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【新文速递】2023年12月24日复合材料SCI期刊最新文章

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今日更新:Composite Structures 4 篇,Composites Part A: Applied Science and Manufacturing 1 篇,Composites Part B: Engineering 4 篇,Composites Science and Technology 1 篇

Composite Structures

Effective modulus of 3D-printable curvilinear fiber reinforced composites

Tengyuan Hao, Javid Mustafa, Garrett Gray, Zubaer Hossain

doi:10.1016/j.compstruct.2023.117811

三维打印曲线纤维增强复合材料的有效模量

This paper presents the coupling between curvilinearity and effective modulus for a set of mathematically admissible high-symmetry and low-symmetry fiber architectures. The contour of the fiber is decomposed into a series of unidirectional short segments and effective modulus is determined using an integration scheme that combines theoretical analysis and finite element simulations. Results show that the modulus of low-symmetry sinusoidal and hyperbolic tangent fibers varies nonlinearly with orientation and controlled by the segments forming the smallest direction cosine with the loading direction. Both the orientation of the midline and amplitude of the fibers strongly influence the effective behavior. For unidirectional fiber reinforced composites, results reveal the existence of a critical fiber-orientation angle of 60° where the modulus is minimum. Fibers are the majority stress carrier below 60°, and above this angle, the matrix carries the load. The approach is applicable to fiber-based composites of arbitrary fiber geometries, and the findings are expected to advance the design of additively manufactured complex composite structures.

本文介绍了一组数学上可接受的高对称性和低对称性光纤结构的曲线性和有效模量之间的耦合。纤维的轮廓被分解成一系列单向短段,并采用理论分析和有限元模拟相结合的积分方案确定有效模量。结果表明,低对称性正弦和双曲切线纤维的模量随取向呈非线性变化,并受与加载方向形成最小余弦方向的纤维段控制。纤维中线的取向和振幅都对有效行为有很大影响。对于单向纤维增强复合材料,结果显示存在一个临界纤维取向角,即模量最小的 60°。在 60° 以下,纤维是主要的应力载体,而在该角度以上,基体则承担载荷。该方法适用于任意纤维几何形状的纤维基复合材料,研究结果有望推动添加式制造复杂复合材料结构的设计。


Quasi-3D free and forced vibrations of poroelastic microplates in the framework of modified couple stress theory

Behrouz Karami, Mergen H. Ghayesh, Nicholas Fantuzzi

doi:10.1016/j.compstruct.2023.117840

修正耦合应力理论框架下孔弹性微板的准三维自由振动和受迫振动

In this study, a comprehensive study on the vibration behaviour of functionally graded thick microplates with material imperfections is presented for free and forced vibrations within a quasi-3D model and the modified couple stress (MCS) theory. Axial, transverse, rotation, and stretching motions are considered for modelling the thick microplate in the framework of the modified power-law scheme and quasi-3D and MCS theories. The microplate deformation is assumed to be infinitesimal and is modelled using the linear strain–displacement relationships. Using a virtual work method, the governing motion equations are derived. For fourfold coupled (axial-transverse-rotation-stretching) characteristics, the partial differential equations components are discretised via trigonometric expressions and the corresponding natural frequencies and time histories (time-dependent deflections) are determined numerically. The methodology and model are initially validated through a comparative analysis between the natural frequencies of the macrolevel simplified structure and those obtained using finite element software. Additionally, the simulation is compared, for validation purposes, with other simplified versions from the literature. Once model's validity is confirmed, an investigation into the quasi-3D free and forced vibrations of the structure is conducted for the new model. The results demonstrate the considerable effect of thickness stretching and material imperfection on the vibration characteristics of the poroelastic thick microplates.

在本研究中,针对准三维模型和修正耦合应力(MCS)理论中的自由振动和受迫振动,对具有材料缺陷的功能分级厚微板的振动行为进行了全面研究。在修正幂律方案、准三维和 MCS 理论的框架内,考虑了厚微板建模时的轴向、横向、旋转和拉伸运动。微板变形被假定为无限小,并使用线性应变-位移关系建模。利用虚功方法推导出支配运动方程。对于四重耦合(轴向-横向-旋转-拉伸)特性,通过三角函数表达式对偏微分方程成分进行离散化,并通过数值确定相应的固有频率和时间历程(随时间变化的挠度)。通过对宏观简化结构的固有频率和使用有限元软件获得的固有频率进行比较分析,初步验证了该方法和模型。此外,还将模拟结果与文献中的其他简化版本进行比较,以进行验证。一旦模型的有效性得到确认,就会针对新模型对结构的准三维自由振动和受迫振动进行研究。结果表明,厚度拉伸和材料缺陷对孔弹性厚微板的振动特性有相当大的影响。


Experimental and simulation study on surface material stripping of Glass Fiber Reinforced Composites by baking soda abrasive Jetting Technology

Jiale Xu, Zhouyu Jiang, Mingzhu Yang, Xiaowen Zhang, Mingliang Wang

doi:10.1016/j.compstruct.2023.117842

小苏打喷射技术对玻璃纤维增强复合材料表面材料剥离的实验和模拟研究

Glass fiber reinforced composites (GFRP) working in a specific environment require regular inspection and maintenance. It is necessary to remove the surface material of fiber reinforced composites to check the fracture of fibers and the damage to matrix that binds fibers in this process. In this paper, the baking soda abrasive jetting was utilized to strip the surface material of glass fiber reinforced epoxy resin (GFREP). The stripping effects of baking soda abrasive jetting technology under different jetting parameters (fiber orientation, jet angle, jet pressure) were explored, and the optimum stripping conditions were determined as parallel to the fiber, 30°, 0.4MPa. Compared with the chemical stripping method (phenol-dichloromethane), baking soda abrasive jetting can better retain epoxy resin between glass fibers. The LS-DYNA was applied to simulate the erosion process of a single abrasive particle under the optimum stripping condition. The plastic deformation of the matrix and the slight bending deformation of the glass fiber under abrasive impact were observed.

