of cell, module and battery.

为了研究清楚上述变化与关联,对于电芯在实际工作时结构与状态的模拟与仿真(即电芯原位膨胀厚度、原位膨胀压力特征参数)非常重要,其具体方式如下图。
In order to study the change and correlation clearly, the modeling and simulation for the actual work structure and status of batteries (in-situ thickness, in-situ pressure characteristic parameter) are very important. as is shown in the following diagram.
图1.电池包-模组-电芯膨胀力关联
Diagram 1 Pack-Module-Cell

材料不可逆损耗与劣化引起的极片/电芯逐渐变厚、析锂等(如下图2)。对于膨胀及析锂评价的现有传统方法非原位、破坏性、成本高、效率低而且无法实现多个样品同步平行测试,已不能满足当前研究开发需求,如对比图表2.
Irreversible loss and degradation lead to electrode /Cell gradually thickness increase, ALP, etc. Ex-situ and destructive traditional methods can't meet current requirement due to its high cost, low efficiency, only one sample can be tested in one experiment.

实现多通道扣电、单层叠片、软包与方壳电芯等原位膨胀力与厚度测量;
Realize Multichannel in-situ pressure and thickness test for Coin, single stack, pouch and prismatic cell;
为电芯材料开发、结构设计、工艺优化及相关机理研究提供支撑;
Provide help for materials development, structural design, process optimization and related mechanism research;

为模组、电池包设计提供可靠的结构参数。 

Provide reliable mechanical parameters for module, pack design.

图2. 新方法优势对比表
Diagram 2. Comparison table of advantages of the new method

1.多通道原位膨胀力测试系统简介Introduction

多通道原位膨胀力测试系统通过集约化集成高精度模架、位移、电压、电流、压力、温湿度等核心零部件与传感器,实现不同工况下多电芯同步原位厚度、膨胀力检测。
Through intensive integration of high-precision die frame, displacement, voltage, current, pressure, temperature and humidity and other core components and sensors, the test system can accurately test In-situ thickness and swelling pressure of multiple cells at one time.

主要功能:
多通道同步电芯原位膨胀力测试;Multichannel In-situ Swelling Analysis System
完全一体化,测试、采集、处理一站式解决;AIO, one-stop solution;
可适配用于扣电、单层叠片、软包与方壳铝壳等各类电芯For coin, single stack, pouch and prismatic cell;
高精度厚度测量分辨率0.1µm,精度±1µm;high precision thickness measurement, resolution is 0.1μm and accuracy is ±1μm;
高精度持续动态压力保证,最高波动±10N;high precision continuous dynamic pressure guarantee, maximum accuracy is ±10N;
全方位电流、电压、压力、厚度、温湿度等数据同步监测采集;synchronous monitoring and collection of Electrochemical parameters, pressure, thickness, temperature, humidity, and so on.
不同测试温度(-40℃~100℃)环境模拟;Environmental simulation at different test temperatures (- 40 ℃~100 ℃);
 
图3. 多通道原位膨胀测试系统
Diagram 3. Multichannel In-situ Swelling Analysis System

2.应用示例Application

2.1多通道电芯原位膨胀力分析

在双通道原位膨胀测试模式下,保证了电芯样品在完全一样的压力控制水平下进行测试;随着电芯充电的进行,电芯膨胀绝对厚度及相对厚度被同步检测;两个同样设计的电芯表现出来的膨胀水平一致(厚度变化一致),但是2号电芯的极化相对更大;
In the dual-channel in-situ expansion test mode, the cell sample is guaranteed to be tested at exactly the same pressure; With the charging of the cell, the absolute thickness and relative thickness of the cell are detected synchronously; Two cells based on the same design exhibit the same level of swelling (thickness changes consistently), but the polarization of cell 2 is relatively larger;

2.2 不同恒压下电芯膨胀性能分析
在恒压力测试模式下,循环过程中电芯膨胀力保持动态不变;随着加载压力增加,电芯膨胀绝对厚度相应降低;随着充电电流的下降(CC+CV阶段),电芯膨胀厚度增加速率逐步减小;
In constant pressure mode, the cell swelling pressure unchanged during charge-discharge. The absolute thickness of cell decreases with the increase of loading pressure. With the decrease of charging current (CC+CV stage), the increase rate of cell expansion thickness gradually decreases.


2.3 不同恒压下电芯膨胀性能分析
析锂为最严重的电芯安全风险之一,所以对于电芯析锂的分析与预测非常重要;通过原位膨胀检测可以对电芯的析锂情况进行预测分析。
ALP(Anode Lithium Plating) is the most safety issue, so the analysis and prediction of ALP is very important. Based on in-situ swelling pressure testing system,) ALP can be predicted.


3.总结Summary

本文采用多通道原位膨胀测试系统CSA1150对电池进行原位膨胀测试,解决现有测量方法一次只能测试一个平行样品的问题,并完全保证了电芯测试的压力控制的一致性,有助于更准确更快速地评估材料改性及工艺配方开发。
In this paper, the multi-channel in-situ swelling test system (CSA1150) is used to test the swelling of cell, which solves the problem that the existing measurement method can only one parallel sample be tested at a time, and fully ensures the consistency of the pressure control of the test, which is helpful to evaluate the material modification and the process formulation development more accurately and quickly.

原位膨胀测试系统参数
来源:锂想生活
System材料控制
著作权归作者所有,欢迎分享,未经许可,不得转载
首次发布时间:2023-09-21
最近编辑:1年前
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