在特定环境中工作的玻璃纤维增强复合材料(GFRP)需要定期检查和维护。在此过程中,有必要去除纤维增强复合材料的表面材料,以检查纤维的断裂情况以及粘结纤维的基体的损坏情况。本文利用小苏打磨料喷射来剥离玻璃纤维增强环氧树脂(GFREP)的表面材料。探讨了小苏打磨料喷射技术在不同喷射参数(纤维方向、喷射角度、喷射压力)下的剥离效果,确定了最佳剥离条件为平行于纤维、30°、0.4MPa。与化学剥离法(苯酚-二氯甲烷)相比,小苏打磨料喷射法能更好地保留玻璃纤维间的环氧树脂。应用 LS-DYNA 模拟了在最佳剥离条件下单个磨料颗粒的侵蚀过程。在磨料冲击下,基体发生了塑性变形,玻璃纤维也发生了轻微的弯曲变形。


A viscoelastic-plastic model for the temperature-dependent creep and recovery behavior during dry fiber fabric compaction

Yanpeng Si, Lishuai Sun, Junzhen Chen, Zhiyong Zhao, Jianjun Jiang, Yujun Li

doi:10.1016/j.compstruct.2023.117843

干纤维织物压实过程中随温度变化的蠕变和恢复行为的粘弹性塑料模型

The preforming process of dry fiber fabric usually involves compaction under constant pressure and specific temperature during fiber-reinforced composite manufacturing. The fabric exhibits time- and temperature-dependent considerable permanent deformation and creep/recovery behavior in compaction. A better understanding of these phenomena, combined with the ability to predict the behavior, will contribute to better control of fiber volume fraction and material composition. This study presented a universal viscoelastic-plastic model to represent the fabric’s visco-effect in compression and recovery stages. The proposed model consisted of a modified Burges element for time-dependent deformation and a plastic element for permanent deformation that occurs in all cases. It used only one set of equations and one set of parameters to characterize the cyclic loading/unloading and the compaction and relaxation phases. It could consider the material densification effect observed experimentally. The model was validated against experimental data for unidirectional (UD), plain woven, and twill woven fabrics. A reasonable match between experiments and prediction was achieved under different compression scenarios.

在纤维增强复合材料制造过程中,干纤维织物的预成型工艺通常包括在恒定压力和特定温度下进行压实。在压实过程中,纤维织物会表现出与时间和温度相关的相当大的永久变形和蠕变/恢复行为。更好地理解这些现象,并结合预测这些行为的能力,将有助于更好地控制纤维体积分数和材料成分。本研究提出了一种通用的粘弹性塑料模型,用于表示织物在压缩和恢复阶段的粘弹性效应。所提议的模型包括一个用于表示随时间变化的变形的改良伯格斯元素和一个用于表示在所有情况下都会发生的永久变形的塑性元素。该模型仅使用一组方程和一组参数来描述循环加载/卸载以及压实和松弛阶段。它可以考虑实验观察到的材料致密化效应。该模型根据单向(UD)、平纹和斜纹机织物的实验数据进行了验证。在不同的压缩情况下,实验与预测之间实现了合理的匹配。


Composites Part A: Applied Science and Manufacturing

Fluorinated interface engineering targeting high-performance multifunctional composites of BN/aramid nanofibers

Haoou Ruan, Xiang Yu, Yunpeng Liu, Yixiao Zhang, Sidi Fan, Fangcheng Lv

doi:10.1016/j.compositesa.2023.107975

以 BN/芳纶纳米纤维高性能多功能复合材料为目标的氟化界面工程学

Aramid nanofibers (ANFs)-based composites have attracted considerable interest in electronic and electrical engineering due to their exceptional thermal stability, high strength, and superior insulating properties. However, the performance of ANFs-based composites is severely confined by interfacial issues. Accordingly, a novel strategy of fluorinated interface engineering is proposed herein, by which the fillers are grafted by the fluorine-containing functional groups. The introduction of interfacial fluorination yields a dense and compact composite structure which stems from the improved compatibility at the matrix-filler interfaces. The tensile strength and thermal conductivity are increased by 30% and 50%, respectively. Additionally, the band structure variation is observed in the fluorinated BNNs, where the electron trap states are formed at the interface. With the deepened deep trap depth and increased density, the breakdown strength is enhanced by 50%. The breakdown phase field simulations also indicate the high discharge energy consumption by the fluorination effect.

芳纶纳米纤维(ANFs)基复合材料因其卓越的热稳定性、高强度和优异的绝缘性能,在电子和电气工程领域引起了广泛关注。然而,ANFs 基复合材料的性能受到界面问题的严重限制。因此,本文提出了一种新颖的氟化界面工程策略,通过含氟官能团接枝填料。通过引入界面氟化,基体与填料界面的相容性得到了改善,从而产生了致密、紧凑的复合结构。拉伸强度和热导率分别提高了 30% 和 50%。此外,在氟化 BNN 中还观察到带状结构的变化,即在界面处形成了电子阱态。随着陷阱深度的加深和密度的增加,击穿强度提高了 50%。击穿相场模拟还表明,氟化效应会消耗大量放电能量。


Composites Part B: Engineering

Electrospun photocrosslinkable hydrogel fibrous membrane with metal ion trapping capability as an artificial periosteum to promote bone regeneration

Xi He, Ruideng Wang, Li Wang, Xinbo Wei, Moyan Zhou, Jiarui Tang, Xin Che, Ruichen Wang, Fang Zhou, Haifeng Liu

doi:10.1016/j.compositesb.2023.111147

 

具有金属离子捕获能力的电纺丝光交联水凝胶纤维膜作为人工骨膜促进骨再生

The periosteum plays a crucial role in both bone development and the healing process of bone fractures. However, few studies have focused on developing artificial periosteum due to the complexity of its construction and the biological risks for clinical practice. To address this issue, we proposed a strategy for the fabrication of a photocrosslinkable natural hydrogel nanofibrous membrane (SFMA-Lap@AcBP) based on methacrylated silk fibroin (SFMA), photoinitiator (Lap), acrylate bisphosphonate (AcBP) through combining electrospinning technology with hydrogel, mimicking the structure and function of periosteum to promote bone regeneration. AcBP were covalently attached to the SFMA hydrogel nanofibrous membrane via conjugation. With the degradation of SFMA-Lap@AcBP hydrogel nanofibrous membrane, the released BP-grafted derivates could promote bone regeneration. Moreover, SFMA-Lap@AcBP hydrogel membranes were found to be able to trap metal ions such as Mg2+ and Ca2+ in vivo, which might play a synergistic role in inducing complete bone regeneration. Furthermore, the hydrogel membranes had excellent cytocompatibility. They could imitate the microenvironment of the extracellular matrix, thereby offering structural and biochemical cues for the adhesion, proliferation, and differentiation of cells, without the need of exogenous cells or inductive growth factors, resulting in a facilitated osteogenesis. After implanting membranes into a cranial periosteal and bone defect in rats, both the amount and quality of new bone in the SFMA-Lap@AcBP group were found to be higher than those in the other groups. Therefore, the hydrogel membrane bionic periosteum was efficient and versatile in inducing bone regeneration, providing a potential strategy to address clinical issues.

骨膜在骨骼发育和骨折愈合过程中都起着至关重要的作用。然而,由于人工骨膜的构造复杂,且在临床实践中存在生物风险,因此很少有研究关注人工骨膜的开发。针对这一问题,我们提出了一种基于甲基丙烯酸化丝纤维素(SFMA)、光引发剂(Lap)和丙烯酸酯双膦酸盐(AcBP)的光交联天然水凝胶纳米纤维膜(SFMA-Lap@AcBP)的制备策略,将电纺丝技术与水凝胶相结合,模拟骨膜的结构和功能,促进骨再生。AcBP 通过共价键连接到 SFMA 水凝胶纳米纤维膜上。随着 SFMA-Lap@AcBP 水凝胶纳米纤维膜的降解,释放出的 BP 接枝衍生物可促进骨再生。此外,研究还发现 SFMA-Lap@AcBP 水凝胶膜能够在体内捕获 Mg2+ 和 Ca2+ 等金属离子,这可能会在诱导完全骨再生方面发挥协同作用。此外,水凝胶膜还具有良好的细胞相容性。它们可以模仿细胞外基质的微环境,从而为细胞的粘附、增殖和分化提供结构和生化线索,而无需外源细胞或诱导生长因子,从而促进骨生成。将水凝胶膜植入大鼠颅骨骨膜和骨缺损处后,发现 SFMA-Lap@AcBP 组新生骨的数量和质量均高于其他组。因此,水凝胶膜仿生骨膜在诱导骨再生方面具有高效性和多功能性,为解决临床问题提供了一种潜在的策略。


Mechanisms of CLDH seeding on hydration kinetics of slag-based geopolymer: Towards aluminosilicate cement phase engineering

Zuhua Zhang, Zhengning Zhou, Huajun Zhu, Ping Duan, Yuan Fang, Zhengwu Jiang

doi:10.1016/j.compositesb.2023.111157

CLDH 播种对矿渣基土工聚合物水化动力学的影响机制:实现铝硅酸盐水泥相工程

Geopolymer and related chemically activated materials are more sustainable aluminosilicate cementitious materials that have less natural materials consumption and CO2 emissions. An intrinsic challenge comes from the lack of sufficient crystalline phases in the binder, which leads to the suffering of volume instability and other issues for this type of cements. This study proposes phase engineering concept, for the first time, and investigates the stargate of using active crystal seeds. Calcined layered double hydroxides (CLDH) was used as a type of seed to understand the impact on hydration kinetics and microstructure of slag-based geopolymer. Through various characterization techniques, it is revealed that during the hydration process of slag, CLDH adsorbs OH− ions and other anions from the solution, leading to a rapid recrystallization and formation of hydrotalcite (Ht) phase. The generated Ht phase serves as nucleation sites, accelerating the formation of C-A-S-H amorphous gel and more Ht phase. Ht nanocrystals consistently exists in the binder, at least in the studied period, together with C-A-S-H nanocrystals and more ordered gel phases. Low modulus of silicate activator is found to enhance the nucleation effect of Ht. This research provides valuable insights into the interactions and mechanisms governing the hydration kinetics and phase evolution in geopolymer, and proves the effectiveness of phase engineering via seeding.

土工聚合物和相关的化学活性材料是更具可持续性的铝硅酸盐胶凝材料,其天然材料消耗量和二氧化碳排放量较少。固有的挑战来自于粘结剂中缺乏足够的结晶相,这导致这类水泥存在体积不稳定等问题。本研究首次提出了相工程概念,并研究了使用活性晶体种子的可能性。煅烧层状双氢氧化物(CLDH)被用作一种种子,以了解其对矿渣基土工聚合物水化动力学和微观结构的影响。通过各种表征技术发现,在矿渣水化过程中,CLDH 会吸附溶液中的 OH- 离子和其他阴离子,导致快速再结晶并形成水滑石(Ht)相。生成的 Ht 相可作为成核点,加速 C-A-S-H 无定形凝胶和更多 Ht 相的形成。至少在研究期间,Ht 纳米晶体始终与 C-A-S-H 纳米晶体和更有序的凝胶相一起存在于粘合剂中。研究发现,硅酸盐活化剂的低模量会增强 Ht 的成核效应。这项研究为了解土工聚合物水化动力学和相演化的相互作用和机制提供了宝贵的见解,并证明了通过播种进行相工程的有效性。


Sustained delivery of chemically modified mRNA encoding amelogenin from self-assembling hydrogels for periodontal regeneration

Jie Pan, Huizhong Tian, Siming Xu, Liwei Zhang, Jiandong Ding, Huijing Wang, Lin Yu, Wei Fu, Xin Liu

doi:10.1016/j.compositesb.2023.111162

利用自组装水凝胶持续传递编码髓鞘素的化学修饰 mRNA,促进牙周再生

Periodontitis is a growing clinical problem worldwide. Despite various approaches that have been devoted to repairing periodontal defects, the clinical outcomes are still limited due to the decline in tissue regenerative potential after periodontitis. Fortunately, chemically modified mRNA (modRNA)-based therapeutics have emerged as a promising strategy to combat incurable diseases. However, the use of modRNA for treating periodontitis is rare and challenging. Herein, a novel therapeutic mRNA platform that allows for sustained delivery and targeted osteogenesis and cementogenesis was developed for periodontal regeneration by combining a self-assembling PLA-PEG-PLA hydrogel and newly synthesized modRNA encoding amelogenin (AMELX) via in vitro transcription. The thermosensitive PLA-PEG-PLA hydrogel significantly prevented modRNA degradation and prolonged the release of encapsulated modRNA by forming an in situ hydrogel depot at 37 °C, resulting in sustained and strong expression of AMELX in human periodontal ligament stem cells (PDLSCs). Moreover, the AMELX modRNA exhibited a great capacity for promoting osteogenesis and cementogenesis of PDLSCs, as evidenced by elevated alkaline phosphatase (ALP) activity, calcium nodule formation, and osteogenesis- and cementogenesis-related gene expression (e.g., ALP, BMP2, CAP, BSP, COL1A1). As a result, after a single local injection, the PLA-PEG-PLA hydrogel enabled AMELX modRNA to persist and release at the defect site, thus successfully regenerating bone and periodontal ligament tissues in periodontal defects of rats. These findings provide a new approach for treating periodontal defects using self-assembling hydrogels to enable safe and effective delivery of AMELX modRNA, thereby offering various possibilities for functional tissue reconstruction with mRNA therapeutics.

牙周炎是全世界日益严重的临床问题。尽管已经有多种方法致力于修复牙周缺陷,但由于牙周炎后组织再生潜力下降,临床效果仍然有限。幸运的是,以化学修饰 mRNA(modRNA)为基础的疗法已经成为一种很有前景的对抗不治之症的策略。然而,使用modRNA治疗牙周炎是罕见和具有挑战性的。在本文中,通过将自组装聚乳酸-聚乙二醇-聚乳酸水凝胶与通过体外转录新合成的编码amelogenin (AMELX)的modRNA结合在一起,开发出了一种新型的治疗mRNA平台,该平台可实现持续递送、靶向成骨和骨水泥生成,用于牙周再生。热敏聚乳酸-聚乙二醇-聚乳酸水凝胶可显著防止modRNA降解,并通过在37 °C下形成原位水凝胶库,延长封装modRNA的释放时间,从而使AMELX在人牙周韧带干细胞(PDLSCs)中得到持续、强有力的表达。此外,AMELX modRNA 在促进牙周韧带干细胞成骨和骨水泥形成方面表现出很强的能力,具体表现为碱性磷酸酶(ALP)活性升高、钙结形成以及成骨和骨水泥形成相关基因(如 ALP、BMP2、CAP、BSP、COL1A1)的表达。因此,在一次局部注射后,PLA-PEG-PLA 水凝胶可使 AMELX modRNA 在缺损部位持续释放,从而成功地使大鼠牙周缺损部位的骨和牙周韧带组织再生。这些发现为利用自组装水凝胶治疗牙周缺损提供了一种新方法,使 AMELX modRNA 能够安全、有效地输送,从而为 mRNA 疗法的功能性组织重建提供了多种可能性。


Degradation of mechanical properties and microstructure evolution of basalt-carbon based hybrid FRP bars in real seawater and sea-sand concrete

Xiangke Guo, Zuquan Jin, Chuansheng Xiong, Bo Pang, Dongshuai Hou, Weihua Li

doi:10.1016/j.compositesb.2023.111163

玄武岩-碳基混合玻璃钢棒材在实际海水和海砂混凝土中的力学性能退化和微观结构演变

The degradation of basalt fibre-reinforced polymer (BFRP) bars induced by alkaline environments hinders their application in seawater and sea-sand concrete (SWSC). The use of carbon fibres (CFs) to partially replace basalt fibres in the preparation of hybrid-FRP (HFRP) bars is an effective method for enhancing the durability of BFRP-bar. To evaluate the effectiveness of using CFs to replace part of the basalt fibres in preparing HFRP bars to enhance the durability of BFRP-bar in real SWSC. The tensile and interlayer interface properties of HFRP bars with different CFs hybrid contents (VCF, %) and arrangements in the SWSC were tested after exposure to seawater at different temperatures. Digital microscopy, scanning electron microscopy, X-ray computed tomography and matrix digestion analysis were used to investigate the microstructural evolution of HFRP bars and SWSC after conditioning. The results showed that the VCF increasing to 10% or 25% significantly alleviated the interlaminar shear strength (ILSS) and tensile strength (TS) losses. The maximum enhancements in the ILSS and TS retention for the SWSC-embedded BFRP bar were 19.12% and 17.55%, respectively. The hybrid CFs changed the failure model of the BFRP-bar. Compared with HFRP bars with CFs in the core, HFRP bars are more likely to deteriorate when the CFs are dispersed circumferentially. The hybrid CFs improved the environmental reduction coefficients (ERC) of TS and ILSS of the HFRP bars. Compared with the SWSC, the ERC of the HFRP bars in the normal concrete was significantly improved.

碱性环境导致玄武岩纤维增强聚合物(BFRP)棒材降解,阻碍了它们在海水和海砂混凝土(SWSC)中的应用。使用碳纤维(CFs)部分替代玄武岩纤维制备混合-FRP(HFRP)棒材是提高 BFRP 棒材耐久性的有效方法。评估使用碳纤维替代部分玄武岩纤维制备 HFRP 棒材以提高 BFRP 棒材在实际 SWSC 中的耐久性的有效性。在不同温度下暴露于海水中后,测试了不同纤维素混合含量(VCF,%)和排列方式的 HFRP 棒材在 SWSC 中的拉伸和层间界面性能。采用数字显微镜、扫描电子显微镜、X 射线计算机断层扫描和基质消解分析来研究调理后 HFRP 棒材和 SWSC 的微观结构演变。结果表明,VCF 增加到 10% 或 25% 后,层间剪切强度(ILSS)和拉伸强度(TS)的损失明显减少。嵌入 SWSC 的 BFRP 棒材的层间剪切强度(ILSS)和拉伸强度(TS)最大保持率分别提高了 19.12% 和 17.55%。混合 CF 改变了 BFRP 棒的破坏模式。与芯部含有 CF 的高频复合材料棒材相比,当 CF 在圆周上分散时,高频复合材料棒材更容易劣化。混合 CF 提高了高频复合材料棒材的 TS 和 ILSS 环境降低系数 (ERC)。与 SWSC 相比,普通混凝土中 HFRP 钢筋的 ERC 得到了显著改善。


Composites Science and Technology

Understanding the behaviors of ZIF-67 reinforced electrospun carbon nanofibers in the preparation and stabilization

Xiangjie Gong, Tao Yang, Yan Song, Xiaodong Tian, Zihui Ma, Zhanjun Liu

doi:10.1016/j.compscitech.2023.110403

 

了解 ZIF-67 增强电纺碳纳米纤维在制备和稳定过程中的行为

MOFs-reinforced electrospun carbon nanofibers offer a wide range of applications in the field of energy storage. In this study, ZIF-67 nanoparticles were produced and combined with polyacrylonitrile for electrospinning before being stabilized and carbonized to form a carbon nanofiber. BET, FT-IR, EA, DSC, and other techniques were used to investigate the stabilizing behaviors of PAN electrospun fiber with varying ZIF-67 concentrations at different temperatures. Under the same stabilizing settings, it was discovered that PAN electrospun fiber containing ZIF-67 nanoparticles could absorb more oxygen, promoting a higher degree of cyclization and crosslinking. Therefore, it was preferred to prepare carbon nanofibers at a lower stabilization temperature. Importantly, the degree of stability and disorder of the PAN/ZIF-67 stabilized fiber has been described by the FT-IR and the Raman spectra. This research deepens understanding about the formation of MOF-reinforced carbon nanofibers and expands our knowledge of the stability of PAN/MOF hybrid fibers.

MOFs 增强电纺碳纳米纤维在储能领域有着广泛的应用。在本研究中,制备了 ZIF-67 纳米粒子,并将其与聚丙烯腈结合进行电纺丝,然后经过稳定和碳化形成碳纳米纤维。利用 BET、FT-IR、EA、DSC 等技术研究了不同浓度的 ZIF-67 在不同温度下对 PAN 电纺纤维的稳定行为。结果发现,在相同的稳定条件下,含有 ZIF-67 纳米粒子的 PAN 电纺纤维能吸收更多的氧气,促进更高的环化和交联。因此,最好在较低的稳定温度下制备碳纳米纤维。重要的是,PAN/ZIF-67 稳定纤维的稳定性和无序度已通过傅立叶变换红外光谱和拉曼光谱进行了描述。这项研究加深了人们对 MOF 增强碳纳米纤维形成的理解,并拓展了我们对 PAN/MOF 混合纤维稳定性的认识。



来源:复合材料力学仿真Composites FEM
ACTMechanicalLS-DYNAAdditiveDeform振动断裂复合材料非线性化学通用电子理论材料储能仿生控制
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【新文速递】2023年12月26日固体力学SCI期刊最新文章

今日更新:International Journal of Solids and Structures 2 篇,Journal of the Mechanics and Physics of Solids 1 篇,Mechanics of Materials 1 篇,Thin-Walled Structures 2 篇International Journal of Solids and StructuresResearch on dynamic deformation behaviors of laser-driving metal sheet precision formingXingquan Zhang, Hangxuan Liu, Yinkai Wang, Shiwei Duan, Yan Zhang, Jinxiu Fang, Shanbao Pei, Wenfeng Hudoi:10.1016/j.ijsolstr.2023.112631激光驱动金属板精密成形的动态变形行为研究Laser shock forming (LSF) is an advanced sheet forming technology. With the aid of forming die, it can realize sheet precise forming, and has extensive application prospects in aeronautic and electronics industries. In the paper, a two-dimensional axial symmetric numerical model of SUS304 stainless steel is established. Finite element method is utilized to explore the dynamic deformation behaviors of the laser-driving sheet impacted by the forming die. The results show that the node velocity of metal sheet increases in an oscillatory manner during initial stage and then it starts to bulge. After collision with die cavity bottom, the central region of metal sheet jumps up reversely, and experiences repeating damped vibration. The metal sheet gradually exhausts the obtained kinetic energy from the shock wave, and the flat sheet is finally shaped into the geometrical shape of die cavity. The sheet forming precision can be improved by way of increasing laser shock pressure. The corresponding experiments are also carried out to verify the predicted results. The applied method and gained results can provide a reference for theoretical research and parameters optimization in LSF.激光冲击成形(LSF)是一种先进的板材成形技术。借助成形模具,它可以实现板材的精密成形,在航空和电子行业具有广泛的应用前景。本文建立了 SUS304 不锈钢的二维轴对称数值模型。利用有限元方法探讨了激光驱动板材在成形模冲击下的动态变形行为。结果表明,金属片的节点速度在初始阶段以振荡方式增加,然后开始隆起。与模腔底部碰撞后,金属片的中心区域反向跃起,并经历重复的阻尼振动。金属片逐渐耗尽从冲击波中获得的动能,最终形成符合模腔几何形状的扁平金属片。通过增加激光冲击压力可以提高金属板的成型精度。为验证预测结果,还进行了相应的实验。所应用的方法和获得的结果可为 LSF 的理论研究和参数优化提供参考。Energy processes and phase transition in granular assembliesXiaoxiao Wang, Yang Liu, François Nicotdoi:10.1016/j.ijsolstr.2023.112634颗粒集 合体中的能量过程和相变Granular assemblies are an illustrative example of complex material where unexpected macroscopic properties may emerge when they are subjected to a given loading. The complexity is the consequence of the huge geometrical disorder governed by particle rearrangements, entailing plastic dissipation at contacts. This local dissipation, associated with the global geometric disorder, is probably a key ingredient responsible for various macroscopic features, such as the strain localization in dense granular assemblies leading to the formation of a shear band. Based on a discrete element method (DEM), this manuscript investigates the energy processes at the microscopic scale in granular assemblies along biaxial loading paths for dense and loose assemblies. The localized shear band domain in a dense specimen is inspected. The analysis of elastic processes suggests a maximum capacity for storing elastic energy, giving rise to a phase transition from a homogeneous state to a heterogeneous one. This phase transition is marked by a significant release of elastic energy associated with plastic dissipation. The elastic-to-plastic energy transfer is shown to be a key ingredient to reach the stationary state regime characterized by a unique dynamic equilibrium. It is signaled by the constant ratios of elastic storage and plastic dissipation over the available energy, whatever the initial density of granular assemblies. Finally, the energy processes inside the shear band domain are shown to be largely dominated by intense plastic dissipation. This suggests that the shear band acts as an optimal dissipative structure in dense specimens where elastic mechanisms continue to be active at a much higher level than they are in the outside shear band domain.颗粒集 合体是复杂材料的一个示例,当它们受到特定载荷时,可能会出现意想不到的宏观特性。这种复杂性是由颗粒重新排列所导致的巨大几何无序造成的,并在接触处产生塑性耗散。这种与全局几何无序相关的局部耗散可能是造成各种宏观特征的关键因素,例如致密颗粒集 合体中的应变局部化导致剪切带的形成。本手稿基于离散元素法(DEM),研究了致密和疏松装配体沿双轴加载路径的颗粒装配体微观尺度的能量过程。对致密试样中的局部剪切带域进行了检测。对弹性过程的分析表明,储存弹性能量的能力达到了最大值,从而产生了从均质状态到异质状态的相变。这种相变的特点是与塑性耗散相关的弹性能量的显著释放。从弹性到塑性的能量转移是达到以独特的动态平衡为特征的静止状态的关键因素。无论颗粒集 合体的初始密度如何,弹性存储和塑性耗散与可用能量的恒定比率都表明了这一点。最后,剪切带域内的能量过程主要由强烈的塑性耗散主导。这表明剪切带在致密试样中是一种最佳耗散结构,其弹性机制的持续活跃程度远高于剪切带域外部。Journal of the Mechanics and Physics of SolidsInitializing intragranular residual stresses within statistically equivalent microstructures for crystal plasticity simulationsRitwik Bandyopadhyay, Krzysztof S. Stopka, Michael D. Sangiddoi:10.1016/j.jmps.2023.105529 为晶体塑性模拟初始化统计等效微结构中的粒内残余应力We propose a mechanics framework to compute intragranular or type III residual stress within a polycrystalline aggregate for which experimental characterization of residual stress is unknown. The framework is built upon the inter-relationship between intragranular misorientation (IGM), geometrically necessary dislocation (GND), and long-range internal stress. Given a spatial distribution of IGM, we first calculate the spatial distribution of GND density; subsequently, we calculate the internal stress and strain fields due to the GND distribution. For demonstration, we consider a synthetic microstructure of a hexagonal close-packed material, namely Ti-7Al, wherein the grain size and orientation distributions are statistically equivalent to the distributions obtained via experimental characterization. We refer to this microstructure as a statistically equivalent microstructure (SEM). In an SEM, each grain is usually treated as a pristine crystal and therefore, the SEM contains no IGM. We propose a technique to introduce IGM within the SEM and, subsequently, calculate the GND density and residual stress distributions in a consistent manner. In the process, we ensure that statistical distributions of the IGM and residual strain within the SEM are statistically equivalent to the same obtained from the experimental characterization of Ti-7Al. While establishing statistically equivalent residual stress, the thermal effects during processing of Ti-7Al are implicitly taken into account. Next, we perform crystal plasticity finite element simulations to demonstrate the implications of the initialization of IGM and type III residual stress. Although the IGM and residual stress are related, the results suggest that the type III residual stress initialization has a much more pronounced effect on microplasticity-driven damage mechanisms, such as high cycle fatigue, even within a well-annealed material such as Ti-7Al, thereby emphasizing the need for its initialization for microstructure-sensitive fatigue analysis. Finally, we demonstrate that initializing thermally induced residual stress within Ti-7Al SEM through a cooling simulation, accounting for the anisotropic nature of the coefficient of thermal expansion, yields a grain-averaged residual stress distribution statistically similar to that obtained from our framework and is a special case of the type II residual stress implementation.我们提出了一个力学框架,用于计算多晶体内部的晶内应力或 III 型残余应力,该多晶体的残余应力实验特征尚不清楚。该框架建立在粒内错向(IGM)、几何必要位错(GND)和长程内应力之间的相互关系之上。给定 IGM 的空间分布,我们首先计算 GND 密度的空间分布;然后计算 GND 分布引起的内应力和应变场。为了演示,我们考虑了一种六方紧密堆积材料(即 Ti-7Al )的合成微观结构,其中的晶粒尺寸和取向分布在统计上等同于通过实验表征获得的分布。我们将这种微观结构称为统计等效微观结构(SEM)。在 SEM 中,每个晶粒通常被视为原始晶体,因此 SEM 中不包含 IGM。我们提出了一种在 SEM 中引入 IGM 的技术,并随后以一致的方式计算 GND 密度和残余应力分布。在此过程中,我们确保扫描电子显微镜内的 IGM 和残余应变的统计分布在统计学上等同于从 Ti-7Al 的实验表征中获得的相同分布。在建立统计等效残余应力的同时,还隐含地考虑了 Ti-7Al 加工过程中的热效应。接下来,我们进行了晶体塑性有限元模拟,以证明初始化 IGM 和 III 型残余应力的影响。虽然 IGM 和残余应力是相关的,但结果表明 III 型残余应力初始化对微塑性驱动的损伤机制(如高循环疲劳)具有更明显的影响,即使是在 Ti-7Al 这种退火良好的材料中也是如此,从而强调了在进行微结构敏感疲劳分析时对其进行初始化的必要性。最后,我们证明了通过冷却模拟初始化 Ti-7Al SEM 中的热诱导残余应力,考虑到热膨胀系数的各向异性,可得到与我们的框架所得到的残余应力分布在统计上相似的晶粒平均分布,是第二类残余应力实施的一个特例。Mechanics of MaterialsImplicit multiscale finite element analysis of polymer physics-based multiscale constitutive model for elastomersJiwon Jung, Gun Jin Yundoi:10.1016/j.mechmat.2023.104904 基于聚合物物理的弹性体多尺度构成模型的隐式多尺度有限元分析This paper proposes a multiscale visco-hyperelastic constitutive model that can predict the material behavior bridging molecular properties to response at the continuum level and its integration within implicit finite element analysis. The proposed model incorporates all parameters having actual physical meaning obtained from molecular simulations based on the tube theory. Despite the advantages that the constitutive equation was determined from molecular network characteristics, applications of the model have been restricted to the simple shape of Finite Element (FE) models with a few cases of specific deformations, owing to its complexity and absence of the implicit formulation. Therefore, the application of the model to the 3D implicit FE analysis with a tangent stiffness was proposed by applying numerical differentiation with the complex step derivative approximation (CSDA) method. Combined with the Neo-Hookean hyperelasticity model, the results from the example analysis applied to the tensile specimen model were examined to manifest the visco-hyperelastic characteristics of elastomers under cyclic loading, stability of the analysis, and further discussion on the visco-hyperelastic constitutive model were proposed.本文提出了一种多尺度粘弹性-超弹性构造模型,该模型可以预测材料行为,将分子特性与连续层面的响应联系起来,并将其集成到隐式有限元分析中。该模型包含了基于管理论的分子模拟中获得的所有具有实际物理意义的参数。尽管该模型的构成方程是根据分子网络特征确定的,但由于其复杂性和缺乏隐式表述,该模型的应用仅限于有限元(FE)模型的简单形状和少数特定变形情况。因此,通过使用复杂阶梯导数近似(CSDA)方法进行数值微分,提出了将该模型应用于具有切线刚度的三维隐式 FE 分析。结合 Neo-Hookean 超弹性模型,对应用于拉伸试样模型的实例分析结果进行了检验,以体现弹性体在循环加载下的粘-超弹性特性、分析的稳定性,并对粘-超弹性构成模型提出了进一步的讨论。Thin-Walled StructuresResearch on somatosensory shock wave pressure measurement method based on PVDF filmYongjian Zhang, Changan Di, Peng Peng, Dahai Li, Xinge Si, Bin Jidoi:10.1016/j.tws.2023.111520基于 PVDF 膜的体感冲击波压力测量方法研究Piezoelectric pressure sensors and human tissue have different pressure impedance coefficients, which results in a discrepancy when accurately measuring the real somatosensory shock wave pressure (SSWP). The aim of this research is to develop a method that can realistically characterize SSWP measurements. To achieve this, the study uses the finite element method to analyze the response of both human tissue and piezoelectric pressure sensors to the same shock wave load. The numerical simulation results show a significant difference in the pressure response between the two under identical shock wave loads. Based on this, the working mode and equivalent model of Polyvinylidene fluoride (PVDF) film for measuring SSWP are determined. Using the finite element method, the same shock wave pressure load is applied to PVDF films with thicknesses of 20μm, 50μm, 100μm, as well as human tissue. The results reveal a good agreement between the pressure response of the PVDF film and human tissue. As the thickness of the PVDF film decreases, particularly at 20μm thickness, the accuracy improves. Additionally, a comparative experiment is conducted using a bionic dummy model. The outcomes indicate that PVDF film is more stable than piezoelectric pressure sensors and can accurately characterize the real SSWP, aligning with the numerical simulation results by up to 98.4%.压电压力传感器和人体组织具有不同的压力阻抗系数,这导致在精确测量真实体感冲击波压力(SSWP)时存在差异。本研究的目的是开发一种能真实描述 SSWP 测量值的方法。为此,研究采用有限元法分析人体组织和压电压力传感器对相同冲击波负载的响应。数值模拟结果表明,在相同的冲击波负载下,两者的压力响应存在显著差异。在此基础上,确定了用于测量 SSWP 的聚偏二氟乙烯(PVDF)薄膜的工作模式和等效模型。利用有限元方法,对厚度分别为 20μm、50μm、100μm 的聚偏二氟乙烯(PVDF)薄膜和人体组织施加了相同的冲击波压力载荷。结果表明,PVDF 膜和人体组织的压力响应非常一致。随着 PVDF 薄膜厚度的减小,尤其是 20μm 厚度时,精确度有所提高。此外,还使用仿生假人模型进行了对比实验。结果表明,PVDF 膜比压电压力传感器更稳定,能准确表征真实的 SSWP,与数值模拟结果的吻合度高达 98.4%。Ground shock attenuation performances of wire-rope-based meta-isolatorsYang Liu, Dongyu Shi, Yu Li, Sanfeng Liu, Huguang He, Hailong Chen, Hualin Fandoi:10.1016/j.tws.2023.111538基于钢丝绳的元隔离器的接地冲击衰减性能In this research, two types of novel meta-isolators were designed based on traditional wire-rope isolators and made by embedding mass-spring resonators into the wire-rope isolator. Measurement methods to reveal attenuation abilities of these meta-isolators were suggested through quasi-static cyclic loading tests, shaking table tests, and in-field explosion experiments. In the quasi-static tests, meta-isolators have greater hysteresis area under the same excitation displacement, which represents much greater energy consumption. Using shaking table tests and measurement, the vibration attenuation ability of the meta-isolators is improved in the designed resonant frequency, and the response amplitudes are significantly reduced compared with the conventional wire-rope isolators. Blast-induced ground shock experiments reveal that the meta-isolators indeed have an advantage over the conventional isolators in the aspect of shock resistance and the attenuation efficiency exceeds 98%, providing a new idea and reference for protective engineering.本研究在传统钢丝绳隔振器的基础上,通过在钢丝绳隔振器中嵌入质量弹簧谐振器,设计了两种新型元隔振器。通过准静态循环加载试验、振动台试验和现场爆炸实验,提出了揭示这些元隔离器衰减能力的测量方法。在准静态试验中,元隔离器在相同的激励位移下具有更大的滞后面积,这意味着更高的能量消耗。通过振动台试验和测量,元隔振器在设计共振频率下的减振能力得到提高,响应振幅比传统钢丝绳隔振器显著减小。爆炸引起的地面冲击实验表明,元隔振器在抗冲击方面确实比传统隔振器更有优势,衰减效率超过 98%,为防护工程提供了新的思路和参考。来源:复合材料力学仿真Composites FEM

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